Power and Energy Commons^™

Recent Process In Transition-Metal-Oxide Based Catalysts For Oxygen Reduction Reaction, Yao Wang, Zi-Dong Wei

Journal of Electrochemistry

Transition metal oxides (TMOs) based catalysts have become the most promising catalysts to be employed in anion exchange membrane fuel cell for the sluggish oxygen reduction reaction (ORR). However, their ORR activity is still far from that of the Pt-based catalysts. Therefore, it is important to develop high performance TMO based catalysts. Electrical conductivity and intrinsic activity have been regarded as the two keys to affect the ORR activity of the TMOs based catalysts. In this review, we focused on the recent progresses in the fundamental viewpoints on the electrical conductivity and intrinsic activity of the TMOs based ORR catalysts. …

Recent Advances In Continuous Models Of Electrochemical Supercapacitors, Hao-Tian Lu, Jing-Hong Zhou, Guang-Hua Ye, Xing-Gui Zhou

Journal of Electrochemistry

Electrochemical capacitors (supercapacitors) have been developed as a new type of energy storage device with high energy and power densities, which have the advantages of both fast charging-discharging as traditional capacitors and high energy density as batteries. Notable improvements in their electrochemical performance have been achieved in recent years owing to the recent advances in understanding of charge storage mechanisms and the development of advanced nanostructured materials. Recently, modeling and simulation of these supercapacitors has been applied as a useful approach to better understand the working mechanisms of the supercapacitors by describing the concentrations and electric fields inside the capacitors. …

Recent Advances In Non-Noble Metal Nanomaterials For Oxygen Evolution Electrocatalysis, Dan-Dan Zhao, Nan Zhang, Ling-Zheng Bu, Qi Shao, Xiao-Qing Huang

Journal of Electrochemistry

Hydrogen is a kind of renewable energies with the merits of environmentally friendly, abundance and high weight energy density, which can replace the fossil energy. The electrolysis of water is regarded as the most effective way to generate hydrogen. Owing to the sluggish kinetics and large overpotential of the anode oxygen evolution reaction (OER), the efficiency of the cathode hydrogen evolution reaction is greatly limited. Therefore, it is highly desirable to explore efficient, stable and low cost electrocatalysts to reduce the overpotential of OER and improve the efficiency of hydrogen evolution. Based on the natural characteristics of non-noble metal catalysts …

Recent Progress In Organic Redox Flow Batteries, Li-Xing Xia, Hao Liu, Lin Liu, Zhan-Ao Tan

Journal of Electrochemistry

Redox flow batteries (RFBs) are promising candidate for balancing instability of grids caused by integration of intermittent renewable energies such as solar energy and wind energy. Along with wide deployments in solar energy and wind energy due to abundance and declining installation cost, it can be predicted that RFBs will enter a period of rapid development. Basically,RFBs are electrochemical energy storage devices that decouple energy and power of the system by storing liquid electrolyte in tanks outside battery system itself. Such a unique framework makes RFBs flexible and fulfills the various demands of grids. During battery operation, redox-active species are …

The New Application Of Battery-Electrode Reaction: Decoupled Hydrogen Production In Water Electrolysis, Yuan-Yuan Ma, Zhao-Wei Guo, Yong-Gang Wang, Yong-Yao Xia

Journal of Electrochemistry

Hydrogen has been considered as a promising alternative to unsustainable fossil fuels because of its high calorific value, clean and abundant resources. Water electrolysis combined with renewable energy is regarded as the best way for hydrogen production, which will become the foundation of future hydrogen economy. For the past few years, many efforts have been employed to develop the cheap and high-performance catalyst for hydrogen evolution reaction and oxygen evolution reaction. However,the coupled hydrogen and oxygen evolution and the use of the expensive membrane have greatly restricted the flexibility of the conventional water electrolysis, and hindered the utilization of renewable …

Design Strategies Toward Highly Active Electrocatalysts For Oxygen Evolution Reaction, Tang Tang, Wen-Jie Jiang, Shuai Niu, Jin-Song Hu

Journal of Electrochemistry

Electrocatalytic water splitting is pivotal for efficient and economical production of hydrogen and oxygen gasses. However, the efficiency of the whole device is largely limited by the oxygen evolution reaction (OER) at the anode due to its sluggish kinetics. Thus, it is imperative to develop inexpensive, highly active OER catalysts to lower the reaction barriers. By examining the underlying critical factors for OER performance, this review outlines general principles for designing efficient nanosized OER catalysts, including (1) enhancing the intrinsic activity of active site by electronic modulation, crystallinity modulation, phase control, defect engineering and spin state engineering; (2) designing appropriate …

Research Progresses In Improvement For Low Temperature Performance Of Lithium-Ion Batteries, Yue-Ru Gu, Wei-Min Zhao, Chang-Hu Su, Chuan-Jun Luo, Zhong-Ru Zhang, Xu-Jin Xue, Yong Yang

