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Full-Text Articles in Engineering

Assessment Of Cu(In, Ga)Se₂ Solar Cells Degradation Due To Water Ingress Effect On The Cds Buffer Layer, Deewakar Poudel, Benjamin Belfore, Shankar Karki, Grace Rajan, Sina Soltanmohammad, Angus Rockett, Sylvain Marsillac Jan 2021

Assessment Of Cu(In, Ga)Se₂ Solar Cells Degradation Due To Water Ingress Effect On The Cds Buffer Layer, Deewakar Poudel, Benjamin Belfore, Shankar Karki, Grace Rajan, Sina Soltanmohammad, Angus Rockett, Sylvain Marsillac

Electrical & Computer Engineering Faculty Publications

The effect of water ingress on the surface of the buffer layer of a Cu(In, Ga)Se2 (CIGS) solar cell was studied. Such degradation can occur either during the fabrication process, if it involves a chemical bath as is often the case for CdS, or while the modules are in the field and encapsulants degrade. To simulate the impact of this moisture ingress, devices with a structure sodalime glass/Mo/CIGS/CdS were immersed in deionized water. The thin films were then analyzed both pre and post water soaking. Dynamic secondary ion mass spectroscopy (SIMS) was performed on completed devices to analyze impurity diffusion …


Evaluation Of Orthophosphate Based Corrosion Inhibitors In Treated Water For El Paso Region, Francisco Solis Jr Jan 2018

Evaluation Of Orthophosphate Based Corrosion Inhibitors In Treated Water For El Paso Region, Francisco Solis Jr

Open Access Theses & Dissertations

Corrosion is an electrochemical phenomenon that involves the deterioration of a metal by the reaction of itself with its surrounding environment. One of the greatest issues for water utilities around the country is to keep the water quality safe. Corrosion can affect the quality of the water that we use on a daily basis by adding a bad taste, increasing the concentration of heavy metals, and allowing outside contaminants to enter the distribution system. The use of phosphate based corrosion inhibitors was tested in two different metals: iron and copper. The phosphate in the inhibitors react with the calcium in …


Identifying Corrosion Zones In Coastal Regions For Metal Pipes -- A Gis Approach, Sanjay Tewari, Francis Manning Aug 2017

Identifying Corrosion Zones In Coastal Regions For Metal Pipes -- A Gis Approach, Sanjay Tewari, Francis Manning

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Transportation agencies often allow metal pipes as an option for cross drains under/along roads and highways. Metal culverts can corrode over time at various rates based on their environmental conditions (e.g., corrosive nature of coastal soils, high water table and saltwater intrusion). This paper focuses on applying readily available soil data such as spatial distribution of soil types and soil characteristics (e.g., pH and conductivity) towards creating a geospatial information system (GIS) based approach to identifying corrosion zones in the coastal regions. A combination of data, obtained from field surveys provided by the Louisiana Transportation Research Center and Web Soil …


Mechanism Of Cathodic Prevention Of Carbon Steel In Concrete, Krittin Rattakham Mar 2017

Mechanism Of Cathodic Prevention Of Carbon Steel In Concrete, Krittin Rattakham

USF Tampa Graduate Theses and Dissertations

In this work, I aim to clarify the mechanism that allows steel to attain higher chloride threshold as it is cathodically polarized. Specifically, I seek to provide empirical information on whether an intrinsic (predominantly interfacial effects of polarization) or an extrinsic (predominantly concentration changes due to polarization) mechanism may be dominant in the beneficial effect of polarization. I carried out this experiment with 12 identical concrete specimens, each with a cast-in steel plate, constantly exposed them to high-chloride environment. The specimens were divided into 4 triplicates and polarized at 4 different level from OCP, -200, -300 to -400 mVSCE …


Effect Of Pet Wrapping On Shear Performance Of Corroded Reinforced Concrete Columns, Dawei Zhang, Yuxi Zhao, Weiliang Jin, Tamon Ueda Jun 2016

Effect Of Pet Wrapping On Shear Performance Of Corroded Reinforced Concrete Columns, Dawei Zhang, Yuxi Zhao, Weiliang Jin, Tamon Ueda

