Engineering Physics Commons^™

Note: A Simple Thermal Gradient Annealing Unit For The Treatment Of Thin Films, C. J. Metting, Johnathan K. Bunn, Ellen A. Underwood, Yihao Zhu, G. Koley, T. Crawford, Jason R. Hattrick-Simpers

Faculty Publications

A gradient annealing cell has been developed for the high-throughput study of thermalannealing effects on thin-film libraries in different environments. The inexpensive gradientannealing unit permits temperature gradients as large as 28 °C/mm and can accommodate samples ranging in length from 13 mm to 51 mm. The system was validated by investigating the effects of annealing temperature on the crystallinity, resistivity, and transparency of tin-doped indium oxide deposited on a glass substrate by magnetron sputtering. The unit developed in this work will permit the rapid optimization of materials properties such as crystallinity, homogeneity, and conductivity across a variety of applications.

Experimental Determination Of Electron-Hole Pair Creation Energy In 4h-Sic Epitaxial Layer: An Absolute Calibration Approach, S. K. Chaudhuri, K. J. Zavalla, K. C. Mandal

Faculty Publications

No abstract provided.

The Effects Of Personality Type On Engineering Student Performance And Attitudes, Richard M. Felder, Gary Felder, E. Jacquelin Dietz

Physics: Faculty Publications

The Myers‐Briggs Type Indicator® (MBTI) was administered to a group of 116 students taking the introductory chemical engineering course at North Carolina State University. That course and four subsequent chemical engineering courses were taught in a manner that emphasized active and cooperative learning and inductive presentation of course material. Type differences in various academic performance measures and attitudes were noted as the students progressed through the curriculum. The observations were generally consistent with the predictions of type theory, and the experimental instructional approach appeared to improve the performance of MBTI types (extraverts, sensors, and feelers) found in previous studies to …

Adherent Cells Avoid Polarization Gradients On Periodically Poled Litao3 Ferroelectrics, Christof Christophis, Elisabetta Ada Cavalcanti-Adam, Maximilian Hanke, Kenji Kitamura, Alexei Gruverman, Michael Grunze, Peter A. Dowben, Axel Rosenhahn

Peter Dowben Publications

The response of fibroblast cells to periodically poled LiTaO₃ ferroelectric crystals has been studied. While fibroblast cells do not show morphological differences on the two polarization directions, they show a tendency to avoid the field gradients that occur between polarization domains of the ferroelectric. The response to the field gradients is fully established after one hour, a time at which fibroblasts form their first focal contacts. If suspension cells, with a lower tendency to establish strong surface contacts are used, no influence of the field gradients is observed.

Infrared Phonon Modes In Multiferroic Single-Crystal Fete2o5br, K. H. Miller, X. S. Xu, H. Berger, V. Cracium, Xiaoxiang Xi, C. Martin, G. L. Carr, D. B. Tanner

Xiaoshan Xu Papers

Reflection and transmission as a function of temperature (7–300 K and 5–300 K respectively) have been measured on single crystals of the multiferroic compound FeTe₂O₅Br utilizing light spanning from the far infrared to the visible. The complex dielectric function and other optical properties were obtained via Kramers-Kronig analysis and by fits to a Drude-Lortentz model. Analysis of the anisotropic excitation spectra via Drude-Lorentz fitting and lattice dynamical calculations have led to the observation of 43 of the 53 modes predicted along the b axis of the monoclinic cell. The phonon response parallel to the a and …

Growth Diagram Of La0.7sr0.3mno3 Thin Films Using Pulsed Laser Deposition, Hangwen Guo, Dali Sun, Wenbin Wang, Zheng Gai, Ivan Kravchenko, Jian Shao, Lu Jiang, Thomas Z. Ward, Paul C. Snijders, Lifeng Yin, Jian Shao, Xiaoshan Xu

Xiaoshan Xu Papers

An experimental study was conducted on controlling the growth mode of La_0.7Sr_0.3MnO₃ thin films on SrTiO₃ substrates using pulsed laser deposition (PLD) by tuning growth temperature, pressure, and laser fluence. Different thin film morphology, crystallinity, and stoichiometry have been observed depending on growth parameters. To understand the microscopic origin, the adatom nucleation, step advance processes, and their relationship to film growth were theoretically analyzed and a growth diagram was constructed. Three boundaries between highly and poorly crystallized growth, 2D and 3D growth, stoichiometric and non-stoichiometric growth were identified in the growth diagram. A good …

Room-Temperature Multiferroic Hexagonal Lufeo3 Films, Wenbin Wang, Jun Zhao, Wenbo Wang, Zheng Gai, Nina Balke, Miaofang Chi, Ho Nyung Lee, Wei Tian, Leyi Zhu, Xuemei Cheng, David J. Keavney, Jieyu Yi, Thomas Z. Ward, Paul C. Snijders, Hans M. Christen, Weida Wu, Jian Shen, Xiaoshan Xu

Xiaoshan Xu Papers

The crystal and magnetic structures of single-crystalline hexagonal LuFeO₃ films have been studied using x-ray, electron, and neutron diffraction methods. The polar structure of these films are found to persist up to 1050 K; and the switchability of the polar behavior is observed at room temperature, indicating ferroelectricity. An antiferromagnetic order was shown to occur below 440 K, followed by a spin reorientation resulting in a weak ferromagnetic order below 130 K. This observation of coexisting multiple ferroic orders demonstrates that hexagonal LuFeO₃ films are room-temperature multiferroics.

