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Articles 12001 - 12030 of 33352

Full-Text Articles in Chemistry

Synthesis, Optical Spectroscopy And Laser Potential Of Pyrylium Tosylates, Jung Jae Koh, Christina Inbok Lee, Mihaela Alexa Ciulei, Haesook Han, Pradip Kumar Bhowmik, Vladimir Kartazaev, Swapan Kumar Gayen Jun 2018

Synthesis, Optical Spectroscopy And Laser Potential Of Pyrylium Tosylates, Jung Jae Koh, Christina Inbok Lee, Mihaela Alexa Ciulei, Haesook Han, Pradip Kumar Bhowmik, Vladimir Kartazaev, Swapan Kumar Gayen

Chemistry and Biochemistry Faculty Research

Safe and inexpensive methods for synthesis of a series of four substituted 2,4,6-triphenylyrylium tosylate salts with different substituents are reported. The synthesis methods use p-toluenesulfonic acid monohydrate instead of conventional acid catalysts including perchloric acid or boron trifluoride diethyl etherate that pose explosion danger and difficult storage problems, respectively. The chemical structures of these salts were established using FTIR, 1H and 13C NMR spectroscopic techniques and elemental analysis. Thermogravimetric analysis (TGA) showed that these salts have good thermal stability, and differential scanning calorimetry (DSC) analysis showed that they have lower melting transitions than the corresponding tetrafluoroborate and perchlorate salts. Solutions …

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Microgel Core/Shell Architectures As Targeted Agents For Fibrinolysis, Purva Kodlekere, L. Andrew Lyon Jun 2018

Microgel Core/Shell Architectures As Targeted Agents For Fibrinolysis, Purva Kodlekere, L. Andrew Lyon

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

We demonstrate the utility of microgel core/shell structures conjugated to fibrin-specific peptides as fibrinolytic agents. Poly(N-isopropylmethacrylamide) (pNIPMAm) based microgels conjugated to the peptide GPRPFPAC (GPRP) were observed to bring about fibrin clot erosion, merely through exploitation of the dynamic nature of the clots. These results suggest the potential utility of peptide–microgel hybrids in clot disruption and clotting modulation.

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Development Of A Direct Aqueous Synthetic Route For The Production Of Elemental Bismuth Nanoparticles, Colin Jon Hiatt Jun 2018

Development Of A Direct Aqueous Synthetic Route For The Production Of Elemental Bismuth Nanoparticles, Colin Jon Hiatt

Dissertations and Theses

Bismuth nanoparticles (Bi NPs) for use as an X-ray contrast material have gained significant traction in recent years due to the high atomic number and generally accepted biological tolerance of bismuth. However, to be considered a viable candidate for use in this application, water solubility is a necessity, which poses a challenge, since bismuth tends to readily oxidize. For this reason, research into the direct aqueous synthesis of Bi NPs is still in its infancy and can be very difficult, as described in Chapter 1. The remaining chapters of the thesis describe the direct aqueous synthesis of Bi NPs starting …

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Visualization And Quantification Of Cancer-Associated Enzymes With Fluorescent Small-Molecule Substrate Probes, Zhenhua Shen Jun 2018

Visualization And Quantification Of Cancer-Associated Enzymes With Fluorescent Small-Molecule Substrate Probes, Zhenhua Shen

LSU Doctoral Dissertations

Fluorescence imaging can be used both as a tool to diagnose diseases and guide treatment in clinical settings, and as a technique to monitor dynamic events or biological species in basic research. Therefore, there is a great need for the development of a multitude of fluorescent probes that can be incorporated with fluorescence imaging techniques to track and report endogenous enzymes with high specificity and selectivity. In contrast to always-on and targeted always-on fluorescent probes that continually emit light, activity-based substrate probes either emit low numbers of photons or are completely quenched. They can be converted to highly fluorescent reporters …

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Improvement Method Of Analysis Motor Oil, M. Imomova, ., B Abduganiyev, O Tulanov Jun 2018

Improvement Method Of Analysis Motor Oil, M. Imomova, ., B Abduganiyev, O Tulanov

Scientific journal of the Fergana State University

Article is about method of analysis quantitative composition of motor oil, also result of analysis «Shell» Ultra and «Shell»Х-100 motor oil

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Influence Of Polymetalocomplexes Of Pectin On The Growth And Development Of Cotton Plant, M. Nurmatova,, S. Rashidova, Jun 2018

Influence Of Polymetalocomplexes Of Pectin On The Growth And Development Of Cotton Plant, M. Nurmatova,, S. Rashidova,

Scientific journal of the Fergana State University

Complexes based on lemon pectin with cobalt ions, which allow supplementing the lack of microelements in the cotton nutrition of "C-6524" variety, do not violate the basic vital functions of plants.

