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Direct Synthesis Of Methane From Co2-H2O Co-Electrolysis In Tubular Solid Oxide Electrolysis Cells, Long Chen, Fanglin Chen, Changrong Xia 2014 University of South Carolina - Columbia

Direct Synthesis Of Methane From Co2-H2O Co-Electrolysis In Tubular Solid Oxide Electrolysis Cells, Long Chen, Fanglin Chen, Changrong Xia

Faculty Publications

Directly converting CO2 to hydrocarbons offers a potential route for carbon-neutral energy technologies. Here we report a novel design, integrating the high-temperature CO2–H2O co-electrolysis and low-temperature Fischer–Tropsch synthesis in a single tubular unit, for the direct synthesis of methane from CO2 with a substantial yield of 11.84%.


Synthesis And Formation Mechanism Of Cuins2 Nanocrystals With A Tunable Phase, Chao Yu, Linlin Zhang, Long Tian, Dan Liu, Fanglin Chen, Cheng Wang 2014 University of South Carolina - Columbia

Synthesis And Formation Mechanism Of Cuins2 Nanocrystals With A Tunable Phase, Chao Yu, Linlin Zhang, Long Tian, Dan Liu, Fanglin Chen, Cheng Wang

Faculty Publications

Chalcopyrite CuInS2 (CIS) hierarchical structures composed of nanoflakes with a thickness of about 5 nm were synthesized by a facial solvothermal method. The thermodynamically metastable wurtzite phase CIS would be obtained by using InCl3 instead of In(NO3)3 as In precursor. The effects of the In precursor and the volume of concentrated HCl aqueous solution on the phases and morphologies of CIS nanocrystals have been systematically investigated. Experimental results indicated that the obtained phases of CIS nanocrystals were predominantly determined by precursor-induced intermediate products. The photocatalytic properties of chalcopyrite and wurtzite CIS in visible-light-driven degradation of …


Host-Guest Interaction Dictated Selective Adsorption And Fluorescence Quenching Of A Luminescent Lightweight Metal-Organic Framework Toward Liquid Explosives, Dan Liu, Xiaojuan Liu, Yongxin Liu, Yang Yu, Fanglin Chen, Cheng Wang 2014 University of South Carolina - Columbia

Host-Guest Interaction Dictated Selective Adsorption And Fluorescence Quenching Of A Luminescent Lightweight Metal-Organic Framework Toward Liquid Explosives, Dan Liu, Xiaojuan Liu, Yongxin Liu, Yang Yu, Fanglin Chen, Cheng Wang

Faculty Publications

In this article, we report the successful preparation of a Mg-based luminescent MIL-53 metal–organic framework (MOF), namely [Mg2(BDC)2(BPNO)]·2DMF (1) (BDC = 1,4-benzene dicarboxylate, BPNO = 4,4’- dipyridyl-N,N’-dioxide, DMF = N,N-dimethylformamide) in a mixed solvent containing a 2 : 3 volume ratio of DMF and ethanol (EtOH) under solvothermal conditions. Desolvated compound 1a can be used as an absorbent for selective adsorption and separation of liquid explosives, including nitroaromatic (nitrobenzene (NB)) and nitroaliphatic (nitromethane (NM) and nitroethane (NE)) compounds, through single crystal-to-single crystal (SC–SC) transformations. As one of the weakly luminescent MOFs, the luminescence of compound 1a could be quenched by …


Simulations Of Diffusion Driven Phase Evolution In Heterogenous Solids, Subramanya Gautam Sadasiva 2014 Purdue University

Simulations Of Diffusion Driven Phase Evolution In Heterogenous Solids, Subramanya Gautam Sadasiva

Open Access Dissertations

With reduction in size, ever greater operational demands are placed on electronics components at all levels of the device, starting from the transistor level to the level of the package and the solder interconnects. Concurrently, there has been a move to more complicated materials systems in order to meet health and environmental guidelines. These trends of reducing size, increasing loads have increased the necessity to understand the mechanisms of the failure. ^ As the length scales are reduced, it becomes increasingly important to consider interfacial and micro-structural effects that can be safely ignored at larger length scales owing to the …


