Materials Science and Engineering Commons^™

Effect Of Garnet Incorporation On The Functional Properties Of Sunscreens, Parinya Chakartnarodom, Kanyarat Munmani, Sureerat Polsilapa, Duangrudee Chaysuwan, Wichit Prakaypan, Passakorn Sonprasarn, Edward Laitila, Nuntaporn Kongkajun

Journal of Metals, Materials and Minerals

Garnet, a silicate mineral, was investigated as a replacement for the TiO2-based compound in sunscreen formulations. Samples containing garnet were evaluated for color shade, viscosity, sun protection factor (SPF), and water resistance. Substituting the TiO2-based compound with garnet reduced both viscosity and SPF but markedly enhanced water resistance. This improvement is attributed to the physical reinforcement provided by garnet particles, which strengthen the sunscreen film and reduce wash-off under water exposure. Garnet incorporation also altered the product’s appearance from white to a darker brownish-beige tone, improving visual compatibility with a wider range of skin tones.

Synthesis And Photoluminescence Properties Of Graphene Quantum Dots Prepared Via Carbonization Under Pressure Reduction, Sutthipoj Wongrerkdee, Pichitchai Pimpang

Journal of Metals, Materials and Minerals

This study reports the synthesis of graphene quantum dots (GQDs) via a bottom-up carbonization approach using citric acid as a precursor under various reduced pressure conditions. The carbonization process was carried out at 250℃ in an ethanol medium, with atmospheric pressures ranging from normal to 20 inHg below atmospheric pressure. The effects of pressure reduction on the size and optical properties of GQDs were systematically investigated. Dynamic light scattering (DLS), UV–Vis spectroscopy, and fluorescence spectroscopy revealed that pressure reduction during synthesis decreased GQDs size and induced a blue-shift in both absorption and emission spectra. The optical bandgap of GQDs was …

Effects Of Welding Currents On Microstructure And Corrosion Behaviors Of Inconel 625 Cladding On 2.25cr-1mo Steel By Hot-Wire Tig, Supparat Saeheng, Hein Zaw Oo, Prapas Muangjunburee

Journal of Metals, Materials and Minerals

Hot-wire tungsten inert gas (HW-TIG) cladding has been applied to the steam turbine rotor welding repair. This study investigated the effects of welding currents on microstructure, hardness, and corrosion behavior. The experiments were conducted using four different welding currents applied to bead-on-plate Inconel 625 welds on a 2.25Cr-1Mo steel substrate as the steam turbine rotor material. The selected welding currents were 125 A, 150 A, 175 A, and 200 A. The percentages of weld dilution for different welding currents were also evaluated. Higher welding currents increased weld dilution, weld bead width, and HAZ size. As the welding current increased, the …

Development Of 4-Vinylbenzyl Chloride (Vbc) Grafted Onto Branched Polyethylenimine (Pei) Onto Bacterial Cellulose Sheet By Gamma-Induced Irradiation Technique For Cu Ion Adsorption, Methinee Wongwai, Supitchaya Kulratkitiwong, Thitirat Rattanawongwiboon, Sarute Ummartyotin

Journal of Metals, Materials and Minerals

Bacterial cellulose extracted and purified from Nata de coco was employed as a platform for Cu2+ ion adsorption. 4-vinylbenzyl chloride (VBC) was successfully grafted at the hydroxyl position by using gamma irradiation. The optimum was typically related to VBC concentration of 2% (v/v) and a radiation dose of 50 kGy. FTIR significantly reported the functional group of C-Cl related to VBC. No change of crystallinity and morphology was observed. The thermal decomposition was stable up to 200℃. The modification of branched polyethylenimine (PEI) was prepared in order to change the functionality to N‒H stretching. This was expected to adsorb Cu2+ …

High Temperature Storage Reliability Of Cu Pillar Flip Chip Interconnects, Kachain Worapakdee, Anusara Srisrual

Journal of Metals, Materials and Minerals

The Cu pillar flip chip is currently designed and used in the optic communication device that it has exhibited low reliability at high temperature. This paper aims to report the reliability of Cu pillar flip chip assembled on electronics board for a new optoelectronic product subjected to high temperature storage testing. The test was performed at 150℃ isothermal condition with the various storage times up to 2000 h. The aged samples were characterized with scanning acoustics microscopy, scanning electron microscopy, and energy dispersive X-ray spectroscopy. Two types of intermetallic compounds (IMCs) were found at beside of the Cu pillar i.e. …

Degradation Of Wastewater By Advanced Oxidation Processes Using Green Synthesised Cuo Nanoparticles, Srinivasan Vishal, Anand Sarvesvaron, Muralidharan Keerthana, Hemanth Sanjay Reddy, A Babu Ponnusami

