Materials Science and Engineering Commons^™

Increasing Solar Energy Conversion Efficiency In Hydrogenated Amorphous Silicon Photovoltaic Devices With Plasmonic Perfect Meta – Absorbers, Jephias Gwamuri

Dissertations, Master's Theses and Master's Reports

Solar photovoltaic (PV) devices are an established, technically-viable and sustainable solution to society’s energy needs, however, in order to reach mass deployment at the terawatt scale, further decreases in the levelized cost of electricity from solar are needed. This can be accomplished with thin-film PV technologies by increasing the conversion efficiency using sophisticated light management methods. This ensures absorption of the entire solar spectrum, while reducing semiconductor absorber layer thicknesses, which reduces deposition time, material use, embodied energy and greenhouse gas emissions, and economic costs. Recent advances in optics, particularly in plasmonics and nanophotonics provide new theoretical methods to improve …

Dynamic Atomistic Study Of Tunnel Functions In Nanostructured Transitional Metal Oxides, Yifei Yuan

Dissertations, Master's Theses and Master's Reports

Alpha (α-) MnO₂ is a well know transitional metal oxide possessing one dimensional 2×2 (4.6 × 4.6 Ų) tunnels for accommodation of various ions. Such a characteristic tunneled structure has enabled the wide applications of α-MnO₂ in the fields of ion exchange, molecular sieves, biosensor, catalysis and energy storage. This PhD dissertation focuses on the dynamic study of ion transport functionality of α-MnO₂ at atomic level using an aberration corrected scanning transmission electron microscopy equipped with a special holder with a scanning tunneling microscopy probe.

The wide application of in situ TEM studying the dynamic …

Thermomechanical Processing Of Aluminum Micro-Alloyed With Sc, Zr, Ti, B, And C, Cameron Mcnamara

Dissertations, Master's Theses and Master's Reports

Critical exploration of the minimalistic high strength low alloy aluminum (HSLA-Al) paradigm is necessary for the continued development of advanced aluminum alloys. In this study, scandium (Sc) and zirconium (Zr) are examined as the main precipitation strengthening additions, while magnesium (Mg) is added to probe the synergistic effects of solution and precipitation hardening, as well as the grain refinement during solidification afforded by a moderate growth restriction factor. Further, pathways of recrystallization are explored in several potential HSLA-Al systems sans Sc. Aluminum-titanium-boron (Al-Ti-B) and aluminum-titanium-carbon (Al-Ti-C) grain refining master alloys are added to a series of Al-Zr alloys to examine …

Overview Of Fiber Optic Sensor Technologies For Strain/Temperature Sensing Applications In Composite Materials, Manjusha Ramakrishnan, Ginu Rajan, Yuliya Semenova, Gerald Farrell

Articles

This paper provides an overview of the different types of fiber optic sensors (FOS) that can be used with composite materials and also their compatibility with and suitability for embedding inside a composite material. An overview of the different types of FOS used for strain/temperature sensing in composite materials is presented. Recent trends, and future challenges for FOS technology for condition monitoring in smart composite materials are also discussed. This comprehensive review provides essential information for the smart materials industry in selecting of appropriate types of FOS in accordance with end-user requirements.

Nd2fe14b: (Nd1-X Dyx)2 Fe14b Core-Shell Structure Formation By Hot Press Liquid Phase Sintering, Li Chen

Dissertations, Master's Theses and Master's Reports

The purpose of this project is to produce Nd rich core-Dy rich shell grain structure in liquid phase sintered alloys by consolidating Dy rich powder mixed with powder. The technical barrier to producing the core-shell microstructure is that the Dy composition variations will homogenize during the consolidation process. This dissertation is based on the hypothesis that compositional homogenization of the core-shell structure can be minimized if consolidation occurs under applied pressure (hot press liquid phase sintering). The hypothesis is tested by comparing the homogenization of the Dy composition to the degree of consolidation with and without applied pressure. It is …

Experimental Investigations Of Fused Filament Fabrication For Applications To Affordable Scientific Hardware, Bas Wijnen

Dissertations, Master's Theses and Master's Reports

This research aims to make science more accessible through the use of open source 3-D printers.

A new control system for CNC machines in general and 3-D printers specifically, is developed and presented that enables web-based control of 3-D tools from any Internet connected device. The system can be set up and controlled entirely from a web interface.

