Development Of A Digestion Procedure Using Fe2+ Ions For Electrochemical Detection Of Mno2 Particles In Drinking Water,
2025
Department of Chemistry, Queen’s University, 90 Bader Lane, Kingston, ON K7L 3N6, Canada; Beaty Water Research Centre, Queen’s University, 69 Union St., Kingston, ON K7L 3N6, Canada
Development Of A Digestion Procedure Using Fe2+ Ions For Electrochemical Detection Of Mno2 Particles In Drinking Water, Kayla Elliott, Sarah Jane Payne, Zhe She
Journal of Electrochemistry
Developing methods for detection contaminants in drinking water is essential to ensuring that safe and acceptable quality drinking water is delivered to consumers. While manganese (Mn) was previously known only as a mere aesthetic issue, recent epidemiological data has shown to have negative neurological effects on humans, especially on children, prompting new health-based guidelines by Health Canada and the World Health Organization. In drinking water, Mn exists predominantly as Mn(II) and Mn(IV), and is regulated based on total Mn levels. Interestingly, measurement of Mn particulate using electroanalytical methods has not yet been reported in the literature. Herein, a digestion procedure …
Regulating Lithium Metal Nucleation And Growth For Dendrite Suppression: From Liquid-Electrolyte To Solid-State Batteries,
2025
Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China
Regulating Lithium Metal Nucleation And Growth For Dendrite Suppression: From Liquid-Electrolyte To Solid-State Batteries, Ao Du, Juan Zhang, Pan Xu, Ya-Jie Li, Kang-Yu Yi, Zhen-Zhen Shen, Hui-Lin Ge, Guang-Wen Zhang, Chao-Hui Zhang, Yu-Hao Wang, Chen-Zi Zhao, Meng-Yang Xu, Yu-Lin Jie, Rui Wen, Shu-Hong Jiao, Si-Qi Shi, Qiang Zhang, Chun-Peng Yang, Yu-Guo Guo
Journal of Electrochemistry
Lithium metal anodes, with a theoretical capacity of up to 3860 mAh·g−1, are regarded as the cornerstone for developing next-generation high-energy-density batteries. However, several key challenges hinder their practical applications, including dendrite formation, unstable solid electrolyte interphase (SEI), side reactions with electrolytes, and associated safety risks. This review systematically explores the mechanisms of lithium nucleation, growth, and stripping in both liquid and solid-state battery systems, analyzing critical theoretical concepts like heterogeneous nucleation thermodynamics, surface diffusion kinetics, space charge effects, and SEI-induced nucleation, which are crucial for understanding the genesis of dendrite growth. Additionally, the review discusses the electrochemical-mechanical …
Biocompatible And Antibacterial Pcl-Tio2@Ag/Γ-Cd Mof Nanocomposite Coating For Corrosion Resistance Of Magnesium Alloy In Simulated Body Fluid,
2025
Department of Chemistry, Yazd University, Yazd, 89195-741, Iran
Biocompatible And Antibacterial Pcl-Tio2@Ag/Γ-Cd Mof Nanocomposite Coating For Corrosion Resistance Of Magnesium Alloy In Simulated Body Fluid, Sara Dehghan-Chenar, Hamid R. Zare, Zahra Mohammadpour, Maryam Sadat Mirbagheri-Firoozabad
Journal of Electrochemistry
Magnesium alloys are promising candidates for bio-implant applications due to their biodegradability and biocompatibility. However, their rapid corrosion remains a critical limitation. This study presents the development of a multifunctional nanocomposite coating designed to enhance the corrosion resistance and antibacterial properties of magnesium alloy implants. The coating comprised γ-cyclodextrin metal-organic frameworks (γ-CD MOFs) decorated with TiO2@Ag core-shell nanoparticles, embedded in a polycaprolactone (PCL) matrix. Immersion tests in a simulated body fluid (SBF) revealed an initially higher corrosion rate for the PCL-TiO2@Ag/γ-CD MOF coating compared to the coating without TiO2@Ag nanoparticles; however, it demonstrated significant …
Integrating Complete Bond Dissociation In Class Ii Force Fields,
2025
Michigan Technological University
Integrating Complete Bond Dissociation In Class Ii Force Fields, Joshua Kemppainen, Hendrik Heinz, Gregory M. Odegard
Michigan Tech Publications