Journal of Metals, Materials and Minerals

This study highlights the green synthesis of CuO nanoparticles using coconut coir extract and evaluates their photocatalytic performance in the degradation of the Brown G dye. The CuO nano-particles were synthesised through sol-gel method, and the biomolecules like polyphenols, tannins and flavonoids acted as reducing agents to stabilise the nanoparticles. The characterisation of these nanoparticles was carried out through XRD, FTIR and FESEM methods. The nanoparticles were used to degrade the dye Brown G under UV irradiation.  Response surface methodology was used to optimise the operating parameter with Box-Behnken design, which is the most suitable for varying 3 or more …

Dual-Functional Activated Carbon From Coffee Grounds For Crystal Violet Dye Removal And Subsequent Application As An Electrode Material In Energy Storage Devices, Sirikorn Khaophong, Tawatchai Kangkamano, Sonchai Intachai, Panita Kongsune

Journal of Metals, Materials and Minerals

The conversion of agricultural waste into high-value functional materials offers a sustainable strategy to address environmental concerns. In this study, activated carbon was synthesized from spent coffee grounds (CGAC) via KOH activation and used for crystal violet (CV) dye adsorption. Under optimal conditions (0.5 g dosage, 300 mg∙L‒1 CV, 30°C, 120 min), CGAC achieved 91.41% removal efficiency, with adsorption behavior fitting pseudo-second-order kinetics and the Freundlich isotherm. Thermo-dynamic parameters confirmed a spontaneous and endothermic process. Moreover, the reusability study revealed that CGAC maintained a high removal efficiency above 88% after seven adsorption–desorption cycles, demonstrating its structural stability and potential for …

Investigation On The Tribological Properties Of Al2o3-Tic Substrates In Fixed Abrasive Lapping For Data Storage Applications, Benjie Locsing Fernandez, Thanakrit Srisuwan, Duangamol Tungasmita, Sukkaneste Tungasmita

Journal of Metals, Materials and Minerals

Alumina titanium-carbide (Al2O3-TiC) or simply AlTiC substrates were widely used in the magnetic recording industry for their superior mechanical and tribological properties. This study investigated the effect of AlTiC substrate crystal structure, chemical bonding and grain size in slider fix abrasive lapping tribology. Two types of AlTiC substrates, Type-A AlTiC and Type-B AlTiC equipped with an electro lapping guide (ELG), fully functional reader and writer devices were used in the study. The type-B lower material removal rate resulting to rougher surface finish was mainly due weakening caused by the titanium oxycarbide phase, which was the dominant factor, outweighing the minimal …

Surface Properties And In-Vitro Bioactivity Studies Of Tio2 Nanowire Doped Transition Metal (M=Fe, Co, And Mn), Misriyani Misriyani, Enayah Enayah, Z. Ryan Tian, Andi Meutiah Ilhamjaya

Journal of Metals, Materials and Minerals

This study investigates the influence of transition metal (Fe, Co, Mn) doping on the surface properties and in-vitro bioactivity of TiO2 nanowires. It aims to elucidate how transition-metal doping alters the surface behavior and biological response of TiO2 nanowires, enabling their potential use in biocompatible and magnetically responsive materials. Magnetic TiO2 nanowires doped with transition metals (Mx+/TiO2) were successfully prepared by a hydrothermal method using titanium dioxide in alkaline solution. Cations were added with Ti/Mx+ molar ratios of 5 to produce Fe/TNW, Co/TNW, and Mn/TNW. Characterization using SEM and XRD determine their surface properties. In-vitro bioactivity tests were conducted by …

Properties And Printability Of Polylactic Acid Films : An Effect Of Polyglutamate Coated Natto As A Bio-Plasticizer, Natrata Thitinardwong, Thira Chavarnakul, Kawee Srikulkit

Journal of Metals, Materials and Minerals

Polylactic acid (PLA) film, a biodegradable alternative to petroleum-based plastics, has gained significant attention for sustainable packaging applications. However, its limited screen-printability remains a barrier to broader commercial use. This study aims to enhance the screen-printability of PLA film by incorporating a polyglutamate coated natto (designated as Nat-M). PLA/Nat-M films having 1%, 3%, and 5% Nat-M were prepared and evaluated for their key performance indicators, including ink adhesion (ASTM D3359), tone reproduction accuracy, and printing resolution. The screen-printing resolution was optimized between 400 DPI and 500 DPI (dots per inch) to achieve optimal tone reproduction and edge sharpness. Additionally, ink …