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1`- (P-Oxiphenyl) Ferrocene Carboxylate Synthesis, I. Askarov,, N. Tulakov, Jun 2018

1`- (P-Oxiphenyl) Ferrocene Carboxylate Synthesis, I. Askarov,, N. Tulakov,

Scientific journal of the Fergana State University

The article states aromatic derivatives and their significance, the synthesis of the new 1'- (p-hydroxyphenyl) ferrocenecarboxylic acid by the diazotization reaction of ferrocene p-aminophenol, as well as the study of its structure by IR spectroscopy.

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Influence Of Polymetalocomplexes Of Pectin On The Growth And Development Of Cotton Plant, M. Nurmatova,, S. Rashidova, Jun 2018

Influence Of Polymetalocomplexes Of Pectin On The Growth And Development Of Cotton Plant, M. Nurmatova,, S. Rashidova,

Scientific journal of the Fergana State University

Complexes based on lemon pectin with cobalt ions, which allow supplementing the lack of microelements in the cotton nutrition of "C-6524" variety, do not violate the basic vital functions of plants.

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1`- (P-Oxiphenyl) Ferrocene Carboxylate Synthesis, I. Askarov,, N. Tulakov, Jun 2018

1`- (P-Oxiphenyl) Ferrocene Carboxylate Synthesis, I. Askarov,, N. Tulakov,

Scientific journal of the Fergana State University

The article states aromatic derivatives and their significance, the synthesis of the new 1'- (p-hydroxyphenyl) ferrocenecarboxylic acid by the diazotization reaction of ferrocene p-aminophenol, as well as the study of its structure by IR spectroscopy.

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Improvement Method Of Analysis Motor Oil, M. Imomova, ., B Abduganiyev, O Tulanov Jun 2018

Improvement Method Of Analysis Motor Oil, M. Imomova, ., B Abduganiyev, O Tulanov

Scientific journal of the Fergana State University

Article is about method of analysis quantitative composition of motor oil, also result of analysis «Shell» Ultra and «Shell»Х-100 motor oil

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Influence Of Polymetalocomplexes Of Pectin On The Growth And Development Of Cotton Plant, M. Nurmatova,, S. Rashidova, Jun 2018

Influence Of Polymetalocomplexes Of Pectin On The Growth And Development Of Cotton Plant, M. Nurmatova,, S. Rashidova,

Scientific journal of the Fergana State University

Complexes based on lemon pectin with cobalt ions, which allow supplementing the lack of microelements in the cotton nutrition of "C-6524" variety, do not violate the basic vital functions of plants.

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Improvement Method Of Analysis Motor Oil, M. Imomova, ., B Abduganiyev, O Tulanov Jun 2018

Improvement Method Of Analysis Motor Oil, M. Imomova, ., B Abduganiyev, O Tulanov

Scientific journal of the Fergana State University

Article is about method of analysis quantitative composition of motor oil, also result of analysis «Shell» Ultra and «Shell»Х-100 motor oil

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1`- (P-Oxiphenyl) Ferrocene Carboxylate Synthesis, I. Askarov,, N. Tulakov, Jun 2018

1`- (P-Oxiphenyl) Ferrocene Carboxylate Synthesis, I. Askarov,, N. Tulakov,

Scientific journal of the Fergana State University

The article states aromatic derivatives and their significance, the synthesis of the new 1'- (p-hydroxyphenyl) ferrocenecarboxylic acid by the diazotization reaction of ferrocene p-aminophenol, as well as the study of its structure by IR spectroscopy.

