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Articles 1 - 30 of 33132
Full-Text Articles in Chemistry
Purification Of Protoporphyrin Ix Using The Fplc, Ken Overway, Laura Narby
Purification Of Protoporphyrin Ix Using The Fplc, Ken Overway, Laura Narby
Honors Projects
Protoporphyrin IX (PPIX) is the main pigment in brown eggshells, and it is embedded in the shell gland of hens during the final stages of the egg-making process. This natural dye can be used as a substitute for organic sensitizers in dye-sensitized solar cells (DSSCs). One benefit of PPIX is that it is a natural resource and has a high absorption coefficient in the visible and near-infrared region (NIR). Purified PPIX is extremely helpful in dye-sensitized solar cells because it improves electron injection efficiency, can be chemically modified to improve its absorption efficiency, and can be mixed with nanomaterials such …
Reduced Mediators Released By Cyanobacteria During Exoelectrogenesis Detected Using Differential Pulse Voltammetry, Laura T. Wey, Monica Brachi, Yagut Allahverdiyeva, Shelley D. Minteer
Reduced Mediators Released By Cyanobacteria During Exoelectrogenesis Detected Using Differential Pulse Voltammetry, Laura T. Wey, Monica Brachi, Yagut Allahverdiyeva, Shelley D. Minteer
Chemistry Faculty Research & Creative Works
Cyanobacteria generate electrical current through exoelectrogenesis (extracellular electron transfer) downstream of photosynthesis, yet the identity of the endogenous redox mediator(s) responsible remains unresolved. Here, we apply differential pulse voltammetry (DPV) to detect and characterise redox-active species released by Synechocystis sp. PCC 6803 under illumination. To enable sensitive detection, we developed an electrolyte intermediate between BG11 (Blue-Green-11) growth medium and MOPS (3-(N-morpholino)propanesulfonic acid) buffer that minimises background electrochemical interference while maintaining short-term cellular functionality. DPV revealed multiple light-enhanced oxidation peaks (0.1–0.65 V vs. saturated calomel electrode (SCE)) that were not resolvable using cyclic voltammetry, providing evidence that cyanobacteria release reduced compounds …
Computational Studies Of Triplet State Formation In Zinc Dipyrrin Complexes, Reuben Kwabla Adigbli
Computational Studies Of Triplet State Formation In Zinc Dipyrrin Complexes, Reuben Kwabla Adigbli
Electronic Theses and Dissertations
Zinc dipyrromethene complexes are promising earth-abundant photosensitizers due to their strong visible-light absorption and tunable excited states. To rationally design them for photocatalysis and photodynamic therapy, a molecular-level understanding of triplet-state formation is needed, but details of intersystem crossing remain unclear. To study the effect of π-extension, we synthesized an indole-substituted zinc dipyrrin complex: the dipyrromethane ligand was prepared from indole and mesitaldehyde, oxidized to the dipyrromethene, then coordinated with zinc. DFT and TD-DFT calculations determined ground and excited-state geometries and energies in different solvents, modeled absorption spectra, and visualized charge distributions. The results show how solvent polarity shifts energies …
Efficient Removal Of Methyl Orange Dye Via A Mnfe₂O₄/Go Nanocomposite With A Ctab Dual-Layer Surfactant Coating, Taher Karami, Soleiman Bahar, Reza Mostafazadeh
Efficient Removal Of Methyl Orange Dye Via A Mnfe₂O₄/Go Nanocomposite With A Ctab Dual-Layer Surfactant Coating, Taher Karami, Soleiman Bahar, Reza Mostafazadeh
Research outputs 2022 to 2026
This study investigated the adsorption of methyl orange (MO) from aqueous solutions using a novel MnFe₂O₄/GO nanocomposite coated with cetyltrimethylammonium bromide (CTAB). The dual-layer surfactant modification facilitates both electrostatic and lipophilic interactions. This enhancement significantly improves dye removal efficiency. The adsorption process was monitored using spectrophotometry at 464 nm, with various characterization techniques confirming the structural and magnetic properties of the nanocomposite. The optimized parameters for maximum adsorption include a 2-minute ultrasonic dispersion, pH 6.8, and a surfactant-to-adsorbent ratio of 1, achieving a maximum adsorption capacity of 285.7 mg/g. The kinetic data followed a pseudo-second-order model, whereas the adsorption isotherm …