International Conference on Durability of Concrete Structures

In this paper, an experimental study is presented on the influence of PET warping on shear performance, such as diagonal shear cracking load, peak load, and energy dissipation of RC columns with stirrup corrosion before strengthening. The experimental program involved an electrochemical process to accelerate the migration of chlorides from an external electrolyte into the tested columns, a wetting–drying cycle process with a controlled current to speed up the corrosion of the stirrup in the tested columns, the strengthening of corroded columns with PET warping, and a pseudostatic test to determine the shear capacity of the tested beams. The shear …


Influence Of Permeate From Domestic Reverse Osmosis Filters On Lead Corrosion And Leaching From Plastic Pipes, Jyotsna Shrestha May 2016

Influence Of Permeate From Domestic Reverse Osmosis Filters On Lead Corrosion And Leaching From Plastic Pipes, Jyotsna Shrestha

Theses and Dissertations

Reverse Osmosis filters are gaining popularity nowadays, in domestic water supply system, to meet the increasing demand of pure and improved drinking water. There are various types of domestic RO filters with varying sizes, capacities, and treatment stages available. However, there exist a few concerns regarding the RO treatment system. One of the major issues in the quality and distribution of drinking water is the corrosive water that the RO system produces. Therefore, this research herein tends to focus on the corrosive effect of the permeate water on lead metal, as lead is considered a serious problematic drinking water contaminant. …


On The Role Of The Pore Water Chemistry Of Deficient Post-Tension Grout To Promote Steel Corrosion, Samanbar Permeh Mar 2016

On The Role Of The Pore Water Chemistry Of Deficient Post-Tension Grout To Promote Steel Corrosion, Samanbar Permeh

FIU Electronic Theses and Dissertations

Corrosion failure of post-tension tendons with pre-packaged thixotropic grout was documented in Florida Bridges in less than 10 years of service. Analysis of deficient grout in Florida post-tensioned (PT) bridges where severe corrosion developed indicated enhanced sulfate ion concentration, high pore water pH, enhanced moisture and low chloride content. The corrosion wasn’t consistent with the conventional causes of steel corrosion such as bleed water accumulation in grout void spaces, chloride contamination and pore water carbonation. Corrosion development was associated with deficient grout with enhanced sulfate levels. However, limited information is available on the corrosion behavior of PT strand in grout …


Weak Magnetic Field Accelerates Chromate Removal By Zero-Valent Iron, Pian Feng, Xiaohong Guan, Yuankui Sun, Wonyong Choi, Hejie Qin, Jianmin Wang, Junlian Qiao, Lina Li May 2015

Weak Magnetic Field Accelerates Chromate Removal By Zero-Valent Iron, Pian Feng, Xiaohong Guan, Yuankui Sun, Wonyong Choi, Hejie Qin, Jianmin Wang, Junlian Qiao, Lina Li

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Weak magnetic field (WMF) was employed to improve the removal of Cr(VI) by zero-valent iron (ZVI) for the first time. The removal rate of Cr(VI) was elevated by a factor of 1.12-5.89 due to the application of a WMF, and the WMF-induced improvement was more remarkable at higher Cr(VI) concentration and higher pH. Fe2+ was not detected until Cr(VI) was exhausted, and there was a positive correlation between the WMF-induced promotion factor of Cr(VI) removal rate and that of Fe2+ release rate in the absence of Cr(VI) at pH 4.0-5.5. These phenomena imply that ZVI corrosion with Fe2+ …


In-Plant And Distribution System Corrosion Control For Reverse Osmosis, Nanofiltration, And Anion Exchange Process Blends, Samantha Jeffery Jan 2013

In-Plant And Distribution System Corrosion Control For Reverse Osmosis, Nanofiltration, And Anion Exchange Process Blends, Samantha Jeffery

