Materials Science and Engineering Commons^™

Section Abstracts: Astronomy, Mathematics, And Physics With Materials Science

Virginia Journal of Science

Abstracts of the Astronomy, Mathematics, and Physics with Materials Science Section for the 92nd Annual Meeting of the Virginia Academy of Science, May 13-15, 2014, Virginia Commonwealth University, Richmond, Virginia

Nanomaterials Synthesis By A Novel Phenomenon: The Nanoscale Rayleigh-Taylor Instability, S. Yadavali, Ramki Kalyanaraman

Faculty Publications and Other Works -- Materials Science & Engineering

The Rayleigh-Taylor (RT) interfacial instability has been attributed to physical phenomenon in a wide variety of macroscopic systems, including black holes, laser generated plasmas, and thick fluids. However, evidence for its existence in the nanoscale is lacking. Here we first show theoretically that this instability can occur in films with thickness negligible compared to the capillary length when they are heated rapidly inside a bulk fluid. Pressure gradients developed in the evaporated fluid region produce large forces causing the instability. Experiments were performed by melting Au films inside glycerol fluid by nanosecond laser pulses. The ensuingnanoparticles had highly monomodal size …

Dynamic Characteristic Identification Of Seismic-Excited Multi-Story Buildings Through Response-Only Technique, Agung Budipriyanto, Priyo Suprobo

Makara Journal of Technology

Identifying dynamic characteristics of civil engineering structures is still a challenging task. It intends to assess behavior of the structures under time-dependent loads. This paper discusses a methodology suitable for identifying the characteristics of multi-story buildings using only their measured response under earthquake ground excitations. Appropriateness of technique used for structural identification was corroborated through coherence of the structure’s responses. The methodology was applied for identifying the characteristics of 14-story and 20-story office buildings located in a high seismic region. Responses of these two buildings recorded during three different seismic ground motions were investigated. The buildings’ response spectral densities and …

Oxidation Kinetics Of Nicrofer-6025ht For Use In Elevated Temperature Electrochemical Devices, Tyler Cook, Alan Meier, Ph.D.

TECHxpo

Recent advances in high temperature electrochemical devices have prompted research into potential materials for component fabrication.

Design Of A Uv Curing Cartridge For 3d Inkjet Printing, Richard Wiswell

Thinking Matters Symposium Archive

In printing multi-layer electronic circuits, each layer must be formed as a continuous pattern in high resolution from ink jetted liquid droplets and be in precise alignment with the other layers, precluding substrate removal for UV curing. This research seeks to determine the optimal method for in-situ UV curing of the ink jetted material in a single pass. The inkjet replacement cartridge designed for this purpose was constructed of aluminum, fit into the printer head assembly in good alignment with the other ink cartridges, and contained a UV LED for in-situ curing and a cooling fan to maintain safe operating …

Processing And Characterization Of Zr-Based Metallic Glass By Laser Direct Depositon, Heehun Bae

Open Access Theses

Bulk Metallic Glass has become famous for its exceptional mechanical and corrosion properties. Especially, Zirconium has been the prominent constituent in Bulk Metallic Glass due to its superior glass forming ability, the ability to form amorphous phase with low cooling rate, thereby giving advantages in structural applications.

In this study, Zirconium powder was alloyed with Aluminum, Nickel and Copper powder at an atomic ratio of 65:10:10:15, respectively. Using the ball milling process to mix the powders, Zr65 Al10 Ni 10 Cu15 amorphous structure was manufactured by laser direct deposition.

Laser power and laser scanning speed were optimized to increase the …

Shear Rheological Characterization Of Gel Healing Response And Construction Of Rheo-Piv System, Abhishek Deepak Bawiskar

Open Access Theses

Thermo-reversible gels are solvent-filled 3D networks of polymer chains interconnected by physical (transient) crosslinks. On applying a high shear stress, the crosslinks are broken and these gels show a typical stress-strain behavior due to cohesive fracture of the gel. When heated above a critical temperature and cooled back to room temperature, all the crosslinks are re-formed. Interestingly, partial to full recovery of broken crosslinks is also observed by simply letting the gel stand at room temperature. In this study, the fracture and healing behavior of a model acrylic triblock copolymer gel has been characterized by shear rheometry. A mathematical model …

Detailed Finite Element Analysis And Preliminary Study Of The Effects Of Friction And Fastener Pre-Tension On The Mechanical Behavior Of Fastened Built-Up Members, Francisco Javier Bonachera Martin