Optimizing Multi-Layer/Multi-Physics Passive Adaptive Thermal Enclosures For Climate-Responsive Energy Regulation: A Numerical Study, Rajae Bousselham, Mingjiang Tao, Sergio Granados-Focil, Adriana Hera, Steven Van Dessel
Optimizing Multi-Layer/Multi-Physics Passive Adaptive Thermal Enclosures For Climate-Responsive Energy Regulation: A Numerical Study, Rajae Bousselham, Mingjiang Tao, Sergio Granados-Focil, Adriana Hera, Steven Van Dessel
Chemistry
Adaptive facades regulate heat transfer by adjusting their thermal behavior in response to environmental conditions. Passive adaptive systems, including stimuli-responsive thermal storage materials, tunable radiative coatings, and variable-conductivity layers, offer significant potential for material-based thermal regulation. However, their combined potential remains unexplored, as most studies examine individual mechanisms in isolation. As a result, trade-offs among energy savings, material usage, design complexity, and climate responsiveness are often underrepresented, overlooking coupled interactions in multilayer assemblies limiting their effectiveness. This study develops a transient three-dimensional numerical framework coupling heat transfer with multi-objective optimization to evaluate trade-offs between minimizing annual energy consumption and enclosure …
A Review Of Gallium And Germanium Recovery From Industrial Solid Residues, Ernest V. Oteng, Marthias Silwamba, Lana Alagha, Alex Luyima
A Review Of Gallium And Germanium Recovery From Industrial Solid Residues, Ernest V. Oteng, Marthias Silwamba, Lana Alagha, Alex Luyima
Mining Engineering Faculty Research & Creative Works
The global demand for critical elements such as gallium (Ga) and germanium (Ge), and the shift toward circular mining has accelerated the development of new extraction and recovery processing these metals from industrial solid residues. This transition is driven by a substantial surge in demand for advanced technologies and the depletion of primary ore. Consequently, industrial solid residues, particularly zinc processing residues, smelter slags, flue dusts, and coal fly ash, are emerging as viable alternative sources. These residues incorporate Ga and Ge through isomorphic substitution in phases such as ferrites, silicates, and glassy aluminosilicates, and are enriched by industrial processes, …
Microwave Spectrum And Iodine Nuclear Quadrupole Coupling Constants Of Difluorodiiodomethane, Cf2i2, Michael J. Carrillo, Michael J. Tubergen, Garry S. Grubbs, S. A. Cooke, Stewart E. Novick
Microwave Spectrum And Iodine Nuclear Quadrupole Coupling Constants Of Difluorodiiodomethane, Cf2i2, Michael J. Carrillo, Michael J. Tubergen, Garry S. Grubbs, S. A. Cooke, Stewart E. Novick
Chemistry Faculty Research & Creative Works
The high-resolution rotational spectrum of difluoro diiodomethane is reported for the first time. A molecular-beam broadband Fourier transform microwave spectrometer recorded the spectrum over the frequency range of 5.9–18.1 GHz. The rotational constants, centrifugal distortion constants, nuclear quadrupole coupling constants, and nuclear spin-rotation constants for the two equivalent iodine nuclei were determined from fitting 1378 hyperfine transitions of 163 rotational transitions: A = 2743.79691(18)MHz, B = 587.83103(5) MHz, C = 528.72470(5) MHz, χaa = −1213.287(6) MHz, χbb – χcc = −885.210(5) MHz, and χab = 1437.721(5) MHz. 31 dipole-forbidden/quadrupole-allowed transitions, arising from the large nuclear quadrupole coupling effect of iodine, …
Ph-Compensated Hydrogen Peroxide Quantification Using A Dual-Modal Fiber-Optic Probe, Homayoon Soleimani Dinani, Bohong Zhang, Maryam Karimi, Rex E. Gerald, Shelley D. Minteer, Jie Huang
Ph-Compensated Hydrogen Peroxide Quantification Using A Dual-Modal Fiber-Optic Probe, Homayoon Soleimani Dinani, Bohong Zhang, Maryam Karimi, Rex E. Gerald, Shelley D. Minteer, Jie Huang
Electrical and Computer Engineering Faculty Research & Creative Works
