Biogeochemistry Commons^™

Aluminum As A Tracer Of Dust Deposition To The Ocean: A Case Study From The Bermuda Region, Tara Elizabeth Williams

OES Theses and Dissertations

Aluminum (Al), a major component of mineral aerosol (dust), partially dissolves in seawater and is widely used as a tracer for estimating time‐averaged dust fluxes to the ocean. Such estimates rely on dissolved Al (DAl) inventories in the surface mixed layer (SML), an assumed SML residence time of DAl (_TDAl), the fractional solubility of Al in dust (Al_S), and the mass fraction of Al in dust. In this study, dust flux estimated from seasonal, water-column DAl data from the Bermuda Atlantic Time-series Study (BATS) region are compared with direct dust flux estimated from contemporaneous measurements of …

Tracing The Journey Of Dissolved Organic Matter: From Leaf Litter Photodegradation To Microbial Processing In Tropical Streams, Samantha Nicole Sullivan

Chemistry & Biochemistry Theses & Dissertations

Dissolved organic matter (DOM) is a major reservoir of organic carbon in aquatic ecosystems and plays a central role in global carbon cycling through its transformation and remineralization to carbon dioxide (CO₂). As DOM moves from terrestrial environments into streams and rivers, its chemical composition is altered by a combination of microbial and photochemical oxidation processes that regulate both its reactivity and its persistence during transport. However, the molecular mechanisms governing these oxidative transitions, particularly in tropical ecosystems characterized by strong hydrologic seasonality and substantial inputs of plant-derived material, remain insufficiently resolved. This dissertation integrates ultrahigh-resolution mass spectrometry, optical characterization, …

Modeling Aerosol Transport During High Particulate Matter Episodes In El Paso-Juarez Region And Mitigating Mining-Related Emissions Of Rare Earth Elements (Rees) To The Air, Suzan Aranda Luna

Open Access Theses & Dissertations

This dissertation examines the use of the HYSPLIT model to develop a methodology for the transport and dispersion of air masses affecting particulate matter (PM) concentrations in the El Paso Region, and bioleaching experiments as an alternative to mitigating rare-earth concentrations in the air. Chapter 2 describes the study methodology, 3 and 4 cover the modeling methodology using two-representative high PM2.5 episodes, occurring on February 28, 2024, and June 19, 2024, respectively. These sections encompass the analysis of backward trajectories using four different meteorological datasets to build trajectory frequency maps, the exploratory model analysis of modeled outputs from lower to …

What Limits Dryland Ecosystems? Patterns Of Soil Fertility And Resource Limitation In The Chihuahuan Desert, Dylan Stover

Open Access Theses & Dissertations

Human activities are substantially altering global resource cycles with widespread implications for biogeochemistry and ecosystem functioning globally. Drylands, regions where precipitation is outweighed by water losses, are especially sensitive to these large shifts in resource cycles due to their inherently low and variable resource availability. In these regions, resource availability and biological activity are often concentrated around plants – or fertile islands – and predominantly driven by pulses of water. However, our knowledge of the processes influencing biological productivity in drylands – patterns of soil fertility and resource limitation – remains lacking, and their unique biogeochemical and biological processes create …

Direct And Satellite-Based Quantification Of Greenhouse Gas Fluxes In Small Ponds., Mark Christopher Tierney

Electronic Theses and Dissertations

As evidenced by their historic losses due to anthropogenic activities, wetlands are undervalued ecosystems that provide numerous ecosystem services, from recreational opportunities to carbon (C) storage. However, these wetlands are also the largest natural source of atmospheric methane (CH₄). Additionally, small water bodies (< 10,000 m²) are disproportionately large emitters relative to larger lakes and reservoirs. As construction and restoration efforts proceed, it is crucial to identify wetlands that need restoration and to understand the factors driving both greenhouse gas (GHG) fluxes and the C balance of these systems. This dissertation investigates the drivers of greenhouse gas fluxes …

