Biogeochemistry Commons^™

Unveiling The Vital Role Of Blue Carbon In Mangroves: Understanding Environmental Influences, Jahnelle Howe

Dissertations, Theses, and Capstone Projects

Mangrove ecosystems provide essential ecological services, including carbon sequestration, coastal protection, and heavy metal retention. However, their resilience and functionality are increasingly influenced by hurricanes, climate variability, and anthropogenic contamination. This dissertation integrates three research efforts examining mangrove canopy dynamics, carbon storage, and heavy metal contamination in two Puerto Rican mangrove systems: La Parguera and Laguna Grande.

Using remote sensing techniques (LiDAR and NDVI analysis), we assessed the impact of Hurricane Maria (Category 4, 2017) on mangrove canopy structure and vegetation health. Results revealed significant canopy height loss, with greater damage at Laguna Grande, where pre-storm canopy height and human …

Investigating Potential Sugar-Related Uncertainties In A Proxy For Ancient Co2, Liam Cooper

Student Theses and Dissertations

The ε_p proxy for ancient pCO₂ can potentially estimate ancient pCO₂ as from the evolution of rubisco-based photosynthesis, using the difference in stable carbon isotope ratios (δ¹³C) between fixed and inorganic carbon, assuming this difference is proportional to pCO₂. This study aims to address uncertainty with the use of photosynthetic microbes in proxies for ancient pCO₂. While previous studies address uncertainties related to the δ¹³C of initial fixed photosynthate (e.g., growth rate), we aim to address the effects of downstream carbon allocation. Specifically, if a significant fraction of fixed …

Tracing The Sources Of Nitrogen In Submarine Groundwater Discharge And Primary Producers In The Great South Bay Estuary, Nia H. Rene

Dissertations, Theses, and Capstone Projects

The primary aim of this research was to elucidate the impact of submarine groundwater discharge (SGD) and septic effluent on coastal primary producers in the Great South Bay (GSB). The study focused on three main objectives: assessing the impact of precipitation patterns on SGD, tracing nitrogen sources into the GSB, and determining the impact of these nitrogen sources on coastal primary producers. The research revealed that current precipitation patterns significantly influence SGD across different seasons, highlighting the seasonal variability in groundwater discharge and its implications for nutrient loading in coastal waters. A suite of tracers was employed to identify and …

Towards Sociobiogeochemistry: Critical Perspectives On Anthropogenic Alterations To Soil Nitrogen Chemistry Via U.S. Urban And Suburban Development, Christopher D. Ryan

Dissertations, Theses, and Capstone Projects

The ecological impacts of changes to land use are relevant to concerns about climate change, eutrophication of waterbodies, and reductions in biodiversity. As a foundational component of ecosystem functioning, changes to soil biogeochemistry have significant effects on overall ecosystem health. With cities continuing to grow and develop in extent, the impacts of urbanization and suburbanization on soils are of particular concern. Despite a wide range of natural climatic and geologic conditions, several factors have driven similar patterns of land transformation and management across the United States. In particular, federal initiatives including the Home Owners Loan Corporation, the Federal Housing Administration, …

Understanding The Impacts Of Freshwater Fluxes On The Biogeochemistry Of The Coastal Arctic: A Case Study Of Prudhoe Bay, Francesca Lingo

Dissertations and Theses

The Arctic region, undergoing significant environmental changes due to rapid warming, faces alterations in air temperatures, melting permafrost, declining sea ice, and changes in riverine inputs. These shifts have profound implications for Arctic coastal ecology and biogeochemical cycles. This study, focusing on Alaska's North Slope, explores the influence of freshwater fluxes on water optical properties, vital for accurate satellite remote sensing interpretations. Our approach combined field measurements, existing data, and satellite remote sensing retrievals to identify biogeochemical gradients and their seasonal and interannual variations. A novel finding was the unique CDOM composition in Prudhoe Bay, characterized by a lower molecular …

Fine Characterization Of Leafing Phenology In The Brazilian Atlantic Forest By Optical And Microwave Remote Sensing, James B. Bell