A Top-Electrode-Based Liquid-Solid Triboelectric Nanogenerator For Energy Harvesting And Ethanol Detection, Subrat Bhol, Nakul Charan Sahu, Sunit Gaurav Mohanty, Vicky Raj Maddala, Basanta Kumar Panigrahi, Premkumar Bhosale

Journal of Metals, Materials and Minerals

Liquid-solid triboelectric nanogenerators (LS-TENGs) offer a promising avenue for self-powered energy harvesting and sensing by exploiting contact electrification at fluid-dielectric interfaces, where droplet dynamics drive charge separation for electrical output without external power. In this work, a top-electrode LS-TENG was fabricated using a polytetrafluoroethylene (PTFE) film on a PMMA substrate with deionised water droplets, achieving an open-circuit voltage of ‒3.4 V, short-circuit current of 3.6 μA, and peak power of 1.48 nW at 100 MΩ under optimised conditions of 2 cm drop height, 45° tilt, and 50 μL volume. Performance scaled with droplet kinetics and volume due to enhanced contact …

Co-Sputtered Cuni Heteroatomic Electrocatalyst For Enhanced 5-Hydroxymethylfurfural Selective Electrochemical Conversion, Moumita Dikshit, Baleeswaraiah Muchharla, Luz Vazquez Rivera, Kapil Kumar, Sunita Sanwaria, Kishor Kumar Sadasivuni, Abdennaceur Karoui, Sandeep Kumar, Adetayo Adedeji, Bijandra Kumar

Civil & Environmental Engineering Faculty Publications

The electrochemical conversion of biomass-derived 5-hydroxymethylfurfural (HMF) represents a promising, economically viable, and environmentally sustainable approach for producing value-added chemicals using renewable energy and in situ hydrogen generated through water electrolysis. However, the electrochemical hydrogenation (ECH) of HMF remains challenging due to the inherently low catalytic activity and selectivity of the electrodes, compounded by competition with the kinetically favored hydrogen evolution reaction (HER) in aqueous electrolytes. In this work, we demonstrate that Cu_xNi_100-x heteroatomic thin films, fabricated via direct current (DC) magnetron co-sputtering, achieve a more than one order of magnitude increase in the HMF to 2,5-Bis-hydroxymethylfuran …

Distributed Temperature Sensing In The Spray-Cooled Shell Of A 150-Ton Dc Electric Arc Furnace Using Brillouin Optical Fiber Technology, Farhan Mumtaz, Yeshwanth Reddy Mekala, Koustav Dey, Rony Kumer Saha, Ogbole Collins Inalegwu, Manoj Kumar Pullagura, Bohong Zhang, Muhammad Roman, Nicholas Dionise, Zane Voss, Jeffrey D. Smith, Ronald J. O'Malley, Rex E. Gerald, Jie Huang

Electrical and Computer Engineering Faculty Research & Creative Works

This paper presents the deployment and validation of a Brillouin - distributed temperature sensing (DTS) system for real-time thermal monitoring of the spray-cooled upper shell of a 150-ton direct current Electric Arc Furnace (DC EAF) at Big River Steel Plant, Osceola, AR, USA. A four-channel Brillouin DTS system from OZ Optics was employed, with one active channel instrumented using an in-house-fabricated Brillouin scattering-depressed single-mode optical fiber (SMF28e+). The 60 m optical fiber sensor was fabricated, with 20 m allocated for thermal measurement and 40 m used as lead-in fiber to isolate the interrogator from the furnace environment. The fiber was …

The Efficacy Of Hybrid Manufacturing For High Stress Automotive Parts, Logan Trimmer

Harrisburg University Other Works

Presentation covering the broad strokes of the project. The goal was to prove the viability of hybrid/additive manufacturing for high stress automotive applications. This project focused on recreating a piston from an old engine to examine if hybrid manufacturing could be used for such applications. On a small scale, hybrid manufacturing was able to be more cost effective if the costs of the equipment and electricity were ignored. The decision to ignore those costs came from the inability to find accurate prices for industrial casting.

Revisiting The Life Cycle Of Margalefidinium Polykrikoides Group Iii, Eduardo Pérez-Vega, Kenneth N. Mertens, Pjotr Meyvisch, Margaret R. Mulholland

OES Faculty Publications

Dinoflagellates produce cysts as a strategy to withstand environmental stressors, with nutrient depletion generally considered a key trigger for cyst production. Resting cysts are thick-walled, typically composed of one to several layers, and characterized by a prolonged dormancy period. In contrast, pellicle cysts possess a thin, single wall and exhibit no dormancy or a markedly shorter dormancy than resting cysts of the same species. Margalefidinium polykrikoides produces pellicle and resting cysts, whereas its congener, M. fulvescens, has been shown to produce pumpkin-like structures. Using phase-contrast microscopy, time-lapse microscopy, FlowCam, and attenuated total reflection Fourier transform infrared microspectroscopy (ATR μ-FTIR), …

