Materials Science and Engineering Commons^™

Superhydrophilic Porous Coooh Nano-Architecture With Abundant Oxygen Vacancies For Enhanced Urea Electrooxidation At Ampere-Level Current Densities, Wen-Jing Lv, Xiao-Man Tang, Xue-Tong Wang, Wen-Cai Liu, Jian-Wen Zhu, Guo-Jing Wang, Yuan-Zhi Zhu

Journal of Electrochemistry

The conversion of urea-containing wastewater into clean hydrogen energy has gained increasing attention. However, challenges remain, particularly with sluggish catalytic kinetics and limited long-term stability of urea oxidation reaction (UOR). Herein, we report the loosely porous CoOOH nano-architecture (CoOOH LPNAs) with hydrophilic surface and abundant oxygen vacancies (O_v) on carbon fiber paper (CFP) by electrochemical reconstruction of the CoP nanoneedles precursor. The resulting three-dimensional electrode exhibited an impressively low potential of 1.38 V at 1000 mA·cm⁻² and excellent durability for UOR. Furthermore, when tested in an anion exchange membrane (AEM) electrolyzer, it required only 1.53 V at …

First Principles Materials Discovery And Design For Photovoltaic And Solar Thermal Alloys Using High Throughput Methods, Andrew Pike

Dartmouth College Ph.D Dissertations

Materials selection has been a challenge since the dawn of time. With the advent of computational methods and high throughput databases, materials can be discovered and assessed before they are even synthesized. In this thesis I will discuss my work towards designing new materials for clean energy uses, especially alloys which have been underexplored from computational methods. To begin, I present a case study explaining the synthesis of the Yb₁₄ZnSb₁₁ thermoelectric material. Next, I explore the class of AM₂Pn₂ Zintl materials. From the previously identified BaCd₂P₂, it is suspected that …

Structure Regulation Engineering For Biomass-Derived Carbon Anodes Enabling High-Rate Dual-Ion Batteries, Rui Zhou, Rui Liu, Yun-Nuo Li, Si-Jie Jiang, Tian-Tian Jing, Yan-Song Xu, Fei-Fei Cao

Journal of Electrochemistry

Dual-ion batteries (DIBs) usually use carbon-based materials as electrodes, showing advantages in high operating voltage, potential low cost, and environmental friendliness. Different from conventional “rocking chair” type secondary batteries, DIBs perform a unique working mechanism, which employ both cation and anion taking part in capacity contribution at an anode and a cathode, respectively, during electrochemical reactions. Graphite has been identified as a suitable cathode material for anion intercalation at high voltages (> 4.8 V) with fast reaction kinetics. However, the development of DIBs is being hindered by dynamic mismatch between a cathode and an anode due to sluggish Li^{+ …}

Design And Optimization Of Anode Catalysts For Direct Ethanol Fuel Cells: Advances And Challenges In C-C Bond Activation And Selective Modulation Of The C1 Pathway, Kai-Chi Qin, Meng-Tian Huo, Yu Liang, Si-Yuan Zhu, Zi-Hao Xing, Jin-Fa Chang

Journal of Electrochemistry

Direct ethanol fuel cells (DEFCs) are a promising alternative to conventional energy sources, offering high energy density, environmental sustainability, and operational safety. Compared to methanol fuel cells, DEFCs exhibit lower toxicity and a more mature preparation process. Unlike hydrogen fuel cells, DEFCs provide superior storage and transport feasibility, as well as cost-effectiveness, significantly enhancing their commercial viability. However, the stable C–C bond in ethanol creates a high activation energy barrier, often resulting in incomplete electrooxidation. Current commercial platinum (Pt)- and palladium (Pd)-based catalysts demonstrate low C–C bond cleavage efficiency (

Effect Of Saccharin On Crystallization Behavior Of Electroless Cobalt Plating, Yu-Xin Luo, Jing-Jing Wang, Lu Wang, Zi-Yi Yan, Yi Ma, Xin Bo, Jing-Shuang Dang, Zeng-Lin Wang

Journal of Electrochemistry

In the process of electroless cobalt plating, the saccharin additive can significantly change the surface morphology, texture orientation, and conductivity of the cobalt coating layer. When the amount of saccharin was 3 mg·L^–1, the cobalt coating transformed from disordered large grains to a honeycomb structure, with a preferred orientation of (002) facet on hexagonal close-packed (HCP) cobalt crystals. The resistivity of the cobalt film decreased to 14.4 μΩ·cm, and further decreased to 10.7 μΩ·cm after the annealing treatment. When the concentration of saccharin was increased, the grain size was gradually refined and a “stone forest” structure was observed, …