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Investigation Of Structure And Dynamics Of Deep Eutectic Solvent Using Infrared Spectroscopy, Yaowen Cui Jun 2018

Investigation Of Structure And Dynamics Of Deep Eutectic Solvent Using Infrared Spectroscopy, Yaowen Cui

LSU Doctoral Dissertations

Deep Eutectic Solvents (DES) are liquid mixtures prepared from solids. As a new class of green solvents, DES not only share many properties with ionic liquids, such as low volatility, conductivity, tailorable constituents, but also have some advantages over ionic liquids, like easier preparation, safe and inexpensive materials, biodegradability, low toxicity, and excellent solubility. Because of those attractive properties, DES has been studied in many scientific and engineering fields. However, compared with the great number of studies of the application, many questions about structure and dynamics of DES are unanswered. To shed light on the mystery of solvent or solvation …

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Flexible To Rigid Nanoporous Polyurethane-Acrylate (Puac) Type Materials For Structural And Thermal Insulation Applications, Nicholas Leventis, Chariklia Sotiriou-Leventis, Abhishek Bang Jun 2018

Flexible To Rigid Nanoporous Polyurethane-Acrylate (Puac) Type Materials For Structural And Thermal Insulation Applications, Nicholas Leventis, Chariklia Sotiriou-Leventis, Abhishek Bang

Chemistry Faculty Research & Creative Works

Novel urethane-acrylate (UAC) Star monomers and polyurethane-acrylate (PUAC) aerogel polymers derived therefrom are described herein, along with other novel, related monomers and polymers. Also described herein are processes for preparing the UAC Star monomers, the PUAC aerogel polymers, and the other related monomers and polymers. The PUAC and related polymers herein are useful in various applications including in structural and thermal insulation.

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N-Glycosylation In The Protease Domain Of Trypsin-Like Serine Proteases Mediates Calnexin-Assisted Protein Folding, Hao Wang, Shuo Li, Juejin Wang, Shenghan Chen, Xue-Long Sun, Qingyu Wu Jun 2018

N-Glycosylation In The Protease Domain Of Trypsin-Like Serine Proteases Mediates Calnexin-Assisted Protein Folding, Hao Wang, Shuo Li, Juejin Wang, Shenghan Chen, Xue-Long Sun, Qingyu Wu

Chemistry Faculty Publications

Trypsin-like serine proteases are essential in physiological processes. Studies have shown that N-glycans are important for serine protease expression and secretion, but the underlying mechanisms are poorly understood. Here, we report a common mechanism of N-glycosylation in the protease domains of corin, enteropeptidase and prothrombin in calnexin-mediated glycoprotein folding and extracellular expression. This mechanism, which is independent of calreticulin and operates in a domain-autonomous manner, involves two steps: direct calnexin binding to target proteins and subsequent calnexin binding to monoglucosylated N-glycans. Elimination of N-glycosylation sites in the protease domains of corin, enteropeptidase and prothrombin inhibits corin and enteropeptidase cell surface …

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Sulfonamide Synthesis Via Calcium Triflimide Activation Of Sulfonyl Fluorides, Nicholas Ball, Paramita Mukherjee, Cristian P. Woroch, Leah Cleary, Mark Rusznak, Ryan W. Franzese, Matthew R. Reese, Joseph W. Tucker, John M. Humphrey, Sarah M. Etuk, Sabrina C. Kwan, Christopher W. Am Ende Jun 2018

Sulfonamide Synthesis Via Calcium Triflimide Activation Of Sulfonyl Fluorides, Nicholas Ball, Paramita Mukherjee, Cristian P. Woroch, Leah Cleary, Mark Rusznak, Ryan W. Franzese, Matthew R. Reese, Joseph W. Tucker, John M. Humphrey, Sarah M. Etuk, Sabrina C. Kwan, Christopher W. Am Ende

Pomona Faculty Publications and Research

A method using calcium triflimide [Ca(NTf2)2] as a Lewis acid to activate sulfonyl fluorides toward nucleophilic addition with amines is described. The reaction converts a wide array of sterically and electronically diverse sulfonyl fluorides and amines into the corresponding sulfonamides in good yield.

