Research Progress On Transition State Of Organic Electrode Materials,
2021
1. State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, Hebei, China;2. Department of Materials Science & Engineering, Southern University of Science and Technology, Shenzhen 518055, Guangdong, China;
Research Progress On Transition State Of Organic Electrode Materials, Xue-Qian Zhang, Zhou-Guang Lu, Wei-Wei Huang
Journal of Electrochemistry
With the increasing requirements for high energy density, long lifetime, high safety, environmentally friendly fabrication, and sustainable development of large energy storage devices, the society calls for new electrode materials in rechargeable batteries beyond traditional inorganic materials which are limited by specific capacity. Organic electrode materials have been widely used in rechargeable batteries due to their advantages of large theoretical capacity, designable structures and environmentally friendly fabrications. In this review, the radical intermediates of organic electrode materials produced in the charging-discharging process (redox reaction) and their types are systematically reviewed. The stability of radical intermediates controlled by changing the structure …
Research Progress In Electrodeposition Technology Of Titanium-Based Iridium Oxide Electrode,
2021
College of Environmental Science and Engineering, Huazhong University of Science and Technology ,Wuhan 430074, Hubei, China;
Research Progress In Electrodeposition Technology Of Titanium-Based Iridium Oxide Electrode, Dan-Dan Wu, Xu Wu
Journal of Electrochemistry
Titanium-based iridium oxide electrode has been widely used in various fields, such as electrocatalytic oxidation, biomedical applications, hydrometallurgical metal recovery, electro-osmotic dewatering, etc. At present, it is mainly prepared by traditional thermal decomposition method, however, which has high cost, cumbersome process, mainly relying on manual labor and cannot be mass-produced yet. It is, therefore, urgently necessary to explore new preparation technologies by focusing on electrodeposition technology, with technological characteristics such as eco-friendly and sustainable development. This article systematically discusses the research progress in iridium oxide electrodeposition preparation technology from the aspects of deposition solution formulation, base material selection and treatment, …
Preparations And Electrocatalytic Ethanol Properties Of Palladium Intercalated Hydrotalcite,
2021
School of Environment and Architecture,University of Shanghai for Science and Technology, Shanghai 200093, China;
Preparations And Electrocatalytic Ethanol Properties Of Palladium Intercalated Hydrotalcite, Shou-Xun Hu, Liang Li, Jun-Hao Yang, Liu-Qiang Li, Zhi-Hao Jin
Journal of Electrochemistry
High-performance electrocatalysts play a vital role in the commercial application of direct fuel cells. Current anode materials still have such problems as low activity, easy poisoning and high cost. In this study, a new type of nano- palladium (Pd) catalyst was prepared by dipping method using layered double hydroxides (LDHs) as the carrier. X-ray diffractometer, scanning electron microscope (SEM), inductively coupled plasma mass spectrometer (ICP-MS), energy spectrometer, transmission electron microscope (TEM), cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscope were used to analyze the structure and electrocatalytic performance of the catalyst. The results showed that the newly prepared Pd/Mg-Al-LDHs still maintained …
Research Progress Of Sio2 Regrowth During Selective Etching Process In 3d Nand Manufacture Procedure,
2021
1. College of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;
Research Progress Of Sio2 Regrowth During Selective Etching Process In 3d Nand Manufacture Procedure, Zi-Han Zhou, Yun-Wen Wu, Ming Li, Su Wang
Journal of Electrochemistry
As one of the most significant memory chips in semiconductor market, NAND has been developed from two-dimension (2D) to three-dimension (3D). Due to the three-dimensional memory structure of 3D NAND, the capacity density, read-write speed and reliability of memory chips have been greatly improved, as well as the reduction of power dissipation. It is by nitride-oxide selective etching process in the alternate stacked structure of 3D NAND that the inter-dielectric layers can be obtained. The more stack layers, the better performance of chips will be. Meanwhile, however, silicon dioxide (SiO2) would regrow on the corner of oxide layers, …
Influence Of Resveratrol On Performance Of Long-Term Storage’S Lithium-Ion Battery Electrolyte,
2021
Lithium ion battery lab, School of Materials & Physics, China University of Mining & Technology, Xuzhou 221116, Jiangsu, China;
Influence Of Resveratrol On Performance Of Long-Term Storage’S Lithium-Ion Battery Electrolyte, Lei Zhang, Xu-Ping Zhang, Si-Wei Zhang, Quan-Chao Zhuang
Journal of Electrochemistry
