Engineering Commons^™

Aliovalent Dopants In Zno Nanocrystals: Synthesis To Electronic Structure, Dongming Zhou

Doctoral Dissertations

Semiconductor nanocrystal doping has stimulated broad interest for many applications including solar energy conversion, nanospintronics, and phosphors or optical labels. The study of the chemistry and physics of doped colloidal semiconductor nanocrystals has been dominated in the literature by isovalent dopants such as Mn²⁺ and Co²⁺ ions in II-VI semiconductors, in which the dopant oxidation state is the same as the cation ions. Until recently, aliovalent dopants has received much attention due to the plasmonic properties. Aliovalent is when the oxidation states of the dopant in the lattice differs from the cation ions. In the plasmonic semiconductor nanocrystals, …

Computational Studies Of Structure–Function Relationships Of Supported And Unsupported Metal Nanoclusters, Hongbo Shi

Doctoral Dissertations

Fuel cells have been demonstrated to be promising power generation devices to address the current global energy and environmental challenges. One of the many barriers to commercialization is the cost of precious catalysts needed to achieve sufficient power output. Platinum-based materials play an important role as electrocatalysts in energy conversion technologies. In order to improve catalytic efficiency and facilitate rational design and development of new catalysts, structure–function relationships that underpin catalytic activity must be understood at a fundamental level. First, we present a systematic analysis of CO adsorption on Pt nanoclusters in the 0.2-1.5 nm size range with the aim …

Analyses Of Densely Crosslinked Phenolic Systems Using Low Field Nmr, Jigneshkumar Patel

Doctoral Dissertations

A uniform dispersion of reactants is necessary to achieve a complete reaction involving multi-components, especially for the crosslinking of rigid high-performance materials. In these reactions, miscibility is crucial for curing efficiency. This miscibility is typically enhanced by adding a third component, a plasticizer. For the reaction of the highly crystalline crosslinking agent hexamethylenetetramine (HMTA) with a strongly hydrogen-bonded phenol formaldehyde resin, furfural has been traditionally used as the plasticizer. However, the reason for its effectiveness is not clear. In this doctoral thesis work, miscibility and crosslinking efficiency of plasticizers in phenolic curing reactions are studied by thermal analysis and spectroscopic …

Protein-Nanoparticle Co-Engineering: Self-Assembly, Intracellular Protein Delivery, And Crispr/Cas9-Based Gene Editing, Rubul Mout

Doctoral Dissertations

Direct cytoplasmic delivery of gene editing nucleases such CRISPR/Cas9 systems and therapeutic proteins provides enormous opportunities in curing human genetic diseases, and assist research in basic cell biology. One approach to attain such a goal is through engineering nanotechnological tools to mimic naturally existing intra- and extracellular protein delivery/transport systems. Nature builds transport systems for proteins and other biomolecules through evolution-derived sophisticated molecular engineering. Inspired by such natural assemblies, I employed molecular engineering approaches to fabricate self-assembled nanostructures to use as intracellular protein delivery tools. Briefly, proteins and gold nanoparticles were co-engineered to carry complementary electrostatic recognition elements. When these …

Adaft: A Resource-Efficient Framework For Adaptive Fault-Tolerance In Cyber-Physical Systems, Ye Xu

Doctoral Dissertations

Cyber-physical systems frequently have to use massive redundancy to meet application requirements for high reliability. While such redundancy is required, it can be activated adaptively, based on the current state of the controlled plant. Most of the time the physical plant is in a state that allows for a lower level of fault-tolerance. Avoiding the continuous deployment of massive fault-tolerance will greatly reduce the workload of CPSs. In this dissertation, we demonstrate a software simulation framework (AdaFT) that can automatically generate the sub-spaces within which our adaptive fault-tolerance can be applied. We also show the theoretical benefits of AdaFT, and …

Polyorganosiloxanes: Molecular Nanoparticles, Nanocomposites And Interfaces, Daniel H. Flagg

Doctoral Dissertations

Five research projects described. First, a reproducible, lab-scale synthesis of MQ silicone copolymers is presented. MQ copolymers are commercially important materials that have been ignored by the academic community. One possible reason for this is the difficulty of controlling and reproducing the preparative copolymerizations that have been reported. A reproducible method for lab-scale preparation was developed that controls molecular weight by splitting the copolymerization into the discrete steps of sol growth from silicate precursor and end-capping by trimethylsiloxy groups. Characterization of MQ products implicates that they are composed of highly condensed, polycyclic structures. The MQ copolymers prepared in the first …

