Process Intensification For Rare Earth Elements Adsorption By Resonant Vibratory Mixing (Rvm),
2025
Montana Technological University
Process Intensification For Rare Earth Elements Adsorption By Resonant Vibratory Mixing (Rvm), Mehran Saddat
Graduate Theses & Non-Theses
Rare earth elements (REE) are crucial to the advancement of modern technologies. REE applications include electronics, defense systems, wind turbines, catalysts, magnets, and aircraft. Bastnasite, monazite, and xenotime are the primary resources, while the secondary resources, including coal ash, E-waste, and acid mine drainage, are for REE extraction. The primary processing techniques are chemical leaching, ion exchange, chemical precipitation, pyrometallurgy, solvent exchange, biosorption, and adsorption. Adsorption technique is simple, cost-effective, and environmentally friendly, with higher efficiency but at the cost of a longer mixing time. Therefore, there is a pressing need for an optimized mixing technique to improve the adsorption …
Concerted Rattling-Induced Strong Anharmonicity And Phonon Coherence Lead To Ultralow Glasslike Thermal Conductivity In Tlagte,
2025
Indian Institute of Technology Kanpur
Concerted Rattling-Induced Strong Anharmonicity And Phonon Coherence Lead To Ultralow Glasslike Thermal Conductivity In Tlagte, Shantanu Semwal, Yi Xia, Chris Wolverton, Koushik Pal
Mechanical and Materials Engineering Faculty Publications and Presentations
Ordered crystalline compounds exhibiting ultralow and glass-like thermal conductivity are both fundamentally and technologically important, where phonon quasi-particles dominate their heat transport. Understanding the microscopic mechanisms that govern such unusual transport behavior is necessary to unravel the complex interplay of crystal structure, phonons, and collective excitations of these quasi-particles. Here, we use state-of-the-art first-principles calculations based on quantum density functional theory to investigate the origin of experimentally measured unusually low and glassy thermal conductivity in semiconducting TlAgTe that possesses disconnected chains of Tl atoms within its three-dimensional crystalline framework made up of distorted AgTe4 tetrahedra. Utilizing a unifying framework of …
Study Of Isocyanate-Free Vegetable Oil-Based Polyurethane Coating With A Silicon-Based Compound For Coating Properties,
2025
Pittsburg State University
Study Of Isocyanate-Free Vegetable Oil-Based Polyurethane Coating With A Silicon-Based Compound For Coating Properties, Ajay Kumar
Electronic Theses & Dissertations
The development of sustainable and environmentally friendly polyurethane coatings has garnered significant attention in recent years. This research focuses on the development of isocyanate-free coatings derived from carbonated soybean oil (CSBO) using a solvent- and catalyst-free approach. The coatings were synthesized by reacting CSBO with ethylenediamine (EDA) and varying weight percentages of 3-aminopropyltriethoxysilane (APTES), which were added to enhance the coating property, as it contains silicon in it, to evaluate their mechanical and thermal properties. Fourier Transform Infrared Spectroscopy (FTIR) confirmed the successful formation of urethane linkages, with a significant reduction in C=O peak intensity after 10 days of curing, …
In-Situ Investigations Of Calcium-Magnesium-Aluminosilicates (Cmas) Infiltration Effects On Thermal Barrier Coatings Under Extreme Environments Replicating Jet Engines,
2025
Embry-Riddle Aeronautical University
In-Situ Investigations Of Calcium-Magnesium-Aluminosilicates (Cmas) Infiltration Effects On Thermal Barrier Coatings Under Extreme Environments Replicating Jet Engines, Zachary Stein
Doctoral Dissertations and Master's Theses
Calcium-magnesium-aluminosilicate (CMAS) particulates, such as sand or volcanic ash, are ingested by gas turbine jet engines during operation. When operating within high abundance regions, these particulates negatively interact and degrade the high temperature thermal barrier coatings (TBC) protecting underlying superalloy turbine blades vital to engine operation. These CMAS particulates melt within the engine and infiltrate into the ceramic coatings. In electron-beam physical vapor deposited (EB-PVD) TBCs, the CMAS within the intercolumnar gaps stiffens the coatings and causes thermomechanical induced high stress concentrations, risking crack formation. While molten, the CMAS thermochemically alters and destabilizes the coating, also risking coating failure. Premature, …