Dissertations and Theses

Tropical forests provide important ecosystem functions in the global biosphere, but they remain among the most poorly understood elements of land surface models, especially with regard to their seasonal dynamics. For instance, in seasonally dry forests, the pattern of the annual green-up in their canopies closely follows annual patterns of rainfall. The same, however, does not occur in wet forest canopies which are dominated by evergreen trees. In the latter, water is not scarce enough to limit leaf photosynthetic function. Canopy leafing phenology in these forests is therefore poorly characterized by optical remote sensing methods which are not sensitive to …

Shallow Water Coral Distribution And Its Response To Climate Change, Amaury De Jesus

Dissertations and Theses

Shallow water corals are one of the main reef-building organisms that secrete carbonates as their skeletons, and therefore, are one of the major sinks of CO2 in the ocean. These reef builders are also very crucial to marine environments and human society. As the global energy demand continues rising, fossil fuel burning increases at a faster pace despite the increase in energy supply using clean and renewable energy. The increase of CO2 in the atmosphere has been shown to exacerbate global warming and may cause ocean acidification, threatening the habitat of shallow-water corals. Many recent observations show alarming signs of …

Nutrient Dynamics And Ecosystem Development Of Urban Forests, Gisselle A. Mejía

Dissertations, Theses, and Capstone Projects

Urban growth and expansion are a major component of global environmental change, with impacts on climate, air and water quality, biodiversity, and human well-being. Forests embedded in urban landscapes are critical in mitigating these impacts at local, regional, and continental scales. However, assessing urban forests is difficult because cities are heterogenous in physical, chemical, biological, and social dimensions. This heterogeneity has constrained how urban forests are defined, and therefore, how they are studied. The objective of this dissertation is to determine how these biophysical and social factors drive ecological processes in urban forests and will address three outstanding challenges in …

The Interaction Of Different Primary Producers And Physical And Chemical Dynamics Of An Urban Shallow Lake, Majid Sahin

Dissertations, Theses, and Capstone Projects

An artificial urban shallow lake, Prospect Park Lake (PPL), is situated on a terminal moraine in Brooklyn New York, and supplied with municipal water treated with ortho-phosphates. The constant input of the phosphate nutrient is the primary source of eutrophication in the lake. The numerous pools along the water course houses various aquatic phototrophs, which influence the water quality and the state of the system, driving conditions into favoring the survival of their species. In the first half of the dissertation, the focus of the project is on analyzing how the different primary producers in different regions of PPL affect …

Carbon And Nitrogen Dynamics Of A Lagoon Salt Marsh In Davenport, California, Mark D. Gormley

Dissertations, Theses, and Capstone Projects

Wetlands are complex environments that play a critical role in regulating the global biogeochemical cycle of carbon (C) and nitrogen (N). Wetlands are critical contributors to global climate change and atmospheric chemistry since they store as much as 33% of the world’s soil organic carbon (SOC), release more than 20% of the atmospheric methane (CH₄), and produce nitrous oxide (N₂O), an extremely potent greenhouse gas (GHG). Despite the enormous radiative forcing potential of carbon dioxide (CO₂), CH₄ and N₂O derived from wetlands, uncertainties over the rates of C sequestration and GHG …

Increased Carbon Capture By A Silicate-Treated Forested Watershed Affected By Acid Deposition, Lyla L. Taylor, Charles T. Driscoll, Peter M. Groffman, Greg H. Rau, Joel D. Blum, David J. Beerling J. Beerling

Advanced Science Research Center

Meeting internationally agreed-upon climate targets requires carbon dioxide removal (CDR) strategies coupled with an urgent phase-down of fossil fuel emissions. However, the efficacy and wider impacts of CDR are poorly understood. Enhanced rock weathering (ERW) is a land-based CDR strategy requiring large-scale field trials. Here we show that a low 3.44 t ha−1 wollastonite treatment in an 11.8 ha acid-rain-impacted forested watershed in New Hampshire, USA, led to cumulative carbon capture by carbonic acid weathering of 0.025–0.13 t CO2 ha−1 over 15 years. Despite a 0.8–2.4 t CO2 ha−1 logistical carbon penalty from mining, grinding, transportation, and spreading, by 2015 …