Non-Equispaced Fast Fourier Transforms In Turbulence Simulation, Aditya M. Kulkarni

Masters Theses

Fourier pseudo-spectral method on equispaced grid is one of the approaches in turbulence simulation, to compute derivative of discrete data, using fast Fourier Transform (FFT) and gives low dispersion and dissipation errors. In many turbulent flows the dynamically important scales of motion are concentrated in certain regions which requires a coarser grid for higher accuracy. A coarser grid in other regions minimizes the memory requirement. This requires the use of Non-equispaced Fast Fourier Transform (NFFT) to compute the Fourier transform, by solving a system of linear equations.

To achieve similar accuracy, the NFFT needs to return more Fourier coefficients than …

Belief-Space Planning For Resourceful Manipulation And Mobility, Dirk Ruiken

Doctoral Dissertations

Robots are increasingly expected to work in partially observable and unstructured environments. They need to select actions that exploit perceptual and motor resourcefulness to manage uncertainty based on the demands of the task and environment. The research in this dissertation makes two primary contributions. First, it develops a new concept in resourceful robot platforms called the UMass uBot and introduces the sixth and seventh in the uBot series. uBot-6 introduces multiple postural configurations that enable different modes of mobility and manipulation to meet the needs of a wide variety of tasks and environmental constraints. uBot-7 extends this with the use …

Characterization Of Electronic And Ionic Transport In Soft And Hard Functional Materials, Lawrence A. Renna

Doctoral Dissertations

Control over concurrent transport of multiple carrier types is desired in both soft and hard materials. For both types of materials, I demonstrate ways to characterize and execute governance over both electronic and ionic transport, and apply these concepts in the fabrication of devices with applications in conducting composites, photovoltaics, electrochemical energy storage, and memristors. In soft materials, such as polymers, the topology of the binary polymer mesoscale morphology has major implications on the charge/ion transport. Traditional approaches to co-continuous structures involve either using blends of polymers or diblock copolymers. In polymer blends, the structures are kinetically trapped and …

Modeling The Economic And Environmental Performance Of Offshore Wind Energy, Alexana Cranmer

Doctoral Dissertations

Offshore wind is a growing source of energy globally. Like any energy technology, it has impacts on the environment. In the case of renewable energy, we need a way to consider the environmental benefits as well as the environmental costs. This dissertation develops a set of models to examine the economic and environmental costs and benefits and the trade-offs between them. We ask how much offshore wind energy should be sited, and where should that offshore wind energy be located? The first model estimates the economic impact of wake interactions between wind farms. Wind farm sites are chosen through a …

Vitreous Gel Physics, Svetlana Morozova

Doctoral Dissertations

The transparent vitreous, which fills the posterior cavity of the eye, is incredibly engineered. The charged polyelectrolyte hyaluronic acid (HA) network swells to maintain the pressure in the eye, while stiff collagen type II bundles help absorb any external mechanical shock. Our investigations have contributed to a few key developments related to the physical properties of the vitreous: (1) The stiff collagen network that supports the soft gel network is self-assembled from single triple-helix collagen proteins. Electrostatic interactions drive this assembly, such that the size and concentration are optimized at physiological salt concentrations. The width of the assemblies remarkably changes …

Explorations Into Machine Learning Techniques For Precipitation Nowcasting, Aditya Nagarajan

Masters Theses

Recent advances in cloud-based big-data technologies now makes data driven solutions feasible for increasing numbers of scientific computing applications. One such data driven solution approach is machine learning where patterns in large data sets are brought to the surface by finding complex mathematical relationships within the data. Nowcasting or short-term prediction of rainfall in a given region is an important problem in meteorology. In this thesis we explore the nowcasting problem through a data driven approach by formulating it as a machine learning problem.

