Energy Systems Commons^™

Lithium Molybdate-Sulfur Battery., Ruchira Ravinath Dharmasena

Electronic Theses and Dissertations

Rechargeable energy storage systems play a vital role in today’s automobile industry with the emergence of electric vehicles (EVs). In order to meet the targets set by the department of energy (DOE), there is an immediate need of new battery chemistries with higher energy density than the current Li- ion technology. Lithium–sulfur (Li–S) batteries have attracted enormous attention in the energy-storage, due to their high specific energy density of 2600 Wh kg^-1 and operational voltage of 2.0 V. Despite the promising electrochemical characteristics, Li-S batteries suffer from serious technical challenges such as dissolution of polysulfides Li₂S_{x …}

The Design Of An Innovative Automotive Suspension For Formula Sae Racing Applications, Jared Darius

Senior Honors Theses

This thesis details an analytical approach to an innovative suspension system design for implementation to the Formula SAE collegiate competition. It focuses specifically on design relating to geometry, mathematical modeling, energy element relationships, and computer analysis and simulation to visualize system behavior. The bond graph approach is utilized for a quarter car model to facilitate understanding of the analytical process, then applied to a comparative analysis between two transverse half car models. The second half car model contains an additional transverse linkage with a third damper, and is compared against the baseline of the first half car model without the …

Effect Of Biomass Inlet Concentration On Mixing In A Double Screw Pyrolyzer, Breanna L. Marmur, Theodore J. Heindel

Breanna L. Marmur

The renewable energy industry relies on double screw pyrolyzers to convert cellulosic biomass into bio-oil. Bio-oil can then be converted into synthetic gasoline, diesel, and other transportation fuels, or can be converted into biobased chemicals for a wide range of applications. One of the processes by which bio-oil is produced in industry today is through fast pyrolysis, the fast thermal decomposition of organic material in the absence of oxygen. One type of pyrolyzer, a double screw pyrolyzer, features two intermeshing screws encased in a reactor which mechanically conveys and mixes the biomass and heat carrier media. The mixing effectiveness of …

Performance Analysis Of An Exhaust Heat Recovery System Utilizing Heat Pipes, Metal Foam, And Thermoelectric Generators, Michael Resciniti

Scholar Week 2016 - present

This paper highlights a new type of modified heat pipe assisted thermoelectric generator system for automobile exhaust waste heat recovery. This system employs the use of metal foam as a heat transfer aid to increase the thermal energy transferred through the system. In this system, heat pipes are inserted into a metal foam block that is exposed to the exhaust gas stream. The metal foam increases heat transfer in a similar way that fins increase heat transfer. To confirm that this system provides a greater conversion of thermal energy, an experimental prototype was built and tested. Tests were conducted with …

Nanosheets Of Cuco₂O₄ As A High-Performance Electrocatalyst In Urea Oxidation, Camila Zequine, Ram K. Gupta, Pawan K. Kahol

Posters

The urea oxidation reaction (UOR) is a possible solution to solve the world’s energy crisis. Fuel cells have been used in the UOR to generate hydrogen with a lower potential compared to water splitting, decreasing the costs of energy production. Urea is abundantly present in agricultural waste and in industrial and human wastewater. Besides generating hydrogen, this reaction provides a pathway to eliminate urea, which is a hazard in the environment and to people’s health. In this study, nanosheets of CuCo₂O₄ grown on nickel foam were synthesized as an electrocatalyst for urea oxidation to generate hydrogen as a green fuel. …

Metal-Doped Catalysts For Hydrogen Evolution Reaction, Tucker Morey, Ram K. Gupta, Pawan K. Kahol

Posters

The highly efficient electrochemical hydrogen evolution reaction (HER) provides a promising way to solve energy and environment problems. In this work, various transition metals (Fe, Co, Ni, Cu, Ag, and Pt) were selected to support on molybdenum carbides by a simple organic-inorganic precursor carburization process. X-ray diffraction (XRD) analysis results indicated that the ß-MO₂C phase was formed in all metal-doped samples. X-ray photo­electron spectroscopy analysis indicated that the binding energy of MO₂+ species (MO₂C) shifted to a lower value after metal was doped on the molybdenum carbide surface. Comparing with pure ß-MO₂C, the elec­trocatalytic activity for HER was improved by …

Almond Based Electrocatalyst For Fuel Cell Applications, Kinsey Morey, Tucker Morey, Brooks Neria, Khamis Siam, Pawan K. Kahol