A tool was designed to help apply science to the developing world. The developing world remains plagued by lack of access to safe drinking water. A methodology is provided for the design, development, and technical validation of a low-cost open-source water testing …

Nanosphere Lithography And Its Application In Rapid And Economic Fabrication Of Plasmonic Hydrogenated Amorphous Silicon Photovoltaic Devices, Chenlong Zhang

Dissertations, Master's Theses and Master's Reports

Solar photovoltaic (PV) devices harvest energy from solar radiation and convert it to electricity. PV technologies, as an alternative to traditional fossil fuels, use clean and renewable energy while minimizing pollution. For decades researchers have been developing thin film solar cells as an important alternatives to the relatively expensive bulk crystal solar cell technology. Among those, hydrogenated amorphous silicon (a-Si:H) solar cells prevails for good efficiency, non-toxic and materially abundant nature. However, a-Si:H thickness must be minimized to prevent light induced degradation, so optical enhancement is necessary. Light manipulation has to be applied and carefully engineered to trap light within …

Methodology For Analyzing Epoxy-Cnt Phononic Crystals For Wave Attenuation And Guiding, Madhu Kolati

Dissertations, Master's Theses and Master's Reports

Phononic crystals (PhnCs) control, direct and manipulate sound waves to achieve wave guiding and attenuation. This dissertation presents methodology for analyzing nanotube materials based phononic crystals to achieve control over sound, vibration and stress mitigation. Much of the analytical work presented is in identifying frequency band gaps in which sound or vibration cannot propagate through these PhnCs. Wave attenuation and mitigation analysis is demonstrated using finite element simulation. Engineering principles from current research areas of solid mechanics, solid-state physics, elasto-dynamics, mechanical vibrations and acoustics are employed for the methodology. A considerable effort is put to show that these PhnCs can …

Direct Experimental Evidence For Differing Reactivity Alterations Of Minerals Following Irradiation: The Case Of Calcite And Quartz, Isabella Pignatelli, Aditya Kumar, Kevin G. Field, Bu Wang, Yingtian Yu, Yann Le Pape, Mathieu Bauchy, Gaurav Sant

Materials Science and Engineering Faculty Research & Creative Works

Concrete, used in the construction of nuclear power plants (NPPs), may be exposed to radiation emanating from the reactor core. Until recently, concrete has been assumed immune to radiation exposure. Direct evidence acquired on Ar⁺-ion irradiated calcite and quartz indicates, on the contrary, that, such minerals, which constitute aggregates in concrete, may be significantly altered by irradiation. More specifically, while quartz undergoes disordering of its atomic structure resulting in a near complete lack of periodicity, calcite only experiences random rotations, and distortions of its carbonate groups. As a result, irradiated quartz shows a reduction in density of around …

Developing The Stress Strain Curves For An Epoxy Undergoing High Speed Impact, Stanford L. Howdyshell 7867559

Williams Honors College, Honors Research Projects

The Hopkinson Split Bar test can be used to accurately develop the relationship between the stress and strain a material undergoes during a high speed impact (rates of 1000/s). This information has many industrial uses, for example the auto industry can use this technology to analyze how materials will behave under crash-like circumstances. In this experiment the stress-strain curves were developed for the PC-Plumbing epoxy.

One of the variables that can be adjusted in the Split Hopkinson Bar test is the ration between the height of the sample and the width of the sample (Hs/Ds). This experiment investigated how three …

Diffusive Behavior Of Physically Cross-Linked Hydrogels, Morgan A. Stilke

Williams Honors College, Honors Research Projects

A hydrogel is a water swollen polymeric network that has the potential to transform a variety of biomedical applications because of its biocompatibility and water content. Unfortunately, hydrogels typically have poor mechanical robustness. The majority of the content is water, while the remaining structure consists of a physical network, a covalent network, or a combination of both, yielding strength and toughness. There are several strategies attempted to improve mechanical properties including double network hydrogels comprised of two interpenetrating networks: one being a highly crosslinked sacrificial network and the other being a weakly crosslinked network that maintains reversibility after deformation. However, …

Oxidation Resistance Of Nanocrystalline 316l Stainless Steel Processed By High Pressure Torsion, Kevin J. Meisner

Williams Honors College, Honors Research Projects

High Pressure Torsion (HPT) is a materials processing method used to refine the grain size of metallic materials through the application of simultaneous axial and torsional strain. HPT is reported to result in nanocrystalline structure, which the current scientific literature suggests may improve the high temperature oxidation resistance by enhancing diffusion of solutes, particularly Cr, to the surface to form a protective external oxide scale. If oxidation resistance is improved, this possibly allows the use of 316L in oxidizing environments where more expensive alloys are typically used. However, the influence of grain refinement to nanoscale on various properties have been …

Galvanic Corrosion On Monel K-500 And 1018 Carbon Steel Couple, John K. Nnyanzi

Williams Honors College, Honors Research Projects

The purpose of this research project was to evaluate galvanic damage on 1018 Carbon Steel coupled to Monel K-500 at varying rotation speeds on a rotating cylinder electrode in an aerated solution of ASTM artificial seawater. The work in this project is and attempt to study corrosion behavior for a Monel fastener coupled to a Carbon Steel plate. Polarization curves of each material at different rotation speeds were created to predict the corrosion behavior for a galvanic couple of Carbon Steel and Monel. The Potentiodynamic sweeps predict an increase in the corrosion current density for the galvanic couple when then …

Static And Dynamic Behavior Of Carbon Fiber Reinforced Aluminum (Carall) Laminates, Gurpinder Singh Dhaliwal

