Processing And Mechanical Characterization Of Polyurea Aerogels,
2011
Missouri University of Science and Technology
Processing And Mechanical Characterization Of Polyurea Aerogels, Jared M. Loebs
Masters Theses
"The use of aerogels historically has been limited to extreme cases largely in part to the nature of their mechanical properties. Until recently many aerogels produced have been brittle and weak, though looking at their specific strength would suggest otherwise. This thesis outlines the processing and major mechanical properties of a relatively new type of aerogel, polyurea aerogel, that shows promise in a variety of fields including structures.
Processing polyurea aerogel begins with a liquid solution that solidifies to form a solid gel filled with liquid that is later removed by supercritical drying. Once dry, polyurea aerogels are difficult to …
Design Of A Hydrogen Community For Santa Monica,
2011
Missouri University of Science and Technology
Design Of A Hydrogen Community For Santa Monica, Vijay Mohan
Masters Theses
"Hydrogen systems infrastructure development and fuel cell vehicles (FCVs) have the potential to replace the gasoline internal combustion engine vehicles thus increasing energy security and reducing greenhouse gas emissions. Hydrogen fueling infrastructure development is critical for the commercialization and consumer acceptability of the FCVs, thus recognizing hydrogen as an affordable transportation fuel. This paper presents the conceptual design of a scalable and reproducible hydrogen fueling station in Santa Monica, California. The various hydrogen production technologies have been evaluated and the usage of renewable energy sources such as biogas and landfill gas has been emphasized. The technical specifications of the hydrogen …
Integrated Reliable And Robust Design,
2011
Missouri University of Science and Technology
Integrated Reliable And Robust Design, Gowrishankar Ravichandran
Masters Theses
"The objective of this research is to develop an integrated design methodology for reliability and robustness. Reliability-based design (RBD) and robust design (RD) are important to obtain optimal design characterized by low probability of failure and minimum performance variations respectively. But performing both RBD and RD in a product design may be conflicting and time consuming. An integrated design model is needed to achieve both reliability and robustness simultaneously. The purpose of this thesis is to integrate reliability and robustness. To achieve this objective, we first study the general relationship between reliability and robustness. Then we perform a numerical study …
Impact Of Combustion Phasing On Energy And Availability Distributions Of An Internal Combustion Engine,
2011
Missouri University of Science and Technology
Impact Of Combustion Phasing On Energy And Availability Distributions Of An Internal Combustion Engine, Shawn Nicholas Wildhaber
Masters Theses
"High fuel efficiency has become an extremely desirable trait for internal combustion engines. This motivation has driven extensive research on methods to improve fuel efficiency on engines of various sizes. Many of these methods involve changes to the properties of the combustion process. One way to induce these property changes is through varying the phasing of combustion. Combustion phasing can be defined as the time in the engine cycle, specifically the compression and expansion strokes, where combustion occurs. A change in combustion phasing causes a change in combustion duration. The duration of combustion impacts how the energy and work potential …
Numerical Comparison Of Thermal And Kinetic Modification Of Hydrogen And Oxygen,
2011
Missouri University of Science and Technology
Numerical Comparison Of Thermal And Kinetic Modification Of Hydrogen And Oxygen, John Benjamin Gaither
Masters Theses
"This document describes a new modeling technique used to compare thermal and kinetic modification of hydrogen and oxygen gas. The thermal model uses an equilibrium thermodynamic analysis to determine the heat required for given mole fractions of molecular and dissociated products. A kinetic model is developed for a mono-energetic electron beam and a Maxwellian energy distribution. The kinetic model uses electron impact cross sections for excitation, dissociation, and ionization tabulated from available source data between 0-1000 eV. Cross sections are used to calculate forward reaction rates, electron penetration depths, and associated product concentrations for excited, dissociated, and ionized species. The …
3-Dimensional Computational Fluid Dynamics Modeling Of Solid Oxide Fuel Cell Using Different Fuels,
2011
Missouri University of Science and Technology
3-Dimensional Computational Fluid Dynamics Modeling Of Solid Oxide Fuel Cell Using Different Fuels, Sachin Laxman Puthran
Masters Theses