Predicting the physical and mechanical properties of organic materials from purely chemical understandings remains a significant challenge due to the limitations of conventional force fields in molecular dynamics (MD). In this work, we present a novel reformulation of Class II force fields that integrates Morse bond potentials with newly derived cross-term interactions, explicitly capturing complete bond dissociation while maintaining computational efficiency. This reformulated functional form combines the stability of fixed-bond models with the reactive capabilities of bond-breaking force fields, achieving accurate and robust MD predictions across crystalline, semi-crystalline, and amorphous organic systems. Extensive benchmarking confirms its predictive accuracy and speed, …
Investigation Of Electrochemical Corrosion Fatigue Mitigation Strategies For Mild Carbon Steel,
2025
Louisiana Tech University
Investigation Of Electrochemical Corrosion Fatigue Mitigation Strategies For Mild Carbon Steel, Joel Andrew Hudson
Doctoral Dissertations
Corrosion fatigue remains a critical durability challenge for steels used in boiler tubes and other safety-critical components, where the interaction of cyclic stresses and corrosive environments accelerates material degradation. This dissertation comprises three experimental studies aimed at advancing mitigation strategies and test methodologies: (1) enhancing corrosion resistance through electrodeposited Fe-Ni anodic coatings, (2) inducing synthetic crack closure to suppress fatigue crack growth, and (3) developing an accessible, low-cost, automated testing system to investigate environmentally assisted cracking (EAC) under controlled laboratory conditions. The first study examined the corrosion behavior of Fe and Fe-Ni electrodeposits synthesized from sulfate-based baths and applied to …
A Magnesium Alloy With High Corrosion Resistance, Hardness And Elastic Modulus Enabled By Elemental Synergy,
2025
North Carolina State University
A Magnesium Alloy With High Corrosion Resistance, Hardness And Elastic Modulus Enabled By Elemental Synergy, Alexander Helmer, Manoj V. Mugale, Tushar Borkar, Rajeev K. Gupta
Mechanical Engineering Faculty Publications
A magnesium alloy containing Ca, Ti, Zn, and In was synthesized via high-energy ball milling of elemental powders followed by spark plasma sintering. X-ray diffraction and scanning electron microscopy revealed a homogeneous matrix with dispersed Mg-rich phases and intermetallics. Potentiodynamic polarization tests revealed low corrosion current density (9.6 f 2.1 mu A/cm2), a noble corrosion potential (-1197 f 4 mVSCE), and a clear passive region, indicating excellent corrosion resistance. Nanoindentation tests showed high hardness (2.61 f 0.21 GPa) and elastic modulus (55.35 f 5.47 GPa), exceeding those of commercial Mg alloys.
Test Data: Raised Or Recessed? Finding The Optimal Gate Architecture For Improving The Static Performance Of Graphene Transistors,
2025
Rochester Institute of Technology
Test Data: Raised Or Recessed? Finding The Optimal Gate Architecture For Improving The Static Performance Of Graphene Transistors, Ivan Puchades, Tzu-Jung Huang, Andrew Spencer, Luke Ingraham, Anibal Pacheco
Data
As silicon CMOS technology approaches its scaling limits, graphene offers a compelling alternative as the active material channel in transistors due to its high carrier mobility and atomically thin profile, which provide strong electrostatic control and promise high-performance analog applications. However, roadblocks such as device-to-device variation, high contact resistance, poor dielectric interfaces, and non-uniform graphene quality have limited the adoption of graphene field effect transistors (GFETs). Hence, further investigations are required for mitigating these issues at a material, e.g., by improving graphene transfer, and device level, e.g., by finding an appropriate gate architecture. In this work, we directly compare two …
Effect Of Cryo-Milling On Pla/Cmc And Pla/ Caco3 Composites: A Comparison Study,
2025
Thomas Jefferson University
Effect Of Cryo-Milling On Pla/Cmc And Pla/ Caco3 Composites: A Comparison Study, Fatemeh Mahdiyeh-Boroujeni, Ron Kander
School of Design and Engineering Papers
This study examines a new approach for improving the dispersion of hydrophilic fillers into a hydrophobic polymer matrix, a long-standing challenge that often limits the thermal and mechanical performance of biocomposites. Two different fillers, natural cellulose microcrystals (CMC) and mineral calcium carbonate (CaCO3), were incorporated into polylactic acid (PLA) at five different weight fractions. Biocomposite films were prepared using physical mixing and cryo-milling, followed by hot pressing. Cryo-milling was explored as a strategy to enhance filler distribution within the matrix. Thermal properties, crystallization behavior, and mechanical performance were characterized using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and tensile testing, …
