Chemistry Of Inclusions By Size In Three Primary Copper Anodes,
2025
Missouri University of Science and Technology
Chemistry Of Inclusions By Size In Three Primary Copper Anodes, Charles Campbell, Michael Moats
Materials Science and Engineering Faculty Research & Creative Works
Three copper anodes from different commercial electro refineries were characterized to measure inclusion chemistry, size (diameter), and morphology. An automated scanning electron microscope (SEM) paired with energy-dispersive X-ray spectroscopy (EDS) was used to examine hundreds of inclusions near the mold and set sides of each anode. The investigation revealed that in the two anodes with less impurities (99.65% Cu and 99.75% Cu), many of the inclusions were Cu2O with an average diameter of 2 microns. The greater impurity anode (99.05% Cu, 4076 ppm Pb, 1939 ppm As, 635 ppm Bi) contained significant numbers of complex oxide inclusions, averaging 4.6 microns …
Tensile Performance Sensitivity To Variations Of Standard 17-4 Ph Heat Treatments On Lpbf-Produced Material,
2025
Missouri University of Science and Technology
Tensile Performance Sensitivity To Variations Of Standard 17-4 Ph Heat Treatments On Lpbf-Produced Material, Ben Brown, Cory Read, Joseph Newkirk, Frank Liou
Materials Science and Engineering Faculty Research & Creative Works
Standard heat treatments for metals of a particular composition are typically designed with the assumption of a conventional starting microstructure, such as that produced by casting or wrought processing. When applied to metals fabricated by Laser Powder Bed Fusion (LPBF) metal additive manufacturing (AM), these heat treatments can produce inconsistent performance due to the unique as-built microstructures. This study investigates how modifications to standard heat treatments for 17-4 PH steel influence the microstructure and mechanical properties of LPBF-fabricated material. Specimens were produced and subjected to varying solutionizing and homogenizing treatments followed by standard aging treatments. Microstructures were characterized using optical …
Melting Behavior Of Direct Reduced Iron Pellets With Different Carbon Content In Molten Steel And Molten Slag,
2025
Missouri University of Science and Technology
Melting Behavior Of Direct Reduced Iron Pellets With Different Carbon Content In Molten Steel And Molten Slag, Fabian Andres Calderon Hurtado, Joseph Govro, Arezoo Emdadi, Ronald J. O'Malley
Materials Science and Engineering Faculty Research & Creative Works
This study investigates the melting behavior of direct reduced iron (DRI) pellets in molten slag and steel baths, focusing on how the carbon content influences the melting rate through the stirring effects of gas evolution on heat transfer. A computational model using COMSOL Multiphysics 6.1 is developed to simulate the temperature profile at the pellet's core and the gas evolution resulting from the reaction between FeO and carbon within the pellet. The model is validated using experimental data from this study as well as literature on the DRI pellet–molten slag system. Results indicate that, despite the increased enthalpy demand associated …
Selective Nickel Leaching And Preparation Of Battery-Grade Nickel Carbonate From Copper-Rich Industrial Intermediate,
2025
Missouri University of Science and Technology
Selective Nickel Leaching And Preparation Of Battery-Grade Nickel Carbonate From Copper-Rich Industrial Intermediate, Janaka Jayamini Wijenayake, Michael S. Moats, Lloyd Masuzyo Mseteka, Lana Alagha
Materials Science and Engineering Faculty Research & Creative Works
The rising demand for electric vehicles (EVs) has driven a significant increase in nickel consumption, a critical element in EV battery production. An industrially viable hydrometallurgical process was developed for the selective recovery of nickel from a copper-rich industrial intermediate, containing approximately 70 wt.% Cu and 6 wt.% Ni, predominantly as sulfides alongside minor impurities. Approximately 90% of nickel was selectively extracted via single-stage atmospheric pressure leaching using HCl and H2O2 at 95 °C for 12 h, with the majority of copper retained in the leach residue, which can be utilized as a valuable feedstock for copper smelters. The selectivity …
Laboratory Investigation Of High-Temperature Preformed Particle Gels For Fluid Control In Granite Cores For Geothermal Applications,
2025
Missouri University of Science and Technology