"Solid oxide fuel cell (SOFC) technology has been of great interest over many years due to its flexibility in using different fuels for operation; including the fundamental fuel i.e. Hydrogen. Various computational and numerical models have been developed along with experimental work to evaluate the performance as well as to identify and overcome the problems faced in the development of SOFC's. In an attempt to achieve efficient operation with respect to design and combined thermal and electrochemical perspective, the main objective of the proposed study is to present a three-dimensional computational model, which will serve as a framework for the …
Analysis And Modeling Of Depth-Of-Cut During End Milling Of Deposited Material,
2011
Missouri University of Science and Technology
Analysis And Modeling Of Depth-Of-Cut During End Milling Of Deposited Material, Haythem Gaja
Masters Theses
"This study addresses depth-of-cut detection and tool-workpiece engagement using an acoustic emission monitoring system during milling machining for a deposited material. Online detection of depth-of-cut presents many technical difficulties. Researchers have used various types of sensors and methods to assess the depth-of-cut and surface errors. Due to the strong correlation between acoustic emission and cutting depth during the depth end milling process, it is useful to forecast the depth-of-cut from the acoustic emission signal. This work used regression analysis to model and detect the depth-of-cut. The experiments were carried out on a Fadal vertical 5-Axis computer numerical control machine using …
Solar Powered Residential Hydrogen Fueling Station,
2011
Missouri University of Science and Technology
Solar Powered Residential Hydrogen Fueling Station, Aanchal Shah
Masters Theses
"Interest towards the hydrogen fuel technology is increasing but its potential benefits will not be felt until hydrogen vehicles and the fueling infrastructure captures a substantial market share. Though there has been a rapid progress in the hydrogen fuel cell technology, a major challenge to the commercialization of fuel cell vehicles is the lack of hydrogen fueling infrastructure. The development of a commercial hydrogen fueling station is a challenge due to its high initial cost and safety concerns. Residential fueling stations provide an innovative solution to this issue since they also produce electricity and heat for the residential buildings in …
Development Of Hybrid Composite Bipolar Plates For Proton Exchange Membrane Fuel Cells,
2011
Missouri University of Science and Technology
Development Of Hybrid Composite Bipolar Plates For Proton Exchange Membrane Fuel Cells, Nathaniel James Richie
Masters Theses
"Bipolar plates are one of the most expensive components of a PEM fuel cell and by far the heaviest. Bipolar plates are responsible for providing flow fields for reaction gases, acting as current collectors for electrons liberated during the chemical reaction inside the cell, and providing structural support for the fuel cell stack. Current PEM fuel cell bipolar plate technology is built on the use of sintered graphite which is costly and requires time-consuming machining. Furthermore, due to the brittle nature of graphite, plates must be made relatively thick which adds significant weight and volume to larger stacks, such as …
Effect Of Initial Conditions On Molecular Mixing In A High Schmidt-Number Rayleigh-Taylor Mixing Layer,
2011
Missouri University of Science and Technology
Effect Of Initial Conditions On Molecular Mixing In A High Schmidt-Number Rayleigh-Taylor Mixing Layer, Lakshmi Ayyappa Raghu Mutnuri
Masters Theses
"Characterizing molecular mixing in Rayleigh-Taylor instability (RTI) driven flows where the density and velocity fields are coupled is essential for developing exacting predictive models. Sensitivity of the Rayleigh Taylor mixing layer to initial conditions is a topic that is being explored extensively in interests of accurate turbulent mix model development and its direct consequence in various applications like design of inertial confinement fuel capsule and atmospheric modeling. As part of the current work, an experimental investigation of the effect of initial conditions on molecular mixing in a low Atwood number(~7.5 x 10⁻⁴), high Schmidt number(~1000), RTI driven mixing layer is …
Femtosecond And Nanosecond Laser Fabricated Substrate For Surface-Enhanced Raman Scattering,
2011
Missouri University of Science and Technology
Femtosecond And Nanosecond Laser Fabricated Substrate For Surface-Enhanced Raman Scattering, Adam Hamdorf
Masters Theses
