Preparation And Characterization Of The Silane-Phosphonic Acid Composite Passivation Coating For Electrogalvanized Steel,
2010
State Key Laboratory for Corrosion and Protection,Institute of Metal Research,Chinese Academy of Sciences,Shenyang 110016,China;
Preparation And Characterization Of The Silane-Phosphonic Acid Composite Passivation Coating For Electrogalvanized Steel, Yong Guan, Jian-Guo Liu, Chuan-Wei Yan
Journal of Electrochemistry
A new silane-phosphonic acid composite passivation coating process has been developed for the protection of electrogalvanized steel based on N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane(AAPTMS),γ-(2,3-epoxypropoxy)propyltrimethoxy-silane(GPTMS) and 1-hydroxy ethylidene-1,1-diphosphonic acid(HEDP).The results of X-ray photoelectron spectroscopy(XPS),Fourier transform infrared spectroscopy(FTIR),potentiodynamic polarization scan,electrochemical impedance spectroscopy(EIS) and neutral salt spray(NSS) tests indicated that the major structure of the prepared silane-phosphonic acid composite passivation coating consisted mainly of Si—O—Si and Si—O—P bonds.The area of white rust was not more than 5% of the total panal after 120 h NSS test,which could be compared favourably with the chromate colour passivation coating.However,the corrosion reaction on the anode of the silane-phosphonic acid composite passivation …
Initial Stage Of Atmospheric Corrosion Of Ndfeb(M35) In A Simulated Marine Atmosphere,
2010
State Key Laboratory for Corrosion and Protection,Institute of Metal Research,Chinese Academy of Sciences,Shenyang 110016,China;
Initial Stage Of Atmospheric Corrosion Of Ndfeb(M35) In A Simulated Marine Atmosphere, Chun-Ling Li, Yuan-Tai Ma, Ying Li, Fu-Hui Wang
Journal of Electrochemistry
This study detailed the atmospheric corrosion behaviour of sintered NdFeB(M35) in a simulated marine atmosphere with 80% relative humidity(RH).The dissolution and subsequent reaction of NaCl particles cause the attack of NdFeB.The corrosion presented three representative types:if the electrolyte covered magnetic phase and Nd-rich phase,the Nd-rich phase was corroded firstly due to galvanic effect;if the electrolyte covered magnetic phase,magnetic phase was corroded along the grain boundary;if the electrolyte located near the position of defects,corrosion progressed along with the defect because of low concentration of oxygen inside the defect.With corrosion progressing,local corrosion areas were mutually connected,with Nd-rich phase and grain boundary being …
Photoelectrochemical Properties Of N, S, And Cl Modified Nano Tio2 Thin Films,
2010
Key Laboratory of Shanghai Colleges and Universities for Electric Power Corrosion Control and Applied Electrochemistry,Department of Energy Source and Environment Engineering,Shanghai University of Electric Power,Shanghai 200090,China;State Key Laboratory for Physical Chemistry of Solid Surface,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,Fujian,China;
Photoelectrochemical Properties Of N, S, And Cl Modified Nano Tio2 Thin Films, Hong Yun, Chang-Jian Lin, Jing Li, Rong-Gui Du
Journal of Electrochemistry
The nitrogen(N),sulfur(S) and chlorine(Cl) modified nano TiO2 thin films were prepared by adding Ti(O-n-Bu)4 as the precursor into concentrated HNO3,H2SO4 and HCl Solutions,respectively,on different substrates in a sol-gel process.The photoelectrochemical performances of N,S and Cl modified nano TiO2 thin films have been studied by UV-vis(DRS),photocurrent curves,EIS and OCP-time curves.N-modified TiO2 nano films show better surface structure,which helps to improve the quantum efficiency of nano TiO2 thin films.
