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Reversible Mn Segregation At The Polar Surface Of Lithium Tetraborate, Christina L. Dugan, Robert L. Hengehold, Stephen R. McHale, Juan A. Colon Santana, John W. McClory, Volodymyr T. Adamiv, Yaroslav V. Burak, Ya B. Losovyj, Peter A. Dowben 2013 Air Force Institute of Technology

Reversible Mn Segregation At The Polar Surface Of Lithium Tetraborate, Christina L. Dugan, Robert L. Hengehold, Stephen R. Mchale, Juan A. Colon Santana, John W. Mcclory, Volodymyr T. Adamiv, Yaroslav V. Burak, Ya B. Losovyj, Peter A. Dowben

Faculty Publications

We find Mn surface segregation for single crystals of Mn doped Li2B4O7, nominally Li1.95Mn0.05B4O7(001), but as the temperature increases, evidence of this Mn surface segregation diminishes significantly. At room temperature, the surface photovoltaic charging is significant for this pyroelectric material but is quenched at a temperature well below that seen for the undoped Li2B4O7 samples. The suppression of surface charging in the region of 120 °C that accompanies the temperature of Mn dissolution in the bulk of Li2B4 …


Universal Scaling And Intrinsic Classification Of Electro-Mechanical Actuators, Sambit Palit, Ankit Jain, Muhammad A. Alam 2013 Purdue University

Universal Scaling And Intrinsic Classification Of Electro-Mechanical Actuators, Sambit Palit, Ankit Jain, Muhammad A. Alam

Birck and NCN Publications

Actuation characteristics of electromechanical (EM) actuators have traditionally been studied for a few specific regular electrode geometries and support (anchor) configurations. The ability to predict actuation characteristics of electrodes of arbitrary geometries and complex support configurations relevant for broad range of applications in switching, displays, and varactors, however, remains an open problem. In this article, we provide four universal scaling relationships for EM actuation characteristics that depend only on the mechanical support configuration and the corresponding electrode geometries, but are independent of the specific geometrical dimensions and material properties of these actuators. These scaling relationships offer an intrinsic classification for …


Localized Surface Plasmon Resonance Induced Structure-Property Relationships Of Metal Nanostructures, Subramanian Vilayurganapathy 2013 Western Michigan University

Localized Surface Plasmon Resonance Induced Structure-Property Relationships Of Metal Nanostructures, Subramanian Vilayurganapathy

Dissertations

The confluence of nanotechnology and plasmonics has led to new and interesting phenomena. The industrial need for fast, efficient and miniature devices which constantly push the boundaries on device performance tap into the happy marriage between these diverse fields. Designing devices for real life application that give superior performance when compared with existing ones are enabled by a better understanding of their structure-property relationships. Among all the design constraints, without doubt, the shape and size of the nanostructure along with the dielectric medium surrounding it has the maximum influence on the response and thereby the performance of the device. Hence …


Engineered Interfaces And Nano-Scale Thin Films For Solid Oxide Fuel Cell Electrolytes, Manjula I. Nandasiri 2013 Western Michigan University

Engineered Interfaces And Nano-Scale Thin Films For Solid Oxide Fuel Cell Electrolytes, Manjula I. Nandasiri

Dissertations

Solid state electrolytes with high oxygen ionic conductivity at low temperatures are required to develop cost effective and efficient solid oxide fuel cells. This study investigates the influence of engineered interfaces on the oxygen ionic conductivity of nano-scale multilayer thin film electrolytes. The epitaxial Sm2O3 doped CeO2 (SDC) and Sc2O3 stabilized ZrO2 (ScSZ) are selected as the alternative layers for the proposed multilayer thin film electrolyte based on the optimum structural, chemical, and electrical properties reported in the previous studies. The epitaxial SDC(111)/ScSZ(111) multilayer thin films are grown on high …


Multipactor Discharge In High Power Microwave Systems: Analyzing Effects And Mitigation Through Simulation In Icepic, Robert L. Lloyd 2013 Air Force Institute of Technology

