Applied Mechanics Commons^™

La0.7Sr0.3Fe0.7Ga0.3O3-Δ As Electrode Material For A Symmetrical Solid Oxide Fuel Cell, Zhibin Yang, Yu Chen, Chao Jin, Guoliang Xiao, Minfang Han, Fanglin Chen

Faculty Publications

In this research, La_0.7Sr_0.3Fe_0.7Ga_0.3O_3−δ (LSFG) perovskite oxide was successfully prepared using a microwave-assisted combustion method, and employed as both anode and cathode in symmetrical solid oxide fuel cells. A maximum power density of 489 mW cm⁻² was achieved at 800 °C with wet H₂ as the fuel and ambient air as the oxidant in a single cell with the configuration LSFG|La_0.8Sr_0.2Ga_0.83Mg_0.17O_3−δ|LSFG. Furthermore, the cells demonstrated good stability in H₂ and acceptable sulfur tolerance.

La0.6Sr1.4Mno4+Δ Layered Perovskite Oxide: Enhanced Catalytic Activity For The Oxygen Reduction Reaction, Yarong Wang, Zhibin Yang, Fanliang Liu, Chao Jin, Jiao Wu, Ming Shen, Ruizhi Yang, Fanglin Chen

Faculty Publications

Efficient electrocatalysts for the oxygen reduction reaction (ORR) is a critical factor to influence the performance of lithium–oxygen batteries. In this study, La_0.6Sr_1.4MnO_4+δ layered perovskite oxide as a highly active electrocatalyst for the ORR has been prepared, and a carbon-coating layer with thickness <5 nm has been successfully introduced to enhance the electronic conductivity of the as-prepared oxide. XRD, XPS, Raman, SEM and TEM measurements were carried out to characterize the crystalline structure and morphology of these samples. Rotating ring-disk electrode (RRDE) technique has been used to study catalytic activities of the as-prepared catalysts for the ORR in 0.1 M KOH media. RRDE results reveal that carbon-coated La_0.6Sr_1.4MnO_4+δ exhibits better catalytic activity for the ORR. For the carbon-coated La_0.6Sr_1.4MnO_4+δ, the ORR proceeds predominately via a direct four electron process, and a maximum cathodic current density of 6.70 mA cm⁻² at 2500 rpm has been obtained, …

Effects Of Magnetic Field On The Shape Memory Behavior Of Single And Polycrystalline Magnetic Shape Memory Alloys, Ali S. Turabi

Theses and Dissertations--Mechanical and Aerospace Engineering

Magnetic Shape Memory Alloys (MSMAs) have the unique ability to change their shape within a magnetic field, or in the presence of stress and a change in temperature. MSMAs have been widely investigated in the past decade due to their ability to demonstrate large magnetic field induced strain and higher frequency response than conventional shape memory alloys (SMAs). NiMn-based alloys are the workhorse of metamagnetic shape memory alloys since they are able to exhibit magnetic field induced phase transformation. In these alloys, martensite and austenite phases have different magnetization behavior, such as the parent phase can be ferromagnetic and martensite …

High Temperature Flow Solver For Aerothermodynamics Problems, Huaibao Zhang

Theses and Dissertations--Mechanical and Aerospace Engineering

A weakly ionized hypersonic flow solver for the simulation of reentry flow is firstly developed at the University of Kentucky. This code is the fluid dynamics module of known as Kentucky Aerothermodynamics and Thermal Response System (KATS). The solver uses a second-order finite volume approach to solve the laminar Navier– Stokes equations, species mass conservation and energy balance equations for flow in chemical and thermal non-equilibrium state, and a fully implicit first-order backward Euler method for the time integration. The hypersonic flow solver is then extended to account for very low Mach number flow using the preconditioning and switch of …

Shape Memory Behavior Of Single Crystal And Polycrystalline Ni-Rich Nitihf High Temperature Shape Memory Alloys, Sayed M. Saghaian

Theses and Dissertations--Mechanical and Aerospace Engineering

NiTiHf shape memory alloys have been receiving considerable attention for high temperature and high strength applications since they could have transformation temperatures above 100 °C, shape memory effect under high stress (above 500 MPa) and superelasticity at high temperatures. Moreover, their shape memory properties can be tailored by microstructural engineering. However, NiTiHf alloys have some drawbacks such as low ductility and high work hardening in stress induced martensite transformation region. In order to overcome these limitations, studies have been focused on microstructural engineering by aging, alloying and processing.

