Materials Science and Engineering Commons^™

Monitoring Of Overhead Polymer Core Composite Conductors Under Excessive Mechanical Loads Using Fiber Bragg Grating Sensors, Daniel H. Waters

Electronic Theses and Dissertations

This combined experimental and numerical study addresses mechanical effects associated with static and dynamic loading of novel High Temperature Low Sag (HTLS) transmission line polymer core composite conductors. The developed methodology was successfully applied to ACCC® to explain the complex failure mechanisms associated with combined bending and tension loading. Furthermore, the use of Fiber Bragg Grating (FBG) sensors was investigated for the first time to monitor the ACCC® design during installation and in-service.

Transverse low-velocity impacts to the ACCC® conductor having either free or constrained end conditions and large axial tensile loads were performed. It was identified that the most …

Hydraulic Balsa Wood Rising Bridge, Kaitlyn Greenfield

All Undergraduate Projects

What is the solution to allowing tall vessels to navigate past a vehicle bridge that is less than 10 [ft] above the water? To answer this question, a balsa wood bridge was designed, constructed, and tested. The bridge needed to articulate by mechanical means, allow for travel through the bridge, and be able to withstand ample force while the main structure only being constructed of balsa wood and glue. The project was analyzed in sections. These sections include: the bridge structure and its members, the hydraulic lift, and the pins needed for the bridge and hydraulic lift to operate. The …

Valorization Of Xylan In Agroforestry Waste Streams, Harrison Appiah

Graduate Theses, Dissertations, and Problem Reports (ETD)

Valorization of Xylan in Agroforestry Waste Streams.

Harrison Appiah

Microwave-assisted deep eutectic solvent and gamma-valerolactone metallic chloride catalyzed conversion of xylan to furfural were investigated using a 2x3 factorial experimental design at two levels of percent microwave power, reaction time, and catalyst concentration. The levels of each factor studied were (20%, 60% microwave power, 2, 4 minutes, and 10, 20mg) respectively. The effect of three metallic chloride catalysts (LiCl, FeCl3.6H20, CuCl2) on the conversion of xylan to furfural was also investigated. The gamma-valerolactone-ferric chloride sent system exhibited the highest mean yield of furfural (56.50%). The next highest furfural yield of …

Processing Of 3d Porous Biomaterial Scaffolds To Enhance The In Vitro Breast Cancer Tumor Microenvironment, Zi Wang

Electronic Theses and Dissertations, 2020-2023

Tumors contain heterogeneous cell populations within the tumor microenvironment (TME). TME supports tumor progression and development via the function of multiple cell types and cell-extracellular matrix (ECM) interactions. 3D porous biomaterial scaffolds can be a type of in vitro tumor models to mimic TME ECM. Current tumor models lack structural complexity replicating tumor ECM, tunable mechanical properties, and have limited mass exchange between cells and their microenvironment. In this work, we firstly developed scaffolds with a hierarchical pore structure via the Freeze-FRESH(FF) fabrication technique that combines 3D printing and freeze-casting. Later, we studied the effect of varying processing parameters and …

Properties And Structures Of Alkali Molybdenum Iron Phosphate Glasses For Nuclear Waste Immobilization, Jincheng Bai

Doctoral Dissertations

"The development of glasses to immobilize nuclear wastes requires a detailed understanding of how composition affects the critical properties required to design wasteforms, including thermal stability and chemical durability. Those properties depend on the molecular-level structures of the glasses. The principal objective of this research was to develop a comprehensive understanding of the composition-structure-property relationships, including the effects of processing conditions, for glasses in the alkali- molybdenum-iron-phosphate systems that could then be used to inform the development of wasteforms of interest to the US Department of Energy.

The molecular-level structures of the alkali molybdenum iron phosphate glasses were analyzed by …

Solidification Cracking In Binary Al-Cu Alloys Additively Manufactured Through Laser Powder Bed Fusion, Keegan Muller

Electronic Theses and Dissertations, 2020-2023

Laser Powder Bed Fusion (LPBF) is an additive manufacturing technique with growing relevance in industry. However, alloys with a high susceptibility to micro-cracking during solidification cannot be feasibly manufactured through LPBF, such as in selected high-strength Al-alloys. The cracking susceptibility (CS) of Al-alloys varies with composition, so modeling CS with respect to composition is crucial in designing compatible alloys for LPBF. In a theoretical modeling of solidification cracking based on the Scheil equation, the relative CS is taken as the maximum value of |dT/d(fs^1/2)| when solidification is near completion. However, experimental observations of the crack density in Al-alloys suggest that …

(Quinolin-8-Yl) Tin Synthons In Transmetalation Reactions With Transition Metals Yield Multimetallic Organometallic Molecules And Clusters, Arjun Chandra Bhowmick