Stacking Principle And Magic Sizes Of Transition Metal Nanoclusters Based On Generalized Wulff Construction, S. F. Li, X. J. Zhao, X. S. Xu, Y. F. Gao, Zhenyu Zhang

Xiaoshan Xu Papers

Nanoclusters with extra stability at certain cluster sizes are known as magic clusters with exotic properties. The classic Wulff construction principle, which stipulates that the preferred structure of a cluster should minimize its total surface energy, is often invoked in determining the cluster magicity, resulting in close-shelled Mackay icosahedronal clusters with odd-numbered magic sizes of 13, 55, 147, etc. Here we use transition metal clusters around size 55 as prototypical examples to demonstrate that, in the nanometer regime, the classic Wulff construction principle needs to be generalized to primarily emphasize the edge atom effect instead of the surface energy. Specifically, …

A Tunable Electromagnetic Band-Gap Microstrip Filter, Greg A. Lancaster

Master's Theses

In high frequency design, harmonic suppression is a persistent struggle. Non-linear devices such as switches and amplifiers produce unwanted harmonics which may interfere with other frequency bands. Filtering is a widely accepted solution, however there are various shortcomings involved. Suppressing multiple harmonics, if desired, with traditional lumped element and distributed component band-stop filters requires using multiple filters. These topologies are not easily made tunable either. A new filter topology is investigated called Electromagnetic Band-Gap (EBG) structures.

EBG structures have recently gained the interest of microwave designers due to their periodic nature which prohibits the propagation of certain frequency bands. EBG …

Oblique-Length Contraction Factor In The Special Theory Of Relativity, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

In this paper one generalizes the Lorentz Contraction Factor for the case when the lengths are moving at an oblique angle with respect to the motion direction. One shows that the angles of the moving relativistic objects are distorted.

Scaling Of The Coercive Field In Ferroelectrics At The Nanoscale, R. V. Gaynutdinov, M. Minnekaev, S. Mitko, A. L. Tolstikhina, A. Zenkevich, Stephen Ducharme, Vladimir M. Fridkin

Stephen Ducharme Publications

The scaling of the coercive field in ferroelectric films at the nanoscale is investigated experimentally. The scaling in the films of copolymer vinylidene fluoride and BaTiO3 with thickness equal by the order of value to the critical domain nucleus size 1–10 nm reveals deviation from the well-known Kay–Dunn law. At this thickness region coercive field does not depend on thickness and coincides with Landau–Ginzburg–Devonshire value.

Changing Molecular Band Offsets In Polymer Blends Of (P3ht/P(Vdf–Trfe)) Poly(3-Hexylthiophene) And Poly(Vinylidene Fluoride With Trifluoroethylene) Due To Ferroelectric Poling, Freddy Wong, Godohaldo Perez, Manuel Bonilla, Juan A. Colon-Santana, Xin Zhang, Pankaj Sharma, Alexei Gruverman, Peter A. Dowben, Luis G. Rosa

Peter Dowben Publications

Photoelectron emission and inverse photoemission spectroscopy studies of polymer blends of poly(vinylidene fluoride (70%) – trifluoroethylene (30%)) P(VDF–TrFE 70 : 30) and regio-regular poly(3- hexylthiophene) (P3HT) provide evidence of changes in the molecular band offsets as a result of changes in the ferroelectric polarization in P(VDF–TrFE). Investigation of the blends with higher concentrations of the semiconducting P3HT component revealed that the organic semiconductor component of the blend dominates the electronic structure in the vicinity of the chemical potential. Specifically, the states of P3HT at the conduction band minimum and valence band maximum fall within the HOMO–LUMO gap of the dielectric …

Induced Magneto-Electric Coupling In Ferroelectric/Ferromagnetic Heterostructures, Jeffery Carvell, Ruihua Cheng, Peter A. Dowben, Q Yang

Peter Dowben Publications

Using an external magnetic field, we have demonstrated room temperature control of the electric polarization of a ferroelectric polymer, polyvinylidene fluoride (PVDF), in an artificial multiferroic structure. For ferroelectric PVDF polymer thin films in an iron-PVDF-iron heterostructure, both the ferroelectric coercivity and polarization display a hysteresis dependence on the external magnetic field. We also find that the thickness of the PVDF layer has an effect on the magnetoelectric coupling in our samples. We observe a giant magnetoelectric coupling with values as large as 3700 V/cm Oe to 41700 V/cm Oe.

