Engineering Commons^™

Corrosion And Passivation Behavior Of Laser Powder Bed Fusion Produced Ti-6al-4v Under Various Prior Plastic Deformation Strains, P. Qin, L. Y. Chen, Y. J. Liu, S. X. Liang, H. Sun, L. C. Zhang

Research outputs 2022 to 2026

This work investigated the corrosion behavior of LPBF-produced Ti-6Al-4V under varying compression strains in a 3.5 wt% NaCl solution. It identifies that increasing compression strain causes significant alterations in the acicular a'-Ti phase (coarsening, breakage, and further coarsening). Corrosion resistance decreases with higher strains due to deformed a'-Ti phases, leading to increased film growth kinetics (from 0.09× 10−10 cm2/s increase to 12.75 × 10−10 cm2/s). Samples under higher strains (e.g., 32%) exhibit fluctuations in corrosion behavior due to initiated cracks and subsequent crevice corrosion. These findings are vital for understanding LPBF-produced Ti-6Al-4V in applications requiring mechanical strength and corrosion resilience.

Corrosion Of Oil Pipeline: A Case Study On The Niger Delta Region Of Nigeria., Victor U. Okoro

Corrosion Research

Corrosion of oil pipelines in Nigeria, particularly in the Niger Delta region, has extensive and detrimental environmental and societal impacts. This issue results in substantial financial losses and reputational damage for oil companies operating in the area. Local communities suffer economically, affecting agriculture and food security. Furthermore, corrosion-related oil spills lead to air quality degradation by releasing volatile organic compounds and greenhouse gases, contributing to respiratory issues and worsening climate change.

These oil spill cleanups are costly and time-consuming, with estimated expenses reaching billions of dollars. Using the Nembe Creek Trunk Line (NCTL) case study, it is evident that addressing …

Evaluation Of Residual Flexural Behavior Of Corroded Fiber-Reinforced Super Workable Concrete Beams, Jingjie Wei, Nima Farzadnia, Alfred Addai-Nimoh, Kamal Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This Study Investigates the Effect of Macro Synthetic Fiber (MSF) Volume and Crack Widths on Corrosion of the Reinforcing Bars and Residual Flexural Behavior of Fiber-Reinforced Super-Workable Concrete (FR-SWC) Beams Exposed to Accelerated Corrosion. FR-SWC Beams Prepared with 0, 0.33%, and 0.66% MSF Were Pre-Cracked at 0.2-, 0.4-, and 0.75-Mm Widths Before Corrosion Testing. the Controlled Crack Width Was Initiated in One Set of Beams that Were Then Unloaded. the Crack Width Was Maintained for Another Set of Beams during Corrosion Testing by Inserting a Shim. Test Results Showed that the Use of 0.33% and 0.66% MSF Reduced Crack Development …

Corrosion Related To The Nuclear Waste Containers, Ali Ebrahimzadeh Pilehrood

Corrosion Research

The disposal of nuclear waste is a demanding topic, and the existing methods, whether it is temporary storage in spent fuel pools or storage in geological repositories, both face the risk of corrosion-related problems. Any failure in these storage methods can potentially lead to the release of radioactive materials into the environment. To avert such catastrophic scenarios, people in the nuclear industry consistently monitor and maintain these storage facilities endlessly and attempt to improve the plans designed to store nuclear waste. Here, I will examine the nuclear waste management organization (NWMO) plan in Canada. Choosing an appropriate location for the …

Corrosion Case Study On Pipeline, Kangze Ren

Corrosion Research

The Kashagan pipeline leaks were likely caused by sulfur stress corrosion cracking, a combined corrosion mechanism developed by the presence of high pressure, the high level of hydrogen sulfide(the main "ingredient" of sour gas), and poor metallurgical choice. Improper welding and poor metallurgical examination were blamed for causing the leaking issue. The purpose of the current review is to raise the alarm about the inappropriate corrosion management of Kashagan oil production and its societal and environmental consequences.

