Engineering Commons^™

Process-Property-Microstructure Relationships In Laser-Powder Bed Fusion Of 420 Stainless Steel., Subrata Deb Nath

Electronic Theses and Dissertations

Laser-powder bed fusion (L-PBF) is an additive manufacturing technique for fabricating metal components with complex design and customized features. However, only a limited number of materials have been widely studied using L-PBF. AISI 420 stainless steel, an alloy with a useful combination of high strength, hardness, and corrosion resistance, is an example of one such material where few L-PBF investigations have emerged to date. In this dissertation, L-PBF experiments were conducted using 420 stainless steel powders to understand the effects of chemical composition, particle size distribution and processing parameters on ensuing physical, mechanical and corrosion properties and microstructure in comparison …

Self-Healing Microcapsules As Concrete Aggregates For Corrosion Inhibition In Reinforced Concrete, Homero Castaneda, Marwa Hassan, Miladin Radovic, Jose Milla

Publications

Reinforced Concrete (RC) structures are vital to the US’s civil infrastructure for their strength and versatility. Unfortunately, RC elements deteriorate rapidly when exposed to corrosive environments. One possible solution is to extend the life of RC elements and systems using microencapsulated corrosion inhibitors to reduce the rebar corrosion rate. The capsules house an anodic corrosion inhibitor agent including calcium nitrate (CN) and triethanolamine (TEA). The integration of such microencapsulated materials will enhance the durability and extend the useful life by controlling the corrosion precursors and the corrosion process during damage evolution. Therefore, this work aims to develop and characterize the …

Sustainability-Based Long-Term Management Of Bridges Under Multi-Hazard Exposure, Mohamed Soliman

Publications

Bridges are under deterioration due to various mechanical and environmental stressors. Hydraulic-related hazards (e.g., flood and scour), aggressive environmental conditions, and seismic events (e.g., earthquake) are recognized as the most significant threats to the safety of bridges. In traditional risk assessment methods for structures susceptible to damage due to floods and other natural hazards (e.g., corrosion and seismic events), future hazard predictions are conducted using historic return periods and climate records. However, recent increase in flood intensity in central-southern states indicate that future hazard occurrence rate may not necessarily follow past trends. Accordingly, current design, assessment, and management methodologies should …

Cysteine As An Eco-Friendly Corrosion Inhibitor, Hany A. Elazab Dr

Chemical Engineering

In this paper, the aim was finding the most efficient corrosion inhibitor for mild steel placed in a 0.5M Sulfuric acid. The comparison was implemented between Cysteine (an eco-friendly corrosion inhibitor) and 4 different Ions-Cysteine Inhibitors (Copper- Cysteine, Nickel-Cysteine, Iron-Cysteine, and Cobalt-Cysteine). The solutions were prepared and evaluated while placed with a working electrode of mild steel with a copper rod attached to its end. To determine the best eco-friendly corrosion inhibitors two experiments were implemented: Electrochemical Impedance Spectra, and Linear Polarization. By the end of the experiment it was found that Copper- Cysteine was the most efficient eco-friendly corrosion …

Localized Strain And Associated Failure Of Structural Materials, Hayden N. Hermes, Andrea Nicolas, Michael Sangid, Noelle C. Easter, James T. Burns

The Summer Undergraduate Research Fellowship (SURF) Symposium

Aircraft are made primarily out of strong and lightweight aluminum alloys, which are relatively low cost, easy to produce, and have allowed for several innovations in the airplane industry. Even though these alloys are highly corrosion resistant, they are susceptible to failure since airplanes experience some of the harshest fatigue and corrosion conditions. Predicting the location of crack initiation on these corroded materials could lead to preventative safety of aluminum components on an aircraft. To study the mechanisms leading to cracking, precorroded AA7050 samples were fatigue loaded to failure, virtually reconstructed form post-mortem characterizations, and modeled accordingly to obtain the …

Vertical Electrical Impedance Measurements On Concrete Bridge Decks Using A Large-Area Electrode, Jeffrey David Barton

Theses and Dissertations

In regions where chloride-based deicing salts are applied to bridge decks, corrosion of the interior steel reinforcement is a major problem. Vertical electrical impedance (VEI) is an effective measurement technique to quantitatively assess the cover protection on bridges against aggressive chemical penetration of reinforced concrete. In its current form, traditional vertical electrical impedance is time-consuming and destructive because a direct connection to the reinforcing steel is required to provide a ground reference. A new method using a large-area electrode (LAE) permits VEI measurement without a direct electrical connection to the steel reinforcement. The LAE creates a nondestructive, semi-direct, low impedance …