Hydrothermal Reduction Synthesis Of Lifepo4 And Its Electrochemical Performance,
2010
The State Key Laboratory of Optoelectronic Materials and Technologies,School of Physics and Engineering,Sun Yat-Sen University,Guangzhou 510275,China;
Hydrothermal Reduction Synthesis Of Lifepo4 And Its Electrochemical Performance, Hong-Li Zou, Guang-Hui Zhang, Pei-Kang Shen
Journal of Electrochemistry
The cathode materials of LiFePO4 were prepared via a hydrothermal reduction method using FeCl3 as Fe source and iron as a reducing agent.The results showed that ferric salt could be reduced to ferrous salt completely under the hydrothermal condition and pure-phase LiFePO4 was obtained based on the test results of XRD and FTIR.Carbon-coated LiFePO4 was synthesized by pyrolysisng glucose at high temperature.The morphologies of pure LiFePO4 displayed cluster-like while the LiFePO4/C displayed sphere-like particles.The electrochemical test showed that the LiFePO4/C had good rate performance,while LiFePO4 delivered much lower discharge capacity.
Effects Of Solvents And Electrolyte Salts On The Electrochemical Reduction Of Oxygen In Non-Aqueous Electrolytes,
2010
State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,Fujian,China;
Effects Of Solvents And Electrolyte Salts On The Electrochemical Reduction Of Oxygen In Non-Aqueous Electrolytes, Yan-Yan Tian, Wei Wu, Jun Gao, Yong Yang
Journal of Electrochemistry
The electrochemical reduction processes of oxygen in different non-aqueous solvents such as acetonitrile(MeCN),propylene carbonate(PC) and their mixtures were investigated by cyclic voltammetry method.The results indicated a one electron reduction of oxygen to O2-occured in these systems as a first step reduction,no matter whether in tetrabutylammonium hexafluorophosphate(TBAPF6)/MeCN or TBAPF6/PC electrolyte.However,the CV curves in 0.1 mol·L-1 TBAPF6/MeCN showed a couple of reversible redox peaks,indicating that the reduction process of oxygen was irreversible in the 0.1 mol·L-1 TBAPF6/PC electrolyte.In the PC-based electrolyte,the reduction current peak reduced largely and the oxidation peak …
Corrosion Electrochemical Behavior Of Am60 Magnesium Alloys In Automobile Engine Coolants,
2010
College of Chemistry and Chemical Engineering,Chongqing University,Chongqing 400044,China;
Corrosion Electrochemical Behavior Of Am60 Magnesium Alloys In Automobile Engine Coolants, Ling-Jie Li, Sha Wang, Yin Xiao, Jun Lan, Jing-Lei Lei, Sheng-Tao Zhang, Fu-Sheng Pan
Journal of Electrochemistry
The polarization measurements and electrochemical impedance spectroscopy(EIS) were used to study the corrosion electrochemical behavior of AM60 magnesium alloys in three kinds of commercial coolants for automobile engine.Results show that the tested commercial coolants are slightly corrosive to AM60 magnesium alloys and their corrosivity varies from coolant to coolant.The coolant C is the least corrosive among the studied commercial coolants and the coolant A is more corrosive than the coolant B and C.The coolant C appears to be the most promising coolant for automobile engine made by magnesium alloys.The coolant resistivity plays an important role in the corrosion of AM60 …
Electrodeposition Of Lead Dioxide From Dluoroborate Solutions,
2010
Science School,Nanjing University of Technology,Nanjing 210009,China;
Electrodeposition Of Lead Dioxide From Dluoroborate Solutions, Chun-Mei Kong, Yong-Ming Tang, Wen-Zhong Yang, Xiao-Yuan Yang
Journal of Electrochemistry
The PbO2 anodes were prepared on platinum from fluoroborate media and its doped solutions by electrodeposition technique.Elecchemical and pysicochemical properties of these PbO2 films were studied by cyclic voltammetry methods,XRD and SEM.The results showed that the presence of BF4-increased PbO2 electrodeposition rate;the prepared lead dioxide consisted of β-PbO2;the preferential orientation of crystals and surface morphology were affected a lot by doping F-and Fe3+.The FB/F-Fe-PbO2 electrode exhibited regular-shaped layers with compact morphology.Furthermore,increasing current density also change the preferential orientation of PbO2 crystals.