Long Term Nutrient And Chlorophyll A Dynamics Across Long Island Sound And Impacts On Dissolved Oxygen Conditions Within The Western Sound (1991-2019), Sherry Perreira

Dissertations and Theses

Nitrogen overload, eutrophication, and hypoxia have been challenging and persistent water quality problems in Long Island Sound (LIS) over the past decades with major impacts on commercial industries, ecology, and recreational activities in the region. Recognizing these problems, the EPA enforced three phases of the Clean Water Act (CWA) to reduce nitrogen loads in an effort to improve this important estuary. This study examines how nitrogen (NH₃, NO_x & TDN), chlorophyll a (CHLA), and dissolved oxygen (DO) concentrations changed in LIS over the past 30 years, in response to water quality regulations as well as changes in …

Ecosystem Health In Guánica Bay And La Parguera, Puerto Rico: Remote Sensing Of Ocean Color And Metal Analysis Of Coral Tissue And Surficial Sediments, Jahnelle Howe

Dissertations and Theses

Guánica Bay is an estuary located in southwest Puerto Rico, with a coral reef ecosystem at its periphery. This ecosystem is affected by sediments, nutrients, and contaminants from the watershed through the Bay and into the offshore water. This project evaluates Guánica Bay and La Parguera coastal areas through remote sensing and chemical analysis to assess coastal ecosystem health. The concentration of metals in two coral species and their associated surface sediments was were analyzed by X-ray fluorescence (XRF) and Direct Mercury Analyzer (DMA- 80). Ocean color remote sensing was used to estimate nutrient inputs and phytoplankton biomass through chlorophyll- …

Microbial Degradability Of Terrigenous, Marsh-Exported, And Estuarine Colored Dissolved Organic Matter In Long Island Sound, John R. Supino

Dissertations and Theses

The Long Island Sound is one of the world's most urbanized estuaries, polluted from excess nutrients which impact the quality of water through increased biological productivity. Dissolved organic matter (DOM) is a sensitive indicator of anthropogenic pollution and nutrient enrichment in coastal waters as well as an important part of the carbon cycle and serves as a primary food source for aquatic food webs. Additionally, the colored portion of DOM (CDOM) impacts coastal optical properties, ocean color, and light attenuation. High levels of CDOM have been shown to inhibit the growth of phytoplankton and limit photosynthesis, damaging the food chain …

Investigation Of Biogeochemical Mechanisms Of Greenhouse Gas Production In The Urban Hudson River Estuary, Brian Alan Brigham

Dissertations, Theses, and Capstone Projects

Coastal megacities deposit significant amounts of carbon (C), nitrogen (N) and other pollutants into surrounding waters. These inputs, including wastewater and surface water runoff, may affect estuarine and adjacent wetland biogeochemical cycles, microbial production and ultimately greenhouse gas (GHG) efflux. In many megacities pollutant loading is typically greatest after periods of precipitation when the volume of wastewater and storm water runoff exceeds local sanitation capacity, resulting in the discharge of raw sewage into adjacent waters. These combined sewage overflow (CSO) events have received considerable attention primarily due to their potential impact on human health and eutrophication. However, whether these events …

Marsh-Exported Dissolved Organic Matter Fate In Estuaries, Laura Ann Logozzo

Dissertations and Theses

Dissolved organic matter (DOM) is a significant driver of estuarine productivity and nutrient cycling. The colored component of DOM, chromophoric dissolved organic matter (CDOM), impacts coastal optical properties, ocean color, and light attenuation. While marshes are largely considered sinks for carbon due to their high productivity and low soil carbon degradation rates, laterally they are sources of carbon as optically and chemically distinct DOM to surrounding aquatic ecosystems; these inputs are often essential in sustaining a net heterotrophic system. However, the photoreactivity and bioavailability of marsh-exported DOM is largely uncategorized, thus making it difficult to quantify its impacts on estuarine …

