Engineering Commons^™

Cellulose Nanofiber-Reinforced Impact Modified Polypropylene: Assessing Material Properties From Fused Layer Modeling And Injection Molding Processing, Jordan Elliott Sanders

Electronic Theses and Dissertations

The purpose of this research was to investigate the use of cellulose nanofibers (CNF) compounded into an impact modified polypropylene (IMPP) matrix. A IMPP was used because it shrinks less than a PP homopolymer during FLM processing. An assessment of material properties from fused layer modeling (FLM), an additive manufacturing (AM) method, and injection molding (IM) was conducted. Results showed that material property measurements in neat PP were statistically similar between IM and FLM for density, strain at yield and flexural stiffness. Additionally, PP plus the coupling agent maleic anhydride (MA) showed statistically similar results in comparison of IM and …

Heterogeneous Anisotropy Index And Scaling In Multiphase Random Polycrystals, Muhammad Ridwan Murshed

Theses and Dissertations

Under consideration is the finite-size scaling of elastic properties in single and two-phase random polycrystals with individual grains belonging to any crystal class (from cubic to triclinic). These polycrystals are generated by Voronoi tessellations with varying grain sizes and volume fractions. By employing variational principles in elasticity, we introduce the notion of a 'Heterogeneous Anisotropy Index' and investigate its role in the scaling of elastic properties at finite mesoscales. The index turns out to be a function of 43 variables, 21 independent components for each phase and the volume fraction of either phase. Furthermore, the relationship between Heterogeneous Anisotropy Index …

College Of Engineering Senior Design Competition Fall 2017, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge. The senior design competition helps focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects on …

Synthesis And Characterization Of Thermoresponsive Hydrogels Based On N-Isopropylacrylamide Crosslinked With 4,4′-Dihydroxybiphenyl Diacrylate, Shuo Tang, Martha Floy, Rohit Bhandari, Manjula Sunkara, Andrew J. Morris, Thomas D. Dziubla, J. Zach Hilt

Chemical and Materials Engineering Faculty Publications

A novel crosslinker [4,4′-dihydroxybiphenyl diacrylate (44BDA)] was developed, and a series of temperature-responsive hydrogels were synthesized through free radical polymerization of N-isopropylacrylamide (NIPAAm) with 44BDA. The temperature-responsive behavior of the resulting gels was characterized by swelling studies, and the lower critical solution temperature (LCST) of the hydrogels was characterized through differential scanning calorimetry. Increased content of 44BDA led to a decreased swelling ratio and shifted the LCST to lower temperatures. These novel hydrogels also displayed resiliency through multiple swelling–deswelling cycles, and their temperature responsiveness was reversible. The successful synthesis of NIPAAm-based hydrogels crosslinked with 44BDA has led to a …

Cloudsat-Based Assessment Of Gpm Microwave Imager Snowfall Observation Capabilities, Giulia Panegrossi, Jean-François Rysman, Daniele Casella, Anna Cinzia Marra, Mark Kulie

Department of Geological and Mining Engineering and Sciences Publications

The sensitivity of Global Precipitation Measurement (GPM) Microwave Imager (GMI) high-frequency channels to snowfall at higher latitudes (around 60^◦N/S) is investigated using coincident CloudSat observations. The 166 GHz channel is highlighted throughout the study due to its ice scattering sensitivity and polarization information. The analysis of three case studies evidences the important combined role of total precipitable water (TPW), supercooled cloud water,and background surface composition on the brightness temperature (TB) behavior for different snow-producing clouds. A regression tree statistical analysis applied to the entire GMI-CloudSat snowfall dataset indicates which variables influence the 166 GHz polarization difference (166∆TB)and its …

Note From The Editorial Board

Dartmouth Undergraduate Journal of Science

No abstract provided.

Development Of High-Performing Polydimethylsiloxane-Based Membranes For Carbon Dioxide Separation, Tao Hong

Doctoral Dissertations

Membrane separation is highlighted as one of the most promising approaches to mitigate the excessive CO₂ [carbon dioxide] emission, due to its significant reduction of energy cost compared with many conventional separation techniques. Unfortunately, the separation performance of current membranes does not meet the practical CO₂/N₂ [nitrogen] separation requirements. And due to the huge volume of industrial flue gas, membranes with exceptionally high permeability are needed for practical reasons.

