Materials Science and Engineering Commons^™

Diagnostics And Degradation Investigations Of Li-Ion Battery Electrodes Using Single Nanowire Electrochemical Cells, Naveen Kumar Reddy Palapati, Naveen Kumar Reddy Palapati

Theses and Dissertations

Portable energy storage devices, which drive advanced technological devices, are improving the productivity and quality of our everyday lives. In order to meet the growing needs for energy storage in transportation applications, the current lithium-ion (Li-ion) battery technology requires new electrode materials with performance improvements in multiple aspects: (1) energy and power densities, (2) safety, and (3) performance lifetime. While a number of interesting nanomaterials have been synthesized in recent years with promising performance, accurate capabilities to probe the intrinsic performance of these high-performance materials within a battery environment are lacking. Most studies on electrode nanomaterials have so far used …

Surface Modification Techniques For Increased Corrosion Tolerance Of Zirconium Fuel Cladding, James Carr

Theses and Dissertations

Corrosion is a major issue in applications involving materials in normal and severe environments, especially when it involves corrosive fluids, high temperatures, and radiation. Left unaddressed, corrosion can lead to catastrophic failures, resulting in economic and environmental liabilities. In nuclear applications, where metals and alloys, such as steel and zirconium, are extensively em- ployed inside and outside of the nuclear reactor, corrosion accelerated by high temperatures, neu- tron radiation, and corrosive atmospheres, corrosion becomes even more concerning. The objec- tives of this research are to study and develop surface modification techniques to protect zirconium cladding by the incorporation of a …

Beyond Conventional C-Plane Gan-Based Light Emitting Diodes: A Systematic Exploration Of Leds On Semi-Polar Orientations, Morteza Monavarian

Theses and Dissertations

Despite enormous efforts and investments, the efficiency of InGaN-based green and yellow-green light emitters remains relatively low, and that limits progress in developing full color display, laser diodes, and bright light sources for general lighting. The low efficiency of light emitting devices in the green-to-yellow spectral range, also known as the “Green Gap”, is considered a global concern in the LED industry. The polar c-plane orientation of GaN, which is the mainstay in the LED industry, suffers from polarization-induced separation of electrons and hole wavefunctions (also known as the “quantum confined Stark effect”) and low indium incorporation efficiency that …

The Modification Of Silica Aerogel Materials For Contemporary Use, Lauren White

Theses and Dissertations

Aerogel materials have had limited utility due to their fragility, geometrical limitations, fabrication costs and protracted fabrication times. The objective of this project was to eliminate these limitations. Native, cross-linked and hybrid aerogel monoliths have been fabricated using a newly developed one-pot method without the need for solvent exchange. The key to this technique is the use of an ethanol–water azeotrope mixture, which contains 4.4% water by volume, as both a gelation and supercritical drying solvent. The small water content allows for drying at temperatures close to the supercritical temperature of the dry solvent, where reactions such as silica dissolution …

The Dawn Of New Quantum Dots: Synthesis And Characterization Of Ge1-Xsnx Nanocrystals For Tunable Bandgaps., Richard J. Esteves

Theses and Dissertations

Ge_1-xSn_x alloys are among a small class of benign semiconductors with composition tunable bandgaps in the near-infrared spectrum. As the amount of Sn is increased the band energy decreases and a transition from indirect to direct band structure occurs. Hence, they are prime candidates for fabrication of Si-compatible electronic and photonic devices, field effect transistors, and novel charge storage device applications. Success has been achieved with the growth of Ge_1-xSn_x thin film alloys with Sn compositions up to 34%. However, the synthesis of nanocrystalline alloys has proven difficult due to larger discrepancies (~14%) in …

Investigation And Modeling Of Al3(Sc, Zr) Precipitation Strengthening In The Presence Of Enhanced Supersaturation And Within Al-Cu Binary Alloys, Kyle Deane

Dissertations, Master's Theses and Master's Reports

Diffuse Al-Sc and Al-Zr alloys have been demonstrated in literature to be relatively coarsening resistant at higher temperatures when compared with commonly used precipitation strengthening alloys (e.g. 2000 series, 6000 series). However, because of a limited strengthening due to the low solubility of scandium and zirconium in aluminum, and owing to the scarcity and therefore sizeable price tag attached to scandium, little research has been done in the way of optimizing these alloys for commercial applications.