Team Nathan Suspension, Frankie J. Wiggins, Alex D. Seitz, Justin P. Bautista 2014 California Polytechnic State University - San Luis Obispo

Team Nathan Suspension, Frankie J. Wiggins, Alex D. Seitz, Justin P. Bautista

Mechanical Engineering

Nathan Cooper is an 8-year old boy with Spinal Muscular Atrophy (SMA). SMA has affected Nathan’s muscle development and requires him to use the Standing Dani™ mobility device. The Standing Dani is a motorized standing wheelchair, or Wheelstand. Nathan controls and uses it to get around. Though the Standing Dani performs well for most functions, it has some distinct issues. The primary issue that this project addresses is its lack of suspension and the discomfort that Nathan feels as a result. After talking with our client, we developed several specifications generally related to geometry, safety, vehicle dynamics, and reliability. Many …


Microstructure Development Of Granular System During Compaction, Chen Shang, Marcial Gonzalez 2014 Purdue University

Microstructure Development Of Granular System During Compaction, Chen Shang, Marcial Gonzalez

The Summer Undergraduate Research Fellowship (SURF) Symposium

Granular materials is the second most manipulated material in the industry today. They are easy to transport and more and more newly developed materials cannot stand the process of traditional casting, like energetic materials and bio-materials, but will survive the powder compaction process. Having a better understanding of the microstructure development of granular systems during compaction process, especially for particles that will heavily deform under loading, will give an insight of how to better process the powders to produce materials with overall better performance comparing to bulk materials. The main theory and mechanism applied are Hertz law and nonlocal contact …


Atomistic Simulation And Virtual Diffraction Characterization Of Alumina Interfaces: Evaluating Structure And Stability For Predictive Physical Vapor Deposition Models, Shawn Patrick Coleman 2014 University of Arkansas, Fayetteville

Atomistic Simulation And Virtual Diffraction Characterization Of Alumina Interfaces: Evaluating Structure And Stability For Predictive Physical Vapor Deposition Models, Shawn Patrick Coleman

Graduate Theses and Dissertations

The objectives of this work are to investigate the structure and energetic stability of different alumina (Al2O3) phases using atomistic simulation and virtual diffraction characterization. To meet these objectives, this research performs molecular statics and molecular dynamics simulations employing the reactive force-field (ReaxFF) potential to model bulk, interface, and surface structures in the θ-, γ-, κ-, and α-Al2O3 system. Simulations throughout this study are characterized using a new virtual diffraction algorithm, developed and implemented for this work, that creates both selected area electron diffraction (SAED) and x-ray diffraction (XRD) line profiles without assuming …


Electroencephalography(Eeg) Data Collection And Processing Through Machine Learning, Jayshree Desai 2014 University of Arkansas, Fayetteville

Electroencephalography(Eeg) Data Collection And Processing Through Machine Learning, Jayshree Desai

Graduate Theses and Dissertations

Machine learning methods are an excellent way for understanding the neural basis of human decision making. Some machine learning systems try to eradicate the need for human intuition in data analysis whereas others embrace a collective approach between humans and machines. The objective of this project is to collect Electroencephalography (EEG) signals through wireless sensors, and the process the collected signals through machine learning methods. The EEG data is collected using three EEG electrodes, each being the positive, negative and ground terminals respectively. Since the signal measures in the unit of micro-volts it needs to be amplified using amplifier circuit. …


Understanding The Effects Of Blast Wave On The Intracranial Pressure And Traumatic Brain Injury In Rodents And Humans Using Experimental Shock Tube And Numerical Simulations, Aravind Sundaramurthy 2014 University of Nebraska-Lincoln

Understanding The Effects Of Blast Wave On The Intracranial Pressure And Traumatic Brain Injury In Rodents And Humans Using Experimental Shock Tube And Numerical Simulations, Aravind Sundaramurthy

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Blast induced neurotrauma (BINT) has been designated as the “signature injury” to warfighters in the recent military conflicts. In the past decade, conflicts in Iraq (operation Iraqi freedom) and Afghanistan (operation enduring freedom) as well as the increasing burden of the terrorism around the world resulted in an increased number of cases with blast Traumatic Brain Injury (bTBI). Recently, a lot of research has been done to study the neurological and neurochemical degenerations resulting from BINT using animal models especially rat models. However, it is not clear how and whether the biological outcomes from animal models can be translated to …


