Materials Science and Engineering Commons^™

Synthesis, Device Fabrication, And Characterization Of Two-Dimensional Molybdenum Disulfide, Gustavo Alberto Lara Saenz

Open Access Theses & Dissertations

The miniaturization of electronic devices according to Moore's Law has been propelled by the continuous demand for faster and smaller devices which continue to advance technology. One recent contribution to this trend was the isolation and characterization of one atom thick of graphite, known as graphene, which led to the Nobel Prize in physics in 2010 being awarded to Andre Geim and Konstantin Novoselov. Graphene and its related nanocarbon derivatives have exceptional mechanical, thermal, optical and electronic properties, making them a potential candidate for electronics and optoelectronics applications. However, this material has no intrinsic bandgap and complicated processes are required …

Implementation Of New System For Oxygen Generation And Carbon Dioxide Removal, Angelo Peter Karavolos

Open Access Theses & Dissertations

This research effort develops an integrated system for CO2 removal and O2 production. A unique material, dodeca-tungsto-phosphoric acid (H3PO4W12O3; henceforth referred to as DTPA) is mixed with tetra-ethyl-ortho-silicate Si(OC2H5)4 or TEOS. This mixture exhibits unique properties of heat absorption and high electrical conductivity. In the system described herein, the DTPA resides within a cross linked arrangement of TEOS. The DTPA furnishes a source of O2, while the TEOS furnishes structural support for the large DTPA crystals. In addition, the large amount of H2O within the crystal also adsorbs CO2. It can also be cross-linked with other polymers such as polycarbonate, …

Vascularization In Interconnected 3d Printed Ti-6al-4v Foams With Hydrogel Matrix For Biomedical Bone Replacement Implants, Victor Correa

Open Access Theses & Dissertations

Abstract:

Vascularization or angiogenesis on newly implanted metal orthopedic implants has remained a challenge in the field of tissue engineering. In this research, an interconnected foam structure of Ti-6Al-4V was micro-fabricated by Electron Beam Melting (EBM) technique. The foam in question has a density of 1.77g/cm3 with 60% porosity and a tensile strength of 18GPa. An Extracellular Matrix based hydrogel was added as an aqueous matrix to the foam in question. Hypoxia mimetic stress has been closely related to many wound healing biomedical applications as it increases survival and proliferation molecular signals. To that end, increased expression of Hypoxia-Inducible Factor-1α …

Liquid-Phase Exfoliation Of Two-Dimensional Graphite For Ink-Jet Printing, Monica Michel

Open Access Theses & Dissertations

Over the last decade, the study of two-dimensional (2D) materials has seen an incredible growth due to their unique thermal, mechanical and electronic properties. Solution phase manufacturing offers a way in which they can be produced at large scale by creating dispersions from the exfoliated material. Once created, different options for assembling devices exist. One technique for large scale manufacturing of materials in this form is ink-jet printing, which is a form of additive manufacturing that has proven to be attractive for the printed electronics industry. One challenge that ink-jet printing still faces is the shortage of inks with appropriate …

Investigation Of Ti-6al-4v Alloy Response To Atmospheric Re-Entry Exposure, Jessica Lynn Buckner

Open Access Theses & Dissertations

Ti-6Al-4V is a widely used aerospace alloy for its high strength-to-weight ratio and high operating temperature properties. Despite widespread use, titanium and its alloys have been shown to ignite in oxygen and nitrogen rich test streams. The reactivity of titanium is attributed to the high solubility for oxygen that increases with temperature, accelerating the oxidation rate and resulting in a combustion reaction. When introduced to the monatomic oxygen rich and high enthalpy re-entry environment, Ti-6Al-4V X-link components from the space shuttle Columbia exhibited accelerated oxidation and combustion behavior. Ti-6Al-4V metal plates tested in the simulated re-entry environment of an arc-jet …

Phase Transformation And Growth Kinetics In Reaction Zone Between Uranium Alloy And Zirconium Diffusion Barrier, Young Joo Park

Electronic Theses and Dissertations

U-10wt.%Mo (U10Mo) alloy as a part of monolithic fuel system is being developed under Material Management and Minimization Reactor Conversion (MMMRC) program, tasked with replacing high-enriched uranium (HEU) fuel with low-enriched uranium (LEU) fuel in civilian research and test reactors. Use of U10Mo fuel alloy entails a Zr diffusion barrier to avoid the undesirable interdiffusion and reactions between the U10Mo and Al-alloy cladding. To better understand the interaction between these fuel system constituents, microstructural development and diffusion kinetics in U-Mo-Zr, U-Zr and fuel plate assembly processed by co-rolling and hot isostatic pressing (HIP) were investigated using a variety of analytical …

Urea Pre-Treatment Of N2-Annealed Transition Metal Oxides For Low Cost And Efficient Counter Electrodes In Dye-Sensitized Solar Cell, Hytham Elbohy