Research On Nafion/Sio2 Composite Membrane In All Vanadium Redox Flow Battery,
2010
Institute of Fuel Cell,Shanghai Jiao Tong University,Shanghai 200240,China;
Research On Nafion/Sio2 Composite Membrane In All Vanadium Redox Flow Battery, Dong-Dong Liu, Mao-Cai Lin, Tao Guan, Qing-Chun Yu
Journal of Electrochemistry
The Nafion117/SiO2 composite membrane was prepared by sol-gel method.The results showed that,during composite membrane preparation process,the ratio of MeOH and TEOS did not affect the penetration rate of VO2+ basically,however,the lowest permeability of 427×10-9cm2/s in the membrane was achieved while hydrolysis time was 10 min and natural drying for 24 h after hydrolysis,which reduced by 52 times than that in Nafion117 membrane.The SEM tests proved that SiO2 grains grew bigger in the composite membrane during the natural drying,and most of the holes in Nafion117 were filled.Single cell test showed the battery power efficiency was improved …
Study On Preparing Technology And Corrosion Resistance Of Ti/Zr Based Chromium-Free Chemical Conversion Coating On Zinc Electroplating Layer,
2010
State Key Laboratory for Corrosion and Protection,Institute of Metal Research,Chinese Academy of Sciences,Shenyang 110016,China;
Study On Preparing Technology And Corrosion Resistance Of Ti/Zr Based Chromium-Free Chemical Conversion Coating On Zinc Electroplating Layer, Yong Guan, Jian-Guo Liu, Chuan-Wei Yan
Journal of Electrochemistry
In this paper,we obtained environmental-friendly chromium-free chemical conversion coating on the non-cyanide alkaline zinc electroplating layer by employing the optimized Ti/Zr based conversion technique.At the same time,the performances of the Ti/Zr based conversion coating were compared with chromate colour passivation coating.The corrosion resistances of the conversion coatings were investigated by using neutral salt spray(NSS) test,potentiodynamic polarization and electrochemical impedance spectroscopy(EIS).The results showed that the white rust appeared after 96 hours when the NSS test was performed on the Ti/Zr based conversion coating,which was close to the corrosion resistance rating of chromate colour passivation coating.Compared with the chromate passivation coating,the Ti/Zr …
The Roles Of The Width Of Gas/Liquid/Solid Three-Phase Boundary Zone Of Dispersion Water Films In Atmospheric Corrosion Of Metals,
2010
College of Chemistry and Chemical Engineering,Ocean University of China,Qingdao 266100,Shandong,China;State Key Laboratory for Corrosion and Protection of Metals,Shenyang 110016,China;
The Roles Of The Width Of Gas/Liquid/Solid Three-Phase Boundary Zone Of Dispersion Water Films In Atmospheric Corrosion Of Metals, Jia Wang, Jing Jiang
Journal of Electrochemistry
The roles of TPB(Three-Phase Boundary) width in the corrosion processes of metals under dispersed water films were investigated by electrochemical techniques combined with contact angle measurement.It is found that both cathodic limiting current density and corrosion current density linearly increases with increasing the TPB width,confirming the important role of TPB width in gas/liquid/solid multiphase corrosion systems.Based on above results,the effect of water film thickness on atmospheric corrosion rate was quantitatively evaluated by the TPB width.
