Materials Science and Engineering Commons^™

Layer-By-Layer Assembly Of {Nanoclay-(Sol-Gel Oxide)}N And {Nanoclay-(Oxide Nanoparticle)}N Multilayers: Synthesis And Growth Mechanisms, Hao Chen

All Dissertations

Two new classes of all-inorganic nanostructured multilayers, {MMTx-(sol-gel oxide)}n and {MMTx-(oxide nanoparticle)}n, have been successfully synthesized for the first time. They were made by adapting a layer-by-layer (LbL) assembly method initially developed to synthesize polyelectrolyte-based multilayers. In most previous studies, this electrostatic-assisted LbL assembly method used polyelectrolytes/polymers as the 'structural glue' to prepare multilayers. The synthesis of {MMTx-(sol-gel ZrO2)}n multilayers demonstrates for the first time the feasibility of making sol-gel oxide 'glued' all-inorganic multilayers, thereby introducing an innovative nanoscale fabrication concept. The synthesis of {MMTx-(oxide nanoparticle)}n multilayers further illustrates the versatility of LbL assembly technique by achieving a second new …

Grain Boundary Premelting And Activated Sintering In Binary Refractory Alloys, Xiaomeng Shi

All Dissertations

Quasi-liquid intergranular film (IGF) which has been widely observed in ceramic systems can persist into sub-solidus region whereby an analogy to Grain boundary (GB) premelting can be made.
In this work, a grain boundary (GB) premelting/prewetting model in a metallic system was firstly built based on the Benedictus' model and computational thermodynamics, predicting that GB disordering can start at 60-85% of the bulk solidus temperatures in selected systems. This model quantitatively explains the long-standing mystery of subsolidus activated sintering in W-Pd, W-Ni, W-Co, W-Fe and W-Cu, and it has broad applications for understanding GB-controlled transport kinetics and physical properties. Furthermore, …

Performance Of Nevada’S Aggregates In Alkali-Aggregate Reactivity Of Portland Cement Concrete, Mohammad Shahidul Islam

UNLV Theses, Dissertations, Professional Papers, and Capstones

Alkali-aggregate reaction (AAR) is a form of distress that occurs in concrete and results in serviceability problems, cracks, spalling, and other deterioration mechanisms. There are two categories of AAR, namely, alkali-silica reaction (ASR) and alkali-carbonate reaction (ACR). Alkali-silica reaction is one of the most recognized deleterious phenomena in concrete, and has been a major concern since its discovery in the 1940s. The reaction which occurs between reactive silica or silicates present in some aggregates and alkalis of Portland cement produces an alkali-silica gel that expands in the presence of moisture resulting in concrete cracks. ACR is also a chemical reaction …

Mechanical Behavior Of Alloy 230 At Temperatures Relevant To Ngnp Program, Sudin Chatterjee

UNLV Theses, Dissertations, Professional Papers, and Capstones

Identification and selection of suitable structural materials for heat exchanger application within the purview of the next generation nuclear plant (NGNP) program constitute a major challenge. This challenge stems from the lack of many desired metallurgical and mechanical properties of conventional metallic materials and alloys for applications at temperatures approaching 950 oC. Nickel (Ni)-base Alloy 230 has been highly recommended as a suitable structural material for such application due to its excellent resistance to high-temperature plastic deformation and superior corrosion resistance in many hostile environments. Systematic studies on tensile, fracture toughness, creep, stress-rupture and creep-fatigue behavior of this alloy have …

Characterization And Modification Of Helmet Padding System To Improve Shockwave Dissipation, Katelyn Howay

All Theses

Currently soldiers are being exposed a much higher number of improvised explosive devices (IEDs) and the resulting shockwaves. These shockwaves can cause traumatic brain injuries (TBIs) even without the occurrence of ballistic impact. The focus of this research was to reduce the amount of shockwaves soldiers are exposed to by inserting fibers and woven fabrics into a foam padding system. These fibers and fabrics facilitate the dissipation of the shockwave energy before it is able to penetrate the padding and cause TBIs.
The sound velocity of high-performance fibers, commodity fibers and woven fabric was measured using a Dynamic Modulus Tester. …

Hydrogen Fuel Cell Analysis: Lessons Learned From Stationary Power Generation Final Report, Scott E. Grasman, John W. Sheffield, Fatih Dogan, Sunggyu Lee, Umit O. Koylu, Angie Rolufs

Materials Science and Engineering Faculty Research & Creative Works

This study considered opportunities for hydrogen in stationary applications in order to make recommendations related to RD&D strategies that incorporate lessons learned and best practices from relevant national and international stationary power efforts, as well as cost and environmental modeling of pathways. The study analyzed the different strategies utilized in power generation systems and identified the different challenges and opportunities for producing and using hydrogen as an energy carrier. Specific objectives included both a synopsis/critical analysis of lessons learned from previous stationary power programs and recommendations for a strategy for hydrogen infrastructure deployment. This strategy incorporates all hydrogen pathways and …