Electronic Theses and Dissertations

Photovoltaic cells have shown great promise as an alternative to fossil fuel-based energy sources. Dye-sensitized solar cells (DSSCs) have shown potential as low-cost replacement to silicon solar cells owing to their reduced material costs and simple fabrication techniques. Platinum (Pt) was used as a catalyst in the counter electrode for DSSCs. Metal oxides have been used as an alternative material to Pt. The introduction of oxygen vacancies inside metal oxides helps to facilitate electron transport to the electrolyte to enhance the reduction process of triiodide ions. Annealing n-type metal oxides under a reducing agent gas such as hydrogen (H2) at …

Integrated Tandem Dye Sensitized Solar Cell (Dssc)-Lithium Ion Battery, Geetha Varnekar

Electronic Theses and Dissertations

Efficient renewable energy harvesting and storage are needed for present challenges related to clean environment and increasing energy demand. Different types of energy harvesting technologies such as solar, thermal and wind require excess energy to be stored in batteries, which further adds to the complication and increase in cost to the overall renewable energy system. Integrating the generation and storage of solar energy in a single device would be a more cost effective way towards meeting the increasing energy demand due to its simplicity in design and less space consumptions. Herein, a sustainable photovoltaic cell integrated with an energy storage …

Low Temperature Solution-Processed Sb:Sno2 Nanocrystals For Efficient Planar Perovskite Solar Cells, Yang Bai, Yanjun Fang, Yehao Deng, Qi Wang, Jingjing Zhao, Xiaopeng Zheng, Yang Zhang, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

Inorganic metal oxide electron-transport layers (ETLs) have the potential to yield perovskite solar cells with improved stability, but generally need high temperature to form conductive and defect-less forms, which is not compatible with the fabrication of flexible and tandem solar cells. Here, we demonstrate a facile strategy for developing efficient inorganic ETLs by doping SnO₂ nanocrystals (NCs) with a small amount of Sb using a low-temperature solution-processed method. The electrical conductivity was remarkably enhanced by Sb-doping, which increased the carrier concentration in Sb:SnO₂ NCs. Moreover, the upward shift of the Fermi level owing to doping results in improved …

Microwave Material Characterization Of Alkali-Silica Reaction (Asr) Gel In Cementitious Materials, Ashkan Hashemi

Doctoral Dissertations

"Since alkali-silica reaction (ASR) was recognized as a durability challenge in cement-based materials over 70 years ago, numerous methods have been utilized to prevent, detect, and mitigate this issue. However, quantifying the amount of produced ASR byproducts (i.e., ASR gel) in-service is still of great interest in the infrastructure industry. The overarching objective of this dissertation is to bring a new understanding to the fundamentals of ASR formation from a microwave dielectric property characterization point-of-view, and more importantly, to investigate the potential for devising a microwave nondestructive testing approach for ASR gel detection and evaluation. To this end, a comprehensive …

Synthesis And Functionalization Of A Triaryldiamine-Base Photoconductive/Photorefractive Composite, And Its Application To Aberrated Image Restoration, Yichen Liang

Doctoral Dissertations

"Organic photorefractive (PR) composites have recently emerged as an important class of materials for applications including high-density data storage, optical communication, and biomedical imaging. In an effort to further improve their performance, this study focused on the utilization of functionalized semiconductor nanocrystals to photosensitize triaryamine (TPD)-based PR composites, as well as the application of TPD-based PR composites in the restoration of aberrated optical information. A novel approach to functionalize CdSe quantum dot (QCdSe) was firstly introduced where the sulfonated triarydiamine (STPD) was used as charge-transporting ligand to passivate QCdSe. TPD-based photoconductive and PR composites were photosensitized with the STPD-passivated QCdSe …

On The Spheroidal Graphite Growth And The Austenite Solidification In Ductile Irons, Jingjing Qing

Doctoral Dissertations

"Evolutions of austenite and nodular/spheroidal graphite particles during solidifications of ductile irons were experimentally investigated. Spheroidal graphite particle and austenite dendrite were found nucleated independently in liquid. Austenite dendrite engulfed the spheroidal graphite particles after contact and an austenite shell formed around a spheroidal graphite particle. The graphite diameter at which the austenite shell closed around nodule was determined. Statistically determined graphite size distributions indicated multiple graphite nucleation events during solidification.

Structures in a graphite nodule varied depending on the growth stages of the nodule in ductile iron. Curved graphene layers appearing as faceted growth ledges swept circumferentially around the …

Dft Investigations Of Hydrogen Storage Materials, Gang Wang

Doctoral Dissertations

"Hydrogen serves as a promising new energy source having no pollution and abundant on earth. However the most difficult problem of applying hydrogen is to store it effectively and safely, which is smartly resolved by attempting to keep hydrogen in some metal hydrides to reach a high hydrogen density in a safe way. There are several promising metal hydrides, the thermodynamic and chemical properties of which are to be investigated in this dissertation.

Sodium alanate (NaAlH₄) is one of the promising metal hydrides with high hydrogen storage capacity around 7.4 wt. % and relatively low decomposition temperature of …

Multiphase Field Modeling Of The Formation Path Of Delta Hydrides In Zirconium, Jacob Luke Bair

Doctoral Dissertations

"Zirconium alloys are commonly used in nuclear fuel rod claddings due to their high ductility, good corrosion resistance, and low neutron absorption cross section. Among the most important weaknesses of zirconium alloys is their affinity for hydrogen, resulting in formation of hydrides in the cladding, and leading to embrittlement and mechanical failure. Despite numerous studies on hydride precipitation in zirconium alloys, the nucleation and formation path of stable δ hydrides in α zirconium matrix are not yet fully understood.