Predicting Corrosion Damage In The Human Body Using Artificial Intelligence: In Vitro Progress And Future Applications Applications, Michael A. Kurtz, Ruoyu Yang, Mohan S. R. Elapolu, Audrey C. Wessinger, William Nelson, Kazzandra Alaniz, Rahul Rai, Jeremy L. Gilbert

Publications

Artificial intelligence (AI) is used in the clinic to improve patient care. While the successes illustrate the impact AI can have, few studies have led to improved clinical outcomes. A gap in translational studies, beginning at the basic science level, exists. In this review, we focus on how AI models implemented in non-orthopedic fields of corrosion science may apply to the study of orthopedic alloys. We first define and introduce fundamental AI concepts and models, as well as physiologically relevant corrosion damage modes. We then systematically review the corrosion/AI literature. Finally, we identify several AI models that may be Preprint …

Extending The Service-Life Of Bridges Using Sustainable And Resilient Abutment Systems: An Experimental Approach To Electrochemical Characterization Of Lightweight Mechanically Stabilized Earth, Fariborz M. Tehrani, Kenneth L. Fishman, Farmehr M. Dehkordi

Mineta Transportation Institute Publications

Bridges are critical components of transportation infrastructure. This research addresses the need to extend the service life of bridges by improving the safety and reliability of bridge abutments and reducing their life-cycle cost and footprints. Mechanically stabilized earth (MSE) is a known strategy to enhance the economy and performance of bridge abutments. In addition, the application of rotary-kiln-manufactured lightweight aggregate backfills improves the performance of MSE bridge abutments with a leaner structural system. Such improvements include a reduction of structural demands due to a lower density, free drainage of granular materials, a high internal friction angle, less settlement with no …

Coating Condition Detection And Assessment On The Steel Girder Of A Bridge Through Hyperspectral Imaging, Pengfei Ma, Jiaoli Li, Ying Zhuo, Pu Jiao, Genda Chen

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The organic coating of bridge steel girders is subjected to physical scratches, corrosion, and aging in natural weathering. The breakdown of the coating may cause serviceability and safety problems if left unnoticed. Conventional coating inspection is time-consuming and lacks information about the coating's chemical integrity. A hyperspectral imaging method is proposed to detect the condition of steel coatings based on coating-responsive features in reflectance spectra. A field test was conducted on the real-world bridge, which shows obvious signs of degradation. The hyperspectral signature enables an assessment of the coating's health and defect severity. The results indicated that the coating scratch …

Self-Assembly Of Exfoliated Graphene Flakes As Anticorrosive Coatings For Additive Manufactured Steels, Kaleb Hood, Wen Qian, Yi Xia, Savannah Krupa, Annie Dao, Sarah Ahmed, Samuel Olson, Nam Nguyen, Joseph A. Turner, Jun Jiao

Department of Mechanical and Materials Engineering: Faculty Publications

This study demonstrates the feasibility of using liquid exfoliation of expandable graphite into multilayer exfoliated graphene flakes (EGFs) to form a self-assembled thin film on an air–water interface. The film can coat the surface of additive manufactured (AM) steel substrates to enhance surface properties, specifically AM 316 stainless-steel (AM316), AM 8620 steel (AM8620), and samples of the same alloys made by conventional manufacturing (CM) processes. Liquid exfoliation offers a high yield route for an EGF coating that can cover up to 95% of the sample surface with a single application. The thin, flexible EGFs can coat a rough AM metal …

Corrosion Case Study On Automobile, Grace Ajayi, Xinran Pan, Geethu Sasikala, Marshall S. Yang

Chemistry Publications

No abstract provided.

