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Articles 1 - 11 of 11

Full-Text Articles in Biogeochemistry

Assessing Dissolved Organic Matter Sources And Dynamics In Urban Stormwater: Implications For Greenhouse Gases, Harper W. Schmalz Jan 2026

Assessing Dissolved Organic Matter Sources And Dynamics In Urban Stormwater: Implications For Greenhouse Gases, Harper W. Schmalz

Theses and Dissertations (Comprehensive)

Stormwater management ponds (SWMPs) are important aspects of land-use planning and increasingly recognized as active sites of biogeochemical processing that influence carbon cycling; however, little research has investigated the controls on dissolved organic and dissolved inorganic carbon (DOC and DIC) within these systems. This thesis examined the processing and transformations of dissolved carbon between three compartments to support the development of a greenhouse gas (GHG) box-model for urban stormwater ponds, including SWMP sediment, surface water, and vegetation. The objective of this thesis was to assess the biogeochemical processes that govern the rate and transformation of DOC and DIC between these …


Impacts Of Burn Severity On The Hydro-Physical, Chemical And Thermal Properties Of Sub-Arctic Peat, Joshua B. Meyer Mr Jan 2026

Impacts Of Burn Severity On The Hydro-Physical, Chemical And Thermal Properties Of Sub-Arctic Peat, Joshua B. Meyer Mr

Theses and Dissertations (Comprehensive)

Under current climate change, summer season in the boreal regions of Canada is becoming increasingly warmer and drier. This shift is driving increases in the frequency and intensity of naturally occurring wildfires and allowing access to areas not normally susceptible to fire such as wetlands. In peatland areas, these increasingly large fires can create complex burn scars, which contain a wide variety of different burn severities across different landcover types. This variety calls for a greater understanding of how varying fire intensity affects the hydro physical, chemical, and thermal characteristics of boreal peat. This study aims to deepen that understanding …


Investigating The Thermal Stratification Patterns Of A Shallow Polymictic Boreal Shield Lake And The Effectiveness Of Models In Predicting Shallow Lake Thermal Profiles, Matthew Roberts Jan 2025

Investigating The Thermal Stratification Patterns Of A Shallow Polymictic Boreal Shield Lake And The Effectiveness Of Models In Predicting Shallow Lake Thermal Profiles, Matthew Roberts

Theses and Dissertations (Comprehensive)

Thermal stratification is a core process of lakes which plays a critical role in shaping the ecological dynamics of lakes, influencing major processes like nutrient cycling and oxygen availability. For shallow polymictic lakes, thermal stratification patterns present some unique differences due to the complex and variable nature of these lakes. In this thesis, I examined thermal stratification in a shallow polymictic lake in northwestern Ontario during the ice-free season of 2019 to investigate the frequency, duration, and driving factors of thermal stratification. The lake underwent 146 separate stratification events, with a median duration of 2 hours per event, with a …


Evaluating The Risk Posed By Gadolinium In The Grand River Watershed, Johann Memmel Jan 2024

Evaluating The Risk Posed By Gadolinium In The Grand River Watershed, Johann Memmel

Theses and Dissertations (Comprehensive)

Gadolinium (Gd) is a rare earth element (REE), primarily used in contrast agents for magnetic resonance imaging (MRI), with additional applications in metallurgy, phosphors, neutron shielding, and other niche applications. Both Gd and Gd-based contrast agents (GBCAs, the form used for MRIs) have been detected downstream of wastewater effluent discharges and there is currently little research into the risk this poses to aquatic ecosystems. This study investigated the potential environmental risks of Gd and GBCAs using the Grand River watershed (GRW) in southwestern Ontario as a model ecosystem due to it containing a variety of land uses (urban, industrial, agricultural) …


Assessing Stormwater Management Pond Water Quality, Function, And The Potential Biotic Effects To Receiving Waters, Mitchell Elstone Jan 2024

Assessing Stormwater Management Pond Water Quality, Function, And The Potential Biotic Effects To Receiving Waters, Mitchell Elstone

Theses and Dissertations (Comprehensive)

The use of stormwater management ponds (SWMPs) has been increasing over the past five decades. However, an in-depth understanding of the daily performance of SWMPs and functionality during cold periods is limited. This is in part because mandated monitoring is relatively infrequent, and the assumption that SWMPs are inactive between storm events and during the winter. The goals of this research were to better understand daily stormwater (SW) characteristics, the performance of SWMPs based on current forms of evaluation and assess the potential for SWMP effluent to impact downstream biota. Influent and effluent samples from two SWMPs were collected daily …


Reconstructing Hydrologic Conditions And Metals Supplied By The Peace River To The Peace-Athabasca Delta, Jelle André Faber Jan 2020

Reconstructing Hydrologic Conditions And Metals Supplied By The Peace River To The Peace-Athabasca Delta, Jelle André Faber

Theses and Dissertations (Comprehensive)

The Peace-Athabasca Delta (PAD) in northern Alberta, Canada, is recognized internationally for its ecological, historical, and cultural significance. The delta is mostly within Wood Buffalo National Park, a UNESCO World Heritage Site, and is a Ramsar Wetland of International Importance. The construction of the WAC Bennett Dam (1967) and the Site C Dam (ongoing, 2024) on the Peace River, and expansion of the Alberta Oil Sands industry along the Athabasca River have raised concerns over water quantity and quality in the delta. When industry operations began, effective monitoring had not been implemented. Consequently, pre-industrial reference conditions are unknown and can …