We report a dual-modal fiber-optic probe that integrates electrochemical quantification of hydrogen peroxide (H₂O₂) with co-localized fluorescent pH sensing for pH-indexed interpretation of the H₂O₂ response. H₂O₂ is a reactive oxygen species involved in oxidative stress, inflammation, and cellular signaling, and local pH modulates both its production and electrochemical response. Many electrochemical H₂O₂ sensors exhibit pH-dependent sensitivity, creating ambiguity unless pH is measured and used for compensation, which is difficult in small, heterogeneous, or rapidly changing microenvironments. A three-electrode configuration—working (WE), counter (CE), and Ag/AgCl pseudo-reference (pRE) electrodes—is fabricated directly on the cylindrical surface of a 710-µm-diameter optical fiber using …
A Calibrated And Conformal Deep Learning Framework For Trustworthy Antinuclear Antibody Pattern Recognition With Selective Referral To Experts, Hussein Ali Hussein Al Naffakh, Ahmed Dheyaa Radhi, Raghdah Maytham Hameed, Muntaha Abdullah Reishaan, Fouad A. Majeed, Rozaida Ghazali
A Calibrated And Conformal Deep Learning Framework For Trustworthy Antinuclear Antibody Pattern Recognition With Selective Referral To Experts, Hussein Ali Hussein Al Naffakh, Ahmed Dheyaa Radhi, Raghdah Maytham Hameed, Muntaha Abdullah Reishaan, Fouad A. Majeed, Rozaida Ghazali
Karbala International Journal of Modern Science
Reading antinuclear antibody patterns on human epithelial cells by indirect immunofluorescence is the reference screen for systemic autoimmune rheumatic diseases, but it is slow, subjective, and variable between observers. Deep learning reaches high accuracy on this task, yet most systems return a single prediction without stating how reliable it is, which is unsafe in a diagnostic workflow. This paper presents an intelligent decision support framework built around a single calibrated uncertainty signal. That signal is the control variable for four reliability modules: confidence calibration, conformal prediction, error detection, and selective referral. A feature space out of distribution detector serves as …
A Fundamental Study Of Fatty Acid Ionic Liquids And Their Effects On Biomolecules, Achismita Dutta
A Fundamental Study Of Fatty Acid Ionic Liquids And Their Effects On Biomolecules, Achismita Dutta
Theses and Dissertations
Fatty acid ionic liquids (FAILs) are a class of ionic liquids (ILs) with relatively low toxicity and potential applications in biological systems. This study examined the interactions of tetramethylguanidinium decanoate, tetramethylguanidinium octanoate, choline decanoate, and choline octanoate with lipid membranes, proteins, and nucleic acids. Membrane leakage experiments using model lipid vesicles showed that decanoate-based FAILs produced greater membrane permeabilization than octanoate-based analogues, consistent with their higher membrane permeability. These effects were stronger for the ILs than for decanoate alone and occurred below the critical micelle concentration (CMC), suggesting that micelle formation may not be essential for membrane disruption. The ability …
Gc-Ms Profiling And Antibacterial Activity Of Cold-Macerated Garlic Extracts Against Multidrug-Resistant Uropathogens, Fatima A. Khalaf, Saeed A. Fayadh
Gc-Ms Profiling And Antibacterial Activity Of Cold-Macerated Garlic Extracts Against Multidrug-Resistant Uropathogens, Fatima A. Khalaf, Saeed A. Fayadh
Karbala International Journal of Modern Science
The growing number of cases of multidrug-resistant (MDR) urinary tract infections has made the clinical management of urinary tract diseases a significant challenge; therefore, the need for effective adjunctive therapies cannot be overemphasized. This study evaluated the bioactive components and antibacterial efficacy of cold-macerated garlic extracts obtained using distilled water, 70% ethanol and hexane solvents against antimicrobial-resistant urinary isolates. Out of 250 urine samples that were analyzed, 124 (49.6%) showed significant microbial growth, with Escherichia coli being the most frequently isolated organism. The results of the phytochemical screening and Gas Chromatography-Mass Spectrometry (GC-MS) analysis showed that the ethanolic extract had …