Influence Of Build Plate Location On Tensile Properties And Residual Stresses In Lpbf-Fabricated Stainless Steel 316 Components,
2025
St. Mary's University
Influence Of Build Plate Location On Tensile Properties And Residual Stresses In Lpbf-Fabricated Stainless Steel 316 Components, Yareli Zelaya Pavón
Honors Program Theses and Research Projects
Additive manufacturing (AM), particularly Laser Powder Bed Fusion (LPBF), enables rapid production of complex metal components with minimal waste. Stainless Steel 316 (SS316) is widely used in engineering applications due to its corrosion resistance and mechanical reliability. This study investigates the influence of build plate location on tensile properties and residual stresses in LPBF-fabricated SS316. Twelve tensile specimens and nine unsupported bridge structures were fabricated at different build plate positions using a “machine model.” Tensile testing provided stress-strain data to evaluate peak stress, elastic modulus, and strain at break, while bridge curvature measurements quantified residual stress through warping. Results indicate …
Building Enveloperetrofitting Innovation: Recycled Materials Role In Digital Fabrication And 3d Printing,
2025
Associate Professor, Head of Department of Architecture, Modern Academy for Engineering and Technology, Cairo, Egypt
Building Enveloperetrofitting Innovation: Recycled Materials Role In Digital Fabrication And 3d Printing, Amr Soliman Elgohary, Haytham M. Elbadrawy, Ahmed Elsamanoudi
HBRC Journal
Traditional construction methods are one of the main causes of resource depletion. This research explores the intersection of digital fabrication methods using recycled materials and eco-friendly construction through retrofitting the building envelope to achieve sustainability. Traditional methods of retrofitting existing building elements consume many resources (materials-energy) and produce a lot of waste. In this context, 3D printing, a modern digital manufacturing method, stands out as a promising alternative, offering innovative ways to reduce material and energy consumption and reduce waste in the building construction process. This technique can be used to produce innovative modules that may improve the environmental performance …
Imaging Of Dynamic Processes In Materials With A Laser-Wakefield Accelerator,
2025
Michigan Engineering
Imaging Of Dynamic Processes In Materials With A Laser-Wakefield Accelerator, J. Kang, R. J. Shalloo, M. J. Higgins, S. J.D. Dann, J. N. Gruse, C. I.D. Underwood, A. F. Antoine, C. Arran, C. D. Baird, M. D. Balcazar, N. Bourgeois, J. A. Cardarelli, K. Krushelnick, S. P.D. Mangles, C. D. Murphy, N. Lu, P. P. Rajeev, M. P. Selwood, D. R. Symes, C. P. Ridgers, A. G.R. Thomas, C. Thornton, Z. Najmudin, P. G. Sanders, P. D. Staublin, A. J. Shahani, M. J.V. Streeter
Michigan Tech Publications
Betatron x rays generated from laser-wakefield accelerators are a promising source for imaging dynamic processes in materials. Here, we present proof-of-concept imaging of microstructural evolution in a hypermonotectic Al-Bi alloy, which consists of liquid Bi particles in a solid Al matrix. The images capture the elongation and fragmentation of Bi particles upon isothermal annealing. Because of the femtosecond time scale of the betatron source, the images are not subject to motion blur, whereas the accessibility of the source allows for studies of long-term processes such as annealing. The high-resolution data reveal that the evolution of Bi particles is mediated by …
Production Of Recombinant Β-Galactosidase Protein In Bombyx Mori (Bmn1) Baculovirus Insect Cells,
2025
The Institute of the Chemistry of Plant Substances, Tashkent, Uzbekistan
Production Of Recombinant Β-Galactosidase Protein In Bombyx Mori (Bmn1) Baculovirus Insect Cells, Shuhrat Sh. Khasanov, Jumanazar Ch Mengturayev, Jaloliddin M. Abdurakhmanov, Dilmurodjon B. Turdaliyev, Shakhnoz S. Azimova
CHEMISTRY AND CHEMICAL ENGINEERING
In this study we aimed to obtain a novel recombinant β-galactosidase baculovirus using the Bombyx mori baculovirus – insect cell expression system. A new recombinant plasmid was constructed on the basis of the pBacPAK8 transfer vector and cloned in E. coli cells. Subsequently, a recombinant baculovirus was generated in Bombyx mori cells, and efficient expression of the β-galactosidase gene was observed. The enzymatic activity of the protein was confirmed by the ONPG assay. The results demonstrated that the baculovirus – insect cell system expands the possibilities for producing proteins of industrial significance.