"Surface-enhanced Raman scattering has many applications to chemical science, and shows great promise in the medical field because of its ability to provide "molecular fingerprinting" of probe molecules, whereby a material can be identified and potentially quantified. This is done by enhancing the normally weak Raman spectrum by many orders of magnitude with the use of fabricated substrates. It is therefore desirable to produce repeatable substrates with high enhancement factors for identification and quantification of samples. This thesis introduces a new method for generating such a substrate. By using femtosecond laser machining, gold sputtering, and nanosecond laser annealing, gold nanoparticles …
Selective Laser Sintering Of 13-93 Bioactive Glass,
2011
Missouri University of Science and Technology
Selective Laser Sintering Of 13-93 Bioactive Glass, Krishna C. R. Kolan
Masters Theses
"Bioactive glasses are promising materials for bone scaffolds due to their ability to assist in tissue regeneration. When implanted in vivo, bioactive glasses can convert to hydroxyapatite, the main mineral constituent of human bone and form a strong bond with the surrounding tissues, thus providing an advantage over polymer scaffold materials. Bone scaffold fabrication using additive manufacturing techniques like selective laser sintering (SLS) provide control over pore interconnectivity during the fabrication of scaffold, which helps in mimicking human trabecular bone. 13-93 glass, a third-generation bioactive material designed to accelerate the body's natural ability to heal itself, was used in …
Experimental Investigation Of Cutting Forces, Temperature And Surface Roughness In End-Milling Of Hastelloy C-2000,
2011
Missouri University of Science and Technology
Experimental Investigation Of Cutting Forces, Temperature And Surface Roughness In End-Milling Of Hastelloy C-2000, Ryan Matthews
Masters Theses
"This thesis presents the results of experimental investigation of the effects of cutting parameters (spindle speed, feed per tooth, axial depth of cut and radial depth of cut) on the three components of cutting forces (Fx, Fy, Fz), workpiece temperature and surface roughness in end-milling of Hastelloy C-2000 alloy using design of experiments (DOE) and response surface methodology (RSM). End-milling experiments were conducted using 0.5 inch diameter end-mill on Cincinnati Milacron Sabre 750 vertical machining center using water based flood coolant. An inscribed central composite design of experiment was used to study the four …
Fabrication Of Sers Active Nanostructures By Femtosecond Laser Micromachining,
2011
Missouri University of Science and Technology
Fabrication Of Sers Active Nanostructures By Femtosecond Laser Micromachining, Matthew Aaron Olson
Masters Theses
"This work investigated the surface-enhanced Raman scattering (SERS) enhancement of gold nanoparticles on femtosecond laser created nanostructures on a silicon wafer. The goal was to use the nanostructures to assemble the nanoparticles into three-dimensional aggregates and compare these enhancements to those of two dimensional aggregates. The SERS enhancement generated by the three-dimensional structures was on average 5 x 10⁴ with a high enhancement of 1.2 x 10⁵. The magnitude of this enhancement was on par with previous experiments that tested SERS enhancements on gold nanoparticles, but it did not show any significant enhancement caused by the three-dimensional nature of the …
Electrodeposition Of Metallic Gas Diffusion Layers For Use In Pem Fuel Cells,
2011
Missouri University of Science and Technology
Electrodeposition Of Metallic Gas Diffusion Layers For Use In Pem Fuel Cells, Gargi Tandra
Masters Theses
"This work developed a novel method of using Electrodeposition techniques to fabricate metallic gas diffusion layers (GDLs) for application in proton exchange membrane fuel cells. These GDLs improve the electrical and thermal conductivity of the fuel cells, and their straight, noncircular pores remove water efficiently. The Electrodeposition technique used here relies on a sacrificial copper anode and an aluminum sheet 50 µm thick acts as a cathode. Unlike the other laboratory based methods available for the fabrication of metallic GDLs, this method is simple and cost effective. With controlled deposition parameters and a chemical lift-off process that corrodes the aluminum …
Development Of Virtual Engineering Simulation For Lean Education,
2011
Missouri University of Science and Technology
Development Of Virtual Engineering Simulation For Lean Education, Akalpit Kiran Gadre
Masters Theses
"Global competition and customer demands are pressing modern industry operations to become leaner. The race among the global corporations to "go lean" demands engineers with an in-depth understanding of lean philosophies. An overview of current methods for teaching lean shows that they include small scale hands-on projects, presentations, and guest lectures. There is a need to incorporate a more immersive virtual simulation to further inspire students. Many lean simulation games are available in the market; however, they lack simplicity, ability to store the results, and modeling power.