Multipactor Discharge In High Power Microwave Systems: Analyzing Effects And Mitigation Through Simulation In Icepic, Robert L. Lloyd

Theses and Dissertations

Single surface multipactor in high power microwave systems was investigated computationally and analytically. The research focused upon understanding the cause and parametric dependence of the multipactor process leading to suggested methods of mitigation. System damage due to reaction was also assessed. All simulations were performed using the PIC code developed by AFRL, known as ICEPIC. In recreating the susceptibility curves that define regions of multipactor growth and decay, a discrepancy was found between previous published results and those observed in the current simulation. This was attributed to previous simulations not accounting for the magnetic component in the electromagnetic radiation incident …


Examining The Validity Of Using A Gaussian Schell-Model Source To Model The Scattering Of A Fully Coherent Gaussian Beam From A Rough Impedance Surface, Santasri Basu, Milo W. Hyde IV, Salvatore J. Cusumano, Michael A. Marciniak, Steven T. Fiorino 2013 Air Force Institute of Technology

Examining The Validity Of Using A Gaussian Schell-Model Source To Model The Scattering Of A Fully Coherent Gaussian Beam From A Rough Impedance Surface, Santasri Basu, Milo W. Hyde Iv, Salvatore J. Cusumano, Michael A. Marciniak, Steven T. Fiorino

Faculty Publications

Military applications that use adaptive optics (AO) often require a point source beacon at the target to measure and correct for wavefront aberrations introduced by atmospheric turbulence. However, turbulence prevents the formation of such a point beacon. The extended beacons that are created instead have finite spatial extents and exhibit varying degrees of spatial coherence. Modeling these extended beacons using a Gaussian Schell-model (GSM) form for the autocorrelation function would be a convenient approach due to the analytical tractability of Gaussian functions. We examine the validity of using such a model by evaluating the field scattered from a rough impedance …


Study Of The Growth And Switching Kinetics On Ferroelectric Nanocrystals Of Copolymer Vinylidene Fluoride And Trifluoroethylene On An Atomic Force Microscope, R. V. Gaynutdinov, O. A. Lysova, A. L. Tolstikhina, V. M. Fridkin, S. G. Yudin, Stephen Ducharme 2013 Institute of Crystallography, Russian Academy of Science, Moscow

Study Of The Growth And Switching Kinetics On Ferroelectric Nanocrystals Of Copolymer Vinylidene Fluoride And Trifluoroethylene On An Atomic Force Microscope, R. V. Gaynutdinov, O. A. Lysova, A. L. Tolstikhina, V. M. Fridkin, S. G. Yudin, Stephen Ducharme

Stephen Ducharme Publications

The growth of nanocrystals obtained from Langmuir-Blodgett films of ferroelectric copolymer consisting of 70% vinylidene fluoride and 30% trifluoroethylene has been investigated by atomic force microscopy (AFM). The radius and concentration of nanocrystals are found to depend on the annealing time of the film. A model for nanocrystal growth is proposed which yields adequate time dependences for nanocrystal size parameters. The switching kinetics of individual ferroelectric nanocrystals with an average diameter of 100–200 nm and a height of 15–20 nm has been investigated in the piezoelectric response mode. It is shown that the switching of nanocrystals has an activation character.


An Investigation Into Dual-Axis Solar Tracking, Daniel Spaizman 2013 California Polytechnic State University - San Luis Obispo

An Investigation Into Dual-Axis Solar Tracking, Daniel Spaizman

Physics

This senior project aims to determine a) if using a controlled photon-tracking system does produce greater voltage output than a fixed panel and b) by how much, if so. To do this, I built a dual-axis solar tracker using a small solar panel, some stepper motors, and an Arduino Uno. The majority of my time was spent familiarizing myself with the electrical components and fabricating the device. To test the performance of the panel, the leads of the solar panel were attached to the Arduino to record the output voltages. Two experiments were carried out to discover the answers to …


Note: A Simple Thermal Gradient Annealing Unit For The Treatment Of Thin Films, C. J. Metting, Johnathan K. Bunn, Ellen A. Underwood, Yihao Zhu, G. Koley, T. Crawford, Jason R. Hattrick-Simpers 2013 University of South Carolina - Columbia