Currently, the separation mechanism of most polymeric membranes is based on size-sieving. However, this method is not sufficient for CO₂/N₂ separations due to the …

An Exploration Of Basic Processes For Aqueous Electrochemical Production Of Hydrogen From Biomass Derived Molecules, Brian Fane

Doctoral Dissertations

Polymer electrolyte membrane fuel cells(PEMFCs) are energy conversion devices with significant potential. The factors preventing them from becoming widespread concern production and distribution of hydrogen. Developing an efficient hydrogen infrastructure with an approachable rollout plan is an essential step towards the future of fuel cells. Water electrolysis is limited by the thermodynamics of the process, which leads to high electrical consumption and significant materials challenges. Alternative methods for cleanly generating hydrogen while using a lower cell voltage are required. PEM based electrolyzers can operate with a "depolarized anode", whereby they become significantly less power hungry.

This thesis explores two techniques …

Design And Synthesis Of Analogs Of Myo-Inositol, Serine, And Cysteine To Enable Chemical Biology Studies, Tanei J. Ricks

Doctoral Dissertations

Phosphorylated myo-inositol compounds including inositol phosphates (InsPs) as well as the phosphatidylinositol polyphosphate lipids (PIP_ns) are critical biomolecules that regulate many of the most important biological processes and pathways. They are aberrant in many disease states due to their regulatory function. The same is true of the phospholipid phosphatidylserine (PS) which can serve as a marker to begin apoptosis. However, the full scope of activities of these structures is not clear, particularly since techniques that enable global detection and analysis of the production of these compounds spatially and temporally are lacking. With all of these obstacles in …

Multiscale Modeling Approach To Understand Active Sites In Non-Conventional Catalyst Layers For Fuel Cell Applications, Diana Constanza Orozco Gallo

Doctoral Dissertations

Fuel cells development required stable, active and more abundant catalytic materials. Oxygen reduction reaction (ORR) is the key process to enhance better activity and reduce the fabrication costs. Pt-based has proven to be the best catalyst for ORR and greater efforts has been made in terms of reducing the Pt content in the electrodes, reduce electrode thickness and enhance better catalytic activities. To overcome many of the challenges present, the catalyst layer studies are the great importance in the fuel cell community. Understanding catalyst layer with new catalytic materials, and configurations requires the development of methodological approach to relate structure, …

Transport Of Water And Ions Through Single-Walled Armchair Carbon Nanotubes: A Molecular Dynamics Study, Michelle Patricia Aranha

Doctoral Dissertations

The narrow hydrophobic interior of a carbon nanotube (CNT) poses a barrier to the transport of water and ions, and yet, unexpectedly, numerous experimental and simulation studies have confirmed fast water transport rates comparable to those seen in biological aquaporin channels. These outstanding features of high water permeability and high solute rejection of even dissolved ions that would typically require a lot of energy for separation in commercial processes makes carbon nanotubes an exciting candidate for desalination membranes. Extending ion exclusion beyond simple mechanical sieving by the inclusion of electrostatics via added functionality to the nanotube bears promise to not …

Rogue Rotary - Modular Robotic Rotary Joint Design, Sean Wesley Murphy, Tyler David Riessen, Jacob Mark Triplett

Mechanical Engineering

This paper describes the design process from ideation to test validation for a singular robotic joint to be configured into a myriad of system level of robots.

Multiple Content Adaptive Intelligent Watermarking Schemes For The Protection Of Blocks Of A Document Image, Chetan Kr Mr., S Nirmala Dr.