The Sol-Gel Synthesis And Electrochemical Performance Of Li3V2(Po4)3/C Cathode Material For Lithium Ion Battery,
2010
Faculty of Material and Energy,Guangdong University of Technology,Guangzhou 518006,China;McNair Technology Co.Ltd,Dongguan 523800,Guangdong,China;
The Sol-Gel Synthesis And Electrochemical Performance Of Li3V2(Po4)3/C Cathode Material For Lithium Ion Battery, Li-Ying Liu, Lian Chen, Hai-Yan Zhang, Yu-Chun Zhai
Journal of Electrochemistry
Li3V2(PO4)3/C was synthesized by sol-gel method with citric acid as chelate and C sources. Physical and electrochemical performances of as-prepared materials were characterized through XRD, SEM and galvanostatic charge-discharge tests,etc. The results showed that products produced by calcining at 800 ℃ for 12 h had a single phase crystal structure and relatively small particle sizes with uniform distribution. At 0.1 C, 0.5 C and 1 C, the initial specific discharge capacities were 153.0, 143.1 and 130.6 mAh·g-1, respectively, and capacity efficiencies were 93.1%, 85.4% and 77.3% after 50 cycles, respectively. …
Effect Of Process Parameters On Abnormal Grain Growth During Friction Stir Processing Of A Cast Al Alloy,
2010
Missouri University of Science and Technology
Effect Of Process Parameters On Abnormal Grain Growth During Friction Stir Processing Of A Cast Al Alloy, S. Jana, Rajiv S. Mishra, J. A. Baumann, G. Grant
Materials Science and Engineering Faculty Research & Creative Works
The effects of process parameters and friction stir processing (FSP) run configurations on the stability of nugget microstructure at elevated temperatures were evaluated. Cast plates of an Al-7Si-0.6Mg alloy were friction stir processed using a combination of tool rotation rates and tool traverse speeds. All single pass runs showed some extent of abnormal grain growth (AGG), whereas multi-pass runs were more resistant to AGG. Additionally, higher tool rotation rate was found to be beneficial for controlling AGG. These effects were analyzed by comparing the result of this work with other published results and AGG models. © 2010 Elsevier B.V.
Virtual Coatings Application System,
2010
University of Northern Iowa
Virtual Coatings Application System, Jason M. Ebsensberger, Michael J. Bolick, Richard J. Klein Ii, Eric C. Peterson, Chad J. Zalkin, James B. Fisher, Leslie C. Hughes
Patents (University of Northern Iowa)
A virtual coatings application system has several features to enhance the realism of simulated spray painting. The system generally includes a display screen on which is defined a virtual surface (such as a truck door) that is intended to be virtually painted or coated by the user. Alternatively, the system includes a head-mounted display unit that displays a virtual spray painting environment in which the virtual surface is defined. The user operates an instrumented spray gun controller that outputs one or more signals representing data as to the status of the controls on the spray gun controller. The system also …
Virtual Coatings Application System,
2010
University of Northern Iowa
Virtual Coatings Application System, Jason M. Ebensberger, Michael J. Bolick, Jeremiah G. Treloar, Richard J. Klein Ii, Eric C. Peterson, Chad J. Zalkin, James B. Fisher, Leslie C. Hughes
Patents (University of Northern Iowa)
A virtual coatings application system has several features to enhance the realism of simulated spray painting. The system generally includes a display screen on which is defined a virtual surface (such as a truck door) that is intended to be virtually painted or coated by the user. The user operates an instrumented spray gun controller that outputs one or more signals representing data as to the status of the controls on the spray gun controller. The system also has a motion tracking system that tracks the position and orientation of the spray gun controller with respect to the virtual surface …
Microstructural Evolution During Fatigue Of Ultrafine Grained Aluminum Alloy,
2010
Missouri University of Science and Technology
Microstructural Evolution During Fatigue Of Ultrafine Grained Aluminum Alloy, P. S. De, Rajiv S. Mishra
Materials Science and Engineering Faculty Research & Creative Works
A comparative study of the surface microstructural changes during fatigue of a precipitation hardened (PH) aluminum alloy in ultrafine grained (UFG) and microcrystalline conditions was done using orientation imaging microscopy (OIM). with increase in applied stress amplitude, the fatigue life of fine-grained PH alloy deteriorated. on the other hand, at lower stress amplitudes an improvement in fatigue life was noted. This trend was reversed for the coarse-grained PH alloy. in UFG alloy, the fatigue life improved at all stress amplitudes. the variation in fatigue life response between coarse, fine and ultrafine grain PH alloy was due to the increased interaction …
The Relationship Between Induced Fluid Structure And Boundary Slip In Nanoscale Polymer Films,
2010
Wright State University - Main Campus