Note: A Simple Thermal Gradient Annealing Unit For The Treatment Of Thin Films, C. J. Metting, Johnathan K. Bunn, Ellen A. Underwood, Yihao Zhu, G. Koley, T. Crawford, Jason R. Hattrick-Simpers

Faculty Publications

A gradient annealing cell has been developed for the high-throughput study of thermalannealing effects on thin-film libraries in different environments. The inexpensive gradientannealing unit permits temperature gradients as large as 28 °C/mm and can accommodate samples ranging in length from 13 mm to 51 mm. The system was validated by investigating the effects of annealing temperature on the crystallinity, resistivity, and transparency of tin-doped indium oxide deposited on a glass substrate by magnetron sputtering. The unit developed in this work will permit the rapid optimization of materials properties such as crystallinity, homogeneity, and conductivity across a variety of applications.


Experimental Determination Of Electron-Hole Pair Creation Energy In 4h-Sic Epitaxial Layer: An Absolute Calibration Approach, S. K. Chaudhuri, K. J. Zavalla, K. C. Mandal 2013 University of South Carolina - Columbia

Experimental Determination Of Electron-Hole Pair Creation Energy In 4h-Sic Epitaxial Layer: An Absolute Calibration Approach, S. K. Chaudhuri, K. J. Zavalla, K. C. Mandal

Faculty Publications

No abstract provided.


The Effects Of Personality Type On Engineering Student Performance And Attitudes, Richard M. Felder, Gary Felder, E. Jacquelin Dietz 2013 North Carolina State University at Raleigh

The Effects Of Personality Type On Engineering Student Performance And Attitudes, Richard M. Felder, Gary Felder, E. Jacquelin Dietz

Physics: Faculty Publications

The Myers‐Briggs Type Indicator® (MBTI) was administered to a group of 116 students taking the introductory chemical engineering course at North Carolina State University. That course and four subsequent chemical engineering courses were taught in a manner that emphasized active and cooperative learning and inductive presentation of course material. Type differences in various academic performance measures and attitudes were noted as the students progressed through the curriculum. The observations were generally consistent with the predictions of type theory, and the experimental instructional approach appeared to improve the performance of MBTI types (extraverts, sensors, and feelers) found in previous studies to …


Adherent Cells Avoid Polarization Gradients On Periodically Poled Litao3 Ferroelectrics, Christof Christophis, Elisabetta Ada Cavalcanti-Adam, Maximilian Hanke, Kenji Kitamura, Alexei Gruverman, Michael Grunze, Peter A. Dowben, Axel Rosenhahn 2013 Ruprecht-Karls-University Heidelberg, Karlsruhe Institute of Technology

Adherent Cells Avoid Polarization Gradients On Periodically Poled Litao3 Ferroelectrics, Christof Christophis, Elisabetta Ada Cavalcanti-Adam, Maximilian Hanke, Kenji Kitamura, Alexei Gruverman, Michael Grunze, Peter A. Dowben, Axel Rosenhahn

Peter Dowben Publications

The response of fibroblast cells to periodically poled LiTaO3 ferroelectric crystals has been studied. While fibroblast cells do not show morphological differences on the two polarization directions, they show a tendency to avoid the field gradients that occur between polarization domains of the ferroelectric. The response to the field gradients is fully established after one hour, a time at which fibroblasts form their first focal contacts. If suspension cells, with a lower tendency to establish strong surface contacts are used, no influence of the field gradients is observed.


