Power and Energy Commons^™

A Review Of Proton Exchange Membrane Fuel Cell Catalyst Layer By Electrospinning, Yong Liu, Han Ding, De-Chun Si, Jie Peng, Jian-Bo Zhang

Journal of Electrochemistry

The limitation of catalyst layer for proton exchange membrane fuel cell (PEMFC) in cost, durability and performance constitutes the bottleneck for the commercialization of fuel cell vehicles. Electrospun catalyst layer, with high catalyst utilization, increased triple phase boundary (TPB) and triple phase channel (TPC), has been developed by many researchers. This paper reviews the research progress in the electrospun catalyst layer for PEMFC, combined with the author’s work. Firstly, the development progress of catalyst layer is summarized, and the catalyst layer is classified and analyzed based on its fabrication method and structure character. Next, the fabrication process, physical property characterization, …

Fe-N Doped Hollow Carbon Nanospheres Linked By Carbon Nanotubes For Oxygen Reduction Reaction, Ya-Lin Zhang, Chi Chen, Liang-Liang Zou, Zhi-Qing Zou, Hui Yang

Journal of Electrochemistry

The development of non-precious metal catalysts for oxygen reduction reaction (ORR) is essential for large-scale application of proton exchange membrane fuel cells. Herein, we present the in situ formed Fe-N doped hollow carbon nanospheres linked by carbon nanotubes composite, synthesized by using ZIF-8 as sacrificed template to form polydopamine (PDA) hollow nanospheres, followed by complexing with FeCl₃, high temperature heat-treatment and NH₃-etching. ZIF-8 was gradually decomposed simultaneously with PDA coating due to the loss of Zn²⁺ grabbed by PDA. NH3 etching resulted in the improved surface area, while the reducibility of NH₃ resulted in …

Facile Synthesis Of Pt-Cu Alloy Nanodendrites As High-Performance Electrocatalysts For Oxygen Reduction Reaction, Liu-Xuan Luo, Guang-Hua Wei, Shui-Yun Shen, Feng-Juan Zhu, Chang-Chun Ke, Xiao-Hui Yan, Jun-Liang Zhang

Journal of Electrochemistry

Structures and compositions have significant effects on the catalytic properties of nanomaterials. Herein, a facile etching-based method was employed to synthesize Pt-Cu nanodendrites (NDs) with uniform and homogeneous alloy structures for enhancing oxygen reduction reaction (ORR). The formation of dendritic morphology was ascribed to the etching effect caused by the oxidative etchants of the Br^-/O₂ pair. The atomic ratio of Pt/Cu in Pt-Cu NDs could be easily tuned by altering the ratio of the Pt/Cu precursors, without deteriorating the dendritic morphology. The most active carbon-supported Pt₁Cu₁ NDs (Pt₁Cu₁ NDs/C) exhibited the …

Acid Treated Carbon As Anodic Electrocatalysts Toward Direct Ascorbic Acid Alkaline Membrane Fuel Cells, He-Mu Chen, Chen-Xi Qiu, Yuan-Yuan Cong, Hui-Yuan Liu, Zi-Hui Zhai, Yu-Jiang Song

Journal of Electrochemistry

In order to improve the hydrophilicity and electrocatalytic activity, commercial carbon black (BP 2000) was subjected to acid treatment to obtain acid-treated carbon (ATC). The generation of rich oxygen-containing groups on the surface of the ATC was proved by X-ray photoelectron spectra (XPS), Fourier transform-infra red spectra (FTIR), thermogravimetric analysis (TG) and contact angle measurement. UV-vis spectra were firstly recorded to calculate activation energy (Ea) of ascorbic acid (AA) chemical oxidation in alkaline conditions by oxygen in air and the Ea value was determined to be 37.1 kJ·mol^-1. Additionally, electrochemical impedance spectra (EIS) were used to evaluate unprecedented …

Palladium Adatoms On Gold Nanoparticles As Electrocatalysts For Ethanol Electro-Oxidation In Alkaline Solutions, Hui-Mei Chen, Shang-Qian Zhu, Jia-Le Huang, Min-Hua Shao

Journal of Electrochemistry

Palladium (Pd) is a good catalyst for ethanol electro-oxidation in alkaline solutions. The activity of Pd is further improved in this study by modifying the gold (Au) nanoparticles with Pd adatoms using a simple spontaneous deposition process. The Pd overlayer on the Au core (Au@Pd) is un-uniform with some Au atoms exposed to the electrolyte. The activity of Au@Pd/C toward ethanol oxidation reaction (EOR) is much higher than that of Pd/C in an alkaline solution. The peak current density of Au@Pd/C is 4.6 times higher than that of Pd/C with a 100 mV lower onset potential. The enhanced activity may …

Pd/C Catalysts For Co2 Electroreduction To Co:Pd Loading Effect, Dun-Feng Gao, Cheng-Cheng Yan, Guo-Xiong Wang, Xin-He Bao