Open Access Theses

The characterization of fatigue resistance is one of the main concerns in structural engineering, a concern that is particularly important in the evaluation of existing bridge members designed or erected before the development of fatigue design provisions. The ability of a structural member to develop alternate load paths after the failure of a component is known as member-level or internal redundancy. In fastened built-up members, these alternate load paths are affected by the combination of fastener pre-tension and friction between the structural member components in contact. In this study, a finite element methodology to model and analyze riveted and bolted …

Blast Energy Mitigation In Porous Rocks, Brittany Corinne Essink

Open Access Theses

Geo-materials are commonly used and sought after for blast mitigation applications due to their wide availability and low cost compared to industry trademarked materials. Characterization of these natural geo-materials such as volcanic rocks is of paramount importance in determining their blast mitigation capabilities. While there is a large amount of information available for materials such as concrete or sand blasts, information on the properties of volcanic rocks is far more scarce. This lack of data is due to the wide range of existing natural volcanic rocks and the variation in the minerals and pore structures of the rocks.

In this …

Cztsse Thin Film Solar Cells : Surface Treatments, Chinmay S. Joglekar

Open Access Theses

Chalcopyrite semiconducting materials, specifically CZTS, are a promising alternative to traditional silicon solar cell technology. Because of the high absorption coefficient; films of the order of 1 micrometer thickness are sufficient for the fabrication of solar cells. Liquid based synthesis methods are advantageous because they are easily scalable using the roll to roll manufacturing techniques.

Various treatments are explored in this study to enhance the performance of the selenized CZTS film based solar cells. Thiourea can be used as a sulfur source and can be used to tune band gap of CZTSSe. Bromine etching can be used to manipulate the …

Effect Of Multivalent Ions On The Swelling And Mechanical Behavior Of Superabsorbent Polymers (Saps) For Mitigation Of Mortar Autogenous Shrinkage, Qian Zhu

Open Access Theses

The chemical and physical structure-property relationships of model superabsorbent polymer (SAP) hydrogels were characterized with respect to swelling behavior and mechanical properties in different ionic solutions (Na+ , Ca2+ , and Al3+ ). The model hydrogels were composed of poly(sodium acrylate-acrylamide) (PANa-PAM) copolymer with varying concentrations of PANa (0, 17, 33, 67, and 83 wt.%) and covalent crosslinking densities of 1, 1.5, and 2 wt.%. By synthesizing the hydrogels in-house, systems with independently tunable amounts of covalent crosslinking and anionic functional groups were created, allowing for the relative effects of covalent and ionic crosslinking on the properties of the hydrogels …

Examining The Freezing And Thawing Behavior Of Concretes With Improved Performance Through Internal Curing And Other Methods, Wesley A. Jones

Open Access Theses

Internally cured (IC) concrete has been emerging over the last decade as an effective way to improve the performance of concrete. IC holds promise for producing concretes with an increased resistance to early-age cracking and ultimately enhancing the durability of structures. It is a simple and effective way to ensure proper hydration of cementitious material in high performance concrete mixtures; mixtures in which traditional, external, curing can be ineffective. IC supplies water that is necessary to relieve stress buildup from chemical shrinkage and in turn helping to prevent early age shrinkage cracking.^ The first part of this thesis presents and …

Bioethanol Production From Iles-Iles And Sorghum Starch As Raw Materials (Effect Of Cacl 2 Addition And Saccharification Time), Kusmiyati Kusmiyati, Ali Mahmudi

Makara Journal of Technology

Bioethanol produced from agricultural sources is one alternative energy that has been developed to substitute for petroleum. However, the use of food sources such as corn and cassava to produce bioethanol still face obstacles that lead to the scarcity of food and an increase in food prices. The aim of this study was to produce bioethanol from sorghum and iles-iles, which are not used by humans as food, especially in Indonesia. For both materials, the variables studied were saccharification time (4, 8, 24, and 48 h) and concentration of CaCl2 added to the liquefaction slurry (0, 100, 200, 300, and …

Microstructural Indicators Of Transition Mechanisms In Time-Dependent Fatigue Crack Growth In Nickel Base Superalloys, Ann Elizabeth Heeter

Open Access Theses

Gas turbine engines are an important part of power generation in modern society, especially in the field of aerospace. Aerospace engines are design to last approximately 30 years and the engine components must be designed to survive for the life of the engine or to be replaced at regular intervals to ensure consumer safety. Fatigue crack growth analysis is a vital component of design for an aerospace component. Crack growth modeling and design methods date back to an origin around 1950 with a high rate of accuracy. The new generation of aerospace engines is designed to be efficient as possible …

Synthesis And Characterization Of Soy-Based Polyurethane Foam With Utilization Of Ethylene Glycol In Polyol, Flora Elvistia Firdaus