Revised Load Rating Procedures For Deteriorated Prestressed Concrete Beams, Alex Stripsky, Sergio F. Brena, Jessica Boakye, Scott A. Civjan, Simos Gerasimidis

Structural Engineering and Mechanics Research Reports

The first prestressed concrete bridge in the United States was built in the early 1950s. Since then, several typical sections have been developed for use in bridge construction including I-beams, deck slabs, box beams, double tees, etc. In bridges under aggressive environments, corrosion deterioration of prestressing strands and stirrups has occurred creating challenges associated with determining the strength of deteriorated existing bridge sections. The MassDOT LRFD Bridge Manual includes provisions to estimate strength of corrosion deteriorated prestressed concrete box beams allowing engineers to calculate the load rating of these types of bridges. The provisions are based on the observed condition …

Corrosion Behavior And Mechanism Of Laser Powder Bed Fusion Produced Cocrw In An Acidic Nacl Solution, P. Qin, L. Y. Chen, Y. J. Liu, C. H. Zhao, Hongqi Sun, Laichang Zhang

Research outputs 2022 to 2026

The corrosion behavior and mechanism of the laser powder bed fusion (L-PBF) produced CoCrW were investigated in 0.9 wt% NaCl solution with a pH of 2. The corrosion resistance of the alloy increases after 28 days of immersion because of the formed oxide film, which results in the increased corrosion potential and the decreased passivation current density on the potentiodynamic polarization test. The corrosion mechanism of the L-PBF-produced CoCrW could be explained by the melt pool formed from the laser melting process, that the melt pools were “shrinking” by the formation and dissolution of the oxide film.

Corrosion Behavior And Mechanisms Of The Heat-Treated Ti5cu Produced By Laser Powder Bed Fusion, Xin Wang, Peng Qin, L. Y. Chen, Hongqi Sun, Laichang Zhang

Research outputs 2022 to 2026

This work investigated the corrosion behavior of laser powder bed fusion produced (LPBFed) Ti5Cu and its heat-treated counterparts at 740 and 900 °C (named as HT-740 and HT-900 respectively) in Hank’s solution. The results indicated that the presence of acicular a'-Ti phase in LPBFed Ti5Cu was beneficial to corrosion, but the corrosion resistance of HT-740 and HT-900 were increased owing to the dual-phase microstructure (a'/a-Ti + Ti2Cu) or the increased content of Ti2Cu phase in the microstructure. The Ti2Cu phase could provide an ‘envelope’ protection to the a'/a-Ti phase and slow down the micro-galvanic reaction between a'/a-Ti phase and Ti2Cu …

Seismic Performance Of Ductile Corrosion-Free Reinforced Concrete Frames, Mohamed Meshaly, Maged A. Youssef, Ahmed Elansary

Civil and Environmental Engineering Publications

Corrosion of steel bars is the main cause of the deterioration of reinforced concrete (RC) structures. To avoid this problem, steel rebars can be replaced with glass-fiber-reinforced-polymer (GFRP). However, the brittle behaviour of GFRP RC elements has limited their use in many applications. The use of shape memory alloy (SMA) and/or stainless steel (SS) rebars can solve this problem, because of their ductile behaviour and corrosion resistance. However, their high price is a major obstacle. To address issues of ductility, corrosion, and cost, this paper examines the hybrid use of GFRP, SS, and SMA in RC frames. The use of …

Wavelet Power And Shannon Entropy Applied To Acoustic Emission Signals For Corrosion Detection And Evaluation Of Reinforced Concrete, Jinrui Zhang, Ziye Kang, Dongshuai Hou, Biqin Dong, Hongyan Ma

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Acoustic emission (AE) signals detected from corrosion test on a steel reinforced concrete beam subjected to the coupling effects of corrosive wet-dry cycles and static load are analyzed by power spectral density, wavelet transform, and Shannon entropy. The degradation process of the corroded reinforced concrete beam can be divided into four stages on the basis of the accumulated event number (AEN). Due to the difference of material properties, steel reinforcement and concrete matrix have distinguished AE features. The time-frequency characteristics of AE signals can reflect the microstructural degradation mechanism of steel corrosion and concrete cracking. The corrosion evaluation entails investigating …