Material-Process-Property Relationships Of 17-4 Stainless Steel Fabricated By Laser-Powder Bed Fusion Followed By Hot Isostatic Pressing., Harish Irrinki

Electronic Theses and Dissertations

17-4 PH stainless steel is commonly used in medical, tooling, automotive, chemical and aerospace industries due to its excellent strength and corrosion properties. Additive manufacturing processes such as laser-powder bed fusion (L-PBF) have gained attention and importance due to the potential to produce complex-shaped three-dimensional parts for various industries. In order to manufacture three-dimensional components from 17-4 PH stainless steel powder using L-PBF, it is critical for design and manufacturing engineers to have an awareness of various material options and corresponding processing and post-processing conditions to obtain useful mechanical properties from the process. The goal of this dissertation is to …

Fundamental Investigation Of Magnesium Corrosion Using Experiments And Simulation, Dila Ram Banjade

Theses and Dissertations

Magnesium (Mg) is the lightest of all structural metals and has tremendous potential for applications in the lightweight industry. However, the corrosion of Mg is a significant barrier towards its wider use. Despite years of research, the fundamental understanding of Mg corrosion still remains short. The enhanced hydrogen evolution reaction (HER) with anodic polarization, the modeling of galvanic corrosion and the impact of hydrogen bubbles for galvanically coupled Mg are important aspects of Mg corrosion that need to be understood before any mitigation measures can be taken. The results presented in this work provide a key step in that direction. …

Numerical Study Of Oxidation In Stainless Steel Alloy Ep-823 By Liquid Lead-Bismuth Eutectic, Rajyalakshmi Palaparty

UNLV Theses, Dissertations, Professional Papers, and Capstones

The oxidation of stainless steel is influenced by the presence of oxygen in the surrounding medium; the oxygen reacts with the alloy to form an oxide. In certain environments, such as nuclear reactor coolant systems, minimal oxidation of the stainless steel containment functions as a protective shield from corrosive coolants such as liquid lead-bismuth eutectic.

In the current study, this minimal oxidation is evaluated for a system in which corrosion-resistant stainless steel alloy EP-823 is subject to an environment of flowing oxygenated liquid lead-bismuth eutectic at a temperature of 743 K, whereby the thickness of the forming oxide layer is …

Determination Of Chemical Notch, KChem On Aluminum And Steel When Subjected Under Slow Strain Rate Test In Corrosive Environment, Joshua Teo Lee Kuok

Masters Theses

When designing for any mechanical components or system, the question would arise as to how the material would react to the loads subjected on it? Would the component survive its service load? How would it react to environmental corrosion? To answer these questions, the technique used in this thesis paper is the Slow Strain Rate Test (SSRT) method. Aluminum and steel were chosen as the material to be tested in this paper. Al 7075-T651, and Al 6061-T651 was chosen due to its wide range of application, high strength to weight ratio and ease of machinability. It is highly used in …

Corrosion Behavior Of Plasma Nitrided And Nitrocarburised Supermartensitic Stainless Steel, Frederico Augusto Pires Fernandes, Carlos Alberto Picone, George Totten, Luiz Carlos Casteletti

Mechanical and Materials Engineering Faculty Publications and Presentations

Supermartensitic stainles steels (SMSS's) are a new generation of martensitic steels that have been increasingly used in oil and gas applications due to their adequate corrosion resistance and mechanical properties. In the present study, SMSS specimens (UNS S41425) were solution heat treated and air cooled followed by plasma nitriding and nitrocarburising at 400, 450 and 500°C for 5h. The produced layers were characterized by optical microscopy, microhardness testing, X-ray diffraction and corrosion testing in NaCl 3.5% solution. Surface alloying with nitrogen or both nitrogen and carbon results in increased surface hardness and homogeneous layers in which layer thickness increases with …

Toward A Production Ready Fbj Process For Joining Dissimilar Combinations Of Gadp 1180 Steel And Aa 7085-T76, Kevin Alexander Shirley

Theses and Dissertations

Friction Bit Joining (FBJ) is a new technology that can be used to join dissimilar materials together. This ability makes it a good candidate for creating light weight structures for the automotive industry by combining lightweight materials such as aluminum to stronger materials like advanced high-strength steels. The automotive industry and many other industries have great interest in reducing structure weight to increase fuel efficiency. The purpose of this research is to make FBJ of GADP 1180 to AA 7085-T76 a production ready process by (1) better understanding the effects of process parameters, bit design and tool design on joint …