Recent Insight And Perspective Of Marine-Inspired Biopolymers For Wound Healing Applications - A Review, Muhammad Umar Aslam Khan, Saiqa Yousaf, Abdalla Abdal-Hay, Mohd Faizal Bin Abdullah, Sahar Madani, Muhammad Shahzad Zafar, Goran M. Stojanović, Lobat Tayebi

Electrical & Computer Engineering Faculty Publications

There is an increasing necessity for advanced, sustainable, and biocompatible materials for wound healing as therapeutic and diagnostic products. Marine environments, characterized by high biodiversity, offer an underutilized source of natural resources with enormous potential for creating novel materials for dressings. This review highlights the revolutionary nature of polymeric biomaterials of marine origin, with a focus on polysaccharides, like alginate, chitosan, and carrageenan; proteins, such as collagen and gelatin. These biopolymers are outstanding in their physicochemical properties, such as biodegradability, bioactivity, and modifiable mechanical strength, which enable their use in wound-healing systems. Besides, these biomaterials may be easily chemically and …

Contours Of Duration: Movement Authored Through Form—A Behavior Archive, Jood Senussi Elbeshti

Theses and Dissertations

Insect anatomy offers an elegant example of motion derived from structure. Inspired by insect movement, Contours of Duration employs a cam-and-follower system consisting of moving, leg-like parts, designed to engage a series of rotating cams, such that the shape of each cam’s surface activates the legs in unique ways, generating repetitive movement, and demonstrating how geometry produces distinct motion behaviors over time. Through iterative experimentation and controlled variation, trace emerges as a central methodology, whereby movement, over time, creates a distinct pattern of marks, making motion legible and reflecting how subtle changes to surface and form generate different behavioral outcomes. …

Modeling Of Laser-Produced Plasma Plumes: Expansion, Chemistry, And Thin-Film Deposition, Edmund Tsiri Semaha, Edmund Tsiri Semaha

Theses and Dissertations

Abstract

Laser-assisted material processing involves coupled plasma expansion, chemical reactions, and particle transport that govern the quality of thin-film deposition. This dissertation presents a comprehensive computational investigation of these processes using the OpenFOAM framework. First, the performance of the twoPhaseEulerFoam (tPEF), rhoCentralFoam (rCF), and sonicFoam (sF) solvers is evaluated for modeling laser-produced plasma plume expansion under atmospheric conditions, demonstrating that tPEF accurately captures shock-wave propagation, hydrodynamic behavior, and multispecies interactions. Building on this validation, the reactingFoam (rF) solver is employed to investigate the chemistry of aluminum plasma expanding into an air environment (Al–N₂–O₂). The model incorporates appropriate thermodynamic, transport, and …

Buckling Analysis Of Auxetic Composite Laminates And Optimal Design Using Lamination Parameters And Machine Learning, Hans Bendon Maria Tamil Selvan

Mechanical and Aerospace Engineering Theses

Composite materials are widely used as structural panels in aerospace, automotive, and civil engineering applications, where buckling is often a critical failure mode. This thesis focuses on the analysis and design of composite laminates that maximize buckling performance under prescribed stiffness and thickness constraints.

The first part of the study investigates the buckling behavior of auxetic laminates, which exhibit a negative Poisson's ratio. While previous studies suggest that auxetic laminates can achieve higher critical buckling loads than non-auxetic laminates under simply supported boundary conditions with lateral restraint, the influence of other boundary conditions and plate aspect ratios has not been …

Charge‐Governed Mechanistic Evaluation Of Aav2 Clarification Via Functionalized Flat Sheet And Hollow Fiber Deconstructed Depth Filters, Mara Baughman‐Leach, Mattie Brock, Malgorzata Chwatko, Dibakar Bhattacharyya

Chemical and Materials Engineering Faculty Publications

The expansion of adeno-associated virus (AAV)-based therapeutics has increased the demand for efficient clarification. In this study, a functionalized deconstructed depth filtration platform was developed to dissect how membrane–virus charge, modulated by pH, influences separation. Three charge regimes, positive (pH 4), neutral (pH 6), and negative (pH 8) between the membranes and AAVs, were examined. The flat-sheet system, composed of sequential 1.2, 0.8, 0.45, and 0.1 µm membranes, enabled the first layer-by-layer analysis of depth filtration behavior. This revealed that Stage 1 and Stage 4 dominate clarification. Remarkably, substantial DNA capture (> 75%) was observed even in the largest-pore stage, …