Photocatalytic Activity Of The Mixed Of Ti/Fe/Mo Oxide Composites For Degradation Of Nitrofurazone,
2025
Tashkent Institute of Chemical Technology, Tashkent, Uzbekistan
Photocatalytic Activity Of The Mixed Of Ti/Fe/Mo Oxide Composites For Degradation Of Nitrofurazone, Dilshoda R. Tursunova, Zuhra Ch. Kadirova, Shahlo Sh. Daminova, Kadriya Kh. Gabidullina
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of study is synthesize mixed oxide composites based on titanium dioxide, iron and molybdenum oxides from industrial waste materials and evaluated for their photocatalytic degradation performance of nitrofurazone—a persistent and toxic antibiotic frequently detected in aquatic environments. Various Ti/Mo ratios (T95M5, T87.5M12.5, T75M25, and T50M50) were prepared through thermal treatment at 600 °C and characterized using XRD, UV–Vis and Raman spectroscopy to assess structural and optical properties.XRD and Raman analyses confirmed the presence of anatase-phase TiO₂ and Mo/Fe oxides, with optimal crystallinity and heterojunction formation observed in the T87.5M12.5 composite. UV–Vis spectroscopic studies demonstrated that this composite exhibited …
Gas Chromatographic Analysis Of Fractions Separated By Atmospheric Distillation Of Pyrolysis Distillate,
2025
Tashkent Institute of Chemical Technology, Tashkent, Uzbekistan
Gas Chromatographic Analysis Of Fractions Separated By Atmospheric Distillation Of Pyrolysis Distillate, Gulnora K. Komolova, Lola A. Yusupova
CHEMISTRY AND CHEMICAL ENGINEERING
The primary objective of this study is to optimize the process of isolating the C9 hydrocarbon fraction from pyrolysis distillate and to evaluate the impact of various temperature regimes on the product composition. To achieve this goal, the dry distillation process was conducted at three different temperatures: 152 °C, 159 °C, and 170 °C. Condensate samples obtained from each test were analyzed using gas chromatography (GC). The analysis results revealed that the fraction obtained at 152 °C yielded the most favorable outcome: the C9 fraction yield was 11.11%, which is higher than the values obtained at 159 °C (4.59%) and …
Lightweight Thermal Insulation Brick Based On Jerdanak Clay Shale, Obtained With The Addition Of Sawdust,
2025
Tashkent Institute of Chemical Technology, Tashkent, Uzbekistan
Lightweight Thermal Insulation Brick Based On Jerdanak Clay Shale, Obtained With The Addition Of Sawdust, Mastura Kh. Aripova, Sarvar T. Bozorov
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of this study was to produce lightweight thermal insulation bricks based on Djerdanak clay shale with the addition of wood sawdust. The starting materials were clay shale from the Djerdanak deposit, fireclay made from it, and wood chips—a waste product from the wood processing industry. The optimal brick composition was determined to include 60% clay shale, 40% fireclay made from clay shale, and 14% wood chips (over 100%). The apparent density of the optimal brick composition corresponds to an apparent product density of 1 g/cm³ and a compressive strength of 3.6 N/mm². The microstructure of the material demonstrates …
Waste Utilization Considering Volatiles Circulation Behavior In Cement Kilns,
2025
Tashkent Institute of Chemical Technology, Tashkent, Uzbekistan
Waste Utilization Considering Volatiles Circulation Behavior In Cement Kilns, Geun-Seong Lee, Farrukh B. Erkinov, Zebo A. Babakhanova, Mukhammadamin Sh. Jololdinov, Mastura Kh. Aripova
CHEMISTRY AND CHEMICAL ENGINEERING
Since the cement kiln process has various advantages for waste incineration, the waste utilization as alternative fuel has been widely applied in the cement process. For waste utilization in kiln process, it is necessary to operate within the range of not-affecting the clinker quality and the operation stability, and not-causing pollution problems, with ensuring the smooth clinker production. In order to quantitatively analyze the volatiles circulation phenomena during waste utilization as alternative fuel in the kiln process, the simplified volatiles circulation model is derived based on material balances of volatiles, from which the permissible waste utilization % as alternative fuel …