Spatial Delineation Of Corrosion Zones For Metal Culverts Based On Coastal Louisiana Soil Characteristics, Sanjay Tewari, Francis Manning

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Corrosion of metal pipes used as culverts is a problem that affect many agencies directly involved in designing and maintaining these culverts. The corrosive environment of soil types found in a region could vary in a significant way (mildly corrosive to extremely corrosive) based on soil characteristics. Environmental conditions such as high water table, acidity and presence of various salts could make a soil corrosive to metal pipes. In this article, authors have applied a methodology of processing readily available soil data such as spatial distribution of soil types and soil characteristics (e.g. pH and conductivity) in delineating spatial corrosion …

Assessing Corrosivity Of Galvanized Soil Reinforcements From Electrochemical Tests, Diana Alejandra Cabrera

Open Access Theses & Dissertations

The accurate estimation of the service lives of mechanically stabilized earth (MSE) walls requires a proper evaluation of the corrosion potential through electrochemical test methods. Robust field tests are required to assess the corrosivity of galvanized metal used in MSE walls. To simulate an environment similar to an MSE wall, cylindrical soil specimens about 12 in. (300 mm) in diameter and 10 in. (250 mm) in height were constructed. For every specimen, two instruments were used. The first instrument measured the polarization resistance corrosion tests carried out on galvanized strips and meshes, as well as epoxy-coated rebars. The second instrument …

Detection Of Buried Non-Metallic (Plastic And Frp Composite) Pipes Using Gpr And Irt, Jonas Kavi

Graduate Theses, Dissertations, and Problem Reports (ETD)

This research investigated alternative strategies for making buried non-metallic pipes (CFRP, GFRP, and PVC) easily locatable using Ground Penetrating Radar (GPR). Pipe diameters up to 12" and buried with up to 4 ft. of soil cover were investigated. The findings of this study will help address the detection problem of non-metallic pipelines and speed the adoption of composite pipes by the petroleum and natural gas industry. The research also investigated the possibility of locating buried pipes transporting hot fluids using Infrared Thermography (IRT).

Results from the study have shown that, using carbon fabric and aluminum tape overlay on non‑metallic pipes …

Corrosion Performance Of Zirconium-Based Passivations On Electroplated Zinc Nickel, Madison Morgan Reed

Masters Theses

“Performance requirements for Department of Defense (DoD) electrical components include corrosion and electrical contact resistance. Historically, electroplated cadmium with a chromate conversion coating (CrCC) has been used to meet corrosion and contact resistance standards. However, replacements are needed for these materials because they are toxic and carcinogenic. Electroplated γ-ZnNi has been identified as an acceptable alternative to Cd. This study evaluated commercially available Zr-based thin films and sealers as passivations for potential replacement of CrCCs. Ten different passivations were tested and compared with bare γ-ZnNi. X-Bond and Zircobond passivations were found to provide some improvement to the bare ZnNi corrosion …

Evaluation Of Orthophosphate Based Corrosion Inhibitors In Treated Water For El Paso Region, Francisco Solis Jr

Open Access Theses & Dissertations

Corrosion is an electrochemical phenomenon that involves the deterioration of a metal by the reaction of itself with its surrounding environment. One of the greatest issues for water utilities around the country is to keep the water quality safe. Corrosion can affect the quality of the water that we use on a daily basis by adding a bad taste, increasing the concentration of heavy metals, and allowing outside contaminants to enter the distribution system. The use of phosphate based corrosion inhibitors was tested in two different metals: iron and copper. The phosphate in the inhibitors react with the calcium in …

Evaluation Of Silane-Doped Epoxy Coatings For Resisting Aluminum Corrosion By Oxalic Acid, An A. Niger Metabolite, Alex Pica

Williams Honors College, Honors Research Projects

The goal of this study was to investigate whether silane-doped epoxy coatings are capable of preventing corrosion of aluminum alloy 2024-T3 by oxalic acid, one of the primary metabolites of the fungus Aspergillus Niger. Previous research suggested the success of these types of coatings at preventing AA 2024-T3 corrosion in saline solutions, and this study was meant to build on those findings by investigating the efficacy of the coating in an acidic environment.