Wayne State University Dissertations

STATIC AND DYNAMIC BEHAVIOUR OF CARBON FIBER REINFORCED ALUMINUM (CARALL) LAMINATES

by

GURPINDER SINGH DHALIWAL

Advisor: Dr. Golam Newaz

Major: Mechanical Engineering

Degree: Doctor of Philosophy

The main aim of this research work was to investigate the static and dynamic properties of carbon fiber reinforced aluminum laminates cured without using any external adhesive and acid treatment of aluminum layers. A comprehensive study was undertaken to study the effect of adding epoxy resin rich polyester synthetic surface veil cloth layers on the failure modes and flexural and tensile response of these fiber metal laminates (FMLs). The main purpose of adding veil …

Effects Of Antidepressants On Human Mesenchymal Stem Cell Differentiation On Clinically Relevant Titanium Surfaces, Nancy B. Ayad

Theses and Dissertations

Selective Serotonin Reuptake Inhibitors (SSRIs) are the most frequently prescribed class of drugs worldwide and are implemented in the treatment of depression and other psychiatric disorders. SSRIs relieve depressive symptoms by modulating levels of the neurotransmitter serotonin in the brain. SSRIs block the function of the serotonin transporter, thereby increasing concentrations of extracellular serotonin. However, serotonin levels in the neurons of the brain only account for 5% while the remaining 95% is present outside the brain. Serotonin receptors and transporter are located on bone resident cells (mesenchymal stem cells (MSCs)), osteoblasts and osteoclasts, and serotonergic activity is believed to affect …

Phase Field Modeling Of Electrodeposition Process In Lithium Metal Batteries, Nihal Acharya

Masters Theses

"One of the main weaknesses in long term performance of conventional lithium batteries is the growth of lithium microstructures on the electrode surface due to an electrochemical process, which can eventually lead to failure of these batteries. Suppressing this microstructure growth is a key in developing new generations of lithium metal batteries (LMBs). In this study, a two-dimensional (2D) phase field model is constructed to understand and determine the parameters controlling formation and evolution of microstructures in LMBs. A Ginzburg-Landau free energy functional, which is a function of concentration of Li⁺ and applied voltage, and a system consisting of …

Material Properties Affecting The Penetration Of Metal Targets By Copper Linear Shaped Charges, Kevin Lee Phelps

Masters Theses

"A linear shaped charge (LSC) is an explosive device used in demolition, aerospace, and in other applications that require the cutting of metal. Users of LSC's typically know the size of shaped charge needed to cut their target but commonly encounter previously untested materials. The motivation for this thesis is to provide an understanding as to what target material properties are good indicators of cutting performance so the selection of LSC can be more efficient. The author found that penetration theories for other types shaped charges were insufficient for the LSC, possibly because of the relatively slow projectile created by …

Micro/Nano-Structural Examination And Fission Product Identification In Neutron Irradiated Agr-1 Triso Fuel, I. J. Van Rooyen, T. M. Lillo, H. M. Wen, C. M. Hill, T. G. Holesinger, Y. Q. Wu, J. A. Aguiar

Materials Science and Engineering Faculty Publications and Presentations

Advanced electron microscopic and micro-analysis techniques were developed and applied to study irradiation effects and fission-product behavior in selected low-enriched uranium-oxide/uranium-carbide tristructural-isotropic (TRISO)-coated particles from fuel compacts in four capsules irradiated to burnups of 11.2 to 19.6% fissions per initial metal atom (FIMA) consisting of Baseline, Variant 1, and Variant 3 fuel types. Trend analysis shows precipitates were mostly random in their distribution along the perimeter of the inner pyrolytic carbon-silicon carbide (IPyC-SiC) interlayer with only weak association with kernel protrusion and buffer fractures. Pd is dominantly found in most precipitates in both intra and intergranular locations. Nano-sized Ag is …

Integrating Computational Modeling Modules Into Undergraduate Materials Science And Engineering Education, Lan (Samantha) Li

Materials Science and Engineering Faculty Publications and Presentations

To meet national workforce need, we integrated computational modeling training into undergraduate materials science and engineering (MSE) courses, including Thermodynamics, and Structure of Materials. We also flipped the courses, requiring students to self-study topics outside the class. In the class, the instructors focused on demonstrating real-world materials problems and guiding the students to solve the problems using different computational modeling techniques. Learning the computational modeling concepts within a short period of time was challenging to the students. Another challenge was that the students had various STEM backgrounds, such as MSE, mechanical engineering, and physics. In order to foster student learning, …

Fatigue Properties Of Magnetorheological Elastomers And The Design Of Interfacial Layers To Improve Fatigue Life., Yanfen Zhou

Doctoral

The primary aim of this PhD programme was to understand the fatigue behaviour of magnetorheological elastomers (MREs) and provide a reliable fatigue life predictor for this class of materials. To realise this aim required the study of the dynamic behaviour of MREs using the equi-biaxial bubble inflation test method. Isotropic and anisotropic MREs were fabricated from silicone rubber (SR) filled with soft carbonyl iron (CI) particles. The equi-biaxial fatigue behaviour of these samples was determined using a bubble inflation method. Wöhler (S-N) curves for both isotropic and anisotropic MREs were produced by subjecting the compounds to cycling over a range …