Investigating Diel, Seasonal, And Interannual Variability Of Dissolved And Particulate Stable Carbon Isotope Values In A Eutrophic Boreal Lake, Rachel Henderson Jan 2020

Investigating Diel, Seasonal, And Interannual Variability Of Dissolved And Particulate Stable Carbon Isotope Values In A Eutrophic Boreal Lake, Rachel Henderson

Theses and Dissertations (Comprehensive)

Lakes are globally significant sources, sinks, and conduits of carbon. Cultural eutrophication of freshwater promotes the growth of phytoplankton blooms, which can transform, respire, and sequester large amounts of carbon. Analysis of stable carbon isotopes is a common tool to study the movement of carbon through the aquatic carbon cycle. The causes of temporal variability in δ13C values at different timescales are not well understood, and differ between lakes. In this study, I investigated diel, seasonal, and interannual variability in δ13C values of dissolved inorganic carbon (DIC) and particulate organic carbon (POC) in Lake 227, an …


Influence Of Ligand Complexation On Nickel Toxicity, Speciation And Bioavailability In Marine Waters, Samantha Sherman Jan 2019

Influence Of Ligand Complexation On Nickel Toxicity, Speciation And Bioavailability In Marine Waters, Samantha Sherman

Theses and Dissertations (Comprehensive)

Currently there are no site-specific bioavailability-based prediction models for assessing the impacts of nickel (Ni) in marine environments although there are indications that these may be warranted. The aim of this research was to characterize the complexation of Ni in relation to toxicity and speciation. Various complexing ligands were used, and it was predicted that the binding affinity (logKf) of ligands would be inversely correlated to toxicity based on dissolved Ni concentrations ([NiD]) but that on a free ion concentration ([Ni2+]) basis, toxicity would not vary. A two-phased approach was used; the first was a proof of principle where synthetic …


Using Paleolimnology To Establish Baseline Conditions For Metal Contaminants In Advance Of Proposed Mining To Inform A Northern Community-Led Aquatic Monitoring Program, Tłı̨Chǫ Lands, Northwest Territories, Canada., James Telford Jan 2019

Using Paleolimnology To Establish Baseline Conditions For Metal Contaminants In Advance Of Proposed Mining To Inform A Northern Community-Led Aquatic Monitoring Program, Tłı̨Chǫ Lands, Northwest Territories, Canada., James Telford

Theses and Dissertations (Comprehensive)

The Marian Watershed Stewardship Program (MWSP), a community-driven aquatic ecosystem monitoring program, was developed by the Tłı̨chǫ Government to address concerns regarding the cumulative impacts of multiple potential stressors. In particular, the MWSP aims to develop methods that will be effective for detecting potential pollution from the proposed cobalt-gold-copper-bismuth NICO mine within Tłı̨chǫ Lands. In collaboration with the MWSP, paleolimnological methods and geochemical normalization are used to establish pre-mine baselines of lake sediment metals concentrations in the Marian River watershed prior to mine development. This baseline framework can be used to assess for pollution from surficial sediment once the mine …


Evaluating The Biogeochemical Functioning Of A Constructed Fen On The Post-Mining Landscape Of Athabasca Oil Sands Region, Fort Mcmurray, Alberta, Canada, Felix C. Nwaishi Jan 2016

Evaluating The Biogeochemical Functioning Of A Constructed Fen On The Post-Mining Landscape Of Athabasca Oil Sands Region, Fort Mcmurray, Alberta, Canada, Felix C. Nwaishi

Theses and Dissertations (Comprehensive)

Peatlands have a unique biogeochemical function, characterized by an imbalance between the rates of biomass accumulation and decomposition. These characteristics facilitate the ability of peatlands to support the sequestration of nutrients and carbon. In disturbed peatlands, these functions are compromised. Thus, reclamation targets amongst other key functions, the recovery of biogeochemical functioning. These functions could serve as a measure of recovery to conditions that are present in natural analogues. This thesis examines the recovery of microbially-mediated nutrient transformation processes in a fen peatland that was constructed on a post-mining landscape in the Athabasca oil sands region, Fort McMurray, Alberta. The …


Carbon Dioxide Exchange In A Permafrost-Dominated Boreal Wetland In The Northwest Territories, Canada, Andrea J. Kenward Jan 2010

Carbon Dioxide Exchange In A Permafrost-Dominated Boreal Wetland In The Northwest Territories, Canada, Andrea J. Kenward

Theses and Dissertations (Comprehensive)

Northern boreal wetland complexes are substantial reservoirs for carbon and play a crucial role in both regional and global carbon budgets but they are showing significant signs of impact by climate change. This study examined the carbon dioxide flux of a high boreal wetland during the snowmelt and growing season of 2008 in Scotty Creek Basin, located near Fort Simpson (61°18'N, 121°18'W), Northwest Territories. This basin is not only responding to shifts in atmospheric temperatures, but it is also under additional pressure from increasing permafrost degradation. A dynamic closed-system chamber was used to monitor and quantify mid-day total respiration (R …