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Heavy Metal Accumulation In Seagrasses In Southeastern Florida, Erin Smith Jun 2018

Heavy Metal Accumulation In Seagrasses In Southeastern Florida, Erin Smith

HCNSO Student Theses and Dissertations

Seagrass beds are among the most ecologically important systems in the marine environment. They provide the primary production to nearby coral reef and mangrove communities, and seagrasses comprise a large component of the diets of many marine organisms including fishes, small invertebrate species, and many protected species such as manatees and sea turtles. This consumption provides a pathway for many contaminants to enter the marine food web via the seagrasses. The coastal location of seagrass beds causes them to be especially susceptible to anthropogenic pollution, including accumulation of heavy metals, which has been shown to have many adverse health effects …

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Comparison Between Tetrel Bonded Complexes Stabilized By Σ And Π Hole Interactions, Wiktor Zierkiewicz, Mariusz Michalczyk, Steve Scheiner Jun 2018

Comparison Between Tetrel Bonded Complexes Stabilized By Σ And Π Hole Interactions, Wiktor Zierkiewicz, Mariusz Michalczyk, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The σ-hole tetrel bonds formed by a tetravalent molecule are compared with those involving a π-hole above the tetrel atom in a trivalent bonding situation. The former are modeled by TH4, TH3F, and TH2F2 (T = Si, Ge, Sn) and the latter by TH2=CH2, THF=CH2, and TF2=CH2, all paired with NH3 as Lewis base. The latter π-bonded complexes are considerably more strongly bound, despite the near equivalence of the σ and π-hole intensities. The larger binding energies of the π-dimers are attributed to greater electrostatic attraction and orbital interaction. Each progressive replacement of H by F increases the strength of …

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Oxidation Of N-Doped Multiwalled Carbon Nanotubes And Formation Of Discontinuous Spiraled Carbon Nanoribbons, Aman Preet Kaur, Mark S. Meier, Rodney Andrews, Dali Qian Jun 2018

Oxidation Of N-Doped Multiwalled Carbon Nanotubes And Formation Of Discontinuous Spiraled Carbon Nanoribbons, Aman Preet Kaur, Mark S. Meier, Rodney Andrews, Dali Qian

Chemistry Faculty Publications

The effects of five commonly used wet chemical oxidations were studied for the extent of oxidation of graphitized nitrogen-doped multiwalled carbon nanotubes (N-MWCNTs). KMnO4/ H2SO4 was the most potent oxidant, as it produced the highest fraction of oxygen-containing functional groups. Electron microscopy studies showed that the treatment of annealed N-MWCNTs (G-N-MWCNTs) with H2SO4/HNO3 and H2SO4/KMnO4 mixtures leads to interesting spiraled ribbon textures. A structural model, involving the stacking of coiled subunits to form a discontinuous carbon nanoribbon rather than a continuous ribbon is proposed to …

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Some Chemical, Physical And Physical And Chemical Properties Of High-Mountain Soils Of The Turkestan Ridge, M Tashkuziev Jun 2018

Some Chemical, Physical And Physical And Chemical Properties Of High-Mountain Soils Of The Turkestan Ridge, M Tashkuziev

Karakalpak Scientific Journal

In the article on the basis of obtained results is revealed the relationship between humus content and composition of carbonates, the mechanical composition, the exchange capacity, and the composition of the absorbed bases.

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Some Chemical, Physical And Physical And Chemical Properties Of High-Mountain Soils Of The Turkestan Ridge, M Tashkuziev Jun 2018

Some Chemical, Physical And Physical And Chemical Properties Of High-Mountain Soils Of The Turkestan Ridge, M Tashkuziev

Karakalpak Scientific Journal

In the article on the basis of obtained results is revealed the relationship between humus content and composition of carbonates, the mechanical composition, the exchange capacity, and the composition of the absorbed bases.

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Effects Of Dispersion Corrections And Nonlocality On Density Functional Predictions Of Pressure-Induced Polymorphic Transitions Of Crystalline Diborane, Angela M. Murcia Rios, Darya N. Komsa, Viktor N. Staroverov Jun 2018

Effects Of Dispersion Corrections And Nonlocality On Density Functional Predictions Of Pressure-Induced Polymorphic Transitions Of Crystalline Diborane, Angela M. Murcia Rios, Darya N. Komsa, Viktor N. Staroverov