Investigation Of Creep Threshold Stresses Using In Situ Tem Straining Experiment In An Al-5y2o3-10sic Composite, S. P. Deshmukh, Rajiv S. Mishra, I. M. Robertson

Materials Science and Engineering Faculty Research & Creative Works

Creep behavior of metal matrix composites is similar to dispersion strengthen alloys and characterized by the presence of a threshold stress below which the creep rate is negligible. This threshold stress is attributed, at least in dispersion-strengthened alloys, to dislocation particle interactions in which the detachment of the dislocations from the particle is the rate-limiting step. Creep experiments were performed on an Al-5Y₂O₃-10SiC composite in the temperature range of 473 and 573 K and the nature of the dislocation-particle interaction was determined by performing in situ straining experiments at elevated temperature in a transmission electron microscope. …

Crosslinked Conventional Size And Nanoparticle Size Acrylic Latexes And Their Blends: Investigation Of The Effects Of Crosslinking, Particle Size And Distribution, Glass Transition Temperature And Blending On Film Formation, Properties And Morphology, Ravi Ghanshyambhai Joshi

Master's Theses and Doctoral Dissertations

Synthetic latexes have many product applications including functioning as a binder in paints and coatings. For many years, researchers in industry as well as in academe have been exploring various strategies to improve performance of acrylic latexes mainly to replace traditionally used solvent borne coatings due to increasing environmental concerns and strict governmental regulations. The main goal of the study is to investigate the effects of type (pre-coalescence or post-coalescence) and level of crosslinking, particle size (nano particle size ~ 20-25 nm vs. conventional particle size ~ 120-130 nm) and distribution, glass transition temperature (Tg), and blending on latex film …

Analysis Of Conjugated Polymer Nanotubules Formed By Template Wetting Nanofabrication, Steven D. Bearden Jr.

Doctoral Dissertations

Semiconducting and optoelectric conjugated polymers have potential in micro and nano-electronic applications. Their widely tunable physical conformations and orientations make these polymers ideal material for engineering small scale devices. The polymers have been incorporated into several electronic devices including light-emitting diodes, solar cells, and field-effect transistors. Widespread adoption of these materials will not be a reality until the issues of poor device performance, short lifespans, and device degradation are resolved.

Nanostructures have been demonstrated to have improvements in molecular ordering and electronic transport. In the work presented here, tubular nanostructures of conjugated polymers fabricated by the template wetting nanofabrication process …

Section Abstracts: Astronomy, Mathematics, And Physics & Materials Science

Virginia Journal of Science

Abstracts of papers of the Astronomy, Mathematics, and Physics (Including Materials Science) Section for the 88th Annual Meeting of the Virginia Academy of Science, May 20-21, 2010, James Madison University, Harrisonburg, VA.

Ontology-Based Automatic Classification For News Articles In Indonesian Language, Prajna Wira Basnur, Dana Indra Sensuse

Makara Journal of Technology

Ontology-Based Automatic Classification for News Articles in Indonesian Language. Searching specific information will be difficult if relying only on query. Choosing less specific queries will result in a lot of irrelevant information fetched by the system. One of the most successful ways to overcome this problem is to perform document classification based on the topic. There are many methods that can be used to conduct such a classification, such as using statistical and machine learning approaches. However, those document classification methods require training the data or learning the documents. In this study, the authors attempted to classify documents using a …

Recent Advances In High Density Area Array Interconnect Bonding For 3d Integration, J. M. Lannon, J., C. Gregory, M. Lueck, A. Huffman, D. Temple, Amy J. Moll, William B. Knowlton

Materials Science and Engineering Faculty Publications and Presentations

The demand for more complex and multifunctional micro systems with enhanced performance characteristics for military applications is driving the electronics industry toward the use of best-of-breed materials and device technologies. Threedimensional (3-D) integration provides a way to build complex microsystems through bonding and interconnection of individually optimized device layers without compromising system performance and fabrication yield. Bonding of device layers can be achieved through polymer bonding or metal-metal interconnect bonding with a number of metalmetal systems. RTI has been investigating and characterizing Cu-Cu and CulSn-Cu processes for high density area array imaging applications, demonstrating high yield bonding between sub-I5 11m …

Palm Oil-Based Polyester Binder For Making Fiberboards., Wong Yew Chuan

Student Works (2010-2019)

Palm kernel oil was used as a raw material for the synthesis of polyester polyol.The palm oil based polyester polyol was synthesized using glycerol, phthalic anhydride and fumaric acid. Palm oil based polyester polyol combines with methylene diphenyl diisocyanate (MDI) to form the polyurethane binder. The fibers are derived from empty fruit bunch (EFB) of the palm tree and have the acceptable mechanical properties. In this project, palm fibers were converted into palm fiberboards by using polyurethane (PU) binder under specified pressure and temperature. The binder to fiber ratio was varied from 10% to 30 % by dried weight of …