Steel Bridge Coating Inventory For 2022, Christopher Goff, Sudhir Palle

Kentucky Transportation Center Research Report

The Kentucky Transportation Cabinet (KYTC) has replaced the lead-based coatings on many of its steel bridges over the past 30 years. In the 1980s and 1990s, inorganic zinc primers with vinyl topcoats were the go-to option for coating replacement projects. Since 2000, the typical choice for these projects has been organic zinc primers that are part of a two- or three-coat system. Some of these coatings have localized failures in high-stress areas. KYTC’s current inventory of steel bridges numbers over 1,100 structures. Accounting for expected service lives, to properly maintain protective coatings on these bridges will require the Cabinet to …

Matrix Acidizing In Carbonate Formations, Ofelia Gomez Chacon, Maysam Pournik

Mechanical Engineering Faculty Publications and Presentations

Matrix acidizing in carbonate reservoirs is a process that has been long used to increase productivity in oil and gas producing formations. The main goal is to create wormholes that bypass the damage in the formation. Hydrochloric acid (HCl) is the main acid used for this; however, it has several disadvantages that affect the success of these treatments. Its high reaction rate, inability to divert, and corrosive nature are a few of the reasons why research in this area has focused on finding alternative fluids. This paper discusses studies on successful alternatives to HCl. It has been observed that emulsified …

Novel Peridynamic Models For Material Degradation And Mass Transport, Jiangming Zhao

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Fracture and corrosion are two major causes of structure failure. They can interact with each other, leading to faster material degradation. They are also under the influence of environmental conditions. The corrosion rate highly depends on the transportation rate of involving substances, while the fracture can be accelerated significantly due to fluid flow. These complex mechanisms involved in structure failure have troubled classical models for decades. The peridynamic (PD) theory introduced in 2000 has shown great potential in modeling such problems. In this work, we develop novel PD models for fracture, corrosion, mass transport, and viscous flow, which are building …

The Corrosion Inhibition Behavior Of Thermally Aged Chromate Conversion Coating Applied To Aerospace Aluminum 2219, Michelle Stephane Pierre

FIU Electronic Theses and Dissertations

NASA Kennedy Space Center’s technical standard for corrosion protection of space flight hardware provides guidance concerning temperature restrictions and exposure limits for processing unpainted chromate conversion coatings (CCC) for the Orion crew space vehicle as part of the Artemis program. The standard requires that all CCC treated flight hardware components be fully coated within seven days with a maximum storage time of seven days at ambient temperatures (much less time at higher temperatures). Currently, there is no literature nor qualified industry testing supporting the exposure limits set by the standard. The standard is quite restrictive to processing flight components. In …

Assessment Of Deteriorated Structural Concrete To Provide Durable Repairs, Theodore Hopwood, Christopher Goff, Sudhir Palle

Kentucky Transportation Center Research Report

Most of the structural elements on Kentucky bridges are made of reinforced concrete. Many of these elements deteriorate as a result of corrosion of the reinforcing steel caused by carbonation and — primarily — applications of chlorides by the Kentucky Transportation Cabinet (KYTC). Corrosion of reinforcing steel is reviewed along with assessment procedures that leverage nondestructive evaluation (NDE) methods and related laboratory and field tests. Several maintenance procedures are discussed, including the application of sealers and coatings, patch and major concrete repairs, and electrochemical methods. Incorporating NDE and test results into maintenance procedure selection is discussed. Recommendations are provided on …

First-Principles Magnetic Treatment Of The Uranium Nitride (100) Surface And Effect On Corrosion Initiation, Ember L. Sikorski, Brian J. Jaques, Lan Li

Materials Science and Engineering Faculty Publications and Presentations

The magnetic properties of uranium nitride (UN) surfaces are not well understood experimentally or computationally but they have a significant effect on UN performance as a nuclear fuel. We investigated ferromagnetic (FM), antiferromagnetic (AFM), nonmagnetic (NM), and three hybrid magnetic structures of the most stable UN surface (100). To account for electron correlation and metastability, a U-ramp was performed to an effective Hubbard U-term of 2.0 eV. FM was found to be the most energetically favorable magnetic structure. Type 1 AFM slab was optimized to a new magnetic structure consisting of (100) planes with either all spin-up electrons, all spin-down …