Shape memory properties and microstructure of four Ni-rich NiTiHf alloys (Ni50.3Ti29.7Hf20, Ni50.7Ti29.3Hf20, …

2015 Zips Sae Baja Brakes And Throttle System, Philip A. Bennett

Williams Honors College, Honors Research Projects

The SAE Baja student design team at The University of Akron is one of the longest-standing design teams at the university. The purpose of this team is to design, manufacture, test, and race an off-road vehicle within the guidelines of competition established by the Society of Automotive Engineers. The vehicle is made up of a small number of subsystems including frame, drivetrain, suspension, steering, and braking. The following will discuss all aspects of the design process of the braking and throttle system of the 2015 Zips Baja car. This process includes several steps and considerations such as design goals, system …

Design Of An Sae Baja Racing Off-Road Vehicle Powertrain, Eric T. Payne

Williams Honors College, Honors Research Projects

No abstract provided.

Structure-Thermal Coupling In Viscoelastic Material In Rubber Bushing Of Vehicle System, Zhengui Zhang

Open Access Dissertations

The objective of this research is to utilize the frequency-dependent viscoelastic material model and characterize the dynamic response of rubber bushing under external excitation. Furthermore, with appropriate modeling, two heat generation mechanisms of rubber bushing are explored and their thermal fields are investigated. Due to the nonlinear force-deflection relationship of the viscoelastic material, finding satisfactory mechanical properties of rubber components still poses a great challenge. However, industry nowadays is in urgent demand for precise finite element analysis (FEA) modeling of rubber components. For example, a proper constitutive relationship of rubber components is critical to providing a reliable and trustable simulation …

Mechanistic Modeling Of Cutting Forces In Wavy-Edge Bull-Nose Helical End-Milling Of Inconel 718 Under Different Cooling-Lubrication Strategies, Abdulhakim Ali Sultan

Doctoral Dissertations

“This research presents the results of the development of a mechanistic cutting force prediction model for the wavy-edge bull-nose helical endmill (WEBNHE). The mechanistic model was developed to predict cutting force components and the resultant cutting force in high-speed end-milling of Inconel 718 under two cooling strategies: emulsion and Minimum Quantity Lubrication (MQL). The effects of the cooling strategies are incorporated into the mechanistic model through six cutting force coefficients (K_tc, K_rc, K_ac), and edge force coefficients (K_te, K_re, K_ae), which have been experimentally identified in a separate …

Influence Of Spatial Variations Of Railroad Track Stiffness And Material Inclusions On Fatigue Life, Celestin Nkundineza

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Railroad transportation is very important for economic growth and effective maintenance is one critical factor for its economic sustainability. The high repetitive forces from a moving railcar induce cyclic stresses that lead to rail bending and potential deterioration due to fatigue crack initiation and propagation. Previous research for prediction of fatigue life has been done under the assumptions of a uniform track bed and a homogeneous rail. However the spatial variation of the track stiffness is expected to increase the maximum stresses in the rail and, therefore, accelerate the fatigue process. The research described in this dissertation is focused on …

Modal Characterization And Structural Dynamic Response Of A Crane Fly Forewing, Jose E. Rubio

LSU New Orleans Theses and Dissertations

This study describes a method for conducting the structural dynamic analysis of a crane fly (family Tipulidae) forewing under different airflow conditions. Wing geometry is captured via micro-computed tomography scanning. A finite element model of the forewing is developed from the reconstructed model of the scan. The finite element model is validated by comparing the natural frequencies of an elliptical membrane with similar dimensions of the crane fly forewing to its analytical solution. Furthermore, a simulation of the fluid-structure interaction of the forewing under different airflows is performed by coupling the finite element model of the wing with a …

Investigation Of The Quenching Characteristics Of Steel Components By Static And Dynamic Analyses, Pratik Sarker

LSU New Orleans Theses and Dissertations

Machine components made of steel are subjected to heat treatment processes for improving mechanical properties in order to enhance product life and is usually done by quenching. During quenching, heat is transferred rapidly from the hot metal component to the quenchant and that rapid temperature drop induces phase transformation in the metal component. As a result, quenching generates some residual stresses and deformations in the material. Therefore, to estimate the temperature distribution, residual stress, and deformation computationally; three-dimensional finite element models are developed for two different steel components – a spur gear and a circular tube by a static and …

Utilizing Failure Information For Mission Assessment And Optimization For Complex Systems, Charlie Destefano

Graduate Theses and Dissertations

This paper presents a new failure analysis method, Failure Identification for Mission Analysis (FIMA), which performs a general failure analysis for the overall state of a system, as well as a mission-specific analysis that identifies how failures may have differing effects on the various mission tasks that a system must complete. The FIMA method is capable of being implemented at any point in the design process. During early design stages, the FIMA method will identify various qualitative failure scenarios based on programmed functional relationships and any number of initial failures wished to be simulated. The functional relationships for this method …

Cold Roll Extrusion Machine Redesign Final Design Report, Foja Bains, Bryan Cyr, David Van Schooten