3d-Printable Hydrogel With Rapid Ambient Self-Healing, Anna M. Petre

Research from the Berry Summer Thesis Institute, 2025

Inspired by nature, soft robots composed of compliant (“soft”) materials are well-suited for uncertain, dynamic tasks requiring safe interaction between a robot and its environment. Soft robots with the ability mend minor damage (e.g. perforations, tears) have been enabled by the rapid development of self-healing soft materials. Recently, one of these hydrogel materials (internally dubbed “BeckOHflex”) – made entirely from commercially available precursors – was developed with several appealing characteristics including rapid ambient self-healing, 3D printability on commercial machines, and competitive mechanical properties. However, the self-healing performance of BeckOHflex falls short of competitors that leverage custom-synthesized precursors. This project aims …

Recent Progress And Scientific Challenges In Wire-Arc Additive Manufacturing Of Metallic Multi-Material Structures, Sainand M. Jadhav, Sambhaji Kusekar, Akash Belure, Satyavan Digole, Abhijeet Mali, Muralimohan Cheepu, Manoj Mugale, Suhas Alkunte, Duckbong Kim

Faculty Articles

Metallic multi-material structures are heterogeneous structures characterized by changing composition, microstructures, and site-specific characteristics, advantageous for numerous applications where multifunctionality is desired. Metallic multi-material structures are known as bimetallic structures (BSs), which are functionally graded materials (FGMs). In recent years, wire-arc additive manufacturing (WAAM) advanced as a promising additive manufacturing process to realize the fabrication of these structures due to its high deposition rate, cost-effectiveness, and material utilization efficiency. This review presents a comprehensive overview of the recent progress, processing strategies, and scientific challenges in WAAM of multi-material structures. The paper begins with an introduction to multi-material structures, followed by …

Polymeric Nanocarriers Functionalized With Peptides For Improved Glioblastoma Targeting And Blood–Brain Barrier Permeability, Cristian Antonio Wieczorek Villas Boas, Aaron Priester, Buck E. Rogers, Anthony J. Convertine

Materials Science and Engineering Faculty Research & Creative Works

We report the synthesis of polymeric conjugates designed to penetrate the blood–brain barrier (BBB) and selectively bind glioblastoma (GBM) cells through reversible addition–fragmentation chain transfer (RAFT) polymerization. The resulting materials were engineered to contain peptide macromonomers for cell-specific targeting and integrated DOTA units to facilitate radiolabeling with copper-64 (⁶⁴Cu), yielding radiolabeled conjugates with greater than 95% radiochemical purity. In biodistribution assessments conducted in mice, C1C2 peptide-conjugated polymers showed significantly improved accumulation in brain tissue, supported by brain perfusion analyses confirming efficient BBB penetration. Additionally, flow cytometry evaluations demonstrated specific affinity of GBM-targeted polymer formulations toward U87 glioblastoma cells. …

Performance Properties Of Treated Jute Fabric Laminated By Electrospun Recycled Pet Nanofibers, Md Abdus Shahid, Md Golam Mortuza Limon, Imam Hossain, Md Tanvir Hossain, Tarikul Islam, Md Moslem Uddin

Michigan Tech Publications

Transforming from plastic to environmentally friendly materials is essential for both human health and the protection of the environment. In this work, a modified jute fabric (MJF) laminated with electrospun recycled polyethylene terephthalate (rPET) nanofibers with silver nitrate (AgNO3) is presented. The purpose to apply the silver nitrate and rPET nanofiber mat is to enhance the performance properties of packaging materials like mechanical strength, thermal insulation, moisture resistance, and antibacterial properties. The jute fabric was pretreated with alkali to make it compatible with rPET electrospun nanofibers, which improved breathability with a diameter of 24.70 ± 7.79 nm and an average …

Ceramic Waste As Sustainable Material In Self-Compacting Concrete: Experimental Study And Ann Predictive Modeling, Abderrezak Bouziane, Houssam Slimanou, Mohamed Amin Bouzidi, Nedjima Bouzidi