Posters

Hydrogen is considered one of the cleanest energy sources. Water spitting is one of the efficient ways to produce hydrogen as a fuel at the industrial level. Water splitting via electrolysis requires an efficient electrocatalyst to reduce the voltage required for water splitting. Currently, precious metals such as platinum are considered as one of the most efficient electrocatalysts for hydrogen production via electrolysis of water. The current challenge is to find a cost-effective alternative for this process. Molybdenum and carbon are low cost and abundant mate­rials which could be used for the synthesis of cost-effective electrocatalysts for hydrogen production. In …

Electrocatalytic Properties Of Lanthanum-Based Perovskites For Water Splitting And Energy Storage Applications, Xavier R. Martinez, Khamis Siam, Pawan K. Kahol, Ram K. Gupta

Posters

Recent changes in global weather patterns have punctuated the need for mollification through a cleaner energy option. As part of the plan, hydrogen production for fuel cells offers substantial power without carbon emissions. Overall water splitting, with the aid of a low cost electrocatalyst could prove to be an abundant green fuel source. Utilizing readily available transition metals, three perovskite nanostructures were studied as a multifunctional material for hydrogen production as well as energy storage. LaCoO₃ (LCO), LaFeO₃ (LFO), and LaMnO₃ (LMO) were synthesized and characterized by X-ray diffraction and then dip coated onto nickel foam as electrodes in a …

Molybdenum Oxides For Energy Generation And Storage Using Efficient Clean Method, Camila Zequine, Pawan K. Kahol, Ram K. Gupta

Posters

To solve the growing energy issues, significant efforts have been focused on the search of earth-abundant ele­ments that can provide multifunctional behavior for both energy generation and storage. Due to the low-cost and rich chemical nature, transition metal oxide nanostructures have been used in the fabrication of energy devices, such as fuel cells and lithium batteries. In this work, nickel, cobalt and iron molybdates were synthesized via a simple hydrothermal method in order to fabricate electrodes for oxygen evolution reaction (OER) and a superca­pacitor. FeMoO₄ required an overpotential of 294 mV to achieve a current density of 10 mA/cm2 for …

Implementation Of Solar Car Technology, Greg Mccartney, Marcus Allen, Dedrick Cooper, Lelan Delissa, Eric Mayer

Posters

Under the leadership of Dr. Erik Mayer, Pittsburg State University hosted the first Kansas Solar Race Competition. The purpose of this competition is to motivate students to learn about different aspects of solar car technology. The competition motivates students by bringing multiple teams together in a friendly competition to test out their uniquely engineered and constructed wireless cars. The cars will compete in different competitions such as an agil­ity competition and a drag race. After the competition, the students are able to learn from the ingenuity of other teams and spark a curiosity to continue to learn about solar car …

Construction Of High-Performance 3d Nanostructured Flower-Like Iron-Nickel Sulfide For Supercapacitor, Chen Zhao, Sanket Bhoyate, Chunyang Zhang, Ram K. Gupta, Pawan K. Kahol

Posters

The global energy crisis and environmental pollution have stimulated increasing attention to developing clean and renewable alternative energy sources. One of the most efficient and greenest energy storage devices is supercapacitor which could store energy via electrical double layer and redox reactions. Supercapacitors are widely employed for many portable electronics and hybrid electric vehicles due to their high-power density, fast charge-discharge rate, and good cycle stability. In this work, 3D nanostructured flower-like iron-nickel sulfide was synthesized on the nickel foam using a facile hydrothermal method. The iron-nickel sulfide electrode showed out­standing performance for supercapacitor with a high areal capacitance of …

Design & Evaluation Of Cooling Systems For Photovoltaic Modules, Peter Leary

Honors Theses

There is a persistent need for further development and implementation of renewable energy sources, such as wind and solar. Due to the increase in global population, the disappearance of fossil fuels, and the reality of climate change, renewable power is needed now more than ever. One such renewable power technology is solar photovoltaic, otherwise known as PV. These modules work via silicon cells which are as semiconductors, outputting electrical energy when incident with solar radiation. This is done by separating electrons and protons within the cell. One of the largest issues with PV technology is that there is a linear …

A Constructal Approach To The Design Of Inflected Airplane Wings, Shanae Powell

FIU Electronic Theses and Dissertations

Aeroelastic instabilities such as flutter can be accurately captured by state-of-the-art aeroelastic analysis methods and tools. However, these tools and methods fall short in exposing the reasons behind the occurrence of such instabilities. In this research, the constructal law is used to discover the main cause of the variation in the flutter speed and stress distribution for inflected aircraft wings when compared to its uninflected counterpart. This law considers the design as a physics phenomenon and uses an evolutionary flow principle to explain and predict the occurrence of energy flow configurations (i.e. the flow of stresses throughout the structure).