Journal of Digital Forensics, Security and Law

Most of the documents contain different types of information such as white space, static information and dynamic information or mix of static and dynamic information. In this paper, multiple watermarking schemes are proposed for protection of the information content. The proposed approach comprises of three phases. In Phase-1, the edges of the source document image are extracted and the edge image is decomposed into blocks of uniform size. In Phase-2, GLCM features like energy, homogeneity, contrast and correlation are extracted from each block and the blocks are classified as no-information, static, dynamic and mix of static and dynamic information content …

A Data Hiding Scheme Based On Chaotic Map And Pixel Pairs, Sengul Dogan Sd

Journal of Digital Forensics, Security and Law

Information security is one of the most common areas of study today. In the literature, there are many algorithms developed in the information security. The Least Significant Bit (LSB) method is the most known of these algorithms. LSB method is easy to apply however it is not effective on providing data privacy and robustness. In spite of all its disadvantages, LSB is the most frequently used algorithm in literature due to providing high visual quality. In this study, an effective data hiding scheme alternative to LSB, 2LSBs, 3LSBs and 4LSBs algorithms (known as xLSBs), is proposed. In this method, random …

Minerva 2017, The Honors College

Minerva

This issue of Minerva includes a feature on Honors College research collaboratives; an article on Honors students studying abroad in Singapore and Chile; an article reflecting upon the 15-year anniversary of the Honors College and the importance of mentorship; and articles on Honors students Isaiah Mansour and Aliya Uteova.

Three-Dimensional Vapor Intrusion Modeling Approach That Combines Wind And Stack Effects On Indoor, Atmospheric, And Subsurface Domains, Elham Shirazi, Kelly G. Pennell

Civil Engineering Faculty Publications

Vapor intrusion (IV) exposure risks are difficult to characterize due to the role of atmospheric, building and subsurface processes. This study presents a three-dimensional VI model that extends the common subsurface fate and transport equations to incorporate wind and stack effects on indoor air pressure, building air exchange rate (AER) and indoor contaminant concentration to improve VI exposure risk estimates. The model incorporates three modeling programs: (1) COMSOL Multiphysics to model subsurface fate and transport processes, (2) CFD0 to model atmospheric air flow around the building, and (3) CONTAM to model indoor air quality. The combined VI model predicts AER …

Exploring Energy, Comfort, And Building Health Impacts Of Deep Setback And Normal Occupancy Smart Thermostat Implementation, Zachary Ethan Alderman

Graduate Theses and Dissertations

As smart thermostat adoption rates continue to increase, it becomes worthwhile to explore what unanticipated outcomes may result in their use. Specific attention was paid to smart thermostat impacts to deep setback and normal occupancy states in a variety of conditions while complying with the ventilation and temperature requirements of ASHRAE 90.2-2013. Custom weather models and occupancy schedules were generated to efficiently explore a combination of weather conditions, building constructions, and occupancy states. The custom modeling approach was combined with previous experimental data within the Openstudio graphics interface to the EnergyPlus building modeling engine. Results indicate smart thermostats add the …

An Evaluation Of Borehole Hydraulic Conductivity Equations And Field Determined Soil Water Characteristic Curves, Johnathan Dale Blanchard

Graduate Theses and Dissertations

The methods utilized to determine the hydraulic conductivity of compacted clay liners (CCLs) are of importance for safe guarding the environment from landfill leachate. Therefore, the methods utilized in the analysis of the Two Stage Borehole (TSB) test, as described in the ASTM D6391-11 (Method A, B, and C) standard, were evaluated. Data from hydraulic conductivity tests, as performed on three test pads, were utilized to review the ASTM D6391-11 equations. Additionally, two test pads were instrumented with volumetric water content and soil water matric potential sensors to facilitate the determination of field-obtained soil water characteristic curves (SWCCs) and hydraulic …

Evaluation Of Water Resources And Hydraulic Influences In The Restoration Of The Western Part Of The Mesopotamian Marshlands, Ali Kareem Al-Quraishi

Graduate Theses and Dissertations

The purpose of this study is to assess the water resources and water conveyance system of the western part of the Mesopotamian marshes (Al-Hammar marsh) as well as develop a water conveyance system to distribute water throughout the western Al-Hammar marsh. These processes are significant to identify the current restoration problems and help to create restoration strategies for the marsh. Also, proper management strategy to the Al-Hammar marsh is necessary to preserve the marsh ecosystem, irrigate lands, and provide domestic necessities in the villages.