Mechanical Engineering

This report is a comprehensive review of a redesign of subsystems for a Cold Roll Extrusion Machine, a forging operation, for PCC Rollmet. Three subsystems were addressed in this project: A new Loading system, Feed system, and Lubrication system. The Loading system, and support system during developmental design stages, addressed the timely loading process of pipes onto the forging machine. After two quarters of design iteration, the group decided on a lever arm, hydraulic actuated, loading design. In the final quarter of the project, a quarter scale model of this lever arm was constructed to prove the concept of the …

Direct Synthesis Of Methane From Co2-H2O Co-Electrolysis In Tubular Solid Oxide Electrolysis Cells, Long Chen, Fanglin Chen, Changrong Xia

Faculty Publications

Directly converting CO₂ to hydrocarbons offers a potential route for carbon-neutral energy technologies. Here we report a novel design, integrating the high-temperature CO₂–H₂O co-electrolysis and low-temperature Fischer–Tropsch synthesis in a single tubular unit, for the direct synthesis of methane from CO₂ with a substantial yield of 11.84%.

Highly Transparent, Self-Cleaning, And Antireflective Nanoparticle Coatings, Corey Seth Thompson

Graduate Theses and Dissertations

Current solar panel technologies require a sheet of glass to serve as both mechanical support and to protect the cells from the environment. The reflection from the glass sheet can reflect up to 8% of the incident light, reducing the power output of the panel. Antireflective coatings can be used to allow more light to enter the panel to be converted into usable electricity. However, no solid thin film materials exhibit a low enough index of refraction to serve as antireflective coatings for common solar glass. The main goal of this research was to investigate the self-cleaning, antifogging, and antireflective …

Synthesis And Formation Mechanism Of Cuins2 Nanocrystals With A Tunable Phase, Chao Yu, Linlin Zhang, Long Tian, Dan Liu, Fanglin Chen, Cheng Wang

Faculty Publications

Chalcopyrite CuInS₂ (CIS) hierarchical structures composed of nanoflakes with a thickness of about 5 nm were synthesized by a facial solvothermal method. The thermodynamically metastable wurtzite phase CIS would be obtained by using InCl₃ instead of In(NO₃)₃ as In precursor. The effects of the In precursor and the volume of concentrated HCl aqueous solution on the phases and morphologies of CIS nanocrystals have been systematically investigated. Experimental results indicated that the obtained phases of CIS nanocrystals were predominantly determined by precursor-induced intermediate products. The photocatalytic properties of chalcopyrite and wurtzite CIS in visible-light-driven degradation of …

Host-Guest Interaction Dictated Selective Adsorption And Fluorescence Quenching Of A Luminescent Lightweight Metal-Organic Framework Toward Liquid Explosives, Dan Liu, Xiaojuan Liu, Yongxin Liu, Yang Yu, Fanglin Chen, Cheng Wang

Faculty Publications

In this article, we report the successful preparation of a Mg-based luminescent MIL-53 metal–organic framework (MOF), namely [Mg2(BDC)2(BPNO)]·2DMF (1) (BDC = 1,4-benzene dicarboxylate, BPNO = 4,4’- dipyridyl-N,N’-dioxide, DMF = N,N-dimethylformamide) in a mixed solvent containing a 2 : 3 volume ratio of DMF and ethanol (EtOH) under solvothermal conditions. Desolvated compound 1a can be used as an absorbent for selective adsorption and separation of liquid explosives, including nitroaromatic (nitrobenzene (NB)) and nitroaliphatic (nitromethane (NM) and nitroethane (NE)) compounds, through single crystal-to-single crystal (SC–SC) transformations. As one of the weakly luminescent MOFs, the luminescence of compound 1a could be quenched by …

Simulations Of Diffusion Driven Phase Evolution In Heterogenous Solids, Subramanya Gautam Sadasiva

Open Access Dissertations

With reduction in size, ever greater operational demands are placed on electronics components at all levels of the device, starting from the transistor level to the level of the package and the solder interconnects. Concurrently, there has been a move to more complicated materials systems in order to meet health and environmental guidelines. These trends of reducing size, increasing loads have increased the necessity to understand the mechanisms of the failure. ^ As the length scales are reduced, it becomes increasingly important to consider interfacial and micro-structural effects that can be safely ignored at larger length scales owing to the …

Team Nathan Suspension, Frankie J. Wiggins, Alex D. Seitz, Justin P. Bautista

Mechanical Engineering

Nathan Cooper is an 8-year old boy with Spinal Muscular Atrophy (SMA). SMA has affected Nathan’s muscle development and requires him to use the Standing Dani™ mobility device. The Standing Dani is a motorized standing wheelchair, or Wheelstand. Nathan controls and uses it to get around. Though the Standing Dani performs well for most functions, it has some distinct issues. The primary issue that this project addresses is its lack of suspension and the discomfort that Nathan feels as a result. After talking with our client, we developed several specifications generally related to geometry, safety, vehicle dynamics, and reliability. Many …