Mcl1 And Hexokinase 2 Form A Glucose Metabolic Regulatory Axis, Robert Lee

All ETDs from UAB

Hexokinase 2 (HK2) initiates glucose metabolism by catalyzing the conversion of glucose to glucose-6-phosphate providing the starting substrate for a vast array of metabolic pathways such as glycolysis, pentose phosphate pathway (PPP), amino acid biosynthesis and others. While HK2’s metabolic role in normal physiologic function (such as in cardiomyocytes) and cancers (through driving the Warburg Effect) are well established, there is emerging evidence that supports HK2 is also a critical mediator of protein-protein interactions that regulate cell survival. Through comprehensive review, we explore how HK2 contributes to cell survival through metabolic and protein scaffolding roles. We also investigate a novel …

Compound-Specific Isotope Records Of Dust Provenance And Hydroclimate In The North Pacific And Marginal Seas Of East Asia: Integrating N-Alkane Δ13c And Δd With Standardized Analytical Frameworks, Julian W. Traphagan

LSU Doctoral Dissertations

This dissertation presents advancements in compound-specific isotope analysis (CSIA) through methodological innovation and paleoclimate reconstruction in Central and East Asia. Utilizing plant wax n-alkanes from International Ocean Discovery Program (IODP) and Ocean Drilling Program (ODP) sediment cores, this research reconstructs atmospheric circulation shifts responding to tectonic evolution and climate transitions since the Late Miocene.

Chapter 1 investigates hydrogen isotope compositions (δD_wax) from IODP U1430 (Sea of Japan), ODP 886, and ODP 1208 (North Pacific) to trace dust provenance and hydroclimate changes since ~13 Ma. Results reveal persistently segmented source-to-sink systems: the Sea of Japan dominated by westerly …

Effect Of Seasonal Variability In Methane Emissions And Iron Redox Chemistry At Terrestrial-Aquatic Interfaces, Hermes C. Ruiz

Master's Theses

Methane (CH₄) emissions at terrestrial–aquatic interfaces (TAIs) are significant contributors to the global carbon budget, yet the mechanisms driving methanogenesis remain poorly understood. Limited data exist on how seasonal variations and redox processes influence CH₄ fluxes in these dynamic ecosystems. This study addressed two questions: (1) How are CH₄ fluxes in riverine floodplains and adjacent hillslopes impacted by seasonal variations? (2) What roles do metal redox processes (e.g., iron (Fe)) play in regulating methanogenesis?

In-situ CH₄ flux and solid-phase Fe speciation were quantified in East River, CO, under flooded and drained conditions. Groundwater chemistry, gas flux, and soil physical properties …

Ocean And Coastal Acidification Monitoring Priorities For The Northeast Us And Eastern Canada, Christopher Hunt, Austin Pugh, Jake Kritzer, Samantha Siedlecki, Kumiko Azetsu-Scott, Parker Gassett, Diane Lavoie, Adam Pimenta, Amy Trice, Elizabeth Turner

Faculty Publications

The Interagency Working Group on Ocean Acidification Monitoring Prioritization Plan 2024 calls for Coastal Acidification Networks to identify the ocean and coastal acidification (OCA) monitoring needs most important for their regions. The Northeast Coastal Acidification Network (NECAN) organized a webinar series to study regional needs, which culminated with a workshop in November 2023. This workshop led to the identification of six priority new Monitoring Needs in addition to the maintenance of current monitoring efforts:

• Improve spatial and temporal scale of monitoring co-located OCA variables and biological measurements to better resolve variability of acidification dynamics in concert with biological processes …

Assessing Greenhouse Gas Emissions From Michigan’S Drowned River Mouths Using In Situ And Remote Sensing Methods, Jillian A. Greene

Masters Theses

Freshwater estuaries are natural contributors to the carbon cycle including production and emission of methane (CH4) and carbon dioxide (CO2), potent greenhouse gases (GHGs); however, estimates of their contribution to regional and global GHG emissions is largely unconstrained. Few studies have examined the quantification and drivers of lake CH4 and CO2 production in the Great Lakes region and how it may differ in response to anthropogenic development. In this study, CH4 and CO2 emissions were measured from three drowned river mouth estuaries (DRMs) along the eastern shore of Lake Michigan in 2024. The DRMs exist along a latitudinal gradient ranging …