For …

Design Of A Portable Biogas Purification And Storage System, Anikumar Kosna, Bade Shrestha

Faculty Research and Creative Activities Award (FRACAA)

The objective of this study is to propose and design a commercial portable purification and storage system to commercialize biogas (which mainly consists of 45 - 75 % of methane and 15 - 16% of carbon dioxide), produced from household/non-commercial biogas plants. The selection of purification process is based on the portability of the purification system.

Thermodynamic And Economic Analysis Of Several Hybrid Multigeneration Cycles And Waste Heat Recovery Systems Driven By Concentrated Solar Tower, Kasra Mohammadi

Doctoral Dissertations

In recent decades, growth in the world population, economic and living standards have been responsible for substantial increases in global energy consumption. Moreover, exploitation of fossil fuels to supply energy demands has led to global climate change, which is expected to have far-reaching and long-lasting consequences on the planet. These factors have motivated the importance and necessity of developing more efficient ways for energy conservation and generation that avoid the production of greenhouse gases that contribute to climate change. One method to address these issues is to develop combined production such as multigeneration for simultaneous production of electricity, cooling, fresh …

Ammonia Production From A Non-Grid Connected Floating Offshore Wind-Farm: A System-Level Techno-Economic Review, Vismay V. Parmar

Masters Theses

According to U.S. Department of Energy, offshore wind energy has the potential to generate 7,200 TWh of energy annually, which is nearly twice the current annual energy consumption in the United States. With technical advances in the offshore wind industry, particularly in the floating platforms, windfarms are pushing further into the ocean. This creates new engineering challenges for transmission of energy from offshore site to onshore. One possible solution is to convert the energy produced into chemical energy of ammonia, which was investigated by Dr. Eric Morgan. In his doctoral dissertation, he assessed the technical requirements and economics of a …

Numerical Investigation Of Inclination On The Thermal Performance Of Porous Fin Heatsink Using Pseudospectral Collocation Method, George Oguntala, Gbeminiyi Sobamowo, Raed Abd-Alhameed, James Noras

Karbala International Journal of Modern Science

Numerical investigation of inclination effect on the thermal performance of a porous fin heat sink is presented. The developed thermal model is solved using pseudo-spectral collocation method (PSCM). Parametric studies are carried out using PSCM, and the thermal characterization of heat sink with the inclined porous fin of rectangular geometry is presented. Results show that heat sink of inclined porous fin exhibits higher thermal performance than heat sink of vertical porous fin operating under the same thermal conditions with the same geometrical configurations. Performance of inclined or tilted fin increases with decrease in length-thickness aspect ratio. However, increase in the …

Solar Thermoelectricity Via Advanced Latent Heat Storage, Michele L. Olsen, Eric S. Toberer, David S. Ginley, Philip A. Parilla, Emily L. Warren, Aaron D. Martinez, Jonathan E. Rea, Corey Lee Hardin, Christopher J. Oshman, Nathan P. Siegel

Other Faculty Research and Publications

An aspect of the present disclosure is a system that includes a thermal valve having a first position and a second position, a heat transfer fluid, and an energy converter where, when in the first position, the thermal valve prevents the transfer of heat from the heat transfer fluid to the energy converter, and when in the second position, the thermal valve allows the transfer of heat from the heat transfer fluid to the energy converter, such that at least a portion of the heat transferred is converted to electricity by the energy converter.

Fluorescence Of Cdse/Zns Quantum Dots In Toluene: Effect Of Cyclic Temperature, Ting Chen, Weiling Luan, Shaofu Zhang, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Quantum dots (QDs) are the potential material for the application in optical thermometry, and have been successfully applied to solar cells, LEDs, bio-labeling, structural health monitoring, etc. In this paper, we study the fluorescence properties of CdSe/ZnS QDs in toluene under the action of heating-cooling cycles. The experimental results show that, in a heating-cooling cycle, increasing temperature causes red-shift of the emission peak and the decrease of the PL intensity, and decreasing temperature causes blue-shift of the emission peak and the increase of the PL intensity. The surface structures of the QDs likely are dependent on the cycle numbers, which …

Evaluating Moisture Control Of Variable-Capacity Heat Pumps In Mechanically Ventilated, Low-Load Homes In Climate Zone 2a, Florida Solar Energy Center, Eric Martin

FSEC Energy Research Center®

The well-sealed, highly insulated building enclosures constructed by today's home building industry coupled with efficient lighting and appliances are achieving significantly reduced heating and cooling loads. These low-load homes can present a challenge when selecting appropriate space-conditioning equipment. Conventional, fixed-capacity heating and cooling equipment is often oversized for small homes, causing increased first costs and operating costs. Even if fixed-capacity equipment can be properly specified for peak loads, it remains oversized for use during much of the year. During these part-load cooling hours, oversized equipment meets the target dry-bulb temperatures very quickly, often without sufficient opportunity for moisture control. The …