A Guided Size Exclusion Chromatography Demonstration For Teaching Polymer Separation And Characterization, Daniel Rivero, Nicole Paccha, Amrita Sarkar
A Guided Size Exclusion Chromatography Demonstration For Teaching Polymer Separation And Characterization, Daniel Rivero, Nicole Paccha, Amrita Sarkar
Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works
Practical experience with modern analytical instruments is an essential component of undergraduate chemistry education, yet access to advanced instruments varies widely among institutions because of differences in available resources. Although size exclusion chromatography (SEC) is extensively used in polymer characterization in both academia and industry, undergraduate students at Montclair State University previously had limited opportunities to gain hands-on experience to this technique. To address this need, a demonstration using a multidetector-equipped Malvern Panalytical OMNISEC system was developed and incorporated into a second-year organic chemistry laboratory course during the 2025–2026 academic year. This activity engaged more than 300 undergraduate students representing …
Chemistry In The City Module, Ji Kim
Chemistry In The City Module, Ji Kim
Open Educational Resources
This project integrates a historical environmental health report from the CUNY Digital History Archive into an online Introductory Chemistry course to connect core chemical concepts with real urban pollution issues. Students analyze perchloroethylene contamination in apartments above dry cleaners, apply concepts such as volatility, vapor pressure, and concentration units, and reflect on chemical principles underlying indoor air pollution.
Chemistry In The City Module, Ji Kim
Chemistry In The City Module, Ji Kim
Open Educational Resources
This project integrates a historical environmental health report from the CUNY Digital History Archive into an online Introductory Chemistry course to connect core chemical concepts with real urban pollution issues. Students analyze perchloroethylene contamination in apartments above dry cleaners, apply concepts such as volatility, vapor pressure, and concentration units, and reflect on chemical principles underlying indoor air pollution.
Waste Streams From Next Generation Molten Salt Reactors: The Challenge Of Creating An Insoluble Ceramic For Chloride Salt Waste, Alevtina A. Maksimova, Jake W. Amoroso, Matthew Page, Gregory Morrison, Hans Conrad Zur Loye
Waste Streams From Next Generation Molten Salt Reactors: The Challenge Of Creating An Insoluble Ceramic For Chloride Salt Waste, Alevtina A. Maksimova, Jake W. Amoroso, Matthew Page, Gregory Morrison, Hans Conrad Zur Loye
Faculty Publications
Molten salt reactors (MSRs) design development is of interest to many research groups and companies. Waste management for MSRs is one of the most important issues that needs to be resolved due to its impact on environmental safety, primarily via the dissolution of radionuclides in water. Furthermore, the waste treatment strategy will have a significant influence on the operating cost of MSRs, which is why a reliable process for the immobilization, transportation, storage and disposal of MSR waste must be addressed. This work presents a new approach for the immobilization of chloride salts from molten salt reactors in stable oxyhalide …
Quantitative Analysis Of Blue 1 Dye In Commercial Sports Drinks By Uv -Vis Spectroscopy And Hplc-Dad, Mikayla Bush
Quantitative Analysis Of Blue 1 Dye In Commercial Sports Drinks By Uv -Vis Spectroscopy And Hplc-Dad, Mikayla Bush
Forensic Science Master's Projects
Food dyes are natural or synthetic substances added to foods, beverages, and cosmetics to enhance color and visual appeal. Although they provide no nutritional value, they are widely used to attract consumers, particularly children. Concerns have been raised about the potential health effects of synthetic dyes, including links to hyperactivity in children, tumor formation at high doses, and possible impacts on gut and brain function. In response, regulatory efforts are ongoing. In April 2025, the U.S. Department of Health and Human Services (HHS) and the Food and Drug Administration (FDA) announced an initiative to phase out petroleum-based food dyes, including …
