Biogeochemistry Commons^™

Biogeochemical Control Of Phosphorus Cycling And Primary Production In Lake Michigan, R. S. Walsh, Gregory A. Cutter, W. M. Dunstan, J. Radford-Knoery, J. T. Elder

OES Faculty Publications

A 3-yr study in Lake Michigan has shown a 27 mmol P m^-2 increase in the mass of total P (TP) in the water during spring when the lake is mixed from surface to sediment. This value is an order of magnitude greater than the annual P input from external sources. TP changed in concert with increases in chlorophyll a and organic N and decreases in nitrate and soluble Si. The concentration of soluble reactive PO_4^-3 (SRP) remained relatively constant throughout the study. We hypothesize that the SRP concentration is maintained by a chemical equilibrium with calcium-phosphate …

The Biogeochemistry Of Iodine In Seawater, Lingsu Zhang

OES Theses and Dissertations

Iodate and iodide are the two major species of iodine in seawater. In comparison to iodate, iodide is thermodynamically unstable in oxic seawater. The conversion (or reduction) of iodate to iodide may be mediated via biological activities. Since biological activities vary with the season, the conversion of iodate to iodide may also vary seasonally. The conversion (or oxidation) of iodide to iodate is thermodynamically feasible, but the mechanism is poorly known. Hydrogen peroxide, which is ubiquitous in surface seawater, may oxidize iodide to iodate.

Water samples were collected in the middle and lower Chesapeake Bay in different seasons between 1990 …

The Biogeochemistry Of Hydrogen Sulfide In The Open Ocean, Joël Radford-Knoery

OES Theses and Dissertations

Hydrogen sulfide is a poorly quantified component of the global sulfur cycle. In seawater, its dissolved species (dissolved sulfide) can react with trace metals to form dissolved complexes and insoluble compounds. Therefore, the study of dissolved° sulfide in the open ocean can yield a better understanding of the biogeochemical cycles of sulfur and trace metals.

The biogeochemical cycling of dissolved sulfide was examined using specially developed sampling and analytical methods. In the western North Atlantic and central Equatorial Pacific Oceans, total dissolved sulfide concentrations ranged from /L; they were highest, in the mixed layer and decreased with depth. The depth …

Mat Movement In Coastal Louisiana Marshes: Effect Of Salinity And Inundation On Vegetation And Nutrient Levels, Christopher Martin Swarzenski

Biological Sciences Theses & Dissertations

The present research compared and contrasted the physical structure of floating and rooted marshes, their differing responses to open-water salinities and inundation, as well as the nutrient distribution in the porewaters and sediment. The effects of the physical differences in the two marsh types on the ocurrence of the dominant emergent vegetation was discussed.

The main difference in physical structure of the two marsh types was the presence of a mineral, non-buoyant layer at 25-45 cm depth in the rooted marsh, which could serve as an anchor for the overlying highly organic mat layer found in both marsh types. Porewater …

The Role Of Benthic Fluxes Of Dissolved Organic Carbon In Oceanic And Sedimentary Carbon Cycling, Davd J. Burdige, Marc J. Alperin, Juliana Homstead, Christopher S. Martens

OES Faculty Publications

Benthic fluxes (sediment-water exchange) of dissolved organic carbon (DOC) represent a poorly quantified component of sedimentary and oceanic carbon cycling. In this paper we use pore water DOC data and direct DOC benthic flux measurements to begin to quantitatively examine this problem. These results suggest that marine sediments represent a significant source of DOC to the oceans, as a lower limit of the globally-integrated benthic DOC flux is comparable in magnitude to riverine inputs of organic carbon to the oceans. Benthic fluxes of DOC also appear to be similar in magnitude to other sedimentary processes such as organic carbon oxidation …

Lava-Seawater Interactions At Shallow-Water Submarine Lava Flows, Francis J. Sansone, Joseph A. Resing, Gordon W. Tribble, Peter N. Sedwick, Kevin M. Kelly, Ken Hon

OES Faculty Publications

Hydrothermal plumes associated with nearshore lava flows from Kilauea Volcano, Hawaii were studied on five occasions during 1989-1990 to address the current lack of data on direct lava-seawater interactions. The following enrichments were found in the sea-surface hydrothermal plumes above the active underwater lava flows: H₂, 15,000x ambient seawater concentrations; Mn, 250x; and Si, 20x. Water temperatures reached 46°C. Lower concentrations and temperatures were observed in the plumes with increasing distance from shore, with H₂, Si, and Mn concentrations linearly related to seawater temperature. Unlike deep sea spreading center hydrothermal plumes, no CH₄ enrichment was …

The Kinetics Of Organic Matter Mineralization In Anoxic Marine Sediments, David J. Burdige

OES Faculty Publications

The kinetics of sulfate reduction and inorganic nutrient production (ΣCO_2, ammonium, and phosphate) were examined in the sediments at five sites in the southern Chesapeake Bay, using long term (> 200 d) sediment decomposition experiments. Average first order rate constants for these processes (at 25^oC) decreased from 8.2 to 3.7 yr^-1 in the surface sediments (0-2 cm), to 2.1 to 0.2 yr^-1 at 12-14 cm. The C/N and C/P ratios of the organic matter undergoing decomposition also increased with depth at these sites. Taken together, these results indicate that the reactivity of the organic matter …