Infrared Phonon Modes In Multiferroic Single-Crystal Fete2o5br, K. H. Miller, X. S. Xu, H. Berger, V. Cracium, Xiaoxiang Xi, C. Martin, G. L. Carr, D. B. Tanner 2013 University of Florida

Infrared Phonon Modes In Multiferroic Single-Crystal Fete2o5br, K. H. Miller, X. S. Xu, H. Berger, V. Cracium, Xiaoxiang Xi, C. Martin, G. L. Carr, D. B. Tanner

Xiaoshan Xu Papers

Reflection and transmission as a function of temperature (7–300 K and 5–300 K respectively) have been measured on single crystals of the multiferroic compound FeTe2O5Br utilizing light spanning from the far infrared to the visible. The complex dielectric function and other optical properties were obtained via Kramers-Kronig analysis and by fits to a Drude-Lortentz model. Analysis of the anisotropic excitation spectra via Drude-Lorentz fitting and lattice dynamical calculations have led to the observation of 43 of the 53 modes predicted along the b axis of the monoclinic cell. The phonon response parallel to the a and …


Growth Diagram Of La0.7sr0.3mno3 Thin Films Using Pulsed Laser Deposition, Hangwen Guo, Dali Sun, Wenbin Wang, Zheng Gai, Ivan Kravchenko, Jian Shao, Lu Jiang, Thomas Z. Ward, Paul C. Snijders, Lifeng Yin, Jian Shao, Xiaoshan Xu 2013 University of Tennessee, Knoxville

Growth Diagram Of La0.7sr0.3mno3 Thin Films Using Pulsed Laser Deposition, Hangwen Guo, Dali Sun, Wenbin Wang, Zheng Gai, Ivan Kravchenko, Jian Shao, Lu Jiang, Thomas Z. Ward, Paul C. Snijders, Lifeng Yin, Jian Shao, Xiaoshan Xu

Xiaoshan Xu Papers

An experimental study was conducted on controlling the growth mode of La0.7Sr0.3MnO3 thin films on SrTiO3 substrates using pulsed laser deposition (PLD) by tuning growth temperature, pressure, and laser fluence. Different thin film morphology, crystallinity, and stoichiometry have been observed depending on growth parameters. To understand the microscopic origin, the adatom nucleation, step advance processes, and their relationship to film growth were theoretically analyzed and a growth diagram was constructed. Three boundaries between highly and poorly crystallized growth, 2D and 3D growth, stoichiometric and non-stoichiometric growth were identified in the growth diagram. A good …


Room-Temperature Multiferroic Hexagonal Lufeo3 Films, Wenbin Wang, Jun Zhao, Wenbo Wang, Zheng Gai, Nina Balke, Miaofang Chi, Ho Nyung Lee, Wei Tian, Leyi Zhu, Xuemei Cheng, David J. Keavney, Jieyu Yi, Thomas Z. Ward, Paul C. Snijders, Hans M. Christen, Weida Wu, Jian Shen, Xiaoshan Xu 2013 University of Tennessee, Knoxville

Room-Temperature Multiferroic Hexagonal Lufeo3 Films, Wenbin Wang, Jun Zhao, Wenbo Wang, Zheng Gai, Nina Balke, Miaofang Chi, Ho Nyung Lee, Wei Tian, Leyi Zhu, Xuemei Cheng, David J. Keavney, Jieyu Yi, Thomas Z. Ward, Paul C. Snijders, Hans M. Christen, Weida Wu, Jian Shen, Xiaoshan Xu

Xiaoshan Xu Papers

The crystal and magnetic structures of single-crystalline hexagonal LuFeO3 films have been studied using x-ray, electron, and neutron diffraction methods. The polar structure of these films are found to persist up to 1050 K; and the switchability of the polar behavior is observed at room temperature, indicating ferroelectricity. An antiferromagnetic order was shown to occur below 440 K, followed by a spin reorientation resulting in a weak ferromagnetic order below 130 K. This observation of coexisting multiple ferroic orders demonstrates that hexagonal LuFeO3 films are room-temperature multiferroics.