The Relationship Between Induced Fluid Structure And Boundary Slip In Nanoscale Polymer Films, Nikolai V. Priezjev
Mechanical and Materials Engineering Faculty Publications
The molecular mechanism of slip at the interface between polymer melts and weakly attractive smooth surfaces is investigated using molecular dynamics simulations. In agreement with our previous studies on slip flow of shear-thinning fluids, it is shown that the slip length passes through a local minimum at low shear rates and then increases rapidly at higher shear rates. We found that at sufficiently high shear rates, the slip flow over atomically flat crystalline surfaces is anisotropic. It is demonstrated numerically that the friction coefficient at the liquid-solid interface (the ratio of viscosity and slip length) undergoes a transition from a …
Synthesis Of Mild–Hard Aao Templates For Studying Magnetic Interactions Between Metal Nanowires,
2010
University of New Orleans
Synthesis Of Mild–Hard Aao Templates For Studying Magnetic Interactions Between Metal Nanowires, Jin-Hee Lim, Aurelian Rotaru, Seong-Gi Min, Leszek Malkinski, John B. Wiley
Physics Faculty Publications
The sequential application of mild and hard anodization techniques in the fabrication of porous aluminamembranes allows one to decrease the number of continuous pores in anodized aluminium oxide (AAO) templates. Initially, standard mild anodization techniques were used to create porous templates with 100 nm interpore distances and 70 nm pore diameters. Hard anodization treatment on the same membrane then produced interpore distances of about 265 nm with diameters of 110 nm. At the interface between the two anodization steps, many of the mild-side pores were terminated to create a mild–hard membrane (Mi–Ha AAO) where the functional interpore distances were 200–300 …
Wimax Implementation As Existing Hotspot Network Backhaul In Jakarta,
2010
Departemen Teknik Elektro, Fakultas Teknik, Universitas Indonesia, Depok 16424, Indonesia
Wimax Implementation As Existing Hotspot Network Backhaul In Jakarta, Djamhari Sirat, Muhamad Asvial, Luther B. Marpaung
Makara Journal of Technology
WiMAX Implementation as Existing Hotspot Network Backhaul in Jakarta The development of Broadband Wireless Access (BWA), such as WiMAX, as a global standard for data transmission media has been used by high speed internet access provider. WiMAX application which supported by capabilities of interoperability, flexibility and commercial aspect make the internet services become more efficient, cheaper and easier to the customer. This phenomenon should be responded by ISPs. Based on technical and financial aspect in deciding the implementation of Wireless Network with WiMAX technology as a substitute, this research will observe and analyze the projection of WiMAX technology implementation as …
Plant Growth Modeling Using L-System Approach And Its Visualization,
2010
Agricultural Engineering Department, Agricultural Technology Faculty, University of Gadjah Mada, Bulaksumur, Yogyakarta 55281, Indonesia
Plant Growth Modeling Using L-System Approach And Its Visualization, Atris Suyantohadi, Alfiyan Alfiyan, Mochamad Hariadi, Mauridhi Hery Purnomo
Makara Journal of Technology
The visualization of plant growth modeling using computer simulation has rarely been conducted with Lindenmayer System (L-System) approach. L-System generally has been used as framework for improving and designing realistic modeling on plant growth. It is one kind of tools for representing plant growth based on grammar sintax and mathematic formulation. This research aimed to design modeling and visualizing plant growth structure generated using L-System. The environment on modeling design used three dimension graphic on standart OpenGL format. The visualization on system design has been developed by some of L-System grammar, and the output graphic on three dimension reflected on …
Immobilization Of Saccharomyces Cerevisiae In Rice Hulls For Ethanol Production,
2010
Interdisciplinary Program of Graduate School for Bioenergy and Biomaterials, Chonnam National University, Gwangju 500-757, South Korea
Immobilization Of Saccharomyces Cerevisiae In Rice Hulls For Ethanol Production, Edita Martini, Dian Andriani, Sriramulu Gobikrishnan, Kyeong Eop Kang, Surn-Teh Bark, Changshin Sunwoo, Bambang Prasetya, Don-Hee Park
Makara Journal of Technology
The whole cell immobilization in ethanol fermentation can be done by using natural carriers or through synthetic carriers. All of these methods have the same purpose of retaining high cell concentrations within a certain defined region of space which leads to higher ethanol productivity. Lignocellulosic plant substance represents one of highly potential sources in ethanol production. Some studies have found that cellulosic substances substances can also be used as a natural carrier in cell immobilization by re-circulating pre-culture medium into a reactor. In this experiment, rice hulls without any treatment were used to immobilize Saccharomyces cerevisiae through semi solid state …