Electrolyte of lithium-ion battery usually goes through processes of filling, transportation and storage from the completion of manufacture to the use. Understanding the influence of long-term storage process on performance of lithium-ion battery electrolyte is of theoretical significance for production of lithium-ion battery. Scanning electron microscope (SEM) images showed that the solid electrolyte interface (SEI) film formed on the surface of the graphite electrode was thicker in the base electrolyte after 6 months of storage. The charge/discharge test results showed that the reversible cycle capacity and cycle stability (capacity retention rate) of graphite electrode decreased significantly after 6 months of …
Syntheses Of Na3V2(Po4)2O2F As A Cathode For Sodium Ion Battery Application,
2021
Ningde Contemporary Amperex Technology Co., Ltd., Ningde 352106, Fujian, China;
Syntheses Of Na3V2(Po4)2O2F As A Cathode For Sodium Ion Battery Application, Kai Wu
Journal of Electrochemistry
High-temperature solid-state method, hydro-thermal method and solvo-thermal method have been mainly employed to synthesize Na3V2(PO4)2O2F (NVPF) cathode materials. However, these methods are energy consuming and complicated, which is not applicable for a large scale industrial production. In this study, a rather low-temperature (70℃) co-precipitation strategy was proposed to synthesize NVPF cathode materials. The as-prepared NVPF cathode materials showed a spherical shape with a diameter of 400 ~ 500 nm, and exhibited a sodium storage of 105.6 mAh·g-1 and an efficiency of 90.06%. After a simple thermal process, the specific …
Initial Assessment Of Liquefied Scrap Tire Concrete,
2021
Intertek-PSI
Initial Assessment Of Liquefied Scrap Tire Concrete, Abdulkareem Kuaryouti, Christopher D. Eamon
Civil and Environmental Engineering Faculty Research Publications
A new approach to incorporate scrap tire material into concrete was investigated, where two reclaimed waste tire components, carbon black and fuel oil, were used to replace a portion of water. The effect of “liquid tire” content to water ratios from 5-40% on an otherwise typical concrete mix were assessed, where compressive and flexural strength, flexural toughness, modulus of elasticity, and several fresh concrete properties were determined. Results were compared to typically expected results of traditional shredded tire mixes with equivalent tire content. It was found that the liquid tire mixes experienced significantly less losses of compressive strength and workability …
Development Of Preparations Based On Local
Components For Dust Suppression On Quarry Roads,
2021
Navoi State Mining Institute
Development Of Preparations Based On Local Components For Dust Suppression On Quarry Roads, Olikulov Fakhriyor, Mukhiddinov Bakhоdir, Vapoev Khusniddin, Zhurayev Shokhruh
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of the work is to develop dust-collecting preparations based on local raw materials for the suppression of man-made dust formed on quarry paths. For this purpose, 4 types of the drug were created in the laboratory on the basis of domestic raw materials for dust suppression. The dependence of the viscosity and density of the created preparations on the concentration of components and temperature is studied. For the preparation of the solution of the created drug, a semi-industrial installation is created, which presents the general view and the process of preparing the solution. The spray of the prepared …
Synthesis And Research Of Chelate Forming Sorbent Based On Carbamide, Formaldehyde, Ditizone,
2021
Termez branch of the Tashkent State Technical University
Synthesis And Research Of Chelate Forming Sorbent Based On Carbamide, Formaldehyde, Ditizone, Chorieva Nigora, Ermuratova Nilufar, Turaev Khayit, Kasimov Sherzod
CHEMISTRY AND CHEMICAL ENGINEERING
The purpose of this study is the synthesis and study of a chelating sorbent for the extraction of ions of non-ferrous and noble metals. To achieve this goal, a sulfur-containing chelating sorbent based on carbamide, formaldehyde, and dithizone was synthesized and studied. The optimal conditions for the synthesis of the sorbent have been determined and studies have been carried out on the influence of the molar ratios of the starting materials on the composition, and physicochemical properties of the synthesized sorbent. The optimum temperature of polycondensation was taken as 90 °C, the reaction time is 2.5-3 hours, as a result, …
Synthesis And Spectroscopic Study Of Complex Compounds Of Mn(Ii), Co(Ii), Ni(Ii), Cu(Ii) And Zn(Ii) Acetates With
2-Aminobenzimidazole,
2021
National University of Uzbekistan
Synthesis And Spectroscopic Study Of Complex Compounds Of Mn(Ii), Co(Ii), Ni(Ii), Cu(Ii) And Zn(Ii) Acetates With 2-Aminobenzimidazole, Gapurova Lobar, Kadirova Shakhnoza, Rakhmonоva Dilnoza, Olimova Manzura