Multifunctional Corrosion Control System As A Sustainable Approach For Reinforced Concrete Elements, Homero Castaneda, Miladin Radovic, Brendy Rincon, Oladis Troconis, Arturo Montoya, Changkyu Kim, Loreto Dacio

Data

Corrosion inhibitors can be utilized to decrease the corrosion kinetics and therefore increase the durability of reinforced concrete structures. Recently, a green synthesized organic compound, 1-benzyl-4-phenyl-1H-1,2,3-triazole (BPT), was shown to be a successful green organic corrosion inhibitor for mild steel. Studies suggested that the BPT adsorbs chemically onto the steel and acts as a mixed inhibitor, suppressing both the anodic and cathodic corrosion kinetics of steel. In addition, microcapsules have shown to be an efficient way for a controlled inhibitor release in reinforced concrete structures. On the other hand, geopolymers (GPs) comprised of a long range of covalently bonded alumino-silicates, …

Multifunctional Corrosion Control System As A Sustainable Approach For Reinforced Concrete Elements, Homero Castaneda, Miladin Radovic, Brendy Rincon, Oladis Troconis, Arturo Montoya, Changkyu Kim, Loreto Dacio

Publications

Corrosion inhibitors can be utilized to decrease the corrosion kinetics and therefore increase the durability of reinforced concrete structures. Recently, a green synthesized organic compound, 1-benzyl-4-phenyl-1H-1,2,3-triazole (BPT), was shown to be a successful green organic corrosion inhibitor for mild steel. Studies suggested that the BPT adsorbs chemically onto the steel and acts as a mixed inhibitor, suppressing both the anodic and cathodic corrosion kinetics of steel. In addition, microcapsules have shown to be an efficient way for a controlled inhibitor release in reinforced concrete structures. On the other hand, geopolymers (GPs) comprised of a long range of covalently bonded alumino-silicates, …

A Comparison Between Ultrasonic Guidedwave Leakage And Half-Cell Potential Methods In Detection Of Corrosion In Reinforced Concrete Decks, Ahmad Shoaib Amiri, Ece Erdogmus, Dana Richter-Egger

Durham School of Architectural Engineering and Construction: Faculty Publications

This article presents the advantages and limitations of a recently developed Ultrasonic Guided Wave Leakage (UGWL) method in comparison to the well-known Half-Cell Potential (HCP) method in their ability to detect corrosion in reinforced concrete (RC) bridge decks. This research also establishes a correlation between UGWL data and chloride content in concrete RC slabs. Concrete slabs submerged in a 10% NaCl solution were monitored using both methods over a period of six months. The chloride content from the three cores (0.84, 0.55, and 0.18%) extracted from the slab after the 6-month long process all exceeded the chloride threshold values suggested …

A Review On Alpha Case Formation And Modeling Of Mass Transfer During Investment Casting Of Titanium Alloys, R. Sharon Uwanyuze, Janos E. Kanyo, Sarah F. Myrick, Stefan Schafföner

Materials Science and Engineering Faculty Research & Creative Works

Titanium alloys have excellent corrosion resistance, high temperature strength, low density, and biocompatibility. Therefore, they are increasingly used for aerospace, biomedical, and chemical applications. Investment casting is a well-established process for manufacturing near-net-shape intricate parts for such applications. However, mass transfer arising from metal-mold reactions is still a major problem that drastically impairs the surface and properties of the castings. Although there have been astounding developments over the past 20 years, they remain scattered in various research papers and conference proceedings. This review summarizes the current status of the field, gaps in the scientific understanding, and the research needs for …

Novel And Fast Peridynamic Models For Material Degradation And Failure, Siavash Jafarzadeh