Each coating was applied to an AA 2024-T3 coupon by dissolving the epoxy and varying amounts of 3-aminopropyltriethoxysilane in acetone and then dripping the solution onto …

The Influence Of Organic Pigments On Coating Properties, Sarah Medeiros

Williams Honors College, Honors Research Projects

Abstract

The purpose of this project was to identify the qualities of two synthesized organic pigments added to a coating. These high-performance pigments were benzodipyrrolidone and benzodifuranone, which are π-conjugated monomers. These pigments were each formulated into two different pigment concentrations and compared with a control that had no pigment. This project is limited by time constraints and the number of variables that can be tested in that time. Performance testing was conducted to evaluate the qualities of these coatings. The results demonstrated that the coatings were reproducible and most tests had results that were equal to or exceeded the …

Introduction To H2020 Project C3harme: Next Generation Ceramic Composites For Combustion Harsh Environments And Space, Diletta Sciti, Laura Silvestroni, Luca Zoli, Antonio Vinci, Frederic Monteverde

Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications IV

Materials for aeronautical and space applications largely involve ceramic matrix composites, CMCs, made of carbon or silicon carbide. However, C/C composites suffer from poor erosion resistance while silicon-based ceramics, SiC/SiC or C/SiC composites, may undergo strong ablation due to the formation and volatilization of silica. In recent years, Ultra-High Temperature Ceramics, UHTCs, have shown outstanding erosion resistance at temperatures up to 2000°C or even higher but they still cannot resist to thermal shocks and damage. Therefore, there is an increasing demand for advanced materials with temperature capability in highly corrosive environments to enable space vehicles to resist several launches and …

Identifying Corrosion Zones In Coastal Regions For Metal Pipes -- A Gis Approach, Sanjay Tewari, Francis Manning

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Transportation agencies often allow metal pipes as an option for cross drains under/along roads and highways. Metal culverts can corrode over time at various rates based on their environmental conditions (e.g., corrosive nature of coastal soils, high water table and saltwater intrusion). This paper focuses on applying readily available soil data such as spatial distribution of soil types and soil characteristics (e.g., pH and conductivity) towards creating a geospatial information system (GIS) based approach to identifying corrosion zones in the coastal regions. A combination of data, obtained from field surveys provided by the Louisiana Transportation Research Center and Web Soil …

Design, Material And Surgical Assembly Effects On Fretting Corrosion Behavior Of Modular Tapers In Orthopedic Implants, David Pierre

Dissertations - ALL

Mechanically assisted crevice corrosion (MACC) has become a significant problem in the orthopedic device industry, particularly in modular devices with metal-on-metal (MoM) tapered interfaces. Oxide film abrasion, leading to fretting corrosion in the presence of a crevice, accelerates the corrosion process and in some instances may lead to failure of the implant. Failure is defined as the need for revision surgery. The basic processes of oxide film abrasion and repassivation, and the associated effects (chemical, transport, mechanical and electrical) of these processes have been well described and studied over time.

Despite these advancements, there is much that is still not …

The Effects Of Simulated Inflammatory Conditions On The Corrosion And Fretting Corrosion Of Cocrmo Alloy, Yangping Liu

Dissertations - ALL

In vivo corrosion of CoCrMo alloy and its potential adverse effects on the body have been recognized as major concerns in recent years. While the underlying concepts of general and mechanically-assisted corrosion have been well documented, recent report of inflammatory cell-induced corrosion (ICIC) of CoCrMo alloy challenged traditional understanding of the relationship between biology and corrosion of hip implants. To better understand the role biology may play in the corrosion of CoCrMo-based implants, this study explored the mechanism of ICIC on CoCrMo alloy and investigated how simulated inflammatory (SI) conditions affected the electrochemistry, oxide film and fretting corrosion behavior of …

Comparison Of Intrusive And Non-Intrusive Methods For Corrosion Monitoring Of Fuel Processing Systems, Armando Jacob Espinoza, Thomas Conner Field

Materials Engineering

This presentation contains an assessment of the best overall corrosion monitoring device, intrusive or non-intrusive, for use in the petrochemical industry. Corrosion in the petrochemical industry is a large issue because it causes a deterioration of pipe integrity in fuel processing systems. A reduction of pipe wall integrity due to corrosion could result in a leak or an explosion of fuel processing lines since those systems function at high pressures. The use of corrosion monitoring systems in the petrochemical industry helps to detect early signs of corrosion prior to failure so that proper maintenance can be performed to prevent catastrophe. …

Corrosion Map For Metal Pipes In Coastal Louisiana, Sanjay Tewari

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Transportation agencies often allow metal pipes as an option for cross drains under/along roads and highways. Metal culverts can corrode over time at various rates based on their environmental conditions (e.g., corrosive nature of coastal soils, high water table, and saltwater intrusion).