Physico-Chemical Study Of Interaction In The “Urea – Glycine – Water” System,
2025
National University of Uzbekistan, Tashkent, Uzbekistan
Physico-Chemical Study Of Interaction In The “Urea – Glycine – Water” System, Suvonkul E. Nurmonov, Saydullo Kh. Azimov
CHEMISTRY AND CHEMICAL ENGINEERING
A comprehensive physicochemical study of the aqueous “urea – glycine” system was conducted to establish the mechanisms of intermolecular interaction and stability parameters for the development of modified liquid nitrogen fertilizers (LNF). Isomolar series, visual-polythermal analysis, X-ray phase analysis (XRD), single-crystal X-ray diffraction (SC-XRD), IR spectroscopy, and thermal analysis (DTA/TGA) methods were applied. It was found that the interaction of components in solution leads to the formation of molecular associates stabilized by hydrogen bonds. The XRD and SC-XRD methods confirmed that no new individual chemical compounds are formed in the solid phase. It was proven that the addition of glycine …
Unlocking The Industrial Potential Of Khojaykon Sylvinite Through Mineralogical And Chemical Investigations,
2025
Tashkent Institute of Chemical Technology, Tashkent, Uzbekistan
Unlocking The Industrial Potential Of Khojaykon Sylvinite Through Mineralogical And Chemical Investigations, Elyor D. Eminov, Kholtura Ch. Mirzakulov, Gavkhar E. Melikulova, Ruslan Ch. Yorbobaev, Kamola S. Arifdjanova
CHEMISTRY AND CHEMICAL ENGINEERING
The purpose of this study is to analyze the chemical, mineralogical, and fractional composition of sylvinite from the Khodjaikan deposit in Uzbekistan in order to assess its potential for potassium fertilizer production. Using chemical analysis, XRD, and IR spectroscopy, the ore was found to contain KCl (19.5–30.1%), NaCl (62.08–71.85%), CaCl₂ (1.12–1.32%), and MgCl₂ (0.18–0.32%). The water-insoluble residue, mainly sulfates, carbonates, and silicates, was also identified. These findings are important for improving beneficiation processes and reducing waste. Comparison with the Verkhnekamsk deposit highlights the quality and potential of Khodjaikan sylvinite. The research supports sustainable resource management.
Changes In The Structure And Properties Of Titanium In The Process Of Pressure Treatment,
2025
University of Geological Scinces, Tashkent, Uzbekistan
Changes In The Structure And Properties Of Titanium In The Process Of Pressure Treatment, Sardor S. Abriev, Nasiba U. Abduraimova, Zokir R. Akramov, Yulbarskhon N. Mansurov
CHEMISTRY AND CHEMICAL ENGINEERING
Titanium is classified as a critical metal. It serves as a raw material for a wide range of industries owing to its unique properties – high strength at low density, corrosion resistance, and biocompatibility makes it indispensable. Uzbekistan and China possess primary resources for titanium production. However, the complexity of extraction and particularly processing, combined with high production costs, limits its large-scale use and increases the risk of shortages in industrial manufacturing. In this study, the structural and property evolution of titanium during pressure-based processing was investigated. Technology for producing powder titanium by metal forming methods is proposed. The results …
The Structure And Properties Of Er2o3 And Yb2o3 Based Ceramic Materials, Sintered Under High Pressure,
2025
State association «Scientific and Practical Center for Materials of National Academy of Sciences of Belarus», Minsk, Belarus
The Structure And Properties Of Er2o3 And Yb2o3 Based Ceramic Materials, Sintered Under High Pressure, Vladimir S. Urbanovich, Vadim D. Zhivulko, Eygeniy N. Poddenezhny, Ekaterina E. Trusova, Vladimir S. Niss
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of the work was to obtain high-density optically transparent ceramic samples by sintering cubic modification Er2O3 and Yb2O3 oxides micropowders at the pressure of 7 GPa and the heating current power of 0.6–1.0 kW, which was demonstrated. Non-monotonic dependence of the density on the heating current power has been established. The maximum density values of 9.2 g/cm3 (Er2O3) and 9.8 g/cm3 (Yb2O3) were achieved at the power of 0.8 and 0.9 kW, respectively. During sintering, the cubic phase partially transforms into the …