Laboratory Investigation Of High-Temperature Preformed Particle Gels For Fluid Control In Granite Cores For Geothermal Applications, K. Caleb Darko, Yanbo Liu, Thomas P. Schuman, Mingzhen Wei, Baojun Bai
Chemistry Faculty Research & Creative Works
To understand the applicability of high-temperature preformed particle gel (HT-PPG) for control of short-circuiting in enhanced geothermal systems (EGSs), core flooding experiments were conducted on fractured granite cores under varying fracture widths, gel particle sizes and swelling ratios. Key parameters such as injection pressure, water breakthrough pressure, and residual resistance factor were measured to evaluate HT-PPG performance. The gel exhibited strong injectability, entering granite fractures at pressure gradients as low as 0.656 MPa/m; HT-PPG yields a superior sealing performance by significantly reducing the permeability; and dehydration occurs during HT-PPG propagation, with a dehydration ratio ranging from 4.71% to 11.36%. This …
Additive Manufacturing Of Multi-Material Aircraft Sandwich Structures,
2025
California Polytechnic State University, San Luis Obispo
Additive Manufacturing Of Multi-Material Aircraft Sandwich Structures, Dhriti Mandalam Surendranath Kumar, Cody Van Dyck
College of Engineering Summer Undergraduate Research Program
This SURP proposal is centered around the exploration of the application of 3D printing composite part processing techniques to produce multi-material sandwich structures for high performance applications such as civilian and military aircraft. These processing techniques have the potential to significantly reduce the costs and the environmental impact of existing conventional autoclave composite processing techniques. The exploration of new ‘out-of-autoclave’ composite part processing techniques may help to reduce processing costs and the environmental impact of processing, as well as broaden the engineering applications of cellular core materials beyond their existing engineering applications. 3D printing directly onto sandwich core materials will …
Engaging Students In Materials Engineering Through A Marble-Based Property Ranking Game,
2025
California Polytechnic State University, San Luis Obispo
Engaging Students In Materials Engineering Through A Marble-Based Property Ranking Game, Nathan Cloughley, Alyssa Felix
College of Engineering Summer Undergraduate Research Program
This SURP proposal is centered on the design and development of a Materials Marbles Game, an educational tool designed to introduce students to materials science and materials selection through tactile interaction and hands-on experimentation. The game will incorporate measurement of key material properties—such as mechanical, thermal, electrical, and mass density—using spherical marbles made from different materials. These measurements will then be used to construct a physical Material Property Chart (Ashby-Cebon plot) on a game board, fostering a hands-on, embodied understanding of how different materials behave. The game will also illustrate the thought process behind materials selection, a critical aspect of …
Characterization Of Zwitterion/Salt Electrolyte Blends For Organic Solid Electrolytes In Lithium-Ion Batteries,
2025
California Polytechnic State University, San Luis Obispo
Characterization Of Zwitterion/Salt Electrolyte Blends For Organic Solid Electrolytes In Lithium-Ion Batteries, Sage Alling, Will Vasser
College of Engineering Summer Undergraduate Research Program
Progress toward durable and energy-dense lithium-ion batteries has been hindered by instabilities at electrolyte–electrode interfaces, leading to poor cycling stability, and by safety concerns associated with energy-dense lithium metal anodes. Organic Solid electrolytes (OSEs) can help mitigate these issues; however, OSE conductivity is often limited by sluggish dynamics through rubbery domains. Recent work has suggested that zwitterionic OSEs can self-assemble into superionically conductive domains, permitting decoupling of ion motion and liquid rearrangement timesscales. Although crystalline domains are conventionally detrimental to ion conduction in SPEs, we this work suggests that properly designed semicrystalline OSEs with labile ion–ion interactions and tailored ion …
Active Measurement Of A Micron-Order Gap Under High-Speed And High-Temperature Conditions,
2025
Embry-Riddle Aeronautical University