Thermal Properties Of Novel Materials,
2025
University of South Florida
Thermal Properties Of Novel Materials, Wilarachchige D.C. Bhagya Gunatilleke
USF Tampa Graduate Theses and Dissertations
Thermal properties play an important role in various aspects of applications of technology startingfrom the materials property determinations to device performance improvements and their safety and stability. Measurements of the thermal properties of such materials of interest pose challenges due to the demands of these measurements for determination of intrinsic materials properties. The research included in this dissertation involved both synthesis of novel materials and their measurement of thermal properties. Solid-state materials synthesis involves various synthesis and processing techniques, while specific technological applications demand synthesis of defect-free single crystals. Such synthesis techniques were explored for the research included in this …
Elucidating The Effects Of Water Activity On The Hydration Kinetics And Thermodynamics Of Ye’Elimite–Calcium Sulfate Hydrate Systems,
2025
Missouri University of Science and Technology
Elucidating The Effects Of Water Activity On The Hydration Kinetics And Thermodynamics Of Ye’Elimite–Calcium Sulfate Hydrate Systems, Godwin I. Ogbuehi, Rupack R. Halder, Aditya Kumar, Gaurav Sant, Monday U. Okoronkwo
Materials Science and Engineering Faculty Research & Creative Works
Relative humidity and water activity (aH) reductions have been known to suppress the hydration of anhydrous cement clinker phases. However, the relationship between ye'elimite (C4A3$) hydration kinetics and water activity remain unclear. This study employs experimental and thermodynamic modeling approaches to investigate the influence of water activity on ye'elimite hydration in the "C4A3$ + water", and "C4A3$ + gypsum + water" systems. Experimental findings indicate that as water activity decreases, C4A3$ hydration diminishes until the reaction is brought to a halt at a threshold aH. The critical aHand corresponding solubility constant of C4A3$ (KC4A3S¯) estimated from thermodynamic analysis are 0.46 …
Teaching Strategies In The First-Year Engineering Seminar Course,
2025
West Virginia University
Teaching Strategies In The First-Year Engineering Seminar Course, Wen Juan Mo, Marshal Miezah, Akua Oppong-Anane, Susie Huggins, Lizzie Santiago
Excellence in Education: Teaching Faculty Symposium
This poster highlights innovative teaching strategies implemented in the First-Year Engineering Seminar Course at WVU. Our Fundamental Engineering Program (FEP) team integrates active learning techniques to foster student engagement, critical thinking, engineering identity, as well as major and career exploration.
The Science And Economics Of 3d-Printed Filament Recycling,
2025
Embry-Riddle Aeronautical University
The Science And Economics Of 3d-Printed Filament Recycling, Michael Domingo, Dane Freund, John Mcswiggin, Adam Meadows
Sustainability Conference
In recent years, 3D printing has grown rapidly, both in homes and commercially. This has led to increased demand for plastic filaments, many of which contribute to plastic waste. This project explores the potential of recycling household plastics into 3D printing filament, promoting sustainability and creating a circular economy. Materials like PLA, PETG, ABS, and polypropylene can be recycled or even composted. Existing research has shown that recycled filaments can maintain comparable tensile strength to their virgin counterparts, depending on the recycling process. Furthermore, implementing circular economy practices for plastics could save billions annually by mitigating pollution and reducing landfill …
Effects Of Yttrium And Barium Trace Impurities On The Dielectric Properties Of Srtio3 (111) Single Crystals At Cryogenic Temperatures,
2025
Missouri University of Science and Technology
Effects Of Yttrium And Barium Trace Impurities On The Dielectric Properties Of Srtio3 (111) Single Crystals At Cryogenic Temperatures, Hung Trinh, Alan Devoe, Fatih Dogan
Materials Science and Engineering Faculty Research & Creative Works