Comparison Of Nutrient Concentrations And Primary Production Indicators Across Plume Fronts, Taylor Dishon

Electronic Theses and Dissertations

Coastal buoyant plumes carry low-salinity waters containing particulate and dissolved terrestrial materials with an abundance of nutrients into the coastal ocean, including inorganic nitrogen and phosphorous. Plume fronts act as transport barriers created from the convergence of a fresher plume with an older, saltier plume or with ambient waters, leading to potential accumulation of phytoplankton and nutrients. This accumulation creates an optimal environment for primary production. The primary goals of this study were: to investigate the distribution of and potential relationships between nutrient concentrations and chlorophyll a across plume fronts of the Winyah Bay River Plume, and examine potential relationships …

Using Triple Oxygen Isotopes To Investigate Water Usage In Desert Ecosystems, Cloe V. Knutson

Earth and Planetary Sciences ETDs

In arid environments, maintaining water balance can be more critical for survival than obtaining food. As droughts intensify, understanding how animals manage body water is essential. Triple oxygen isotope analysis provides a novel way to trace water sources in animals, distinguishing contributions from free water, food-derived oxygen, and atmospheric O₂. We developed an equilibration method using CO₂–H₂O oxygen exchange and measured δ^’18O and Δ^’17O values via tunable infrared laser direct spectroscopy (TILDAS). Validated against traditional fluorination methods, this technique enables streamlined analysis of whole blood and plant samples. Applied to …

The Astrobiological Figure Of Humboldt As Pioneer In The Rock Varnish Research, Jose Jordan-Soria

Homage to Alexander von Humboldt: Travels to and from Spain Throughout the Centuries / Homenaje a Alexander von Humboldt: Viajes hacia y desde España de todos los siglos

From Humboldt is particularly interesting -and little know- his description of mineral coatings on rocks 200 years ago, reported in his book Personal Narrative of Travels to the Equinoctial Regions of the New Continent during the years 1799-1804, co-written with Aimé Bonpland, for which is considerate the father of rock coating research. On June 5th 1799 set sail from A Coruña -Spain- to Cumaná -Venezuela- beginning five years of expedition. While they explored the Orinoco River system, in th eriver basin waterfalls, Humboldt observed the presence of dark coating depositions. He ascertained a manganese-rich accretion, reporting similar structures in other …

Phosphorus: From The Origins Of Life To The Origin Of An Industry, Joshua Abbatiello

USF Tampa Graduate Theses and Dissertations

The element phosphorus is a key biogenic element that is often the limiting reagent for life. Phosphorus is quickly bound by metal divalent cations making it virtually insoluble and inert in water (forming the phosphate mineral apatite). Due to this, it becomes imperative to understand alternative pathways to increase biogenically available phosphorus in environments. To that end, this dissertation involved examining olivine as an alternative source of phosphorus to apatite, analyzing a novel grain of iron silicide found via lightning reduction in a fulgurite, and finally sought to understand the impact of phosphate mining through phosphogypsum stacks. Olivine is a …

Unveiling The Vital Role Of Blue Carbon In Mangroves: Understanding Environmental Influences, Jahnelle Howe

Dissertations, Theses, and Capstone Projects

Mangrove ecosystems provide essential ecological services, including carbon sequestration, coastal protection, and heavy metal retention. However, their resilience and functionality are increasingly influenced by hurricanes, climate variability, and anthropogenic contamination. This dissertation integrates three research efforts examining mangrove canopy dynamics, carbon storage, and heavy metal contamination in two Puerto Rican mangrove systems: La Parguera and Laguna Grande.