Journal of Sustainable Construction Materials and Technologies

Recycling of ceramic waste in the construction sector is a promising option for reducing the environmental impacts of the concrete industry. The main objective of this study is the elaboration of a solid predictive model for ceramic waste based self-compacting (SCC) concrete properties, using artificial neural networks (ANN). This further, reduces its environmental impact without compromising satisfactory performance. An experimental approach was adopted with different substitution ratios: 0 to 30 wt% and particle sizes ranging from 3-8 mm and 8-15 mm. Tested properties of modified SCC as compressive strength at 7 and 28 days (fc7, fc28), spread (L), sieve stability …

Comparative Study On The Performance Of Ggbs, Uggbs, And Rha-Incorporated Cement Mortar Mixes, Devansh Goel, Sudarshan D. Kore

Journal of Sustainable Construction Materials and Technologies

The environmental footprint of cement production has accelerated the pursuit of sustainable alternatives in the construction industry. Supplementary cementitious materials (SCMs), particularly those derived from industrial and agricultural waste, offer a promising approach to reducing cement consumption while maintaining performance. This study evaluates the fresh and mechanical behavior of binary, ternary, and quaternary cementitious mortar blends incorporating ground granulated blast-furnace slag (GGBS), ultrafine GGBS (UGGBS), and rice husk ash (RHA) as partial replacements for cement. A total of 32 mortar mixes were designed with water-to-binder (w/b) ratios ranging from 0.3 to 0.5 and varied replacement levels of RHA (0-20%), GGBS …

Magnetic Molecularly Imprinted Polymers For Quercetin Adsorption: Fabrication, Characterization, And Application, Vinitha Ug

Theses and Dissertations

A highly selective Magnetic Molecularly Imprinted Polymer (MMIP) was developed for the detection and purification of Quercetin. The Density Functional Theory was utilized for the selection of suitable monomers based on binding energy interaction between quercetin and monomers (Acrylamide, Acrylonitrile, Methacrylic Acid). From computational studies, Acrylamide was selected as a suitable monomer for the synthesis of MMIP. Under ultrasound irradiation both quercetin and naringin imprinted materials MMIP-Q and MMIP-N were fabricated.

Compared to ultrasound-assisted synthesis, Microwave Synthesis provides uniform heat transfer throughout the reaction solution, which enables uniformity in the size of synthesised material, increases the yield of material and …

Fabrication Of Transparent Conducting Electrodes By Chemical Approaches & Their Application Towards Sensing And Energy Storage, Namuni Sneha

Theses and Dissertations

In the intelligent era, there is a growing demand for developing highly efficient and robust wearable electrodes through simple chemical approaches. We developed highperforming transparent electrodes using interconnected Au nanoparticle networks via a simple liquid-liquid interface approach that offers high conductivity, transparency (>85%), and mechanical durability. Additionally, the prepared electrodes exhibit tunable transmittance and sheet resistance, and the method was also adaptable to various substrates without harsh chemical or thermal treatments.

Furthermore, using Au 1L (1-layer) nanonetwork, a highly transparent breath sensor is fabricated with short response and recovery times (1.1 s and 1.3 s). The Au-1L sensor is …

Effects Of Eogo In Metakaolin-Based Geopolymer, Chaewon Lee, Hoyoung Lee, Jinwoo An, Boo Hyun Nam

Civil Engineering Faculty Publications

Geopolymer concrete uses a geopolymer binder instead of traditional Portland cement; thus, it reduces carbon emissions by a significant amount. In this study, Edge-Oxidized Graphene Oxide (EOGO), a carbon-based nanomaterial, was added into a metakaolin-based geopolymer, and its effect on the mechanical and rheological properties of the mixture was investigated. EOGO was added into the mixture at 0% (control), 0.1%, 0.5%, and 1% of the metakaolin mass. Several experiments were conducted to characterize the properties of the metakaolin–EOGO (MKGO) geopolymer, including its compressive strength, free–free resonance column (FFRC), void content, water absorption, setting time, flow, and rheology. It was found …

Development Of Powder Activator From Agro-Industrial Waste And Its Application In The Preparation Of One-Part Alkali Activated Concrete, Anoop Kn