Temporal Variability Of Fluorescent Dissolved Organic Matter At A Brackish, Tidal Marsh-Estuary Interface, Alana B. Menendez

Dissertations and Theses

Marshes are both terrestrial and aqueous, sitting as an intermediate between land and water. Studies over constrained numbers of tidal cycles have demonstrated that these marshes are net exporters of dissolved organic carbon (DOC) to adjoining estuaries, however, there is need for continuous monitoring to better understand the temporal variability of this flux: tidally, seasonally, and during episodic rain events. Through use of a YSI EXO2 sonde, an in situ optical sensor at the interface of the brackish, tidal Kirkpatrick Marsh and Rhode River sub-estuary in Edgewater, Maryland (located on the northwestern shore of the Chesapeake Bay), we were able …

Estimates Of Micro-, Nano-, And Picoplankton Contributions To Particle Export In The Northeast Pacific, B. L. Mackinson, S. B. Moran, M. W. Lomas, Gillian M. Stewart, R. P. Kelly

Publications and Research

The contributions of micro-, nano-, and picoplankton to particle export were estimated from measurements of size-fractionated particulate 234Th, organic carbon, and phytoplankton indicator pigments obtained during five cruises between 2010 and 2012 along Line P in the subarctic northeast Pacific Ocean. Sinking fluxes of particulate organic carbon (POC) and indicator pigments were calculated from 234Th;238U disequilibria and, during two cruises, measured by a sediment trap at Ocean Station Papa. POC fluxes at 100m ranged from 0.65 to 7.95 mmolm2 d1, similar in magnitude to previous results at Line P. Microplankton pigments dominate indicator pigment fluxes (averaging 6919% of total pigment …

Carbon And Nitrogen Dynamics From Slow Pools Of Soil Organic Matter In A Temperate Forest: Pyrogenic Organic Matter And And Root Litter, Fernanda Dos Santos

Dissertations, Theses, and Capstone Projects

Soil organic matter (SOM) is the dominant reservoir of organic carbon (OC) in terrestrial ecosystems, storing approximately three times the size of the C pool in the atmosphere. In temperate forests, a major fraction of the SOM consists of slowly decaying soil organic C (SOC) pools. While slowly cycling C pools constitute a large reservoir of stable C in soils, the dominant environmental factors controlling this C pool remain unresolved. This research investigates two significant, but poorly characterized slowly decaying C pools: fine root litter (< 2mm) and thermally altered plant biomass (pyrogenic organic matter, PyOM). Specifically, I used compound-specific stable isotope analysis (¹³C and ¹⁵N) as my main methodological approach to examine the (1) …

Carbon Losses From Pyrolysed And Original Wood In A Forest Soil Under Natural And Increased N Deposition, B. Maestrini, S. Abiven, N. Singh, J. Bird, M. W. I. Schmidt

Publications and Research

Pyrogenic organic matter (PyOM) plays an important role as a stable carbon (C) sink in the soils of terrestrial ecosystems. However, uncertainties remain about in situ turnover rates of fire-derived PyOM in soil, the main processes leading to PyOM-C and nitrogen (N) losses from the soil, and the role of N availability on PyOM cycling in soils. We measured PyOM and native soil organic carbon losses from the soil as carbon dioxide and dissolved organic carbon (DOC) using additions of highly 13C-labelled PyOM (2.03 atom %) and its precursor pinewood during 1 year in a temperate forest soil. The field …

Coupling Of Fog And Marine Microbial Content In The Near-Shore Coastal Environment, M. E. Ducker, Gregory D. O'Mullan, K. C. Weathers, A. R. Juhl, M. Uriarte

Publications and Research

Microbes in the atmosphere (microbial aerosols) play an important role in climate and provide an ecological and biogeochemical connection between oceanic, atmospheric, and terrestrial environments. However, the sources and environmental factors controlling the concentration, diversity, transport, and viability of microbial aerosols are poorly understood. This study examined culturable microbial aerosols from a coastal environment in Maine (USA) and determined the effect of onshore wind speed and fog presence on deposition rate, source, and community composition. During fog events with low onshore winds (