A Comparison Of Metals In Several Ahermatypic Corals And Surficial Sediments: Mobile Pinnacles And Hoffa Reef, Northcentral Gulf Of Mexico, Kathryn M. Conko

OES Theses and Dissertations

Metal concentrations in marine sediment and carbonate secreting invertebrates are representative of surrounding environmental chemistry. Aluminum, Ba Ca, Cd, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sr, and Zn were measured in carbonate and terrigenous phases of the $<$63 um fraction of sediment samples from two locations in the northcentral Gulf of Mexico. Enrichment factors indicate that Al, Ba, Cu, Cr, Mg, Mn, and Ni are all slightly depleted in these sediments relative to crustal abundances. Discriminant function analyses shows that the concentrations of five elements differ between locations.

Ahermatypic coral (106 specimens) from five genera collected from the study sites were analyzed for Cd, Cu, Cr, Pb, Zn, Mn, Sr, Ba, Fe, Ca and Mg. Eight elements vary between some genera, Al and Ba also vary in concentration in corals between either location. All elements except Sr are significantly depleted in the coral with respect to Ca in the …

Identification And Quantitation Of Volatile Amines In Marine Sediments, Chuen Mei Huang

Chemistry & Biochemistry Theses & Dissertations

Pore waters which were taken from sediments of the Chesapeake Bay were analyzed to determine the presence of volatile amines. A purge-and-trap technique was used to concentrate the amines. Then, following derivatization with heptaflourobutyric anhydride, the HFBA-amines were analyzed by gas chromatography with electron capture detection and with mass spectrometric detection. One secondary amine, diethylamine with a concentration of 0.3-0.6 uM, was found in a total of three pore water samples from cores collected on two different dates. A primary amine, sec-butylamine with a concentration of O. 05 AIM, was also found in one of these same samples. Another primary …

Nutrient Cycling In Bordenstake Bay Sediments: A Backbarrier Lagoon, Mark J. Herrenkohl

OES Theses and Dissertations

Six sets of sediment cores were collected over a one year period (June 1986 to July 1987) to examine nutrient cycling in Bordenstake Bay, a back barrier lagoon on Virginia's Eastern Shore Peninsula. The sampling times were chosen to examine any seasonal effects (e.g., temperature changes) which may affect the rates of metabolism in these sediments.

The sedimentation rate in Bordenstake Bay is 0.76 ± 0.21 cm/yr, leading to the annual deposition of 7. 05 moles of carbon, 0.46 moles of nitrogen, and 0.15 moles of phosphorus, per square meter of the sediment surface. The remineralization of organic matter in …

The Geochemistry Of Selenium And Sulfur In A Coastal Salt Marsh, David Jay Velinsky

OES Theses and Dissertations

Investigation of the various chemical forms of selenium and sulfur in sediments and pore waters can provide information about various oxidation/reduction processes. Five cores were obtained from the Great Marsh, from April 1985 to June 1986. Sampling times coincided with the seasonal redox cycle known to occur within the marsh system. Sediments were analyzed for various selenium and sulfur phases.

Iron monosulfides and elemental sulfur both display large seasonal changes in concentration and distribution with depth, indicating a coupling with redox conditions. In contrast, the depth distribution of greigite did not show appreciable changes with season. Pyrite underwent large concentration …

Biogeochemical Processes In Sagebrush Ecosystems: Interactions With Terrain, United States, National Aeronautics And Space Administration

Plants

Field data collection to support analysis of TM data was accomplished from June 22 to August 28th. Color infrared aerial photography acquired by a U2 on June 12, 1985 was used to locate and identify several vegetation communities. Forty sites where the USFS has collected long term ground cover were located in the field, delineated on aerial photos and ground photos of current conditions taken.

Microbial Manganese Reduction By Enrichment Cultures From Coastal Marine Sediments, David J. Burdige, Kenneth H. Nealson

OES Faculty Publications

Manganese reduction was catalyzed by enrichment cultures of anaerobic bacteria obtained from coastal marine sediments. In the absence of oxygen, these enrichment cultures reduced manganates when grown on either lactate, succinate, or acetate in both sulfate-free and sulfate-containing artificial seawaters. Sodium azide as well as oxygen completely inhibited microbial manganese reduction by these enrichment cultures, whereas molybdate had no effect on them. The addition of nitrate to the medium slightly decreased the rate of Mn²⁺ production by these enrichment cultures. These findings are consistent with the hypothesis that the manganese-reducing organisms in these enrichment cultures use manganates as terminal …

The Marine Biogeochemistry Of Selenium: A Re-Evaluation, Gregory A. Cutter, Kenneth W. Bruland