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Fracture is one of the main mechanisms of structural failure. Corroded surfaces with chemically-induced damage are, notably, potential sites for crack initiation and propagation in metals, which can lead to catastrophic failure of structures. Despite some progress in simulating fracture and damage using classical models, realistic prediction of complex damage progression and failure has been out of reach for many decades. Peridynamics (PD), a nonlocal theory introduced in 2000, opened up new avenues in modeling material degradation and failure. Existing numerical methods used to discretize PD equations, however, are quite expensive as the PD nonlocal interactions make them unaffordable for …

Probabilistic Prediction Model For Rc Bond Failure Mode, Ahmad Soraghi, Qindan Huang

Civil and Environmental Engineering Faculty Research and Publications

Adequate rebar-concrete bonding is crucial to ensure the reliable performance of reinforced concrete (RC) structures. Many factors such as the concrete properties, concrete cover depth, transverse reinforcement, and the presence of corrosion will affect the bond behavior, and consequently, the structural performance. While many prior studies have focused on the influence of the aforementioned factors on the bond strength, the impact of these factors on the bond failure mode has not been thoroughly investigated. A probabilistic bond failure mode prediction model that considers various influencing factors including loading type and corrosion is developed in this study. This study uses the …

Corrosion Protective Film Formation On Mg Alloys Az 31 By Exposure To Dilute Selenite Solutions, Zhiyuan Feng, Charles C. Xu, Dadi Zhang, Rudolph Buchheit

Chemical and Materials Engineering Faculty Publications

The study of protective film formation on Mg alloys by exposure to sodium selenite solutions was conducted. Anodic polarization studies, electrochemical impedance spectroscopy studies, morphological analysis, and Energy-dispersive X-ray spectroscopy were performed on AZ31 Mg alloy after coating treatment in different concentrations of sodium selenite. The corrosion resistance was improved by around 5 times compared with control. Improved resistance to localized corrosion was observed in the coatings treated by 5 mM or 10 mM sodium selenite. The protection mechanism was ascribed to the transformation of selenite to insoluble selenium, the formation of insoluble MgSeO₃ hydrate, and polymerization of amorphous …

A Data-Driven Method For Online Monitoring Tube Wall Thinning Process In Dynamic Noisy Environment, Chen Zhang, Jun Long Lim, Ouyang Liu, Aayush Madan, Yongwei Zhu, Shili Xiang, Kai Wu, Rebecca Yen-Ni Wong, Jiliang Eugene Phua, Karan M. Sabnani, Keng Boon Siah, Wenyu Jiang, Yixin Wang, Emily Jianzhong Hao, Hoi, Steven C. H.

Research Collection School Of Computing and Information Systems

Tube internal erosion, which corresponds to its wall thinning process, is one of the major safety concerns for tubes. Many sensing technologies have been developed to detect a tube wall thinning process. Among them, fiber Bragg grating (FBG) sensors are the most popular ones due to their precise measurement properties. Most of the current works focus on how to design different types of FBG sensors according to certain physical laws and only test their sensors in controlled laboratory conditions. However, in practice, an industrial system usually suffers from harsh and dynamic environmental conditions, and FBG signals are affected by many …

Assessment Of Cu(In, Ga)Se₂ Solar Cells Degradation Due To Water Ingress Effect On The Cds Buffer Layer, Deewakar Poudel, Benjamin Belfore, Shankar Karki, Grace Rajan, Sina Soltanmohammad, Angus Rockett, Sylvain Marsillac

Electrical & Computer Engineering Faculty Publications

The effect of water ingress on the surface of the buffer layer of a Cu(In, Ga)Se2 (CIGS) solar cell was studied. Such degradation can occur either during the fabrication process, if it involves a chemical bath as is often the case for CdS, or while the modules are in the field and encapsulants degrade. To simulate the impact of this moisture ingress, devices with a structure sodalime glass/Mo/CIGS/CdS were immersed in deionized water. The thin films were then analyzed both pre and post water soaking. Dynamic secondary ion mass spectroscopy (SIMS) was performed on completed devices to analyze impurity diffusion …