Bond Behavior Of Full-Scale Beams Using Sustainable Self-Compacting Concrete,
2025
Missouri University of Science and Technology
Bond Behavior Of Full-Scale Beams Using Sustainable Self-Compacting Concrete, Hayder H. Alghazali, Atheer H.M. Algburi, John J. Myers
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Sustainable concrete is a step towards greener and more eco-friendly concrete construction practices, helping to solve global environmental problems. The present study focuses on the bond behavior between steel reinforcement and greener self-compacting concrete, specifically sustainable self-compacting concrete (SUS-SCC). Three SUS-SCC mixtures with different fly ash (FA) to cement replacement levels of [50, 60, and 70% (by mass)] were developed. Twelve full-scale SUS-SCC beams with a cross-section of (305 x 57) mm and a total length of 3048 mm were cast and tested using a four-point load test setup. The effect of longitudinal and lateral steel reinforcement ratios in the …
Integrating Dft And Machine Learning To Predict Structural Properties In High Entropy Alloys,
2025
Clemson University
Integrating Dft And Machine Learning To Predict Structural Properties In High Entropy Alloys, Nathan Linton
All Dissertations
In the past decade, a paradigm shift in the design of metal alloys has been observed. These new alloys are commonly referred to as high entropy alloys (HEAs), multi-principal element alloys (MPEAs), or complex, concentrated alloys (CCAs). In contrast to conventional alloys, which consist of one main element (for example 80%) with other elements in small amounts, HEAs are made of four or more main elements ranging from 5 to 35% each element. Due to the large presence of multiple elements, HEAs have shown substantial material property improvements over conventional alloys such as steel. For example, they have high ductility …
Additive Manufacturing Of Carbons From Commodity Polyolefins,
2025
The University of Southern Mississippi
Additive Manufacturing Of Carbons From Commodity Polyolefins, Paul Smith
Dissertations
Though tremendous progress has been made engineering carbon materials across length-scales from the molecular to the macroscopic, on-demand macro-structural control of carbons is still developing. Many carbon materials like graphene, carbon nanotubes, activated carbons, and carbon fibers have powder or fiber form factors. Recent research has pioneered on-demand carbon production through additive manufacturing (AM) via 1) extrusion and post-processing of highly filled carbon slurries, or 2) printing and pyrolysis of polymeric carbon precursors such as polyimides, acrylated polyethylene glycol, and phenolics. While groundbreaking, most methods face challenges with adoption due to costly/complex materials and manufacturing processes, and large dimensional changes …
Effect Of Polymer Contaminants Sourced From Coated Paper On The Performance Of The Resulting Recycled Paper,
2025
Clemson University
Effect Of Polymer Contaminants Sourced From Coated Paper On The Performance Of The Resulting Recycled Paper, Ezekiel J. Guevarra
All Theses
The growing demand for sustainable packaging has accelerated the use of paper-based materials as alternatives to plastics. To provide barrier and functional properties, these materials are often modified with polymer coatings. While beneficial during use, such coatings can persist as contaminants during recycling, potentially disrupting fiber bonding and reducing the quality of recycled paper. This study examined the impact of extrusion-coated low-density polyethylene (LDPE) films and two aqueous dispersions (Vapor/Water-Barrier, Acrylic Film (VWAF) and Oil & Grease Barrier (OGBF)) on contaminant distribution and mechanical performance of recycled handsheets. Kraft paper coated at varying levels was repulped and formed into handsheets, …