Journal of Electrochemistry

Nanostructured heterogeneous catalysts have been widely used in the electrochemical carbon dioxide (CO₂) reduction reaction (CO₂RR), which can simultaneously achieve the electrocatalytic conversion of CO₂ to fuels and the storage of renewable energy sources. Carbon supported palladium nanoparticles (Pd/C) catalysts have been previously reported to show excellent CO₂RR performance. However, the crucial role of the metal loading in supported electrocatalysts has been rarely reported. In this work, we study the Pd loading effect on the structure of Pd/C catalysts as well as their activity and selectivity of CO₂RR to CO. The …

Voltage Distribution Of Self-Humidifying Air-Cooled Pemfc, Kai-Feng Tan, Wei-Rong Chen, Ming Han, Xue-Xia Zhang

Journal of Electrochemistry

In this work, the self-adaptive characteristics of self-humidifying air-cooled PEMFC stack was investigated. The performance and the unit-cell voltage distribution of the stack were measured and analyzed through the unit-cell I-V curve fitting. The operating conditions for this experimental study were set as follows: hydrogen pressure at the anode was 2 bar, the fan power used for the reactant oxygen feed and stack cooling was at 0.3 W, and the duration and time gap of water purged from hydrogen chamber were 1 s and 10 s, respectively. The experimental results showed that the self-humidifying air-cooled PEMFC stack used for this …

Durability Performance Of The High-Power Fuel Cell System, Ke-Yong Wang, Wei-Yu Shi, Ren-Fang Wang, Jia Liu, Zhong-Jun Hou

Journal of Electrochemistry

Fuel cell durability is the crucial challenge in fuel cell vehicle, and the lifetime of more than 5000 hours is believed to be necessary for vehicle application. Few works on durability test of the full fuel cell system have been reported. In this work, the long lifetime HySYS-30 fuel cell system was developed in Sunrise Power based on the improved MEA durability and system control strategy. The durability performance of the system was investigated under vehicle duty cycle for more than 6000 hours, and only 8.1% performance loss was observed, implying that the durability of HySYS-30 fuel cell system could …

Caging Porous Co-N-C Nanocomposites In 3d Graphene As Active And Aggregation-Resistant Electrocatalyst For Oxygen Reduction Reaction, Lu-Yang Xiu, Meng-Zhou Yu, Peng-Ju Yang, Zhi-Yu Wang, Jie-Shan Qiu

Journal of Electrochemistry

Oxygen reduction reaction (ORR) is the cornerstone reaction of many renewable energy technologies such as fuel cells and rechargeable metal-air batteries. The Pt-based electrocatalysts exhibit the highest activity toward ORR, but their large implementation is greatly prohibiting by unaffordable cost and inferior durability. During electrode manufacturing and electrochemical reaction, severe aggregation of catalyst nanoparticles induced by size effect further limits the operational performance of electrocatalysts. We report a new strategy for fabrication of active and aggregation-resistant ORR electrocatalyst by caging metal-organic frameworks derived Co-N-C nanocomposites in permeable and porous 3D graphene cages via sprayed drying the mixed colloids of ZIF-67 …

Performance Optimization Of The Differential Protection Schemes, Monir Hossain

LSU New Orleans Theses and Dissertations

Current differential protection principle is superior in terms of sensitivity and speed of operation in comparison with other protection principle used in power systems. From the last five decades, various current differential protection schemes are widely used to protect busbars, transformers, and short-transmission lines. The deployment of high capacity microwave and optical fiber technologies redefined

the line protection systems by facilitating the use of current differential protection schemes for long transmission lines. The common application issue of these schemes is mis-operation due to current transformer (CT) saturation during close-in external faults. Moreover, transformer differential protection schemes face mis-trip due to …

2018 Fall Engr333 Project Final Report (Section A), 2018 Fall Engr333 Section A

ENGR 333

Calvin College currently spends 2.35 million dollars on energy every year. Physical Plant is under pressure to reduce the amount of energy that Calvin purchases from the electrical grid since the college is facing many budget constraints. In addition, President Le Roy signed the President’s Carbon Commitment to achieve carbon neutrality by 2057. With this need to save money on energy and reduce the college’s carbon footprint, the objective of this project was to determine the largest possible reduction in Calvin’s annual energy costs given a five-million-dollar investment in renewable energy.

2018 Fall Engr333 Project Final Report (Section B), Alexander Cooper, Katie Diekema, Grace Fasipe, Daniella Sugijanto, Alec Dejonge, Timothy Dykhuis, Breanna Kooiman, Samuel Olson, Brennan Boice, Tyler Gustman, Daniel Norton, Christopher Vanwhye, Robert Capozzoli, Jared Minderhoud, Clark Richeson, Nathan Schuyten

ENGR 333

What is the largest possible reduction in Calvin College’s annual energy costs from a $5M initial investment in renewable energy? Renewable energy systems are essential for Calvin College to reduce greenhouse gas emissions and achieve carbon neutrality to meet the Carbon Commitment that President Le Roy signed in December 2017. Also, a significant cost reduction could be a positive result of transitioning to renewable energy sources such as geothermal, wind, solar, and biomass. Four renewable energy sources were studied throughout the semester to determine a feasible renewable energy plan for Calvin with a $5M investment.