Transverse Compression Of High-Performance Ballistic Fibers, Zherui Guo 2014 Purdue University

Transverse Compression Of High-Performance Ballistic Fibers, Zherui Guo

Open Access Theses

High performance ballistic fibers have been in use for decades, specifically in protective applications against ballistic impact such as bulletproof vest layers and aircraft turbine engine fragmentation barriers. These high performance fibers have extremely high strength-to-weight ratios and high moduli of elasticity in the axial direction, making them extremely suitable for high impact situations. In particular, para-phenyleneterephthalamide (PPTA for short) fibers such as Kevlar® and ultra-high-molecular-weight polyethylene fibers such as Dyneema® are amongst the more popular high performance fibers in today's world. While the longitudinal mechanical response of these fibers have been extensively researched, their transverse mechanical response …


Meshless Mechanics And Point-Based Visualization Methods For Surgical Simulations, Rifat Aras 2014 Old Dominion University

Meshless Mechanics And Point-Based Visualization Methods For Surgical Simulations, Rifat Aras

Computational Modeling & Simulation Engineering Theses & Dissertations

Computer-based modeling and simulation practices have become an integral part of the medical education field. For surgical simulation applications, realistic constitutive modeling of soft tissue is considered to be one of the most challenging aspects of the problem, because biomechanical soft-tissue models need to reflect the correct elastic response, have to be efficient in order to run at interactive simulation rates, and be able to support operations such as cuts and sutures.

Mesh-based solutions, where the connections between the individual degrees of freedom (DoF) are defined explicitly, have been the traditional choice to approach these problems. However, when the problem …


An Experimental Fatigue And Finite Element Study Of A Welded Joint Of A Snowplow Blade, George Ernest Selburg 2014 Marquette University

An Experimental Fatigue And Finite Element Study Of A Welded Joint Of A Snowplow Blade, George Ernest Selburg

Master's Theses (2009 -)

This study describes a method to evaluate the fatigue life of a welded joint of a snowplow. Fatigue specimens were then fabricated, which simulated the joint and its loading characteristics. The joint in the specimens were characterized by measuring the geometry of the weld and the hardness of the parent material, weld material, and heat affected zone. It was determined that the fatigue crack that developed in the joint was exposed to mode I fracture forces in the normal plane of the crack. The specimens were then tested in a hydraulic closed looped system to determine the mechanism of fatigue …


Phonon Confinement Using Spirally Designed Elastic Resonators In Discrete Continuum, Sourav Banerjee, Raiz U. Ahmed 2014 University of South Carolina, United States

Phonon Confinement Using Spirally Designed Elastic Resonators In Discrete Continuum, Sourav Banerjee, Raiz U. Ahmed

Faculty Publications

Periodic and chiral orientation of microstructures, here we call phononic crystals, have extraordinary capabilities to facilitate the innovative design of new generation metamaterials. Periodic arrangements of phononic crystals are capable of opening portals of non-passing, non-dispersive mechanical waves. Defying conventional design of regular periodicity, in this paper spirally periodic but chiral orientation of resonators are envisioned. Dynamics of the spirally connected resonators and the acoustic wave propagation through the spirally connected multiple local resonators are studied using fundamental physics. In present study the spiral systems with local resonators are assumed to be discrete media immersed in fluid. In this paper …


Redox Stable Anodes For Solid Oxide Fuel Cells, Guoliang Xiao, Fanglin Chen 2014 University of South Carolina - Columbia

Redox Stable Anodes For Solid Oxide Fuel Cells, Guoliang Xiao, Fanglin Chen

Faculty Publications

Solid oxide fuel cells (SOFCs) can convert chemical energy from the fuel directly to electrical energy with high efficiency and fuel flexibility. Ni-based cermets have been the most widely adopted anode for SOFCs. However, the conventional Ni-based anode has low tolerance to sulfur-contamination, is vulnerable to deactivation by carbon build-up (coking) from direct oxidation of hydrocarbon fuels, and suffers volume instability upon redox cycling. Among these limitations, the redox instability of the anode is particularly important and has been intensively studied since the SOFC anode may experience redox cycling during fuel cell operations even with the ideal pure hydrogen as …


Folding Wheelchair Improvement, Matthew Edison Grace, Kevin Alan Miyamoto, Andrey Lee Oliveira 2014 California Polytechnic State University - San Luis Obispo

Folding Wheelchair Improvement, Matthew Edison Grace, Kevin Alan Miyamoto, Andrey Lee Oliveira

Mechanical Engineering

No abstract provided.