Using remote sensing techniques (LiDAR and NDVI analysis), we assessed the impact of Hurricane Maria (Category 4, 2017) on mangrove canopy structure and vegetation health. Results revealed significant canopy height loss, with greater damage at Laguna Grande, where pre-storm canopy height and human …

Investigating Potential Sugar-Related Uncertainties In A Proxy For Ancient Co2, Liam Cooper

Student Theses and Dissertations

The ε_p proxy for ancient pCO₂ can potentially estimate ancient pCO₂ as from the evolution of rubisco-based photosynthesis, using the difference in stable carbon isotope ratios (δ¹³C) between fixed and inorganic carbon, assuming this difference is proportional to pCO₂. This study aims to address uncertainty with the use of photosynthetic microbes in proxies for ancient pCO₂. While previous studies address uncertainties related to the δ¹³C of initial fixed photosynthate (e.g., growth rate), we aim to address the effects of downstream carbon allocation. Specifically, if a significant fraction of fixed …

Diel Patterns Of Biogeochemical Indicators In Tidally-Dominated Creeks, Juliana Calderone

Honors Theses

Marshes and swashes are vital environments as a controlling barrier between land affected by various pollutants and the ocean. Eutrophication and the effects of this process can be detrimental for the areas experiencing it. I am interested in ways areas that have little contact with human interactions compare to areas that are heavily urbanized, and whether either of these locations is at a higher risk for eutrophication. Using spectrophotometry and fluorometry, I analyzed samples collected from the relatively undeveloped and restricted-access locations of Waities Island Beach and Dunn Sound monthly for dissolved nutrients, and chlorophyll. At the time of sampling, …

From Land To Lagoon: The Spatiotemporal Biogeochemical Dynamics Of Arctic Coastal Erosion In Elson Lagoon, Alaska, Sasha Victoria Peterson

Open Access Theses & Dissertations

TThe Arctic is warming rapidly, driving widespread environmental change across coastal landscapes, including permafrost thaw, shoreline erosion, and shifts in sediment and carbon dynamics, pose growing challenges for predicting carbon cycling and climate feedbacks. This dissertation investigates the spatiotemporal variability of erosion, decomposition, and nearshore turbidity in Elson Lagoon, Alaska (1955–2023), to better understand how carbon, nitrogen, and sediment are mobilized, transformed, and potentially emitted as greenhouse gases in Arctic coastal systems. Chapter 2 presents a high-resolution analysis of shoreline change and erosion-driven material fluxes spanning nearly seven decades. Drawing on 795 soil data points, airborne LiDAR, and five shoreline …

The Effect Of Hiv-1 Infection Associated Bacterial Lipopolysaccharide (Lps) On Human Oral Keratinocytes: Implications For Promoting Chronic Inflammation, Md Shafayat Jamil

Theses and Dissertations

Human immunodeficiency virus type 1 (HIV-1) remains a major global health concern, affecting approximately 39 million people worldwide, with 500,000 new infections reported in 2022. While combined antiretroviral therapy (cART) has significantly reduced viral replication, HIV-1 infection is linked to various comorbidities, including oral dysbiosis and accelerated aging. Immune dysregulation in HIV-1–infected individuals promotes the proliferation of pathogenic gram-negative bacteria like Porphyromonas gingivalis, a key contributor to periodontal disease. P. gingivalis secretes lipopolysaccharide (LPS), which adversely affects human oral keratinocytes (HOK), the first line of defense against microbial threats in the oral cavity. HOK recognize LPS as a threat, …

Spatio-Temporal Pattern Of Nutrient Dynamics In The South Texas Coastal Watershed, Mohammad Sadman Alam

Theses and Dissertations

Eutrophication threatens aquatic ecosystems by altering productivity through excessive nutrient inputs. In some systems, primary productivity is limited by nitrogen (N), phosphorus (P), or both, based on the N:P ratio defined by the "Redfield" ratio. South Texas, facing rapid urban growth and industrialization, is at risk of higher nutrient loads, but research on nutrient dynamics in this region is limited. This study investigates nutrient variations in the freshwater (FW) abandoned distributaries of the Rio Grande and hypersaline saltwater (SW) systems. Results showed a significant decrease in dissolved inorganic nitrogen (DIN) and an increase in dissolved inorganic phosphorus (DIP), shifting the …

08 - Blue Carbon Sequestration And Sediment Storage In Seagrass Meadows Of South Bay, Luke C. Clements, Adriana Amrhein, Richard P. Hale

Undergraduate Research Symposium

Blue carbon is stored in coastal and marine ecosystems like seagrass meadows and salt marshes, which helps combat climate change by preventing greenhouse gas emissions. This study examines the role of seagrass in carbon storage by comparing sediment cores from a mud channel and a seagrass meadow in South Bay.