Makara Journal of Technology

The use of vegetable oils on replacing petroleum has attracted attention of many researchers. The chemical structure of vegetable oils are different from petrochemicals, so the structure of soybean oil has to be chemically modified through its unsaturated fatty acid chain in triglyceride. A two step process was conducted for the preparation of soy-polyol in designated temperatures; 50 °C, 60 °C, and 70 °C. Ethylene glycol (EG) as co-reagent was taking part in soy-polyol synthesis, and the soy-polyol was used as a sole polyol for polyurethane synthesis. Referred to the previous study, the existence of EG in polyurethane synthesis can …

Performances Of Free-Space Optical Communication System Over Strong Turbulence, Ucuk Darusalam, Purnomo Sidi Priambodo, Harry Sudibyo, Eko Tjipto Rahardjo

Makara Journal of Technology

We report an experimental of free-space optical communication (FSOC) system that use tube propagation simulator (TPS) as the turbulence medium. The FSOC system use wavelength of 1550 nm at the rate transmission of 1000 Mbps and amplified with EDFA at the output of +23 dBm. Index structure of 10-15–10-13 as the representation of atmosphere index turbulences are used for simulation of intensity distribution model or scintillation. The simulation use gammagamma and K model as well. The beam wave propagation models used in simulation are plane wave, spherical wave and Gaussian wave. Spherical wave achieves highest performance via gamma-gamma in strong …

Performance Evaluation Of An Optimized Floating Breakwater In Oblique Waves With A Higher-Order Boundary Element Method, Faisal Mahmuddin, Masashi Kashiwagi

Makara Journal of Technology

In the previous study, the optimal performance of a two-dimensional (2D) floating breakwater shape was obtained. The performance of this shape was also confirmed with a model experiment in a towing tank. Moreover, the shape’s performance in three dimensions (3D) was investigated in a subsequent study. However, to predict the shape’s performance in a real application more accurately, the shape’s characteristics in oblique waves must also be evaluated. In this study, the performance and characteristics of the model (hydrodynamic forces, body motions, wave elevations, and drift forces) are computed using a higher-order boundary element method (HOBEM). The HOBEM, which is …

High Pressure And Low Temperature Study Of Ammonia Borane And Lithium Amidoborane, Shah Najiba

FIU Electronic Theses and Dissertations

Hydrogen has been considered as a potentially efficient and environmentally friendly alternative energy solution. However, one of the most important scientific and technical challenges that the “hydrogen economy” faces is the development of safe and economically viable on-board hydrogen storage for fuel cell applications, especially to the transportation sector. Ammonia borane (BH₃NH₃), a solid state hydrogen storage material, possesses exceptionally high hydrogen content (19.6 wt%).However, a fairly high temperature is required to release all the hydrogen atoms, along with the emission of toxic borazine. Recently research interests are focusing on the improvement of H₂ discharge …

Influence Of Chemical Composition And Water On The Bulk Modulus Of Pyrope, Shu Huang

FIU Electronic Theses and Dissertations

Garnets are major silicates from the upper mantle to the transition zone. Elastic properties of garnets are essential to interpret the variation of seismic velocities at different depths and construct a model of the Earth’s composition. Due to the chemical flexibility at octahedron sites of the crystal structures, garnets usually exist with multiple components and have many composition variations. Pyrope is an important member in the garnet group. Fe²⁺-Mg²⁺ substitution in pyrope is one of the common solid solutions. We have synthesized and measured three synthetic solid solutions samples (Py₈₃Alm₁₇, Py₅₄Alm …

Co2 Recycling Using Microalgae For The Production Of Fuels, Michael H. Wilson, John Groppo, Andrew Placido, S. Graham, S. A. Morton Iii, Eduardo Santillan-Jimenez, Aubrey Shea, Mark Crocker, Czarena Crofcheck, Rodney Andrews

Center for Applied Energy Research Faculty and Staff Publications

CO₂ capture and recycle using microalgae was demonstrated at a coal-fired power plant (Duke Energy’s East Bend Station, Kentucky). Using an in-house designed closed loop, vertical tube photobioreactor, Scenedesmus acutus was cultured using flue gas as the CO₂ source. Algae productivity of 39 g/(m² day) in June–July was achieved at significant scale (18,000 L), while average daily productivity slightly in excess of 10 g/(m² day) was demonstrated in the month of December. A protocol for low-cost algae harvesting and dewatering was developed, and the conversion of algal lipids—extracted from the harvested biomass—to diesel-range hydrocarbons via catalytic …