State-of-the-art nowcasting systems today are based on numerical models which describe the physical processes leading to …

Achieving Perfect Location Privacy In Wireless Devices Using Anonymization, Zarrin Montazeri

Masters Theses

The popularity of mobile devices and location-based services (LBS) have created great concerns regarding the location privacy of the users of such devices and services. Anonymization is a common technique that is often being used to protect the location privacy of LBS users. This technique assigns a random pseudonym to each user and these pseudonyms can change over time. Here, we provide a general information theoretic definition for perfect location privacy and prove that perfect location privacy is achievable for mobile devices when using the anonymization technique appropriately. First, we assume that the user’s current location is independent from her …

Time Domain Sar Processing With Gpus For Airborne Platforms, Dustin Lagoy

Masters Theses

A time-domain backprojection processor for airborne synthetic aperture radar (SAR) has been developed at the University of Massachusetts’ Microwave Remote Sensing Lab (MIRSL). The aim of this work is to produce a SAR processor capable of addressing the motion compensation issues faced by frequency-domain processing algorithms, in order to create well focused SAR imagery suitable for interferometry. The time-domain backprojection algorithm inherently compensates for non-linear platform motion, dependent on the availability of accurate measurements of the motion. The implementation must manage the relatively high computational burden of the backprojection algorithm, which is done using modern graphics processing units (GPUs), programmed …

Thiol-Ene Chemistry As An Enabler Of New Polymer Structures And Architectures, Joel M. Sarapas

Doctoral Dissertations

This dissertation focuses on two distinct projects: the synthesis and design of novel cell penetrating peptides mimics (CPPMs), and the implementation of the thiol-ene click reaction to generate new polymer architectures and chemistries. Guanidinium-rich CPPMs were generated through both ROMP and RAFT polymerizations, allowing for a comparison to be made across polymer backbone chemistries with respect to both siRNA and protein cellular internalization. A particularly effective methacrylate derived block copolymer was able to deliver siRNA to nearly an entire Jurkat T cell population. The thiol-ene reaction was implemented initially within the context of improving material design for solid polymer electrolytes …

Inference In Networking Systems With Designed Measurements, Chang Liu

Doctoral Dissertations

Networking systems consist of network infrastructures and the end-hosts have been essential in supporting our daily communication, delivering huge amount of content and large number of services, and providing large scale distributed computing. To monitor and optimize the performance of such networking systems, or to provide flexible functionalities for the applications running on top of them, it is important to know the internal metrics of the networking systems such as link loss rates or path delays. The internal metrics are often not directly available due to the scale and complexity of the networking systems. This motivates the techniques of inference …

Particles Confined By Fluid Interfaces: Imaging Particle Motion, Interface Deformation And Capillary Forces, Paul Y. Kim

Doctoral Dissertations

Small solid particles, confined in two-dimensions by fluid interfaces, were studied by a variety of experimental methods to understand particle motion, menisci shapes near interface-supported particles, and capillary interactions among such particles. Unwanted evaporation was circumvented by adopting non-volatile ionic liquids to create the fluid interfaces. A related application, employment of ionic liquids to float cryo-microtomed polymer sections, was also developed. The Brownian motions of nanospheres and nanorods in free-standing ionic liquid films were visualized in situ by high resolution scanning electron microscopy, which images features almost 100× smaller than possible in an optical microscope. For suspensions that are dilute …

Deformation And Adhesion Of Soft Composite Systems For Bio-Inspired Adhesives And Wrinkled Surface Fabrication, Michael Imburgia

Doctoral Dissertations

The study of soft material deformation and adhesion has broad applicability to industries ranging from automobile tires to medical prosthetics and implants. When a mechanical load is imposed on a soft material system, a variety of issues can arise, including non-linear deformations at interfaces between soft and rigid components. The work presented in this dissertation embraces the occurrence of these non-linear deformations, leading to the design of functional systems that incorporate a soft elastomer layer with application to bio-inspired adhesives and wrinkled surface fabrication. Understanding the deformation of a soft elastomer layer and how the system loading and geometry influence …

River And Stream Power Assessment Report Including Culvert And Bridge Vulnerability Analysis: Deerfield River Basin, Massachusetts And Vermont, James G. Macbroom, Roy Schiff, Jessica Louisos

Water Reports

This geomorphic assessment of Deerfield River in western Massachusetts and southern Vermont has been prepared by Milone & MacBroom, Inc. (MMI) on behalf of the University of Massachusetts as part of its "Farms, Floods, and FGM" project, funded by the United States Department of Agriculture – National Institute of Food and Agriculture National Integrated Water Quality Program(USDA – NIFA NIWQP) program. This project is a broad-based geomorphic assessment of the Deerfield River and its adjacent riparian corridor to define its characteristics, processes, and management issues. The river channel is used extensively for hydroelectric power generation and recreation, with agricultural …

Superhero Robotics, Frank Sup, Brian Umberger, Nick Sawyer

Science and Engineering Saturday Seminars

No abstract provided.