OES Faculty Publications

Vertical and horizontal profiles from the North and South Pacific Oceans demonstrate the existence of three species of dissolved selenium: selenite, selenate, and organic selenide (operationally defined). In surface waters, organic selenide makes up about 80% of the total dissolved selenium, selenite concentrations are uniformly low, and selenate concentrations rise with increased vertical mixing. The organic selenide maximum (thought to consist of seleno-amino acids in peptides) coincides with the maxima of primary productivity, pigments, bioluminescence, and dissolved free amino acids. Deep ocean waters are enriched in selenite and selenate, while organic selenide is nondetectable. In suboxic waters of the tropical …

A Pore Water/Solid Phase Diagenetic Model For Manganese In Marine Sediments, David J. Burdige, Joris M. Gieskes

OES Faculty Publications

A steady state diagenetic model is developed which accounts for changes in both the pore water and solid phase manganese profiles in marine sediments as a result of advection, diffusion, and redox reactions. The model is applied to observations on two cores in the E equatorial Atlantic in which pore water and solid phase manganese data are available. In situ reaction rates for manganese oxidation and reduction are estimated. The oxidation rates calculated here are in good agreement with rates measured in laboratory studies. In addition, the calculated manganese oxidation and reduction rates are compared with other estimated rates for …

Some Effects Of The Polychaete Nereis Succinea Frey And Leukart 1847 On The Distribution Of Copper Cadmium And Zinc In Sediments And Water, Gabriela Kitzig August

OES Theses and Dissertations

Two laboratory experiments, each lasting 216 hours, were conducted in order to determine the effects of a burrowing polychaete, Nereis succinea Frey and Leukart, 1847, on the distribution of copper, cadmium, and zinc in sediments and water in environmentally controlled microcosms. Dissolved metal concentrations in microcosms containing worms (experimental) decreased more rapidly than in microcosms without worms (controls). From 72 hours to 216 hours, suspended metal concentrations in experimental microcosms increased while concentrations in controls remained relatively constant. Sediment cadmium concentrations in experimental microcosms increased more over time than in controls. Polychaetes accumulated significant amounts of all three metals. These …

The Marine Geochemistry Of Selenium, Kazufumi Takayanagi

OES Theses and Dissertations

A fluorometric method for the determination of Se (IV) and total selenium in natural waters has been developed and optimized. The detection limit is about 20 pM for both analyses using a one liter sample. The precisions were about 2 % at 338 pM for Se (IV) and at 234 pM for total selenium.

The concentrations of both total selenium and Se (IV) decreased with increasing salinity in the surface waters of the James River and southern Chesapeake Bay. While total selenium seemed to exhibit conservative behavior at salinities above 0.36 ('o)/oo, Se (IV) was apparently removed during estuarine mixing. …

The Effects Of Elevated Calcium Chloride And Magnesium Chloride Levels On Larval Growth And Survival Of Macrobrachium Rosenbergii (De Man) (Decapoda Palaemonidae) Reared In The Laboratory, James Thomas Michaels Ii

OES Theses and Dissertations

The effects of elevated CaCl₂ , MgCl₂ , combination CaCl₂ and MgCl₂ concentrations and their associated ionic strengths on larval growth and survival of the freshwater prawn, Macrobrachium rosenbergii were investigated in the laboratory. Larvae were reared in diluted seawater of 15 parts per thousand salinity with elevated calcium concentrations of 330 parts per million and elevated magnesium concentrations of 1275 parts per million. Control larvae were also reared with elevated NaCl concentrations to duplicate the ionic strength increases of the combination CaCl₂ - MgCl₂ test solution which had the highest ionic strength. A …

Suspended Matter And Light Attenuation In A Turbid Estuary, Daniel E. Campbell

OES Theses and Dissertations

A study was made in Hampton Roads, Virginia, to characterize the suspended matter and to investigate its relationship to the light attenuation coefficient. The study gives a detailed description of the seston and its variations with time and space. An evaluation of the light attenuation coefficient as an indicator of seston distributional parameters was made.

The distribution of the suspended matter is obtained through gravimetric, Coulter counter and microscopic analyses. Microscopic analysis is employed to determine the composition of the seston and ATP determinations give the amount of living biomass. The suspended matter is characterized in terms of weight, numbers, …

Methane Distribution And Production In The Georgia Salt Marsh, Larry P. Atkinson, John R. Hall

CCPO Publications

Bacterial action in the anaerobic sediments of Spartina salt marsh produce large quantities of methane. Water in contact with the marsh has methane concentrations 200-300 times normal oceanic concentrations. The methane content of the water varies from maximum of 1.2 mu l CH sub(4)/ super(l) super(-1) in the summer to a minimum of 0.005 mu l CHl1

Water Chemistry Survey Of Boulder Basin, Lake Mead, P. R. Tramutt, Bureau Of Reclamation

Publications (WR)

The survey results indicate that the impoundment of water behind Hoover Dam has not adversely affected the dissolved oxygen (DO) content and that water quality and DO content were uniform regardless of depth. The study made in April-May 1964 will provide water quality data of Lake Mead prior to releases from Lake Powell as a basis for evaluating Lake Powell's effect on water quality and limnology of Lake Mead. The performance of a DO analyzer was tested and found unsatisfactory at depths below 150 ft. Parameters tested by standard chemical analyses of water samples in the Denver Laboratory and by …