We collected a 100 cm core from the mud channel and a 55 cm core from the seagrass area, taking samples every 10 cm to analyze grain size and organic carbon content. Using a wet sieving method, we separated sand from mud and measured organic carbon through loss on ignition. …

Meeting Carbon Dioxide Removal Demand In 2030: The Potential Of Macroalgae Cultivation And Harvest, Lotta Siebert, Jiajun Wu, Lena-Katharina Bednarz, David Keller, Felix Meier, Christine Merk, Sonja Peterson, Wilfried Rickels

Journal of Ocean and Coastal Economics

A growing number of countries have announced net-zero and net-negative emissions targets, but only a few countries provide incentives for carbon dioxide removal (CDR). We derive estimates of countries' hypothetical demand for CDR in 2030 based on their emissions reduction targets under the Paris Agreement. The aggregated average global demand for CDR in the compliance year 2030 is 1064 MtCO₂, 353 MtCO₂, and 124 MtCO₂ for the low, medium, and high-cost CDR scenarios, respectively. This demand comes exclusively from countries and regions with relatively high GDP per capita, relatively high abatement costs and a limited …

Tracing The Sources Of Nitrogen In Submarine Groundwater Discharge And Primary Producers In The Great South Bay Estuary, Nia H. Rene

Dissertations, Theses, and Capstone Projects

The primary aim of this research was to elucidate the impact of submarine groundwater discharge (SGD) and septic effluent on coastal primary producers in the Great South Bay (GSB). The study focused on three main objectives: assessing the impact of precipitation patterns on SGD, tracing nitrogen sources into the GSB, and determining the impact of these nitrogen sources on coastal primary producers. The research revealed that current precipitation patterns significantly influence SGD across different seasons, highlighting the seasonal variability in groundwater discharge and its implications for nutrient loading in coastal waters. A suite of tracers was employed to identify and …

Global Estimates Of The Storage And Transit Time Of Water Through Vegetation, Andrew Felton, Joshua B. Fisher, Koen Hufkens, Adam J. Purdy, Seth A. Spawn-Lee, Lou F. Duloisy, Gregory R. Goldsmith

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The time it takes for water to transit from the ground back to the atmosphere affects weather, climate, biogeochemistry and ecosystem function. The transit time of water through vegetation, defined as the age of water transpiring from vegetation since time of entry, is a particularly understudied aspect of the terrestrial hydrologic cycle. Here we use a synergy of satellite remote sensing measurements over a five-year period to estimate global aboveground vegetation water storage to be on average 484 km³, roughly half of which is stored in Earth’s water-limited savannah, grassland and shrubland ecosystems. We then combine these storage …

Unveiling Hidden Mercury And Methylmercury Sources: The Role Of Submarine Groundwater Discharge In Coastal Lagoons, Céline Lavergne, Júlia Rodriguez-Puig, Clara Ruiz-González, Maria Montero-Curiel, Gemma Casas, Daniel Romano-Gude, Irene Alorda-Montiel, Júlia Dordal-Soriano, Aaron Alorda-Kleinglass, Marc Diego-Feliu, Javier Gilabert, Alex Campillo-De La Maza, Cristina Romera-Castillo, Natalia Torres-Rodriguez, Lars-Eric Heimbürger-Boavida, Jordi Garcia-Orellana, Valenti Rodellas, Andrea G. Bravo