In this Ph.D. research project, two novel quantitative phase-field models were developed and utilized to advance our understanding of mechanisms of …

Modeling And Evaluation Of Moisture Diffusion In Polymer Composite Materials, Zhen Huo

Doctoral Dissertations

"Fiber-reinforced polymer composites have extensive applications due to their high specific strength, improved product performance, low maintenance and design flexibility. However, moisture absorbed by polymer composites during the service life plays a detrimental role in both the integrity and durability of composite structure. It is essential to understand the moisture diffusion behavior and induced damage in polymer matrix composites under varying hygrothermal conditions. In Part I, the moisture diffusion characteristics in hybrid composites using moisture concentration-dependent diffusion method have been investigated. Also, a multi-stage diffusion model was proposed to explain the deviation of moisture diffusion behavior for sandwich composites from …

Processing Of Al-12si-Tnm Composites By Selective Laser Melting And Evaluation Of Compressive And Wear Properties, Konda Prashanth, Sergio Scudino, Anil Chaubey, Lukas Löber, Pei Wang, Hooyar Attar, Frank Schimansky, Florian Pyczak, Jürgen Eckert

Research outputs 2014 to 2021

Al-12Si (80 vol%)-Ti52.4Al42.2Nb4.4Mo0.9B0.06 (at.%) (TNM) composites were successfully produced by the selective laser melting (SLM). Detailed structural and microstructural analysis shows the formation of the Al6MoTi intermetallic phase due to the reaction of the TNM reinforcement with the Al-12Si matrix during SLM. Compression tests reveal that the composites exhibit significantly improved properties (∼140 and ∼160 MPa higher yield and ultimate compressive strengths, respectively) compared with the Al-12Si matrix. However, the samples break at ∼6% total strain under compression, thus showing a reduced plasticity of the composites. Sliding wear tests were carried out for both the Al-12Si matrix and the Al-12Si-TNM …

Drying Methods For The Fabrication Of Polymer Foam Material, Dalton Echard

Theses and Dissertations

This is a report on the study of the drying of nanoporous polymer foam material fabricated by photolithogtaphic methods. Three drying methods were employed, which were air drying, supercritical drying and freeze drying. After fabrication and drying, physical properties of the polymer foams were measured. These measurements included density of the material, Young’s modulus, surface area, and the shape of the skeletal particles. The measurements determined the effect of the polymer concentration and the effect of drying methods. It was determined that polymer concentration had a much larger effect on the properties of the materials than the drying method.

Effect Of Poisson’S Ratio On Material Properties Characterization By Nanoindentation With A Cylindrical Flat Tip Indenter, Md Mehadi Hassan

Electronic Theses and Dissertations

Nano indentation technology is commonly used to determine the mechanical properties of different kinds of engineering materials. The young’s modulus of the materials can be calculated with the load depth data obtained from an indentation test with a known Poisson’s ratio. In this investigation the NANOVEA micro/nanoindentation tester with a cylindrical flat-tip indenter will be used to find the elastic modulus, hardness and Pile up. Low carbon steel AISI1018, alloy steel AISI 4340 and aluminum alloy 6061 were selected for the case study. Finite element (FE) analysis using axisymmetric 3-D models used to establish the relationship between Poisson’s ratio and …

Fully Solution Processed Pedot:Pss And Silver Nanowire Semi-Transparent Electrodes For Thin Film Solar Cells, Bjorn Vaagensmith

Electronic Theses and Dissertations

Building integrated photovoltaics (BIPV), such as semitransparent organic solar cells (OSC) for power generating windows, is a promising method for implementing renewable energy under the looming threat of depleting fossil fuels. OSC require a solution processed transparent electrode to be cost effective; but typically employ a nonsolution processed indium tin oxide (ITO) transparent electrode. PEDOT:PSS and silver nanowire transparent electrodes have emerged as a promising alternative to ITO and are solution processed compatible. However, PEDOT:PSS requires a strong acid treatment, which is incompatible with high throughput solution processed fabrication techniques. Silver nanowires suffer from a short lifetime when subject to …

Composite Gel Polymer Electrolyte For Lithium Ion Batteries, Roya Naderi

Electronic Theses and Dissertations

Batteries have been ubiquitously utilized in enormous applications such as portable electronics, satellites, computers, medical instruments, and electric cars. The development of battery technology has been through a long journey since the 17th century, paving its way to commercialization of lithium ion batteries in 1991 by Sony. Rechargeable lithium ion batteries represent the most favorable type of batteries for portable applications due to their high energy density compared to other alkali metals. In 1997, lithium polymer batteries with solid polymer/composite electrolyte were introduced where the safety drawbacks of the liquid electrolyte were eliminated but the ionic conductivity of the batteries …