The overall project is divided into three main chapters which address the current ecological and hydrological …

Real-Time, Selective Detection Of Heavy Metal Ions In Water Using 2d Nanomaterials-Based Field-Effect Transistors, Guihua Zhou

Theses and Dissertations

Excessive intake of heavy metals damages the central nervous system and causes brain and blood disorders in mammals. Heavy metal contamination is commonly associated with exposure to mercury, lead, arsenic, and cadmium (arsenic is a metalloid, but classified as a heavy metal). Traditional methods to detect heavy metal ions include graphite furnace atomic absorption spectroscopy (GFAAS), inductively-coupled plasma optical emission spectroscopy (ICP-OES), and inductively-coupled plasma mass spectroscopy (ICP-MS). Recently, many new methods have been proposed to detect heavy metal ions, including atomic absorption spectrometry, fluorescent sensors, colorimetric sensors, electrochemical sensors, X-ray absorption fine structure spectroscopy, ultrasensitive dynamic light scatting assays, …

Proactive Sequential Resource (Re)Distribution For Improving Efficiency In Urban Environments, Supriyo Ghosh

Dissertations and Theses Collection (Open Access)

Due to the increasing population and lack of coordination, there is a mismatch in supply and demand of common resources (e.g., shared bikes, ambulances, taxis) in urban environments, which has deteriorated a wide variety of quality of life metrics such as success rate in issuing shared bikes, response times for emergency needs, waiting times in queues etc. Thus, in my thesis, I propose efficient algorithms that optimise the quality of life metrics by proactively redistributing the resources using intelligent operational (day-to-day) and strategic (long-term) decisions in the context of urban transportation and health & safety. For urban transportation, Bike Sharing …

Controlled Electrochemical Reduction Of Gold And Palladium Metal Precursors In Polyaniline, Nicole Goodwin

UNLV Theses, Dissertations, Professional Papers, and Capstones

Polyaniline (PANI) has been extensively studied due to its unique electrochemical properties. The conjugated polymer is conductive with high chemical stability below 100°C, mechanical strength, and large surface area. The applications of PANI have included chemical sensing, corrosion inhibition coatings, light emitting diode and as a substrate for metal composite catalysts. Both chemical and electrochemical methods have been developed and utilized in the synthesis of PANI/metal composites. The simultaneous reduction of aniline and metal precursor produces a composite of PANI encapsulated metal, reducing the active surface area available for catalysis. Alternatively, chemical reduction of the metal precursor into preformed PANI …

Recursive Non-Local Means Filter For Video Denoising, Redha A. Ali, Russell C. Hardie

Electrical and Computer Engineering Faculty Publications

In this paper, we propose a computationally efficient algorithm for video denoising that exploits temporal and spatial redundancy. The proposed method is based on non-local means (NLM). NLM methods have been applied successfully in various image denoising applications. In the single-frame NLM method, each output pixel is formed as a weighted sum of the center pixels of neighboring patches, within a given search window.

The weights are based on the patch intensity vector distances. The process requires computing vector distances for all of the patches in the search window. Direct extension of this method from 2D to 3D, for video …

Speckle Effects In Target-In-The-Loop Laser Beam Projection Systems, Mikhail Vorontsov

Electro-Optics and Photonics Faculty Publications

In target-in-the-loop laser beam projection scenarios typical of remote sensing, directed energy, and adaptive optics applications, a transmitted laser beam propagates through an optically inhomogeneous medium toward a target, scatters off the target’s rough surface, and returns back to the transceiver plane. Coherent beam scattering off the randomly rough surface results in strong speckle modulation in the transceiver plane. This speckle modulation has been a long-standing challenge that limits performance of remote sensing, active imaging, and adaptive optics techniques. Using physics-based models of laser beam scattering off a randomly rough surface, we show that received speckle-field spatial and temporal characteristics …

Developing Leading And Lagging Indicators To Enhance Equipment Reliability In A Lean System, Dhanush Agara Mallesh

Masters Theses

With increasing complexity in equipment, the failure rates are becoming a critical metric due to the unplanned maintenance in a production environment. Unplanned maintenance in manufacturing process is created issues with downtimes and decreasing the reliability of equipment. Failures in equipment have resulted in the loss of revenue to organizations encouraging maintenance practitioners to analyze ways to change unplanned to planned maintenance. Efficient failure prediction models are being developed to learn about the failures in advance. With this information, failures predicted can reduce the downtimes in the system and improve the throughput.