Journal of Electrochemistry

Lithium-ion batteries (LIBs) have become a new research hotspot due to their high energy density and long service life. However, the temperature characteristics, especially the poor performance at low temperatures, have seriously limited their wider applications. In this report, the research progresses in the low temperature performance of LIBs are reviewed. The main existing limitations of LIBs at low temperatures were systematically analyzed, and followed by discussion on the recent improvements in low temperature performances by developing novel cathode, electrolyte, and anode materials. The developments for improving the low temperature performance of LIBs are prospected. The three most important factors …

Synthesis Of Keggin Polyoxometalates Modified Carbon Paste Electrode As A Sensor For Dopamine Detection, Peng-Fei Dong, Na Li, Hai-Yan Zhao, Min Cui, Cong Zhang, Ju-Jie Ren, Xue-Ping Ji

Journal of Electrochemistry

Polyoxometalates, a class of anionic clusters with structure diversity and size variability, make them very attractive in many fields such as electrochemistry, catalysis and medicine. The Co(C₁₅N₆H₁₂)₂[PW₁₂O₃₈]·5H₂O(Co[PW₁₂O₃₈]) modified carbon paste electrode was prepared in this work, and its electrochemical performances as the sensor for dopamine detection were characterized with electrochemical impedance spectroscopy, cyclic voltammetry and differential pulse voltammetry. The preparation conditions and test conditions were optimized respectively. Under the optimized conditions, the POMs modified carbon paste electrode exhibited good selectivity and sensitivity …

Effects Of Sulfur-Containing Additive On Low Temperature Performance Of Graphite Anode, Ze-Li Wu, Ye-Zhen Zheng, Zhong-Ru Zhang, Yong Yang

Journal of Electrochemistry

The low temperature performance of lithium ion battery mainly depends on the graphite anode, and one of the research focuses is to improve the low temperature performance of the anode by additives. In this paper, the effects of different sulfur-containing functional groups such as DTD (ethylene sulfate), 1,3-PS (1,3-propane sultone) and ES (ethylene sulfite) on low temperature performances of artificial graphite materials were systematically studied. The results in density functional theory (DFT) calculations, cyclic voltammetry (CV), scanning electron microscopy (SEM) and charge-discharge measurement clearly demonstrated that all three sulfur-containing additives could participate in formation of films on the surface of …

An Accurate And Efficient Time Delay Estimation Method Of Ultra-High Frequency Signals For Partial Discharge Localization In Substations, Pengfei Li, Kejie Dai, Tong Zhang, Yantao Jin, Yushun Liu, Yuan Liao

Electrical and Computer Engineering Faculty Publications

Partial discharge (PD) localization in substations based on the ultra-high frequency (UHF) method can be used to efficiently assess insulation conditions. Localization accuracy is affected by the accuracy of the time delay (TD) estimation, which is critical for PD localization in substations. A review of existing TD estimation methods indicates that there is a need to develop methods that are both accurate and computationally efficient. In this paper, a novel TD estimation method is proposed to improve both accuracy and efficiency. The TD is calculated using an improved cross-correlation algorithm based on full-wavefronts of array UHF signals, which are extracted …

Power Utility Tests For Multi-Mw High Energy Batteries, Oluwaseun M. Akeyo, Huangjie Gong, Vandana Rallabandi, Nicholas Jewell, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

This paper reviews the procedures, layouts and metrics described in the new test manual issued by the Electric Power Research Institute (EPRI), in order to determine the performance and functionality of a utility scale battery energy storage system (BESS). In this approach, the large battery unit is connected to the dc-link of a bidirectional power conversion system (PCS), which may be interfaced with either the utility grid or a load bank for the purpose of estimating the BESS operation and performance characteristics, some of which includes; available charge/discharge energy at rated power, continuous charge/discharge duration, battery ramp rate, and ac …

Simulation Studies For A Multi-Mw Hybrid Wind-Solar Pv System For Desalination Plants, Vandana Rallabandi, Nasser Alawhali, Oluwaseun M. Akeyo, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

This paper presents a power system configuration and control schemes for a Multi-MW wind-solar hybrid system, which includes multiple wind turbines and solar panels to support a desalination plant. The wind and solar systems are sized such that the desalination plant obtains, as far as possible, its power from the renewable sources, to minimize the dependence on the utility grid. Each section of the wind turbine system includes a variable speed permanent magnet synchronous generator connected to the grid via a back-to-back voltage source converter. The rectifier operates the wind system at the maximum power point, and the inverter provides …

Effect Of Wireless Communication Delay On Dc Microgrids Performance, Mahmoud Saleh, Yusef Esa, Ahmed Mohamed

Publications and Research

This paper investigates the effect of wireless communication technologies latency on the converters and the bus voltage of centrally communication based controlled DC microgrids (MGs) during islanding. A DC microgrid with its communication based control scheme was modeled to show the impact of latency. Simulation results show that the impact may be severe depending on the design, and the operational condition of the microgrid before latency occurs.