Chemistry Publications

The role of dispersion interactions in density functional calculations of the relative enthalpies of compressed BH3 polymorphs was investigated using plane-wave and Gaussian basis set codes. Addition of semiempirical atom-pairwise dispersion corrections to generalized gradient approximations (GGAs) was found to have little effect on the relative enthalpies of various boron hydride structures. By contrast, the stability ranking obtained with the nonlocal van der Waals density functional (vdW-DF) of Dion and co-workers was substantially more realistic than the rankings predicted by plain and dispersion-corrected GGAs. Of the functionals tested, only vdW-DF correctly predicts that compressed diborane does not leave the B2H6 …

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Formazanate Complexes Of Hypervalent Group‐14 Elements As Precursors To Electronically Stabilized Radicals, Ryan R. Maar, Sara D. Catingan, Viktor N. Staroverov, Joe Gilroy Jun 2018

Formazanate Complexes Of Hypervalent Group‐14 Elements As Precursors To Electronically Stabilized Radicals, Ryan R. Maar, Sara D. Catingan, Viktor N. Staroverov, Joe Gilroy

Chemistry Publications

The stability of molecular radicals containing main‐group elements usually hinges on the presence of bulky substituents that shield the reactive radical center. We describe a family of group‐14 formazanate complexes whose chemical reduction allows access to radicals that are stabilized instead by geometric and electron‐delocalization effects, specifically by the square‐pyramidal geometry adopted by the group‐14 atom (Si, Ge, Sn) within the framework of the heteroatom‐rich formazanate ligands. The reduction potentials of the Si, Ge, and Sn complexes as determined by cyclic voltammetry become more negative in that order. Examination of the solid‐state structures of these complexes suggested that their electron‐accepting …

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A Study Of Fragmentation And Spontaneous Covalent Self-Assembly Of The Azaorcus Ribozyme From Multiple Small Inactive Rna Fragments, Tharuka Sewwandi Jayathilaka Jun 2018

A Study Of Fragmentation And Spontaneous Covalent Self-Assembly Of The Azaorcus Ribozyme From Multiple Small Inactive Rna Fragments, Tharuka Sewwandi Jayathilaka

Dissertations and Theses

The question about the origins of life often appears as a difficult question to answer. A more reliable candidate molecule for the chemical origins of life would be a molecule that is capable of making copies of itself from simple precursors. With the finding of the catalytic activities of RNA molecules by Thomas Cech and Sid Altman in late 1980s, the term ribozyme was introduced to define an RNA molecule with catalytic activity. The RNA World is a conceptual period in the early stages in the development of life because RNA simultaneously possesses evolvability and catalytic function. An RNA molecule …

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A Multi-Size Study Of Gold Nanoparticle Degradation And Reformation In Ceramic Glazes, Nathan Nl. Dinh, Luke T. Dipasquale, Michael C. Leopold, Ryan H. Coppage Jun 2018

A Multi-Size Study Of Gold Nanoparticle Degradation And Reformation In Ceramic Glazes, Nathan Nl. Dinh, Luke T. Dipasquale, Michael C. Leopold, Ryan H. Coppage

Chemistry Faculty Publications

Most traditional ceramic glazes employ high amounts of transition metal colorants that are toxic to the environment and can cause health issues in humans through surface leaching. Gold nanoparticles (Au-NPs) have been found to be environmentally friendly and non-toxic alternative metal colorant in ceramic glazes. The plasmon band observed with Au-NPs can result in vibrant solutions by manipulating NP size, shape, and concentration; however, the effects of traditional firing in both reductive and oxidative kilns on Au-NPs are poorly understood. Aside from ancient art processes whose mechanisms have not been fully explored, the use of Au-NPs as suspended ceramic glaze …

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Deciphering The Mechanism Of O2 Reduction With Electronically Tunable Non-Heme Iron Enzyme Model Complexes, Roshaan Surendhran, Alexander A. D'Arpino, Bao Y. Sciscent, Anthony F. Cannella, Alan E. Friedman, Samantha N. Macmillan, Rupal Gupta, David C. Lacy Jun 2018

Deciphering The Mechanism Of O2 Reduction With Electronically Tunable Non-Heme Iron Enzyme Model Complexes, Roshaan Surendhran, Alexander A. D'Arpino, Bao Y. Sciscent, Anthony F. Cannella, Alan E. Friedman, Samantha N. Macmillan, Rupal Gupta, David C. Lacy