Theses and Dissertations

The environmental concerns associated with the traditional ordinary Portland cement (OPC) such as CO2 emission and high energy demand along with resource depletion as binder has led to the development of alkali activated binders (AABs). Even with the reduction in environmental issues, the implementation of AAB in practice is hindered by the handling issues of liquid activators. Hence, it is required to develop AAB with powdered activators to address the handling issues and to further reduce the environmental issues related to the production of activators. This research investigates the development of one-part alkali-activated concrete (OAAC) system utilising wastederived materials as …

A Review On Connection Forms Between Bridge Guardrails And Bridge Decks, Li Wei, Li Rutao, Jia Ning, Lu Jian

Journal of China & Foreign Highway

In recent years,with the continuous expansion of highway bridge construction in China,there has been a growing public demand to enhance road safety and the protective capabilities of highway bridges.To meet the engineering application requirements of various bridge forms and bridge guardrails,diverse connection structures between bridge guardrails and bridge decks have been studied both domestically and internationally.However,in current engineering practice,the selection of these connection forms remains challenging,lacking clear reference criteria.Using the analytic hierarchy process and supported by experimental data,this paper comprehensively analyzed the advantages and disadvantages of these connection forms by considering factors such as guardrail protection effectiveness,load-bearing reliability,construction convenience,and ease …

Effect Of Granite Machine-Made Sand Properties On Concrete Performance, Wang Jiliang, Wei Xinyuan, Yu Bo

Journal of China & Foreign Highway

As an important stone resource in China,granite is widely used in the preparation of machine-made sand and other building materials due to its stable physical properties and favorable mechanical performance.In order to promote the better application of granite in machine-made sand for cement concrete,this paper analyzed the mineral composition,particle grading,and mica content of granite machine-made sand.It systematically summarized the influence of these characteristics on the mechanical properties,durability,and volumetric stability of concrete.The results show that the concrete performance declines with increasing mica and stone powder content in granite machine-made sand.Properly limiting their content can improve the mechanical properties and durability of …

Wind Tunnel Test Study On Vortex-Induced Vibration Performance Of Cable-Stayed Bridge With Double-Side Box Open Section Composite Main Girder, Zhou Guohua, Du Guoqiang, Pei Shan, Ding Wangxing, Zhu Zhiwen

Journal of China & Foreign Highway

In order to evaluate the vortex-induced vibration (VIV ) performance of a single-tower ground-anchored cable-stayed bridge with a double-side box open section composite main girder,sectional model wind tunnel tests were conducted under different wind angles of attack and wind speeds.The results show that the torsional stiffness of the π-shaped open section main girder is significantly higher than its vertical bending stiffness.The dominant vibration mode of the main girder is the obvious vibration of the main span,while the ground-anchored abutment effectively stabilizes the cable tower through the back stays.At the damping ratio level specified in the code,within the range of prevailing …

Research On Crack Identification Technology Based On Sobel + Matched Filter Joint Algorithm, Wen Yan, Guo Xiaoqian, Tang Youzhi, Yang Enhui, Qiu Yanjun

Journal of China & Foreign Highway

To address the problems of hollow recognition results,high noise,and poor crack continuity in pavement crack identification using the Sobel algorithm,this paper proposed a joint algorithm combining the Sobel algorithm and matched filter for three-dimensional crack recognition of asphalt pavement.A matched filter in the form of a sine function was designed,and the matched filter was used to extract crack features from the results of the Sobel algorithm.The matched filter results were subjected to threshold filtering and connected domain analysis to effectively solve the hollow recognition problem,while also reducing noise and improving crack continuity.The test results show that the Sobel + matched …

Research On Prefabrication Scheme Of Concrete Barrier Based On Anchorage In Cast-In-Situ Layer, Liang Xiaochong, Kang Hanjing, Luo Yongchuan, Wen Zhiquan, Deng Bao

Journal of China & Foreign Highway

In order to improve the on-site construction efficiency of bridge concrete barriers,a prefabrication scheme for bridge concrete barrier installation was proposed.A structure scheme was developed by anchoring transverse steel bars at the bottom of prefabricated wall panels into the integrated cast-in-situ layer,adopting tongue-and-groove connections between adjacent wall panels,and optimizing the structural configuration and reinforcement of the panels.According to the requirements of the Level VI protection standard,full-scale impact tests using a large bus and a large truck were organized in turn.The results show that the prefabricated concrete bridge barrier can effectively withstand continuous impacts from both large buses and trucks.Its structural …