Synthesis Of Chemically Produced Toner (Cpt) By Emulsion Aggregation Process., Ng Wei Goon

Student Works (2010-2019)

This project studied the full process of producing Chemically Produced Toner (CPT) used in laser printer. Latex particles of 0.40 to 0.60 μm were prepared by semicontinuous emulsion polymerization process. A series of latexes was made from the copolymerization of styrene, butyl acrylate and acrylic acid monomers in the presence of surfactants Dowfax 2A1 (anionic) and Ipegal 897 (non-ionic) surfactants with potassium persulphate as the initiator. The addition of different percentage of chain transfer agent (CTA), 1-dodecanethiol was used to control the molecular weight distribution. As the percentage of CTA was increased, the molecular weight and glass transition temperature decreased …

Preparation Of Styrene Acrylic Copolymer Toner Resin By Solution Polymerization., Neo Su Siang

Student Works (2010-2019)

This project has investigated solution polymerization to produce toner resins. There are three stages: (i) synthesis of low molecular weight styrene acrylic copolymer; (ii) synthesis of high molecular weight styrene acrylic copolymer; (iii) mixing high and low molecular weight copolymers. Gel Permeation Chromatography (GPC) was used to study molecular weight distributions, Melt Flow Index (MFI) Instrument to study the flowability of resin, Differential Scanning Calorimetry (DSC) to study the thermal properties of resin, and acid number to quantitate the amount of acidic group in the resin. A comparison of properties between the experimental samples, patent’s claims, and commercial resins had …

A Simple Technique For Surface Area Determination Through Supercritical Co2 Adsorption, Mahmud Sudibandriyo

Makara Journal of Technology

The measurement of specific surface area of porous materials has long been important in physical sciences and is currently growing in importance in applied and environmental science. Numerous systems have been developed for surface area measurement by gas adsorption. Commercial systems are available which can measure a wide range of absolute surface area with relative ease. However, their cost is often prohibitive. In this study, an inexpensive apparatus for surface area measurement has been set up to be used for measuring supercritical adsorption of CO2. The Ono-Kondo Lattice model was used to represent the adsorption isotherm and to determine the …

Fishing Catch And Catch Rate Assesment Of Mini Trawl, Trapnet And Setnet Fisheries, Muhammad Firdaus

Makara Journal of Technology

Fishing Catch and Catch Rate Assesment of Mini Trawl, Trapnet and Setnet Fisheries. This paper is aimed at assessing fishing catch and catch rate of the dragged gear on shrimp, trapnet, and setnet fisheries in Tarakan. The catch and effort data (number and species) and the fishing time of captured units were used in this qualitative analysis of fishing catch and catch rate to describe catch composition and catch rate from three catch fishery units in Tarakan. The result of the research shows that in the catching operation the dragged gear on shrimp has two main catch targets, which are …

Light-Activation Influence On The Thermal Analysis Of A Resin-Modified Glass-Ionomer, Raksha Srinivas

Master's Theses (2009 -)

The acid-base and light polymerization reactions in resin modified glass ionomers (RMGI) have been shown to compete and possibly inhibit one another during early RMGI development. Earlier beginning times of light polymerization initiation may limit the acid-base reaction and if time allowed for the acid-base components to react is increased, the extent of light cure reaction may be lesser. The thermal behavior of a commercially available RMGI was investigated in relation to a light initiation regimen using a differential scanning calorimeter (DSC). The relationship between delay in light initiation or no light initiation and the resultant set matrix of the …

Particle Filter With Binary Gaussian Weighting And Support Vector Machine For Human Pose Interpretation, Indah Agustien, Muhammad Rahmat Widyanto, Sukmawati Nur Endah, Tarzan Basaruddin

Makara Journal of Technology

This paper proposes human pose interpretation using particle filter (PF) with Binary Gaussian Weighting and support vector machine (SVM). In the proposed system, particle filter is used to track a human object, then this human object is skeletonized using thinning algorithm and classified using SVM. The classification is to identify human pose, whether it is normal or abnormal behavior. Here particle filter is modified through weight calculation using Gaussian distribution to reduce the computational time. The modified particle filter consists of four main phases. First, particles are generated to predict target’s location. Second, the weight of certain particles is calculated …

Electric Field Computation Of Wet Insulating Surfaces, Bhargavi Sarang

Electrical & Computer Engineering Theses & Dissertations

High voltage outdoor insulators form the backbone of modem power systems and therefore play a pivotal role in reliable supply of power. The presence of water droplets/films due to rain, fog, etc. enhances the electric field intensity and leads to electrical breakdown subsequently affecting the longevity of the insulator. The magnitude of surface E-fields necessary for initiation of electrical breakdown is a function of water repellent characteristic of an insulator called hydrophobicity. Thus, knowledge of field distribution around water droplets/films at various hydrophobic levels is significant in designing a better insulating material.

The current research analyzed electric field distributions on …