Dissertations and Theses

Transition metal (Hg, Ag, Pd, Ni, Sn, Cu) complexes and clusters form from the reaction of metal salts and QSnX (Q = quinolin-8-yl; X = Q or Cl) synthons. Our original intent was the use of Q2Hg, Q2Sn, or QSnCl as an ambiphilic ligand; however, we observed an apparent redox-trans metalation reaction in most of the cases. Bimetallic Hg-Ag complexes were prepared using Q2Hg as an ambiphilic ligand. Heterobimetallic (Ni-Sn and Pd-Sn) complexes were obtained from the reaction of NiCl2 (or PdCl2) with in situ generated QSnCl. Geometry and electronic configuration of the complexes were investigated using DFT methods. The …

Gas Pressure And Coating Distance For Nanohydroxyapatite Deposition On Stainless Steel 316l Using Flame Spray Technique, Angga Saputra, Utami Dyah Syafitri, Toto Sudiro, Gerald Ensang Timuda, Yessie Widya Sari

Journal of Metals, Materials and Minerals

 Metal implant coating engineering is needed to improve the surface biocompatibility properties of metals.  For this, coating metal surfaces with bioactive and biocompatible biomaterials will be an option. Having high biocompatibility as well as similarity in chemical properties, nanohydroxyapatite may be a candidate as biomaterials for coating the metal implant. The key to the success of metal implant plating is the formation of pores which increase the bioactivity and biocompatibility properties of the implant. In this study, nanohydroxyapatite was used to be coated on stainless steel type 316L (SS316L). To ensure that the coating works properly on the surface, an …

Analysis Of The Impact Factors From The Friction Stir Welding Process For Dissimilar Butt Joints Between Semi-Solid Cast Aluminum 356 And Aisi 1018 Carbon Steel, Worapong Boonchouytan, Jaknarin Chatthong, Rommador Burapa

Journal of Metals, Materials and Minerals

This research aimed to study the impacts of three different rotation speeds of 710, 1000, and 1400 rpm and three welding speeds of 40, 56, and 80 mm·min-1, on dissimilar butt joints between semi-solid aluminum 356 and AISI 1018 carbon steel. Welding tools were made from tungsten carbide material, and the offset was 0 mm. It was found that an increase in the rotation speed and welding speed caused accumulated heat, which led to the appropriate changes in the metallurgical structure. The rotation speed and welding speed factors had the impact on the greater blending of the two metals at …

Laser Powder Bed Fusion Of Ti6al4v-Xcu: Process Parameters, Thywill Ccphas Dzogbewu

Journal of Metals, Materials and Minerals

The original intent of coating biomedical and surgical devices surface with antibacterial agents is to prevent infections. However, the difference in the material properties between the biomedical devices and the coating materials causes the coating material to spall from the biomedical devices. To address the situation, the current research focused on investigating the possibility of using laser powder bed fusion process a subset of additive manufacturing technology to in situ alloy 1 at% Cu with Ti6Al4V. In situ alloying 1 at% Cu with Ti6Al4V would lead to the production of medical and surgical devices with inbuilt antibacterial property. To determine …

Development Of Chemically Grafted Multiwall Carbon Nanotube Onto Cellulose Fiber Sheet And Polyurethane Based Resin Composite For An Active Paper, Siripassorn Sukhkhawuttigit, Sarute Ummartyotin, Yingyot Infahsaeng

Journal of Metals, Materials and Minerals

Cellulose fibers (CFs) and carbon nanotubes (CNTs) were successfully developed on polyurethane substrate as a flexible composite paper. With small amount of CNTs, the composite was prepared by a suction filtration method. The existence of CNT additive in cellulose matrix was investigated based on the correlation of mechanical properties, thermal stability, and electrical properties. Although the highly transparent cellulose sheets impregnated with polyurethane were successfully fabricated, the low transmittance was obtained as the increasing of CNT additive. However, the dielectric properties of composite were enhanced with an addition of CNTs in the composite paper. The electrical conductivity was increased from …

Influence Of Cooling Conditions On Microstructure And Mechanical Property Of Sn-0.3ag-0.7cu Lead-Free Solder, Prajak Jattakul, Tavee Madsa, Piyawan Sunasuan, Niwat Mookam

Journal of Metals, Materials and Minerals

This research has investigated the influence of cooling conditions on the microstructure and mechanical properties i.e., tensile strength and microhardness of Sn-0.3Ag-0.7Cu lead-free solder. In the experiments, casting was performed at 300℃ with comparison between copper and stainless steel molds under slow and fast cooled conditions. X-ray diffractometer confirmed the presence of Cu6Sn5 and Ag3Sn phases in the solder matrix. Lead-free solder solidified under slow cooled conditions exhibited -Sn matrix with larger grain growth as compared to the fast cooled solder. The eutectic area of intermetallic compound (IMC) was found to increase with cooling rate. The tensile strength of slow …

Harrisburg University’S Face Shield Response For Health Care Workers, Matthew A. Walters

Experiential Learning Projects

This project was inducted into the Harrisburg University Digital Common's with a submittal event. The recording for this event can be accessed here: Harrisburg University’s Face Shield Response for Health Care Workers Submittal Event Recording