With this in mind, this dissertation describes research which aims to tackle several important areas of Al-Sc-Zr research that have been yet unresolved. In …

Mse Annual Report 2016, Department Of Materials Science And Engineering, Michigan Technological University

Department of Materials Science and Engineering Annual Reports

Table of Contents

• Faculty and Staff News
• Faculty Research
• Student News
• Senior Design Teams
• Graduate Student News
• Outreach
• Alumni News
• MSE by the Numbers
• Scholarships

Thermal Characterization Of Phase Change Materials For Thermal Energy Storage, Rami Mohammad Reda Saeed

Masters Theses

"The study provides a valuable and useful database for Phase Change Materials (PCMs) for Thermal Energy Storage (TES) applications. Only a few existing studies have provided an overall investigation of thermophysical properties of PCMs in this detailed manner. Several organic PCMs, namely Myristic acid, Capric Acid, Lauryl Alcohol, Palmitic acid and Lauric acid, have been characterized after being carefully selected to cover wide range of TES applications. Insights and information gained from this work will be applied toward the design and modelling of many low temperature thermal energy storage applications. The study experimentally investigated uncertainty of thermal characterization of PCMs …

Hybrid Manufacturing Processes For Fusion Welding And Friction Stir Welding Of Aerospace Grade Aluminum Alloys, Megan Alexandra Gegesky

Masters Theses

"Friction stir welding and processing can provide for joints in aerospace grade aluminum alloys that have preferable material properties as compared to fusion welding techniques. Aerospace grade aluminum alloys such as AA2024-T3 and AA7075-T6 are considered non-weldable by traditional fusion welding techniques. Improved mechanical properties over previously used techniques are usually preferable for aerospace applications. Therefore, by combining traditional fusion welding and friction stir processing techniques, it could be plausible to create more difficult geometries in manufactured parts instead of using traditional techniques. While this combination of fusion welding and friction stir processing is not a new technology, its introduction …

A Study On Non-Metallic Inclusions In Foundry Steel Process, Marc Leonard Harris

Masters Theses

"The effects of sample area and automated SEM/EDS feature analysis parameters (step size, magnification and threshold) on nonmetallic inclusion characterization results has been investigated and optimized. A post-processing program was developed to automatically determine average inclusion chemistry, total element concentrations within inclusions, and for generating joint ternary diagrams with size visualization for representing nonmetallic inclusion populations. Using these tools the evolution of nonmetallic inclusions was examined for 4320 steel at a participating industrial steel foundry. The steel was sampled throughout electric arc furnace melting through ladle refining to the final casting where an in-mold sampling procedure was developed to procure …

Carbon Transfer From Magnesia-Graphite Ladle Refractories To Ultra-Low Carbon Steel, Andrew Arthur Russo

Masters Theses

"Ultra-low carbon steels are utilized in processes which require maximum ductility. Increases in interstitial carbon lower the ductility of steel; therefore, it is important to examine possible sources of carbon. The refractory ladle lining is one such source. Ladle refractories often contain graphite for its desirable thermal shock and slag corrosion resistance. This graphite is a possible source of carbon increase in ultra-low carbon steels. The goal of this research is to understand and evaluate the mechanisms by which carbon transfers to ultra-low carbon steel from magnesia-graphite ladle refractory.

Laboratory dip tests were performed in a vacuum induction furnace under …

Bioactive Poly(Beta-Amino Ester) Biomaterials For Treatment Of Infection And Oxidative Stress, Andrew L. Lakes

Theses and Dissertations--Chemical and Materials Engineering

Polymers have deep roots as drug delivery tools, and are widely used in clinical to private settings. Currently, however, numerous traditional therapies exist which may be improved through use of polymeric biomaterials. Through our work with infectious and oxidative stress disease prevention and treatment, we aimed to develop application driven, enhanced therapies utilizing new classes of polymers synthesized in-house. Applying biodegradable poly(β-amino ester) (PBAE) polymers, covalent-addition of bioactive substrates to these PBAEs avoided certain pitfalls of free-loaded and non-degradable drug delivery systems. Further, through variation of polymer ingredients and conditions, we were able to tune degradation rates, release profiles, cellular …

Improving The Capacity, Durability And Stability Of Lithium-Ion Batteries By Interphase Engineering, Qinglin Zhang

Theses and Dissertations--Chemical and Materials Engineering

This dissertation is focus on the study of solid-electrolyte interphases (SEIs) on advanced lithium ion battery (LIB) anodes. The purposes of this dissertation are to a) develop a methodology to study the properties of SEIs; and b) provide guidelines for designing engineered SEIs. The general knowledge gained through this research will be beneficial for the entire battery research community.