OES Faculty Publications

Mercury loads from Submarine Groundwater Discharge (SGD) may represent an overlooked source of methylmercury (MeHg) to the ocean, affecting human and ecosystem health. The SGD process involves the flow of fresh, saline, or mixed groundwater from coastal aquifers into the oceans classified in different components. Existing studies rarely report the fluxes supplied by the different SGD components; therefore, the relevance of SGD as a source of mercury remains unclear. We aimed to quantify SGD-driven mercury/methylmercury fluxes to the coast, focusing on the largest coastal lagoon in the western Mediterranean. We measured total dissolved mercury and MeHg in surficial and porewaters …

Organic Carbon Decay Mediated By A Mesopelagic Microbial Community: The Relevance Of Carbon Pools And Broad Biochemical Composition, Noah J. Craft, Alexander B. Bochdansky

OES Faculty Publications

The mesopelagic zone is a site of strong microbially driven particle attenuation with depth and thus plays a crucial role in controlling the transfer efficiency of the ocean's biological pump. However, little quantitative information exists on the dependency of decay processes on the source material. Here we followed the decay of ¹⁴C-labeled dead particulate organic carbon (POC) and dissolved organic carbon (DOC) from three different phytoplankton species, and two incubations of live diatoms, in mesopelagic water over 3 months. Commonly used first-order kinetics failed to adequately describe the decay of organic material as rate constants varied from day to day. …

The Δ¹³C Signature Of Dissolved Organic And Inorganic Carbon Reveals Complex Carbon Transformations Within A Salt Marsh, Meagan J. Eagle, Kevin D. Kroeger, John W. Pohlman, Joseph J. Tamborski, Zhaohui Aleck Wang, T. W. Brooks, Jennifer O. Keefe Suttles, Adrian Mann

OES Faculty Publications

Coastal wetlands have high rates of atmospheric CO₂ uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L^-¹), dissolved organic carbon …

Dust Deposition To The Sargasso Sea: A Comparison Of Estimates Using Aluminum In The Surface Ocean Versus Aerosols And Rainwater, T. E. Williams, P. N. Sedwick, B. M. Sohst, K. N. Buck, S. Caprara, R. J. Johnson, D. C. Ohnemus, J. A. Resing, L. E. Sofen, A. Tagliabue, B. S. Twining

OES Faculty Publications

As a major component of mineral aerosol that partially dissolves in seawater, aluminum (Al) has been used to estimate time-averaged dust fluxes to the ocean, based on dissolved aluminum (DAl) concentrations and an assumed replacement time of DAl (tau DAl) in the surface mixed layer, along with the fractional solubility (Als) and mass abundance of Al in dust. We apply this method in the Bermuda region using seasonal water-column DAl concentrations, and compare our results with fluxes estimated from Al measured in Bermuda aerosols and rain. Inventories of DAl over the maximum mixed-layer depth of 200 m and empirically derived …

Evidence Of Mineral Alteration In A Salt Marsh Subterranean Estuary: Implications For Carbon And Trace Element Cycling, J. J. Tamborski, M. J. Eagle, M. T. Thorpe, M. A. Charette, B. L. Kurylyk, S. Rahman, K. D. Kroeger, J. O'Keefe Suttles, A. G. Mann, T. W. Brooks, Z. A. Wang

OES Faculty Publications

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments …

Impacts Of Southern Pine Beetle (Dendroctonus Frontalis Zimmerman) On Loblolly Pine (Pinus Taeda L.) Canopy And Water Use In The Homochitto National Forest, Mississippi, Usa, Sasha Goodnow, Yun Yang, Hui Liu, Ashley Schulz

Endeavors: Mississippi State Undergraduate Research Journal

Abiotic and biotic forest disturbances can have many impacts to forest ecosystem services, including to forest water use. Studies on impacts to forest evapotranspiration have been conducted on the mountain pine beetle (Dendroctonus ponderosae) in western North America, but not on the southern pine beetle (Dendroctonus frontalis), which is a native pest of loblolly pine (Pinus taeda) and shortleaf pine (Pinus echinata), in the southeastern United States. Stressed pine trees produce pheromones that attract southern pine beetles and, with enough stressed trees, beetle populations can quickly grow to epidemic levels and attack healthy trees, which results in widespread tree mortality. …