The pandemic has most definitely been a significant factor in how people operate throughout the past few years. The pandemic was first introduced at the end of 2019 and is still a current issue at the end of 2021. Close to the beginning of the pandemic, health care workers had found themselves with a shortage of protective gear to fight against the virus while working …

Material Analysis Of 3d Welded 5356 Aluminum Alloy, Ryan Fouts

Electronic Theses and Dissertations

Metal 3D printing has been reserved for aerospace and high-end automotive industries because of its cost. A gas metal arc welder (GMAW) on a rugged 3D printer frame could make metal additive manufacturing an option for more industries and consumers. 3D welded aluminum has not been examined in depth as an option for additive manufacturing (AM). Extensive tests are necessary to determine the correct settings to use a metal inert gas (MIG) welder for AM. Porosity within the welded material must be evaluated to better understand the additive process. The material properties of 3D welded aluminum will be tested and …

Biomechanical Investigation Of Plant Vascular Tissue For Bio-Inspired Design And Flexible Composites, Mukesh Roy

Electronic Theses and Dissertations

Since the inception of evolution, nature has continuously optimized all the natural materials. These optimizations are so efficient that scientists and engineers have started taking inspiration from nature. Such inspiration-based solutions provide sustainable development of new materials with enhanced structural properties and functionalities (such as stiffness, stability, toughness, self-healing etc.). This variety of properties and functionalities is mainly due to the hierarchical organization of such components. Abstraction of the hidden cues of the hierarchical organization, principles and underlying structure-function relations are some of the critical approaches of bioinspired materials design. Inspiration from animals and plants has helped develop the design …

Development Of A High Strength Composite Material Using Large Scale 3d Printing Applications Using Waste Plastic And Steel, Naga Sri Madhavareddy

Electronic Theses and Dissertations

This project focuses on developing a high strength composite material for largescale 3D printing applications using recycled materials like High-Density Polyethylene (HDPE) and Steel 430. This material has applications for in-space manufacturing (the Moon or Mars) as well as large-scale manufacturing on earth. In addition to creating a strong useful material, materials that are easily recycled, but are often not recycled, are used. Recycling plastic and metal reduces pollution, saves resources, reduces waste going to landfills, and prevents the destruction of habitats from the polymerization of new plastic and similarly mining new ore. The percentage of HDPE generated from recycled …

Effect Of Composition And Print Orientation On Thermal Conductivity Of 3d Printed Composites, Cory Jacques

Electronic Theses and Dissertations

Additive manufacturing (AM) technologies have become widely used for rapid prototyping and are beginning to be used for end-use applications. Fused Deposition Modeling (FDM) is a type of 3D printing where molten thermoplastic is extruded layer by layer to create parts. There is an increasing need for improvement and diversification of material properties to further extend the use of AM parts. AM parts have not been commonly used in heat transfer applications due to the limited availability of information on thermal conductivity of materials and the effects of printing orientation. A special apparatus was designed and built to experimentally test …

Actin Cytoskeleton Dynamics And Organization Modulated By Macromolecular Crowding, Cation Interaction, And Nanomaterials, Jinho Park

Electronic Theses and Dissertations, 2020-2023

The assembly of actin, the essential cytoskeleton protein, into filaments and bundles/networks is important in various cellular processes including cell movement and morphogenesis. Actin bundle formation occurs in crowded intracellular environments with the aid of actin-crosslinking proteins. The role of actin-crosslinking proteins such as fascin and a-actinin in bundle formation has been investigated, however, how intracellular environments affect actin crosslinker-induced bundle formation is unknown. In the first two parts of this dissertation, we explore the effects of macromolecular crowding and cation interactions on the organization and mechanics of actin crosslinker-induced bundles. To determine how changing environmental conditions modulate actin bundling, …

Contributions To The Performance Of Thin Film Capacitors For High Reliability Applications, Daniel Krueger

Doctoral Dissertations

"Capacitors are critical devices in microelectronic assemblies that must be incorporated into electronic systems through a variety of ways such as integrated or discrete devices. This work has developed new thin film capacitors deposited directly onto multichip module or printed circuit board surfaces to benefit from closer integration that enhances system performance for use in high reliability applications. The capacitors serve as filters or provide tuning and energy storage functions. Unexpected performance was observed during development that included low adhesion of the films to the substrates, higher effective dielectric constants than reported in literature, and low yields. Three publications resulted …

Phase Formation And Thermal Conductivity Of Zirconium Carbide, Yue Zhou

Doctoral Dissertations

“This research focused on the synthesis and phase formation of zirconium carbide with different carbon contents, and lattice thermal conductivity of zirconium carbide with different carbon vacancy, hafnium, and oxygen contents.

Nominally pure phase ZrC_x was synthesized by solid-state reaction of zirconium hydride (ZrHs) and carbon black at a temperature as low as 1300°C. The powder synthesized at 1300C was carbon deficient ZrC_x . Carbon stoichiometry of the as- synthesized powders increased as the synthesis temperature increased. As the synthesis temperature increase, the oxygen content of ZrC_x decreased due to the increasing C site occupancy. Low stoichiometry …