Stacking Principle And Magic Sizes Of Transition Metal Nanoclusters Based On Generalized Wulff Construction, S. F. Li, X. J. Zhao, X. S. Xu, Y. F. Gao, Zhenyu Zhang 2013 Zhengzhou University

Stacking Principle And Magic Sizes Of Transition Metal Nanoclusters Based On Generalized Wulff Construction, S. F. Li, X. J. Zhao, X. S. Xu, Y. F. Gao, Zhenyu Zhang

Xiaoshan Xu Papers

Nanoclusters with extra stability at certain cluster sizes are known as magic clusters with exotic properties. The classic Wulff construction principle, which stipulates that the preferred structure of a cluster should minimize its total surface energy, is often invoked in determining the cluster magicity, resulting in close-shelled Mackay icosahedronal clusters with odd-numbered magic sizes of 13, 55, 147, etc. Here we use transition metal clusters around size 55 as prototypical examples to demonstrate that, in the nanometer regime, the classic Wulff construction principle needs to be generalized to primarily emphasize the edge atom effect instead of the surface energy. Specifically, …


Tests Of An Rf Dipole Crabbing Cavity For An Electron-Ion Collider, A. Castilla, J. R. Delayen 2013 Old Dominion University

Tests Of An Rf Dipole Crabbing Cavity For An Electron-Ion Collider, A. Castilla, J. R. Delayen

Physics Faculty Publications

On the scheme of developing a medium energy electron-ion collider (MEIC) at Jefferson Lab, we have designed a compact superconducting rf dipole cavity at 750 MHz to crab both electron and ion bunches and increase luminosities at the interaction points (IP) of the machine. Following the design optimization and characterization of the electromagnetic properties such as peak surface fields and shunt impedance, along with field nonuniformities, multipole components content, higher order modes (HOM) and multipacting, a prototype cavity was built by Niowave Inc. The 750 MHz prototype crab cavity has been tested at 4 K and is ready for re-testing …


Comparison Of Electromagnetic, Thermal And Mechanical Calculations With Rf Test Results In Rf Dipole Deflecting/Crabbing Cavities, H. Park, S. U. Silva, J. R. Delayen 2013 Old Dominion University

Comparison Of Electromagnetic, Thermal And Mechanical Calculations With Rf Test Results In Rf Dipole Deflecting/Crabbing Cavities, H. Park, S. U. Silva, J. R. Delayen

Physics Faculty Publications

The current requirements of higher gradients and strict dimensional constraints in the emerging applications have required the designing of compact deflecting and crabbing rf structures. The superconducting rf-dipole cavity is one of the first novel compact designs with attractive properties such as higher gradients, higher shunt impedance and widely separated higher order modes. The recent tests performed on proof-of-principle designs of the rf-dipole geometry at 4.2 K and 2.0 K in a vertical test assembly have proven the designs to achieve higher gradients with higher intrinsic quality factors and easily processed multipacting conditions. The design frequency sensitivity to pressure (df/dp) …


Magnetic Bunch Compression For A Compact Compton Source, B.R.P. Gamage, T. Satogata 2013 Old Dominion University

Magnetic Bunch Compression For A Compact Compton Source, B.R.P. Gamage, T. Satogata

Physics Faculty Publications

A compact electron accelerator suitable for Compton source applications is in design at the Center for Accelerator Science at Old Dominion University and Jefferson Lab. Here we discuss two options for transverse magnetic bunch compression and final focus, each involving a 4-dipole chicane with M56 tunable over a range of 1.5-2.0m with independent tuning of final focus to interaction point \beta*=5mm. One design has no net bending, while the other has net bending of 90 degrees and is suitable for compact corner placement.


Compact Superconducting Rf-Dipole Cavity Designs For Deflecting And Crabbing Applications, Subashini De Silva, Jean R. Delayen, A. Castilla 2013 Old Dominion University

Compact Superconducting Rf-Dipole Cavity Designs For Deflecting And Crabbing Applications, Subashini De Silva, Jean R. Delayen, A. Castilla

Physics Faculty Publications

Over the years the superconducting parallel-bar design has evolved into an rf-dipole cavity with improved properties. The new rf-dipole design is considered for a number of deflecting and crabbing applications. Some of those applications are the 499 MHz rf separator system for the Jefferson Lab 12 GeV upgrade, the 400 MHz crabbing cavity system for the proposed LHC high luminosity upgrade, and the 750 MHz crabbing cavity for the medium energy electron-ion collider in Jefferson Lab. In this paper we present the optimized rf design in terms of rf performance including rf properties, higher order modes (HOM) properties, multipacting, and …


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