This project was focused on applying available soil data, such as spatial distribution of soil types and soil characteristics (e.g., pH and conductivity), towards creating a Geographic Information System (GIS) based map to identify corrosion zones in coastal Louisiana. The effect of the soil characteristics (pH and conductivity) was incorporated in to the published corrosion models for calculating …

Corrosion Studies Of Stainless Steel Blades, Dhruv S. Kothari

Theses

Corrosion is a subject of interest to interdisciplinary research communities that includes fields of materials science, chemistry, physics, metallurgy and chemical engineering. In order to understand the mechanisms of corrosion and the function of corrosion inhibitors, the reactions at the interfaces between the corrosive electrolyte and a steel surface, particularly at the initial stages of the corrosion process, need to be described. Naturally, these reactions are strongly affected by the nature and properties of the steel surfaces. It is however seen that the majority of recent corrosion and corrosion-inhibition investigations are limited to electrochemical testing, with ex situ analysis of …

Comparison Of Chemical-Use Between Hydraulic Fracturing, Acidizing, And Routine Oil And Gas Development, Mary Kay Camarillo, William T. Stringfellow, J. K. Domen, S. B. Shonkoff

All Faculty Articles - School of Engineering and Computer Science

The potential hazards and risks associated with well-stimulation in unconventional oil and gas development (hydraulic fracturing, acid fracturing, and matrix acidizing) have been investigated and evaluated and federal and state regulations requiring chemical disclosure for well-stimulation have been implemented as part of an overall risk management strategy for unconventional oil and gas development. Similar evaluations for chemicals used in other routine oil and gas development activities, such as maintenance acidizing, gravel packing, and well drilling, have not been previously conducted, in part due to a lack of reliable information concerning on-field chemical-use. In this study, we compare chemical-use between routine …

Nano-Channels Early Formation Investigation On Stainless Steel 316ti After Immersion In Molten Pb-Bi, Abu Khalid Rivai, Mardiyanto Mardiyanto, Annette Heinzel

Makara Journal of Technology

Development of fuel cladding and structural materials in Pb-Bi environment, especially at high temperature, is a critical issue for the deployment of LFR (Lead alloy-cooled Fast Reactor) and ADS (Accelerator Driven Transmutation System). This is because of the corrosive characteristic of Pb-Bi to metals as constituent materials of fuel cladding and structural of the reactors. Corrosion test of a high-chromium austenitic stainless steel i.e. SS316Ti in molten Pb-Bi at 550 ºC has been carried out for about 300 hours continuously. The characterization using SEM-EDS (Scanning Electron Microscopy - Energy Dispersive X-ray Spectroscopy) showed that an iron oxide as the outer …

Mechanism Of Cathodic Prevention Of Carbon Steel In Concrete, Krittin Rattakham

USF Tampa Graduate Theses and Dissertations

In this work, I aim to clarify the mechanism that allows steel to attain higher chloride threshold as it is cathodically polarized. Specifically, I seek to provide empirical information on whether an intrinsic (predominantly interfacial effects of polarization) or an extrinsic (predominantly concentration changes due to polarization) mechanism may be dominant in the beneficial effect of polarization. I carried out this experiment with 12 identical concrete specimens, each with a cast-in steel plate, constantly exposed them to high-chloride environment. The specimens were divided into 4 triplicates and polarized at 4 different level from OCP, -200, -300 to -400 mV_{SCE …}

Electrochemical Methods To Characterize Drilled Shaft Deficiencies, Sarah Jo Mobley

USF Tampa Graduate Theses and Dissertations

In recent years drilled shafts have become the preferred foundation method for marine bridges. Typically, the drilled shaft is selected over traditional driven piles due to soil strata encountered, construction economy, increased lateral stiffness requirements, and/or vibration control considerations. The most critical component in drilled shaft construction is borehole stabilization. Wall sloughing or groundwater inclusion can have devastating effects on the strength of the finished shaft however recent research has shown that the materials, more specifically the slurry, used to accomplish stabilization may be having a negative impact on the durability of the finished product. This thesis investigates the durability …