Commercially available single crystals of (111) SrTiO3 were found to contain impurities of varying amounts that strongly affected their dielectric performance at cryogenic temperatures. Three crystals with total impurities of 111, 126, and 625 ppm, primarily of barium and yttrium, were analyzed. Relative permittivity (εr) and loss tangent were investigated with high resolution as a function of temperature (4 K to 100 K), DC voltage (0 V/cm to 800 V/cm), and frequency (100 Hz to 1 MHz). An impurity level as low as ≈500 ppm barium resulted in an increase of the maximum permittivity (εm) to approximately 50,000 at …
Scientific Characterization Of Historic Mortars Dating From The 15th-Century Of A Historical Building In Algeria: A Case Study,
2025
University of Science and Technology Houari Boumedienne, USTHB, Algiers, Algeria
Scientific Characterization Of Historic Mortars Dating From The 15th-Century Of A Historical Building In Algeria: A Case Study, M. E. Belgacem, N. Rabahi-Touloum, R. Neves, Y. Ouldkhaoua
Journal of Sustainable Construction Materials and Technologies
This research investigates the historic mortars (Aggregate/Binder (A/B) ratio) of a historical patrimony building, dating from the 15th century, in Algeria, for restoration purposes. It is well known that thorough characterization is essential for successful restoration. To this end, several techniques, including Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), and X-ray Fluorescence (XRF), optical microscope were used to characterize the historic mortars. A mechanical test was used to characterize the compressive strength of a historic mortar. For a comprehensive characterization, A/B ratios were estimated using both Digital Image Analyses (DIA) and chemical analyses. The results obtained provided clear information on …
Universal Crackling Noise Links Plasticity In Nanoindentation With Compression In Metallic Glasses,
2025
University of Illinois at Urbana-Champaign
Universal Crackling Noise Links Plasticity In Nanoindentation With Compression In Metallic Glasses, Jordan Sickle, Wesley H. Higgins, Kerry A. Baker, Mayisha Nakib, Xiaojun Gu, George M. Pharr, Wendelin Wright, Karin A. Dahmen
Faculty Journal Articles
For decades, compression tests have been a standard method for identifying materials properties. However, these tests are slow, destructive, and require fabricating multiple potentially expensive bulk samples. Nanoindentation is fast, almost non-destructive, and requires only a single sample, to which large numbers of indents can be applied. Furthermore, nanoindentation is widely applicable, even to materials that are too brittle for traditional compression tests. Here, we show that nanoindentation is sufficient for extracting much of the same information that is measured in traditional sample compression tests in metallic glasses. The dynamics and statistics of the plasticity of two types of metallic …
Few-Layered Conductive Graphene Foams For Electrical Transdifferentiation Of Mesenchymal Stem Cells Into Schwann Cell-Like Phenotypes,
2025
Cleveland State University
Few-Layered Conductive Graphene Foams For Electrical Transdifferentiation Of Mesenchymal Stem Cells Into Schwann Cell-Like Phenotypes, Ekin G. Simsar, Peifu Cheng, Tugce Dogruel, Maxsam Donta, Juhyung Jung, Naomi A. Asante, Donald S. Sakaguchi, Surya K. Mallapragada, Piran R. Kidambi, Metin Uz
Chemical & Biomedical Engineering Faculty Publications
This study investigates the potential of few-layered conductive graphene foams as 3D platforms for the electrical transdifferentiation of mesenchymal stem cells (MSCs) into Schwann cell (SC)-like phenotypes for peripheral nerve injury (PNI) treatment. The 3D graphene foams (3D-GF) are cytocompatible with MSCs and created a favorable microenvironment for the cells to attach, grow, proliferate, and transdifferentiate. We demonstrated that MSCs cultured within 3D-GF can be transdifferentiated into SC-like phenotypes using the synergistic effects of electrical stimulation and 3D porous and conductive structure. Our immunocytochemistry and gene expression analyses showed the expression of Schwann cell markers and enhanced secretion of growth …
Characterization And Antibacterial Properties Of Centrifugally Spun Polyvinylpyrrolidone/Copper(Ii) Acetate Composite Fibers,
2025
The University of Texas Rio Grande Valley
Characterization And Antibacterial Properties Of Centrifugally Spun Polyvinylpyrrolidone/Copper(Ii) Acetate Composite Fibers, Batool Ibrahim, Roberto Curiel, Sara Ibrahim, Luis A. Materon, Oleg Ermolinsky, Helia Magali Morales, Jason Parsons, Mataz Alcoutlabi