Catalytic Synthesis Of Protoberberine Alkaloids And Their Evaluation As Selective Dopamine Receptor Ligands, Ashok Reddy Gudipally
Catalytic Synthesis Of Protoberberine Alkaloids And Their Evaluation As Selective Dopamine Receptor Ligands, Ashok Reddy Gudipally
Dissertations, Theses, and Capstone Projects
Dopamine regulates motor control, cognition, reward, motivation, and neuroendocrine signaling. Disruption of dopaminergic neurotransmission is closely linked to central nervous system disorders, including Parkinson’s disease, schizophrenia, addiction, and related neuropsychiatric conditions. Because these functions are mediated by multiple dopamine receptor subtypes with distinct roles in physiology and disease, the discovery of subtype-selective ligands remains an important goal in neuropharmacology. Within this context, protoberberine alkaloids, particularly tetrahydroprotoberberines (THPBs), are attractive molecular frameworks because they combine structural complexity with broad biological relevance, including measurable activity in CNS-related diseases. Prior work from our laboratory and others established (–)-stepholidine (1.60) as an important lead …
Development Of Ultrafast Protein Digestion And Standards Free Quantitation Methods For Mass Spectrometric Analysis, Praneeth Ivan Joel Fnu
Development Of Ultrafast Protein Digestion And Standards Free Quantitation Methods For Mass Spectrometric Analysis, Praneeth Ivan Joel Fnu
Dissertations
A wide variety of biologically important molecules, such as enzymes, antibodies, hormones, transporters and receptors are proteins by composition and they play key roles in biological functions such as cellular regulation, communication, metabolism and physiological function. Protein dysfunctions and abnormalities are associated with numerous diseases, making proteins critical targets for understanding disease mechanisms and developing therapeutic interventions. Protein-based therapeutics such as monoclonal antibodies, hormones and vaccines gained popularity due to their high specificity, efficacy, and ability to treat complex diseases that are often difficult to address with small-molecule drugs.
Given the important role of proteins in a variety of biological …
Synthesizing Viscoelasticity: Living Polymers, Micro-Macro Relations, And Paths For Resolution, Adam M. Hasler
Synthesizing Viscoelasticity: Living Polymers, Micro-Macro Relations, And Paths For Resolution, Adam M. Hasler
Graduate Masters Theses
This thesis investigates the relationship between macroscopic rheological signals and underlying microscopic dynamics in complex fluids, specifically focusing on ”living polymers” within the cetyltrimethylammonium bromide (CTAB) and sodium salicylate (NaSal) surfactant system. The research addresses the inverse parameterization problem, demonstrating how bulk measurements like zero-shear viscosity can mask fundamentally different physical topologies, such as purely cylindrical, reptating micelles versus highly branched networks. Through the successful synthesis of viscoelastically ”degenerate” samples, the study utilizes an array of characterization techniques including frequency sweeps, Large Amplitude Oscillatory Shear (LAOS) to resolve these unique underlying states. Furthermore, the work explores further avenues of study …
Electrolyte Development And Interfacial Reactions At Multivalent Metal Anode For Next Generation Energy Storage Systems, Leslie Gates
Electrolyte Development And Interfacial Reactions At Multivalent Metal Anode For Next Generation Energy Storage Systems, Leslie Gates
Graduate Masters Theses
The increasing demand for safe, sustainable, and high-performance energy storage systems has driven significant interest in multivalent-ion batteries, including aluminum, magnesium, and zinc-based systems. These technologies have attracted attention due to their high theoretical energy densities, natural abundance, low cost, and environmentally benign nature. However, their development remains hindered by a limited fundamental understanding of electrolyte development and interfacial processes at the electrode–electrolyte interface, where complex electrochemical interactions govern battery performance and stability.