Friction Test Machine, Kyle Raymon Schless, Lynda Beatriz Tesillo, Mustapha Nadri 2014 California Polytechnic State University - San Luis Obispo

Friction Test Machine, Kyle Raymon Schless, Lynda Beatriz Tesillo, Mustapha Nadri

Mechanical Engineering

No abstract provided.


Lightweight Uav Launcher, Ben Miller, Christian Valoria, Corinne Warnock, Jake Coutlee 2014 California Polytechnic State University - San Luis Obispo

Lightweight Uav Launcher, Ben Miller, Christian Valoria, Corinne Warnock, Jake Coutlee

Mechanical Engineering

This report discusses the design, construction, and testing of a lightweight, portable UAV launcher. There is a current need for a small team of soldiers to launch a US Marine Tier II UAV in a remote location without transport. Research was conducted into existing UAV launcher designs and the pros and cons of each were recorded. This research served as a basis for concept generation during the initial design development stage. It was required that the design weigh less than 110 lbs, occupy a smaller volume than 48" x 24" 18" in its collapsed state, be portable by a single …


Formula Sae Hybrid Carbon Fiber Monocoque / Steel Tube Frame Chassis, Matthew Hagan, John Rappolt, John Waldrop 2014 California Polytechnic State University - San Luis Obispo

Formula Sae Hybrid Carbon Fiber Monocoque / Steel Tube Frame Chassis, Matthew Hagan, John Rappolt, John Waldrop

Mechanical Engineering

The Cal Poly Formula SAE Team created this project in order to design and fabricate a high-performance chassis which would be competitive at 2013 FSAE Lincoln, and to document the process so that future teams could more easily create a chassis. One of the main goals was to reduce weight from the 143- lb 2012 chassis subsystem. A weight of 95 lb was achieved, with 82 lb in the chassis structure itself and a predicted torsional stiffness of 1700 lb*ft/deg. Composite materials design and manufacturing techniques were developed during the project. Design, testing, and manufacturing processes are detailed, and results …


Automated Foosball Table, Jim R. Stefani, Alex J. Herpy, Brett Gordon Jaeger, Kevin S. Haydon, Derek Alan Hamel 2014 California Polytechnic State University - San Luis Obispo

Automated Foosball Table, Jim R. Stefani, Alex J. Herpy, Brett Gordon Jaeger, Kevin S. Haydon, Derek Alan Hamel

Mechanical Engineering

This project is the second iteration of an automated foosball table for Yaskawa America as a trade show display. The table is meant to provide an interactive experience which highlights the speed and precision of the Yaskawa hardware. The first iteration of the project was mainly focused on creating the physical hardware for the system and to begin the basic programming for the system. This phase of the project was focused on finalizing the physical hardware of the system, implementing the vision system and to continue the basic programing of the system AI. A third team will be assigned to …


Modification Of A Draw Bar Type Arena Harrow To Three Point Mounted Type Harrow, Clayton Alan Brown 2014 California Polytechnic State University, San Luis Obispo

Modification Of A Draw Bar Type Arena Harrow To Three Point Mounted Type Harrow, Clayton Alan Brown

BioResource and Agricultural Engineering

This senior project will be the design, and construction of a three point hitch to be attached to a draw bar type spike tooth harrow. Currently used by the Cal Poly Rodeo Team to cultivate their arena before performances, and practices.

The attachment will allow the harrow to be pulled in both directions to create different types of soil affects.

Also the fabrications has a minimal budget so the majority of the materials will be scrap material already in position of the rodeo team or donated to the project.


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