The goal of this research is to develop a virtual simulation platform, enabling …
Risk Assessment For Conceptual Design Of Hydrokinetic Turbines,
2011
Missouri University of Science and Technology
Risk Assessment For Conceptual Design Of Hydrokinetic Turbines, Praveen Kailkere Srinivas
Masters Theses
"Hydrokinetic energy is a relatively new concept in the field of renewable energy. The rotor of the turbine, immersed in water, uses the velocity from the flowing water to generate power. Thus the hydrokinetic turbines are also known as zero head turbines. These turbines can be installed in rivers, oceans and sea beds. The design of these systems depends on the site conditions, installation and maintenance costs. Since this technology has not been assessed for its potential power producing capabilities, not much research has been done in order to harness this form of renewable energy and to study the impact …
Development Of Virtual Cnc Machine Tools And Web-Based Machining Process Simulation: Mechanistic Cutting Force Models And Determination Of Specific Force Coefficients In Helical End Milling,
2011
Missouri University of Science and Technology
Development Of Virtual Cnc Machine Tools And Web-Based Machining Process Simulation: Mechanistic Cutting Force Models And Determination Of Specific Force Coefficients In Helical End Milling, Vinay Rao Talekar
Masters Theses
"This thesis presents the results of the investigations of mechanistic modeling and simulation of cutting forces in high speed end milling of titanium alloy, Ti-6Al-4V, and the determination of specific cutting and edge force coefficients for carbide bull-nose helical end-mill. A generalized mathematical model representing the outer geometry of an end-mill and the cutter edge geometry is presented. Mechanistic cutting force models have been developed for a general helical end-mill and modeled specifically for a bullnose helical end-mill. A MATLAB code for the mechanistic cutting force models have been developed for the simulation of cutting force components in end milling …
A Comparison Of Bootstrap, Binomial Inference, And Monte Carlo Methods For Demand Distribution Modeling,
2011
Missouri University of Science and Technology
A Comparison Of Bootstrap, Binomial Inference, And Monte Carlo Methods For Demand Distribution Modeling, Swithin Samuel Razu
Masters Theses
"Analysis of customer preferences is one of the most important tasks in new product development. How customers come to appreciate and decide to purchase a new product impacts market share and, therefore, the success of the new product. Unfortunately, when designers select a product concept early in the product development process, the "true" customer preferences and therefore, market share of the new product is unknown. Conjoint analysis is a statistical methodology that has been used to forecast the market share of a product concept from customer preference survey data. Although conjoint analysis has been increasingly incorporated in design research as …
Evaluation Of Skin-Core Adhesion Bond And Low-Velocity Impact Behavior Of Honeycomb Sandwich Structures,
2011
Missouri University of Science and Technology
Evaluation Of Skin-Core Adhesion Bond And Low-Velocity Impact Behavior Of Honeycomb Sandwich Structures, Ramanjaneya R. Butukuri
Masters Theses
"Composite sandwich structures offer several advantages over conventional structural materials such as lightweight, high bending and torsional stiffness, superior thermal insulation and excellent acoustic damping. Some of the failure mechanisms in a composite sandwich structure are de-bonding of the composite facesheets from the core structure and damage due to low-velocity impact. In the first part of this work, adhesive fillet formation and adhesive mechanical strength are evaluated as a function of several different sandwich construction design variables. The effect of film adhesive thickness is studied. A process for reticulation of the adhesive is applied and studied. Optimized combinations of core …