Electronic Theses and Dissertations

The integration of advanced technologies into existing water treatment facilities (WTFs) can improve and enhance water quality; however, these same modifications or improvements may adversely affect finished water provided to the consumer by public water systems (PWSs) that embrace these advanced technologies. Process modification or improvements may unintentionally impact compliance with the provisions of the United States Environmental Protection Agency’s (USEPA’s) Safe Drinking Water Act (SDWA). This is especially true with respect to corrosion control, since minor changes in water quality can affect metal release. Changes in metal release can have a direct impact on a water purveyor’s compliance with …


Evaluating Corrosion Control Alternatives For A Reverse Osmosis, Nanofiltration And Anion-Exchange Blended Water Supply, Rebecca J. Wilder Jan 2012

Evaluating Corrosion Control Alternatives For A Reverse Osmosis, Nanofiltration And Anion-Exchange Blended Water Supply, Rebecca J. Wilder

Electronic Theses and Dissertations

The research reported herein describes the study activities performed by University of Central Florida (UCF) on behalf of the Town of Jupiter Water Utilities (Town). The Town recently changed its water treatment operations from a combination of reverse osmosis (RO), lime softening (LS) and anion-exchange (IX) to a combination of RO, IX and nanofiltration (NF). Although this treatment change provided enhanced water to the surrounding community in terms of better contaminant removal and reduced DBP formation potential, integration of the NF process altered finished water quality parameters including pH, alkalinity and hardness. There was concern that these changes could result …


Impact Of Corrosion Inhibitor Blended Orthophosphate On Water Quality In Water Distribution Systems, Abdulrahman Alshehri Jan 2008

Impact Of Corrosion Inhibitor Blended Orthophosphate On Water Quality In Water Distribution Systems, Abdulrahman Alshehri

Electronic Theses and Dissertations

The impact of blended orthophosphate (BOP) inhibitor addition on the corrosion of iron, copper, and lead in drinking water distribution systems was studied under changing water quality environment. Release of iron, copper, and lead were monitored at varying inhibitor doses and changing blends of source waters (groundwater, surface water, and desalinated water). Solid corrosion products on pipe surfaces under BOP treatment were evaluated with surface characterization techniques. Performance of the BOP inhibitor was compared to other corrosion control strategies. Iron scales for iron and galvanized steel coupons incubated in different blended waters in the presence of BOP inhibitor were analyzed …


Using Electrochemical Monitoring To Predict Metal Release In Drinking Water Distribution Systems, Rajendra D. Vaidya Jan 2007

Using Electrochemical Monitoring To Predict Metal Release In Drinking Water Distribution Systems, Rajendra D. Vaidya

Electronic Theses and Dissertations

Corrosion of distribution system piping and home plumbing materials is a major concern in the water community. Iron release adverse affects aesthetic water quality and the release of copper and lead is regulated by the Lead and Copper rule (LCR) and can adversely affect consumer health. Corrosion control is typically done by pH regulation and/or addition of corrosion inhibitors. Monitoring of corrosion control is typically done after the fact by monitoring metal release, functional group concentration of the selected chemical species or water quality. Hence, the associated laboratory analyses create a significant delay prior to the assessment of corrosion in …


Verification Of Pilot-Scale Iron Release Models, Stephen Glatthorn Jan 2007

Verification Of Pilot-Scale Iron Release Models, Stephen Glatthorn

Electronic Theses and Dissertations

A model for the prediction of color release from a pilot distribution system was created in 2003 by Imran. This model allows prediction of the release of color from aged cast iron and galvanized steel pipes as a function of water quality and hydraulic residence time. Color was used as a surrogate measurement for iron, which exhibited a strong linear correlation. An anomaly of this model was an absence of a term to account for pH, due to the influent water being well stabilized. A new study was completed to evaluate the effectiveness of corrosion inhibitors against traditional adjustment. Two …


Avoid Sulfuric Acid Corrosion In Metallic Stacks, João F. Gomes Jan 2005

Avoid Sulfuric Acid Corrosion In Metallic Stacks, João F. Gomes

João F Gomes

Acidic gaseous effluents frequently cause corrosion on metallic stacks. This paper presents a method for prevision of probability of corrosion occurrence caused by gaseous effluents containing sulphur oxides which is based on the sulphur trioxide and moisture content measured in stack