Active Measurement Of A Micron-Order Gap Under High-Speed And High-Temperature Conditions, Andrew Becker
Doctoral Dissertations and Master's Theses
The hypersonic regime poses numerous challenges that researchers face in the development of hypersonic flight vehicles. Due to their excellent thermomechanical properties, ultra-high-temperature ceramics (UHTCs) have risen as a promising solution to act as a protective barrier between the harsh environment and surface materials of these flight bodies. The mechanical operation of a portable hypersonic simulation device was developed in-house and tested at Argonne National Laboratories (ANL) to gather in-situ material response of prospective UHTC samples when exposed to a hypersonic regime. An edge detection-based algorithm was developed and used in LabVIEW to monitor the health and operation of the …
Machine Learning Classification Of Eeg Responses To Pain-Related Vs Non-Pain-Related Stimulus In Preterm Infants,
2025
York University
Machine Learning Classification Of Eeg Responses To Pain-Related Vs Non-Pain-Related Stimulus In Preterm Infants, Lojain Hamwi, Hang Du, Sara Jasim, Xiaogang Wang, Vibhuti Shah, Carol Cheng, Lorenzo Fabrizi, Maria Fitzgerald, Judith Meek, Nicole Racine, Ian Stedman, Rebecca Pillai Riddell
Michigan Tech Publications
INTRODUCTION: Unmanaged pain in preterm infants can lead to long-term developmental consequences. Current pain assessment methods lack specificity, resulting in possible pain mismanagement in Neonatal Intensive Care Units (NICUs). This study explores the application of machine learning (ML) to differentiate between pain-related and non-pain-related cortical activity in preterm infants. OBJECTIVE: To evaluate the performance of ML models in distinguishing cortical EEG activity during a painful procedure in preterm infants across different postmenstrual ages (PMAs). METHODS: This observational study was conducted from June 2015 to May 2024 at Mount Sinai Hospital in Toronto, Canada, and University College London Hospital, United Kingdom. …
Characterization Of The Fatigue Threshold Behavior Of Uhmwpe,
2025
University of California - Berkeley
Characterization Of The Fatigue Threshold Behavior Of Uhmwpe, Bethany B. Smith, Anurag Roy, Robert O. Ritchie, Lisa A. Pruitt
Faculty Journal Articles
Ultra-high-molecular-weight-polyethylene (UHMWPE) has been the material of choice for bearings in total joint replacements (TJRs) for decades as a result of its excellent wear resistance, chemical inertness, energetic toughness, low friction, and biocompatibility. Utilization of this polymer in orthopedic devices requires oxidation, wear, and fatigue resistance. Balancing these important properties by tailoring processing techniques and modulating microstructural features has been an ongoing endeavor in the field. Research into the clinical applications of UHMWPE has primarily focused on the challenges of wear and oxidation while studies into the realm of fatigue have been more limited. Literature gaps exist in fully understanding …
Bridging Materials And Energy Storage Mechanisms In Zn-I2 Batteries,
2025
Key Laboratory for Colloid and Interface Chemistry Ministry of Education, School of Chemistry and Chemical Engineering Department, Shandong University, Jinan 250100, China
Bridging Materials And Energy Storage Mechanisms In Zn-I2 Batteries, Rong-Qi Liu, Wen-Shuo Shang, Jin-Tao Zhang
Journal of Electrochemistry
Zinc-iodine (Zn-I2) batteries have emerged as a compelling candidate for large-scale energy storage, driven by the growing demand for safe, cost-effective, and sustainable alternatives to conventional systems. Benefiting from the inherent advantages of aqueous electrolytes and zinc metal anodes, including high ionic conductivity, low flammability, natural abundance, and high volumetric capacity, Zn-I2 batteries offer significant potential for grid-level deployment. This review provides a comprehensive overview of recent progress in three critical domains: positive-electrode engineering, zinc anode stabilization, and in situ characterization methods. On the cathode side, anchoring iodine to conductive matrices effectively mitigates polyiodide shuttling and enhances …
Series Reports From Professor Wei’S Group Of Chongqing University: Advancements In Electrochemical Energy Conversions (2/4): Report 2: High-Performance Water Splitting Electrocatalysts,
2025