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of the work is to develop a synthesis procedure and obtain new complex compounds of transition metal acetates with 2-aminobenzimidazole (L), to study the composition and structure of the synthesized compounds by elemental, thermal, X-ray phase analysis and IR spectroscopy. A procedure for the synthesis of new complex compounds of Mn(II), Cо(II), Ni(II), Cu(II) and Zn acetates with 2-aminobenzimidazole was developed and the composition and structure of the synthesized complex compounds were studied using modern physicochemical methods. Coordination competing donor centers, electronic and geometric structures of the ligand molecule were studied on the basis of a quantum-chemical calculation …
Effect Of Light On The Resistance Of Bi/Pb Superconductors Synthesized By Solar Energy,
2021
Materials Science Institute, SPA “Physics-Sun”
Effect Of Light On The Resistance Of Bi/Pb Superconductors Synthesized By Solar Energy, Gulamova Dilbara, Echonkulov Elyor, Jalilov Dilshod, Bobokulov Sirojiddin
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of the work is to expand the capabilities of solar technologies and areas of practical use of superconductors. The effect of white light on the interaction of superconducting ceramics with a magnet at room temperature was investigated. It has been established that the magnet is “ejected” by ceramic samples of nominal Bi1,7Pb0,3Sr2Ca(n-1)CunOy, (n = 5-20) under the influence of white light and there is no effect in the dark. The resistance of Bi/Pb superconducting ceramics is reduced by exposure to light compared to resistance in the dark. The resistance of ceramics containing higher superconducting higher superconducting phases Tc …
Spectrophotometric Color Determination
Of Ceramic Pigments For Construction Ceramics
And Regional Innovation System,
2021
Tashkent Chemical-Technological Institute
Spectrophotometric Color Determination Of Ceramic Pigments For Construction Ceramics And Regional Innovation System, Kadyrova Dilorom, Mansurov Yulbarskhon, Abdusattarov Shakirjan
CHEMISTRY AND CHEMICAL ENGINEERING
The purpose of this work is the spectrophotometric determination of the color of ceramic pigments for the development of technology for the production of high-quality ceramic paints of a wide color palette for decorating building ceramics, porcelain and faience products. In this regard, using the principles of heterovalent isomorphic substitution of atoms in crystals, the compositions of ceramic pigments were designed on the basis of the anorthite derivatives containing transition elements with the general formula Са1-хMexAl2+xSi2-xО8, where calcium and silicon ions were replaced by aluminum and transition element, Ме – Cо, Ni, Fe, Cr. The color characteristics were taken on …
Fluid Separation And Network Deformation In Wetting Of Soft And Swollen Surfaces,
2021
University of Kentucky
Fluid Separation And Network Deformation In Wetting Of Soft And Swollen Surfaces, Zhuoyun Cai, Artem Skabeev, Svetlana Morozova, Jonathan T. Pham
Chemical and Materials Engineering Faculty Publications
When a water drop is placed onto a soft polymer network, a wetting ridge develops at the drop periphery. The height of this wetting ridge is typically governed by the drop surface tension balanced by elastic restoring forces of the polymer network. However, the situation is more complex when the network is swollen with fluid, because the fluid may separate from the network at the contact line. Here we study the fluid separation and network deformation at the contact line of a soft polydimethylsiloxane (PDMS) network, swollen with silicone oil. By controlling both the degrees of crosslinking and swelling, we …
Characterization, Immobilization, And Polymer Related Applications Of Watermelon Seed Powder, A Practical Source Of Urease Enzyme,
2021
Louisiana State University and Agricultural and Mechanical College
Characterization, Immobilization, And Polymer Related Applications Of Watermelon Seed Powder, A Practical Source Of Urease Enzyme, Anthony Quan Quoc Mai
LSU Doctoral Dissertations
Urease enzyme was crystallized almost a century ago, and to this day its intrinsic stability is not ideal for everyday applications. This work introduces a new process by which a naturally encapsulated material, watermelon seed powder (WMSP), is characterized for its stability and activity. WMSP enzymatic activity has been measured for over a year at various storage conditions—exposed to ambient atmosphere for a year, WMSP retained above 90% activity. In aqueous conditions, the enzyme maintained above 60% activity after two months; with the addition of a preservative that number stays at about 90%. There is a pH shift of the …
Cellulose-Based Polymer Electrolyte Derived From Waste Coconut Husk: Residual Lignin As A Natural Plasticiser,
2021
Universiti Malaya
Cellulose-Based Polymer Electrolyte Derived From Waste Coconut Husk: Residual Lignin As A Natural Plasticiser, Chua Kai Ying
Student Works (2020-2029)