School of Integrative Biological & Chemical Sciences Faculty Publications
The demand for effective antibacterial materials is growing rapidly in today’s world. Both metallic and metal oxide nanoparticles have been widely used as antibacterial agents against various bacterial species due to their unique mechanisms of destroying bacterial membrane cells. The current study explores the antibacterial activity of centrifugally spun fibers prepared from copper acetate polyvinylpyrrolidone (PVP) ethanol precursor solutions against both Gram-negative and Gram-positive bacteria. During the synthesis of the composite fibers, the physical and chemical conditions were optimized. The structure and morphology of the PVP/Cu-Ac fibers were analyzed using scanning electron microscopy (SEM), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy …
Functional Cellulose Nanomaterials In Value-Added Applications,
2025
Louisiana State University and Agricultural and Mechanical College
Functional Cellulose Nanomaterials In Value-Added Applications, Mohammad Shayan
LSU Doctoral Dissertations
Cellulose nanomaterials (CNMs), including cellulose nanocrystals (CNCs) and cellulose nanofibrils (CNFs), offer potential value-added applications. This dissertation explores their versatility through three applications. In the first application, CNCs and CNFs were combined to create a pH-sensitive film by immobilizing anthocyanins from red cabbage extract (RCE). The addition of RCE altered the suspension's rheological, optical, and mechanical properties, with films containing 30 wt.% RCE exhibiting optimal performance and rapid pH responsiveness for seafood packaging. The second application addressed zinc dendrite growth and short circuits in aqueous zinc-ion batteries (ZIBs) by fabricating a hybrid NFC/Al(OH)3 /PTFE protective layer for zinc anodes. …
Strategies For Obtaining High-Performance Li-Ion Solid-State Electrolytes For Solid-State Batteries,
2025
Hubei Key Laboratory of Electrochemical Power Sources, College of Chemistry & Molecular Science, Wuhan University, Wuhan, Hubei 430072, P. R. China
Strategies For Obtaining High-Performance Li-Ion Solid-State Electrolytes For Solid-State Batteries, Yi-Cheng Deng, Zi-Chang You, Geng-Zhong Lin, Guo Tang, Jing-Hua Wu, Zhi-Min Zhou, Xiang-Chun Zhuang, Li-Xuan Yang, Zhen-Jie Zhang, Zhao-Yin Wen, Xia-Yin Yao, Chang-Hong Wang, Qian Zhou, Guang-Lei Cui, Ping He, Hui Li, Xin-Ping Ai
Journal of Electrochemistry
With the widespread adoption of lithium-ion batteries (LIBs), safety concerns associated with flammable organic electrolytes have become increasingly critical. Solid-state lithium batteries (SSLBs), with enhanced safety and higher energy density potential, are regarded as a promising next-generation energy storage technology. However, the practical application of solid-state electrolytes (SSEs) remains hindered by several challenges, including low Li+ ion conductivity, poor interfacial compatibility with electrodes, unfavorable mechanical properties and difficulties in scalable manufacturing. This review systematically examines recent progress in SSEs, including inorganic types (oxides, sulfides, halides), organic types (polymers, plastic crystals, poly(ionic liquids) (PILs)), and the emerging class of soft …
High-Voltage Solid-State Lithium Batteries: A Review Of Electrolyte Design, Interface Engineering, And Future Perspectives,
2025
School of Energy and Power Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China
High-Voltage Solid-State Lithium Batteries: A Review Of Electrolyte Design, Interface Engineering, And Future Perspectives, Cheng Yang, Zi-Xin Liang, Ming-Yun Zhang, Ming-Zhe Chen, Kai Zhang, Li-Min Zhou
Journal of Electrochemistry
Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance. The development of high-voltage positive electrode materials matched with lithium metal anode have advanced the energy density of solid-state lithium batteries close to or even exceeding that of lithium batteries based on a liquid electrolyte, which is expected to be commercialized in the future. However, in high voltage conditions (> 4.3 V), the decomposition of electrolyte components, structural degradation, and interface side reactions significantly reduce battery performance and hinder its further development. This review summarizes the latest research progress …