Optimal Placement Of Distributed Energy Storage Systems In Distribution Networks Using Artificial Bee Colony Algorithm, Choton K. Das, Octavian Bass, Ganesh Kothapalli, Thair S. Mahmoud, Daryoush Habibi

Research outputs 2014 to 2021

The deployment of utility-scale energy storage systems (ESSs) can be a significant avenue for improving the performance of distribution networks. An optimally placed ESS can reduce power losses and line loading, mitigate peak network demand, improve voltage profile, and in some cases contribute to the network fault level diagnosis. This paper proposes a strategy for optimal placement of distributed ESSs in distribution networks to minimize voltage deviation, line loading, and power losses. The optimal placement of distributed ESSs is investigated in a medium voltage IEEE-33 bus distribution system, which is influenced by a high penetration of renewable (solar and wind) …

2018 Fall Engr333 Poster, Alexander Cooper, Katie Diekema, Grace Fasipe, Daniella Sugijanto, Alec Dejonge, Timothy Dykhuis, Breanna Kooiman, Samuel Olson, Brennan Boice, Tyler Gustman, Daniel Norton, Christopher Vanwhye, Robert Capozzoli, Jared Minderhoud, Clark Richeson, Nathan Schuyten, 2018 Fall Engr333 Section A

ENGR 333

• $158k initial investment in Geothermal systems for various Calvin-owned residential buildings
• $3.34M initial investment in solar panels for Calvin’s rooftops
• The overall savings would be $233,850 per year
• Emissions would be reduced by 864 tons of CO2 emissions per year
• The recommended investment would be fully paid back in 11-15 years

2018 Fall Engr333 Seminar Presentation, Rachel Evans, Alex Gross, Daniella Sugijanto, Jake Shaarda

ENGR 333

File for student presentation, given by students in the Fall 2018 class of ENGR333.

Battery-Buffered Frequency-Controlled Smart Load With Time-Of-Use Energy Arbitrage, Ahmed Jabbar Abbas Zurfi

Theses and Dissertations

In existing long-established power systems, the grid control and balancing are implemented on the generation side in centralized schemes. As the use of renewable, non-dispatchable, inverter-based (inertia-less) energy sources is becoming increasingly pervasive in modern power systems, this paradigm will change and the need for decentralized demand-side control will be imperative to ameliorate the grid’s dynamic performance and stability. Battery energy storage (BES) is one of the essential constituents that will empower this transition. Battery energy storage systems (BESS) are eminent for their features of scalability, mobility, high energy density, and rapid response in tracking abrupt power fluctuations. These features …

Development Of A Rapid Fatigue Life Testing Method For Reliability Assessment Of Flip-Chip Solder Interconnects, Cody Jackson Marbut

Graduate Theses and Dissertations

The underlying physics of failure are critical in assessing the long term reliability of power packages in their intended field applications, yet traditional reliability determination methods are largely inadequate when considering thermomechanical failures. With current reliability determination methods, long test durations, high costs, and a conglomerate of concurrent reliability degrading threat factors make effective understanding of device reliability difficult and expensive. In this work, an alternative reliability testing apparatus and associated protocol was developed to address these concerns; targeting rapid testing times with minimal cost while preserving fatigue life prediction accuracy. Two test stands were fabricated to evaluate device reliability …

Comparison Of Organic And Inorganic Solar Photovoltaic Systems, Khulan Orgil

Electrical Engineering

This senior project report addresses the consumer’s need for accurate and easily accessible information when making a solar panel purchasing decision. Thus, the project analyzes and compares the costs and benefits of organic and inorganic photovoltaic systems during their life cycle. The cost comparison includes analysis of the environmental and economic costs of materials, production, installation, and disposal. The benefit comparison includes analysis of the economic, environmental, and social benefits accrued during the system’s lifetime. With the project’s data, consumers can make more informed decisions to fit their specific needs.

Power Optimization Of Solar Powered Standalone Wireless Sensor System, Rajan Amatya

Masters Theses

Wireless sensor systems are common in applications where harsh environmental conditions or remote locations make it difficult to run wires. Having these sensor systems self-powered is essential as it is difficult for battery replacement. Using solar as an alternative source of energy can be a medium to charge the battery in such scenarios. With an increasing number of portable devices powered by battery; more and more research is focused on low-power design technique. For this thesis, a microcontroller (Texas Instruments MSP432) was used along with a digital sensor (Bosch BME280) to provide temperature, pressure and humidity information, and Wi-Fi module …

Grid-Tied Solar System, Virginia Yan

Electrical Engineering

Distribution level solar energy generation has gained importance and popularity, because it helps create a sustainable electricity system while reducing the harmful environmental impacts our current power systems have. This project proposes an alternative energy source, a laboratory-scale grid-connected photovoltaic system. A KC120-1 solar panel produces 120 Watts maximum. A grid-tied solar power inverter does DC-to-AC conversion and minimizes energy transfer losses. The inverter also has an anti-islanding feature, which senses a power outage and prevents back-feeding through isolating the circuit. The circuit breakers isolate electrical components and protect the circuit. Schweitzer Engineering Laboratories SEL-751 feeder protection relay and SEL-735 …