Magnetoelectric Coupling At The Euo/Batio3 Interface, Shi Cao, P Liu, Jinke Tang, Haidong Lu, C W. Bark, Sangjin Ryu, Chang-Beom Eom, Alexei Gruverman, Peter A. Dowben

Peter Dowben Publications

Magnetization modulation by ferroelectric polarization switching is reported for the ferromagnetic-ferroelectric EuO/BaTiO₃heterostructure. The value of the magnetization critical exponent β is consistent with the expected Heisenberg-like ferromagnetism of EuO and reported Curie temperature. The critical exponent is seen to decrease with increased magnetic coupling. The results are discussed in the context of data obtained earlier for epitaxial La_0.67Sr_0.33MnO₃/BaTiO₃ heterostructures, where magnetization increases and critical exponent b also declines with ferroelectric polarization pointing away from ferromagnetic layer. The observed similarity between two systems illustrates an importance of charge doping in magnetoelectric coupling, …

Adsorption Of Tcnqh-Functionalized Quinonoid Zwitterions On Gold And Graphene: Evidence For Dominant Intermolecular Interactions+, Lingmei Kong, Lucie Routaboul, Pierre Braunstein, Hong-Gi Park, Jaewu Choi, John P. Colon Cordova, E Vega, Luis G. Rosa, Bernard Doudin, Peter A. Dowben

Peter Dowben Publications

We experimentally investigate the electronic structure of the strongly dipolar, quinonoid-type molecule obtained by TCNQH-functionalization (TCNQH = (NC)₂CC₆H₄CH(CN)₂) of (6Z)-4-(butylamino)-6-(butyliminio)- 3-oxocyclohexa-1,4-dien-1-olate C₆H₂(...NHR)₂(...O)₂ (where R = n-C₄H₉) to be very similar after deposition from solution on either graphene or gold substrates. These zwitterion adsorbate thin films form structures that are distinct from those formed by related quinonoid molecules previously studied. We argue that adsorbate–adsorbate interactions dominate and lead to a Stranski–Krastanov ‘island growth’ mechanism.

Applications Of High Throughput (Combinatorial) Methodologies To Electronic, Magnetic, Optical, And Energy-Related Materials, Martin L. Green, Ichiro Takeuchi, Jason R. Hattrick-Simpers

Faculty Publications

High throughput (combinatorial) materials science methodology is a relatively new research paradigm that offers the promise of rapid and efficient materials screening, optimization, and discovery. The paradigm started in the pharmaceutical industry but was rapidly adopted to accelerate materials research in a wide variety of areas. High throughput experiments are characterized by synthesis of a “library” sample that contains the materials variation of interest (typically composition), and rapid and localized measurement schemes that result in massive data sets. Because the data are collected at the same time on the same “library” sample, they can be highly uniform with respect to …

Compact Superconducting Crabbing And Deflecting Cavities, Subashini De Silva

Physics Faculty Publications

Recently, new geometries for superconducting crabbing and deflecting cavities have been developed that have significantly improved properties over those the standard TM110 cavities. They are smaller, have low surface fields, high shunt impedance and, more importantly for some of them, no lower-order-mode with a well-separated fundamental mode. This talk will present the status of the development of these cavities.

Superconducting Rf-Dipole Deflecting And Crabbing Cavities, Subashini De Silva, Jean R. Delayen

Physics Faculty Publications

Recent interests in compact deflecting and crabbing structures for future accelerators and colliders have initiated the development of novel rf structures. The superconducting rf-dipole cavity is one of the first compact designs with attractive properties such as high gradients, high shunt impedance, the absence of lower order modes, and widely separated higher order modes. Two rf-dipole cavities at 400 MHz and 499 MHz have been designed, fabricated and tested as proof-of-principle designs of compact deflecting and crabbing cavities for the LHC high luminosity upgrade and Jefferson Lab 12 GeV upgrade. The first rf tests have been performed on the rf-dipole …

Compact Superconducting Rf-Dipole Cavity Designs For Deflecting And Crabbing Applications, Subashini De Silva, Jean R. Delayen, A. Castilla

Physics Faculty Publications

Over the years the superconducting parallel-bar design has evolved into an rf-dipole cavity with improved properties. The new rf-dipole design is considered for a number of deflecting and crabbing applications. Some of those applications are the 499 MHz rf separator system for the Jefferson Lab 12 GeV upgrade, the 400 MHz crabbing cavity system for the proposed LHC high luminosity upgrade, and the 750 MHz crabbing cavity for the medium energy electron-ion collider in Jefferson Lab. In this paper we present the optimized rf design in terms of rf performance including rf properties, higher order modes (HOM) properties, multipacting, and …

Hom Damping Coupler Design For The 400-Mhz Rf Dipole Compact Crab Cavity For The Lhc Hilumi Upgrade, Zenghai Li, Lixin Ge, Jean R. Delayen, Subashini U. De Silva

Physics Faculty Publications

Crab cavities are adapted as the baseline design for the LHC HiLumi upgrade to achieve head-on beam-beam collisions for further improvement in luminosity. A 400- MHz compact RF dipole crab cavity design was developed by a joint effort between Old Dominion University and SLAC under the support of US LARP program. This design has shown very favorable RF parameters and can fit into the available beamline spacing for both vertical and horizontal crabbing schemes. A niobium proof-of-principle cavity based on such a design has been manufactured for vertical test. In addition, there are stringent wakefield requirements that needed to be …