Three-Dimensional Microstructural Effects On Multi-Site Fatigue Crack Nucleation Behaviors Of High Strength Aluminum Alloys, Yan Jin

Theses and Dissertations--Chemical and Materials Engineering

An experimental method was further developed to quantify the anisotropy of multi-site fatigue crack initiation behaviors in high strength Al alloys by four-point bend fatigue testing under stress control. In this method, fatigue crack initiation sites (fatigue weak-links, FWLs) were measured on the sample surface at different cyclic stress levels. The FWL density in an alloy could be best described using a three-parameter Weibull function of stress, though other types of sigmoidal functions might also be used to quantify the relationship between FWL density and stress. The strength distribution of the FWLs was derived from the Weibull function determined by …

Understanding Electrical Conduction In Lithium Ion Batteries Through Multi-Scale Modeling, Jie Pan

Theses and Dissertations--Chemical and Materials Engineering

Silicon (Si) has been considered as a promising negative electrode material for lithium ion batteries (LIBs) because of its high theoretical capacity, low discharge voltage, and low cost. However, the utilization of Si electrode has been hampered by problems such as slow ionic transport, large stress/strain generation, and unstable solid electrolyte interphase (SEI). These problems severely influence the performance and cycle life of Si electrodes. In general, ionic conduction determines the rate performance of the electrode, while electron leakage through the SEI causes electrolyte decomposition and, thus, causes capacity loss. The goal of this thesis research is to design Si …

Synthesis Of Titania Thin Films With Controlled Mesopore Orientation: Nanostructure For Energy Conversion And Storage, Suraj R. Nagpure

Theses and Dissertations--Chemical and Materials Engineering

This dissertation addresses the synthesis mechanism of mesoporous titania thin films with 2D Hexagonal Close Packed (HCP) cylindrical nanopores by an evaporation-induced self-assembly (EISA) method with Pluronic surfactants P123 and F127 as structure directing agents, and their applications in photovoltaics and lithium ion batteries. To provide orthogonal alignment of the pores, surface modification of substrates with crosslinked surfactant has been used to provide a chemically neutral surface. GISAXS studies show not only that aging at 4°C facilitates ordered mesostructure development, but also that aging at this temperature helps to provide orthogonal orientation of the cylindrical micelles which assemble into an …

Three-Dimensional Microstructure-Based Models For Fatigue Crack Nucleation And Fatigue Crack Branching In High Strength Al Alloys, Lin Yang

Theses and Dissertations--Chemical and Materials Engineering

This study is concerned with using numerical three-dimensional microstructure-based models to quantify the multi-site fatigue crack initiation behaviors by simulating the effects of pores in a cast aluminum alloy, and to analyze the mechanism of fatigue crack branching in thick aluminum alloy plates. It has been recently recognized the three-dimensional effects of pores on fatigue crack initiation, which provide opportunity to quantitatively identify the fatigue weak-link density and strength distribution in aluminum alloy. The stress and strain fields around a micro-pore in an A713 aluminum alloy (an elasto-plastic media) under cyclic loading were quantified as a function of pore position …

Lnvestigation Of The Critical Role Of Polymeric Binders For Silicon Negative Electrodes In Lithium-Lon Batteries, Jiagang Xu

Theses and Dissertations--Chemical and Materials Engineering

Silicon is capable of delivering a high theoretical specific capacity of 3579 mAh g^-1, which is about 10 times higher than that of the state-of-the-art graphite-based negative electrodes for lithium-ion batteries (LIBs). However, the poor cycle life of silicon electrodes, caused by the large volumetric strain during cycling, limits the commercialization of silicon electrodes. As one of the essential components, the polymeric binder is critical to the performance and durability of lithium-ion batteries as it keeps the integrity of electrodes, maintains conductive path and must be stable in the electrolyte. The guideline for binder selection of silicon electrodes …

First-Principles Studies Of Structure-Property Relationships: Enabling Design Of Functional Materials, Qunfei Zhou

Theses and Dissertations--Chemical and Materials Engineering

First-principles calculations based on quantum mechanics have been proved to be powerful for accurately regenerating experimental results, uncovering underlying myths of experimental phenomena, and accelerating the design of innovative materials. This work has been motivated by the demand to design next-generation thermionic emitting cathodes and techniques to allow for synthesis of photo-responsive polymers on complex surfaces with controlled thickness and patterns. For Os-coated tungsten thermionic dispenser cathodes, we used first-principles methods to explore the bulk and surface properties of W-Os alloys in order to explain the previously observed experimental phenomena that thermionic emission varies significantly with W-Os alloy composition. Meanwhile, …

Mdm2 Case Study: Computational Protocol Utilizing Protein Flexibility Improves Ligand Binding Mode Predictions, Anthony Thomas Ascone

Graduate Theses/Dissertations

Recovery of the P53 tumor suppressor pathway via small molecule inhibitors of onco-protein MDM2 highlights the critical role of computational methodologies in targeted cancer therapies. Molecular docking programs in particular, provide a quantitative ranking of predicted binding geometries based on binding free energy allowing for the screening of large chemical libraries in search of lead compounds for cancer therapeutics. This study found improved binding mode predictions of medicinal compounds to MDM2 using the popular docking programs AutoDock and AutoDock Vina, while adopting a rigid-ligand/flexible-receptor protocol. Crystal structures representing small molecule inhibitors bound to MDM2 were selected and a total of …