Improving A Transient Stability Control Scheme With Wide-Area Synchrophasors And The Microwecc, A Reduced-Order Model Of The Western Interconnect, Robin Hallett

Graduate Theses & Non-Theses

This thesis is composed of two research projects. The first project investigated the feasibility of improving a generator tripping control scheme using wide-area synchrophasors and the second project focused on building a reduced-order model of the western North American power system (wNAPS) for use in a real-time digital simulator.

Transient stability is a major reliability issue for power systems. Radially-connected power plants are especially prone to transient stability problems. An example of this is the fourgenerator Colstrip power plant located in southeast Montana, USA. The Colstrip generators are protected by a tripping control system called the Acceleration Trend Relay (ATR) …

Real Time Operation Of Smart Homes With Pv And Battery Systems Under Variable Electricity Rate Schedules And Transactive Power Flow, Huangjie Gong, Oluwaseun M. Akeyo, Vandana Rallabandi, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

According to some utility schedules, the electricity rate is variable such that homes may be encouraged to buy and store power in a battery when it is inexpensive, and self-consume or sell to the grid during other times. Power arbitrage through a battery energy storage (BES), can help maintain consumer comfort and minimize residential electricity bills. This paper reports the calculated daily energy costs incurred by different types of homes for a given utility electricity rate schedule. The homes exchange power among each other behind a section of the distribution network. A free market system is formed and the electricity …

Impact Of Communication Latency On The Bus Voltage Of Centrally Controlled Dc Microgrid During Islanding, Mahmoud Saleh, Yusef Esa, Ahmed Mohamed

Publications and Research

Maintaining a sustainable and reliable source of energy to supply critical loads within a renewable energy based microgrid (MG) during blackouts is directly related to its bus voltage variations. For example, voltage variation might trigger protection devices and disconnect DERs within the MG. Centrally controlled MGs (CCMGs) type is dependent on communication. Therefore, it is very important to analyze the impact of communication networks performance degradation, such as latency, on the bus voltage of CCMGs. This paper investigates the effect of wireless communication technologies latency on the bus voltage and performance of centralized DC MGs. Two mathematical models were developed …

Electrochemical Hydrogenation Of Acetone To Produce Isopropanol Using A Polymer Electrolyte Membrane Reactor, Chen Li, Ashanti M. Sallee, Xiaoyu Zhang, Sandeep Kumar

Civil & Environmental Engineering Faculty Publications

Electrochemical hydrogenation (ECH) of acetone is a relatively new method to produce isopropanol. It provides an alternative way of upgrading bio-fuels with less energy consumption and chemical waste as compared to conventional methods. In this paper, Polymer Electrolyte Membrane Fuel Cell (PEMFC) hardware was used as an electrochemical reactor to hydrogenate acetone to produce isopropanol and diisopropyl ether as a byproduct. High current efficiency (59.7%) and selectivity (>90%) were achieved, while ECH was carried out in mild conditions (65 degrees C and atmospheric pressure). Various operating parameters were evaluated to determine their effects on the yield of acetone and …

Interface Model Of Pem Fuel Cell Membrane Steady-Dtate Behavior, Russell L. Edwards, Ayodeji Demuren

Mechanical & Aerospace Engineering Faculty Publications

Modeling works which simulate the proton-exchange membrane fuel cell with the computational fluid dynamics approach involve the simultaneous solution of multiple, interconnected physics equations for fluid flows, heat transport, electrochemical reactions, and both protonic and electronic conduction. Modeling efforts vary by how they treat the physics within and adjacent to the membrane-electrode assembly (MEA). Certain approaches treat the MEA not as part of the computational domain, but rather an interface connecting the anode and cathode computational domains. These approaches may lack the ability to consistently model catalyst layer losses and MEA ohmic resistance. This work presents an upgraded interface formulation …

Implementation Of Secure Dnp3 Architecture Of Scada System For Smart Grids, Uday Bhaskar Boyanapalli

Master of Science in Computer Science Theses

With the recent advances in the power grid system connecting to the internet, data sharing, and networking enables space for hackers to maliciously attack them based on their vulnerabilities. Vital stations in the smart grid are the generation, transmission, distribution, and customer substations are connected and controlled remotely by the network. Every substation is controlled by a Supervisory Control and Data Acquisition (SCADA) system which communicates on DNP3 protocol on Internet/IP which has many security vulnerabilities. This research will focus on Distributed Network Protocol (DNP3) communication which is used in the smart grid to communicate between the controller devices. We …

Design, Simulation, And Construction Of An Ieee 14-Bus Power System, John Albert Boudreaux

LSU Master's Theses

Today’s bulk power system is massive, complex, and very dynamic. The U.S. power grid spans from coast to coast and even as far reaching as Canada. With the addition of new technologies such as renewable energies and power electronics to aid in power conversion and control, the power system grows more complex by the day. The most common approach of analyzing power system stability is through computer modeling and simulation. Due to the vast size and inaccessibility of transmission systems, real time testing can prove difficult. The motivation of this project was to design, simulate, and construct an IEEE 14 …