The goal of this thesis is to predict …

Automated Program Profiling And Analysis For Managing Heterogeneous Memory Systems, Adam Palmer Howard

Masters Theses

Many promising memory technologies, such as non-volatile, storage-class memories and high-bandwidth, on-chip RAMs, are beginning to emerge. Since each of these new technologies present tradeoffs distinct from conventional DRAMs, next-generation systems are likely to include multiple tiers of memory storage, each with their own type of devices. To efficiently utilize the available hardware, such systems will need to alter their data management strategies to consider the performance and capabilities provided by each tier.

This work explores a variety of cross-layer strategies for managing application data in heterogeneous memory systems. We propose different program profiling-based techniques to automatically partition program allocation …

Free-Space Measurements Of Dielectrics And Three-Dimensional Periodic Metamaterials, Clifford E. Kintner

Graduate Theses and Dissertations

This thesis presents the free-space measurements of a periodic metamaterial structure. The metamaterial unit cell consists of two dielectric sheets intersecting at 90 degrees. The dielectric is a polyetherimide-based material 0.001” thick. Each sheet has a copper capacitively-loaded loop (CLL) structure on the front and a cut-wire structure on the back. Foam material is used to support the unit cells. The unit cell repeats 40 times in the x-direction, 58 times in the y-direction and 5 times in the z-direction. The sample measures 12” × 12” × 1” in total. We use a free-space broadband system comprised of a pair …

Geophysical Delineation Of Megaporosity And Fluid Migration Pathways For Geohazard Characterization Within The Delaware Basin, Culberson County, Texas, Jonathan David Woodard

Electronic Theses and Dissertations

ABSTRACT

Differential dissolution of gypsum karst within the Delaware Basin poses a significant threat to infrastructure that society depends on. The study area is located in Culberson County, Texas and traverses a distance of approximately 54 kilometers along RM 652 within the Gypsum Plain which is situated on the northern margin of the Chihuahua Desert and includes outcrops of Castile and Rustler strata that host karst geohazards. Regions of karst geohazard potential have been physically surveyed proximal to the study area in evaporites throughout the Castile Formation outcrop; minimal hazards, in comparison to the Castile Formation, have been documented in …

Water Chemistry Dynamics In Four Vernal Pools In Maine, Usa, Lydia H. Kifner

Electronic Theses and Dissertations

Vernal pools are small seasonal wetlands that are a common landscape feature that contribute to biodiversity in northeastern North American forests. However, even basic information about their biogeochemical functions, such as carbon cycling, is limited. Dissolved gas concentrations (CH₄, CO₂) and other water chemistry parameters were monitored weekly at the bottom and surface of four vernal pools in central and eastern Maine, USA, from April to August 2016. The vernal pools were supersaturated with respect to CH₄ and CO₂ at all sampling dates and locations. Concentrations of dissolved CH₄ and CO₂ ranged …

Green Chemistry Oxidative Modification Of Peptoids Utilizing Bleach And Tempo, Jesse Leland Roberts

Graduate Theses and Dissertations

Biotherapeutic drugs, derived from biological molecules such as proteins and DNA, are becoming an integral and exceptionally critical aspect of modern medicine. Compared to common pharmaceutical drugs, biotherapeutics are much larger in size and have greater target specificity, allowing them to treat many chronic diseases ranging from cancer to rheumatoid arthritis. The major issue with protein based therapeutics is that they readily undergo proteolysis, or enzymatic degradation, when administered through subcutaneous injections. Traditionally, biotherapeutic modification procedures have centered on the use of PEG derivatives. This process, called PEGylation, is unfavorable due to the increases in molecular weights of the proteins …