National Key Laboratory of Special Power Supplies, National-Municipal Joint Engineering Laboratory for Chemical Process Intensification and Reaction, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China
Series Reports From Professor Wei’S Group Of Chongqing University: Advancements In Electrochemical Energy Conversions (2/4): Report 2: High-Performance Water Splitting Electrocatalysts, Ling Zhang, Wang-Yang Wu, Qiu-Yue Hu, Shi-Dan Yang, Li Li, Rui-Jin Liao, Zi-Dong Wei
Journal of Electrochemistry
The unavailability of high-performance and cost-effective electrocatalysts has impeded the large-scale deployment of alkaline water electrolyzers. Professor Zidong Wei’s group has focused on resolving critical challenges in industrial alkaline electrolysis, particularly elucidating hydrogen and oxygen evolution reaction (HER/OER) mechanisms while addressing the persistent activity-stability trade-off. This review summarizes their decade-long progress in developing advanced electrodes, analyzing the origins of sluggish alkaline HER kinetics and OER stability limitations. Professor Wei proposes a unifying “12345 Principle” as an optimization framework. For HER electrocatalysts, they have identified that metal/metal oxide interfaces create synergistic “chimney effect” and “local electric field enhancement effect”, enhancing selective …
Local Electric Fields Coupled With Cl− Fixation Strategy For Improving Seawater Oxygen Reduction Reaction Performance,
2025
School of Marine Science and Engineering, Hainan University, Haikou 570228, Hainan, China
Local Electric Fields Coupled With Cl− Fixation Strategy For Improving Seawater Oxygen Reduction Reaction Performance, Yu-Rong Liu, Miao Zhang, Yan-Hui Yu, Ya-Lin Liu, Jing Li, Xiao-Dong Shi, Zhen-Ye Kang, Dao-Xiong Wu, Peng Rao, Ying Liang, Xin-Long Tian
Journal of Electrochemistry
Development of robust electrocatalyst for oxygen reduction reaction (ORR) in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries (SZABs). Herein, constructing a local electric field coupled with chloride ions (Cl−) fixation strategy in dual single-atom catalysts (DSACs) was proposed, and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte, with a high half-wave potential (E1/2) of 0.868 V and a good maximum power density (Pmax) of 182 mW·cm−2 in the assembled SZABs, much higher than those of the Pt/C catalyst (E1/2: 0.846 V; Pmax: 150 mW·cm−2 …
Significantly Enhanced Oxygen Reduction Reaction Activity In Co-N-C Catalysts Through Synergistic Boron Doping,
2025
Laboratory of Advanced Power Source, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China; School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei, 230026, China; Jilin Province Key Laboratory of Low Carbon Chemical Power Sources, Changchun 130022, China; State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese, Academy of Sciences, Changchun 130022, China
Significantly Enhanced Oxygen Reduction Reaction Activity In Co-N-C Catalysts Through Synergistic Boron Doping, Chang Lan, Jing-Sen Bai, Xin Guan, Shuo Wang, Nan-Shu Zhang, Yu-Qing Cheng, Jin-Jing Tao, Yu-Yi Chu, Mei-Ling Xiao, Chang-Peng Liu, Wei Xing
Journal of Electrochemistry
The weak adsorption energy of oxygen-containing intermediates on Co center leads to a considerable performance disparity between Co-N-C and costly Pt benchmark in catalyzing oxygen reduction reaction (ORR). In this work, we strategically engineer the active site structure of Co-N-C via B substitution, which is accomplished by the pyrolysis of ammonium borate. During this process, the in-situ generated NH3 gas plays a critical role in creating surface defects and boron atoms substituting nitrogen atoms in the carbon structure. The well-designed CoB1N3 active site endows Co with higher charge density and stronger adsorption energy toward oxygen species, …
Microstructure Densification In Cement Pastes Enabled By Novel Graphene Types,
2025
Missouri University of Science and Technology
Microstructure Densification In Cement Pastes Enabled By Novel Graphene Types, Sahil Surehali, Taihao Han, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath
Materials Science and Engineering Faculty Research & Creative Works