Polymer electrolyte (PE) finds many applications in the fabrication of electrochemical devices such as batteries, solar cells, supercapacitors, and electrochromic windows. The usage of cellulose from the waste of coconut husk is one alternative in using natural polymer as a green electrolyte. However, due to its high crystallinity, the usage of plasticiser is advantageous to reduce the crystallinity of cellulose. Lignin which co-exists with cellulose in the cell walls of the plants could act as a natural plasticiser in preparing a good polymer electrolyte. In this work, cellulose was isolated from waste coconut husk (Cocos nucifera), modified into water-soluble carboxymethylcellulose …
Scale Model Test To Estimate Thermal Damage By Fire In Aircraft Cargo,
2021
Qingdao Institute of Bioenergy and Bioprocess Technology
Scale Model Test To Estimate Thermal Damage By Fire In Aircraft Cargo, Jian Gao, Tsuneyoshi Matsuoka, Yuji Nakamura
Progress in Scale Modeling, an International Journal
The Federal Aviation Administration (FAA) requires fire detectors to alarm within one minute of the start of a fire in cargo compartments of airplanes. To determine whether such alarm timing works, investigations of the thermal damage to ceilings and other structures during the early stage of a fire were accomplished to demonstrate compliance with these FAA regulations. The objective was to test the feasibility of predicting convective heat transfer in early stage of a cargo compartment fire by conducting reduced scale (lab scale) experiments. First, the scaling laws was derived and validated. Then, full-scale and half-scale experiments were performed with …
Microstructure And Mechanical Properties Of Porous Copper And Copper Brazed With Cu-Based Filler Metal,
2021
Universiti Malaya
Microstructure And Mechanical Properties Of Porous Copper And Copper Brazed With Cu-Based Filler Metal, Mian Muhammad Sami
Student Works (2020-2029)
In recent time, the heat dissipation rate of electronics increased due to the high volumetric power density they experience. In such circumstances, cooling devices with high heat transfer performance are required. Therefore, adopting porous metal can be critical in applications requiring thermal management due to its large internal surface area and high permeability for fluids. The cooling system can be composed of porous copper to enhance heat transfer making it suitable for replacement in active cooling systems, such as heat sink and heat exchanger. Effective joining of porous copper (Cu) to a copper substrate is significant when considering porous copper …
A Pi Based Coordinated Maximum Power Point Tracking Controller For Grid Connected Photovoltaic System,
2021
Universiti Malaya
A Pi Based Coordinated Maximum Power Point Tracking Controller For Grid Connected Photovoltaic System, Md Haidar Islam
Student Works (2020-2029)
The global demand for electric energy has continuously increased over the last few decades. Photovoltaic (PV) sources are predicted to become one of the biggest contributors to electricity generation among all renewable energy generation candidates by 2040. The photovoltaic system a renewable energy source that has attracted the attention of researchers in recent years. The power output of a photovoltaic system has a complex dependence on varying environmental conditions such as solar irradiation and ambient temperature which cannot be controlled, thereby making the current versus voltage (I-V) and power versus voltage (P-V) characteristics of photovoltaic arrays nonlinear. Therefore, maximum power …
Under Pressure: Hydrogel Swelling In A Granular Medium,
2021
Princeton University
Under Pressure: Hydrogel Swelling In A Granular Medium, Jean François Louf, Nancy B. Lu, Margaret G. O'Connell, H. Jeremy Cho, Sujit S. Datta
Mechanical Engineering Faculty Research
Copyright © 2021 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). Hydrogels hold promise in agriculture as reservoirs of water in dry soil, potentially alleviating the burden of irrigation. However, confinement in soil can markedly reduce the ability of hydrogels to absorb water and swell, limiting their widespread adoption. Unfortunately, the underlying reason remains unknown. By directly visualizing the swelling of hydrogels confined in three-dimensional granular media, we demonstrate that the extent of hydrogel swelling is …
Doped-Magnesium Manganese Oxide Cathode For Rechargeable Magnesium Batteries,
2021
Universiti Malaya
Doped-Magnesium Manganese Oxide Cathode For Rechargeable Magnesium Batteries, Nurhidayu Harudin
Student Works (2020-2029)
Magnesium has numerous good characteristics that make it attractive as an electrode material for rechargeable batteries. There are many advantages of Magnesium (Mg) such as available in abundance, ease of handling, low toxicity and environmental friendly. Due to its benefits, magnesium ion battery can be considered as an alternative to lithium in future. In the present work, the improvement electrochemical properties of magnesium-based cathode material, MgMn2O4 was done by adding calcium (Ca) and strontium (Sr) as dopant i.e MgMn2-xCaxO4 and MgMn2-xSrxO4. These materials with compositions of x=0.1,0.2,0.3,0.4,0.5 were synthesized by self-propagating combustion method using citric acid as a reducing agent. …