Publications and Research

A homologous series of electronically tuned 2,20,200-nitrilotris(N-arylacetamide) pre-ligands (H3LR) were prepared (R ¼ NO2, CN, CF3, F, Cl, Br, Et, Me, H, OMe, NMe2) and some of their corresponding Fe and Zn species synthesized. The iron complexes react rapidly with O2, the final products of which are diferric mu-oxo bridged species. The crystal structure of the oxidized product obtained from DMA solutions contain a structural motif found in some diiron proteins. The mechanism of iron mediated O2 reduction was explored to the extent that allowed us to construct an empirically consistent rate law. A Hammett plot was constructed that enabled …

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Microwave Popped Co(Ii)-Graphene Oxide Hybrid: Bifunctional Catalyst For Hydrogen Evolution Reaction And Hydrogen Storage, Lin Wei, Karen Lozano, Yuanbing Mao Jun 2018

Microwave Popped Co(Ii)-Graphene Oxide Hybrid: Bifunctional Catalyst For Hydrogen Evolution Reaction And Hydrogen Storage, Lin Wei, Karen Lozano, Yuanbing Mao

School of Integrative Biological & Chemical Sciences (Formerly Dept. of Chemistry)

In an effort to develop a multifunctional catalyst for hydrogen generation and adsorption applications, a facile and cost-effective microwave popping method was used to synthesize popped graphene oxide (PGO) and Co-PGO hybrid. Both samples have been explored and compared as hydrogen storage materials and as electrocatalysts for hydrogen evolution reaction (HER) for the first time. The loading of Co(II) species on the surface of the PGO enhanced the hydrogen storage capability of PGO from 0.04wt% to 0.08wt% as measured at 293K and 800 mmHg. Co-PGO is also acting as a better electrocatalyst for HER compared to the PGO counterpart.

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Synthesis And Characterization Of (Pyno−)2gacl: A Redox-Active Gallium Complex, Jacob M. Kirsh , '17, Audra J. Woodside , '19, B. C. Manor, P. J. Carroll, Paul R. Rablen, Christopher R. Graves Jun 2018

Synthesis And Characterization Of (Pyno−)2gacl: A Redox-Active Gallium Complex, Jacob M. Kirsh , '17, Audra J. Woodside , '19, B. C. Manor, P. J. Carroll, Paul R. Rablen, Christopher R. Graves

Chemistry & Biochemistry Faculty Works

We report the synthesis of a gallium complex incorporating redox-active pyridyl nitroxide ligands. The (pyNO−)2GaCl complex was prepared in 85% yield via a salt metathesis route and was characterized by 1H and 13C NMR spectroscopies, X-ray diffraction, and theory. UV–Vis absorption spectroscopy and electrochemistry were used to access the optical and electrochemical properties of the complex, respectively. Our discussion focuses primarily on a comparison of the gallium complex to the corresponding aluminum derivative and shows that although the complexes are very similar, small differences in the electronic structure of the complexes can be correlated to the identity of the metal.

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Quadruplexes In ‘Dicty’: Crystal Structure Of A Four-Quartet G-Quadruplex Formed By G-Rich Motif Found In The Dictyostelium Discoideum Genome, A. Guédin, Linda Yingqi Lin , '20, S. Armane, L. Lacroix, J.-L. Mergny, S. Thore, Liliya A. Yatsunyk Jun 2018

Quadruplexes In ‘Dicty’: Crystal Structure Of A Four-Quartet G-Quadruplex Formed By G-Rich Motif Found In The Dictyostelium Discoideum Genome, A. Guédin, Linda Yingqi Lin , '20, S. Armane, L. Lacroix, J.-L. Mergny, S. Thore, Liliya A. Yatsunyk

Chemistry & Biochemistry Faculty Works

Guanine-rich DNA has the potential to fold into non-canonical G-quadruplex (G4) structures. Analysis of the genome of the social amoeba Dictyostelium discoideum indicates a low number of sequences with G4-forming potential (249–1055). Therefore, D. discoideum is a perfect model organism to investigate the relationship between the presence of G4s and their biological functions. As a first step in this investigation, we crystallized the dGGGGGAGGGGTACAGGGGTACAGGGG sequence from the putative promoter region of two divergent genes in D. discoideum. According to the crystal structure, this sequence folds into a four-quartet intramolecular antiparallel G4 with two lateral and one diagonal loops. The G-quadruplex …

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