The primary barriers hindering graphene's widespread adoption as a performance-enhancing additive in cement-based systems have traditionally been its prohibitive cost and the sustainability concerns associated with conventional manufacturing processes. However, these impediments have recently been mitigated by advancements in detonation synthesis techniques, enabling scalable, cost-effective, and environmentally favorable production of novel graphene types—specifically fractal graphene (FG) and reactive graphene (RG). This paper explores the influence of ultra-low dosages of FG and RG (≤ 0.04 % by mass of cement, which results in ∼20 % increase in compressive strengths) on the pore-structure features of cement pastes. Compared to the control paste, …
Improvement Of Lithium-Metal Electrode All-Solid-State Batteries Performance By Shot Peening And Magnetron Sputtering,
2025
Institute of Science Tokyo
Improvement Of Lithium-Metal Electrode All-Solid-State Batteries Performance By Shot Peening And Magnetron Sputtering, Atsuro Okumura, Manabu Kodama
15th International Conference on Shot Peening
To enable fast charging in lithium-metal anode all-solid-state batteries, suppressing lithium dendrite formation at the solid electrolyte (SE) interface is critical. Increasing fracture toughness via shot peening (SP) and improving interfacial contact with Au sputtering can inhibit dendrite growth. However, conventional sputtering may reduce toughness due to localized thermal damage. This study investigated magnetron sputtering as a low-damage, plasma-based Au deposition method. SEs with and without SP were fabricated and coated via normal and magnetron sputtering. Critical current density (CCD) and fracture toughness were evaluated. Without SP, CCD improvement was limited regardless of sputtering method due to poor bonding. With …
Hydrogen Embrittlement In Shot-Peened Steel,
2025
Purdue University
Hydrogen Embrittlement In Shot-Peened Steel, Jia-Huei Tien, David R. Johnson, David Bahr
15th International Conference on Shot Peening
This work investigates the role of shot peening on hydrogen embrittlement resistance in quenched and tempered 1070 steel. Thermal desorption spectroscopy results revealed that shot-peened specimens contained nearly twice the hydrogen (H) content of unpeened samples when charged under the same electrochemical conditions, suggesting the introduction of additional trapping sites occur during peening. The mechanism underlying this behavior can be associated with increased dislocation density and is more consistent with the HELP mechanism. Residual stress measurements show a significant relaxation of compressive stresses in shot-peened specimen after H charging, indicating H enhanced dislocation rearrangement. Both unpeened and peened specimens exhibited …
Anisotropic Residual Stress Measurements In Additively Manufactured 316 Stainless Steel Parts,
2025
Purdue University
Anisotropic Residual Stress Measurements In Additively Manufactured 316 Stainless Steel Parts, Rajeshree Varma, Donovan Stumpf, Paul R. Mort
15th International Conference on Shot Peening
Additive manufacturing (AM) using laser powder bed fusion (L-PBF) is increasingly used to produce complex parts for industries like aerospace and medical devices. The intrinsic characteristics of AM – layer-wise deposition and rapid thermal cycling – generate significant, anisotropic, residual stresses that can compromise part quality and performance. Recent studies highlight how these stresses are strongly influenced by process parameters and build orientation. X-ray diffraction (XRD) techniques, including sin²ψ and advanced two-dimensional approaches, have become the preferred methods for non-destructive, directionally resolved measurement of residual stress in AM metals. This review surveys advancements in XRD residual stress methods with a …
From Strain To Stress: Stress Map Testing Of Almen Strips,
2025
Purdue University
From Strain To Stress: Stress Map Testing Of Almen Strips, Donovan Stumpf, Rajeshree Varma, Paul R. Mort
15th International Conference on Shot Peening
Almen strips have long been used to evaluate shot peening intensity, with arc height serving as a proxy for compressive residual stress. Stress mapping tests (SMT) in this work involve the controlled flattening of an Almen test strip onto a spatial pressure sensor, acting as an inferential measurement for the net bending moment caused by the relaxation of the peened strip. This work explores how stress mapping tests add insight into the stress state of Almen strips, potentially offering a fast and practical alternative to residual stress depth profiling. SMT data analysis provides a framework for relating Almen gauge height …