This thesis investigates electrode–electrolyte interactions in both a novel aluminum electrolyte and divalent magnesium and zinc systems. Beginning with the development and characterization of a novel aluminum …
Multicomponent Reaction-Initiated Synthesis Of Polyheterocyclic Compounds, Ashutosh Nath
Multicomponent Reaction-Initiated Synthesis Of Polyheterocyclic Compounds, Ashutosh Nath
Graduate Doctoral Dissertations
Efficient synthesis of novel heterocycles with biological interest remains a challenge in modern organic chemistry. This dissertation presents the development of efficient synthetic strategies that combine multicomponent reactions (MCRs) with sequential reactions for rapid access a diverse array of polyheterocyclic compounds. The projects are: 1) Groebke-Blackburn-Bienaymé (GBB) reaction followed by N-acylation and Friedel-Crafts (FC) cyclization for the construction of imidazopyridine- and indole-fused azepinones involving an unusual ring-expansion process. 2) Modified GBB condensation products for intramolecular Diels-Alder (IMDA) cycloaddition and dehydrative re-aromatization to access imidazopyridine-fused isoquinolinones. 3) Integration of the Ugi-three component reaction (Ugi-3CR) and Pictet-Spengler (PS) reaction followed by …
Enhanced Osseointegration Of Functionally Graded Co˗Cr˗Mo˗Ti/Ha Implants: In Vitro And In Vivo Study In A Rabbit Model, Afrah M. Al Hussainey, Randa Kamel Hussain, Aseel Mustafa Abdul Majeed
Enhanced Osseointegration Of Functionally Graded Co˗Cr˗Mo˗Ti/Ha Implants: In Vitro And In Vivo Study In A Rabbit Model, Afrah M. Al Hussainey, Randa Kamel Hussain, Aseel Mustafa Abdul Majeed
Karbala International Journal of Modern Science
The present investigation aims to evaluate the effects of acid and laser surface treatments on the surface characteristics, biocompatibility, and osseointegration of functionally graded implants fabricated from a Co–Cr–Mo–Ti/HA alloy. The implant surfaces were modified using either an Nd: YAG laser or hydrochloric acid (HCl), while untreated implants served as controls. Atomic force microscopy (AFM) showed that the acid-treated surface exhibited the highest mean surface roughness (Sa) of 58.10 ± 0.24 nm compared to the laser-treated surface (42.64 ± 0.83 nm) and the untreated surface (37.73 ± 0.89 nm). The MTT assay also demonstrated a favourable cellular response on the …
In Situ Electrochemical Characterization Techniques For Active Hydrogen In Electrocatalytic Nitrate Reduction To Ammonia, Hong-Mei Li, Mei Yi, Zhao-Yu Jin, Ming-Hao Xie, Khalid M. Omer, Yong Guo, Pan-Pan Li
In Situ Electrochemical Characterization Techniques For Active Hydrogen In Electrocatalytic Nitrate Reduction To Ammonia, Hong-Mei Li, Mei Yi, Zhao-Yu Jin, Ming-Hao Xie, Khalid M. Omer, Yong Guo, Pan-Pan Li
Journal of Electrochemistry
Electrocatalytic nitrate reduction to ammonia (NitRR) represents a sustainable pathway that integrates environmental remediation with the production of high-value ammonia. However, the activity and selectivity of this process are limited by the generation, consumption, and dynamic equilibrium of the key transient intermediate—active hydrogen (*H). Precise modulation of *H necessitates a comprehensive understanding of its behavior, which relies fundamentally on advanced in situ electrochemical characterization techniques. However, a systematic review dedicated to the rational selection and application of in situ electrochemical techniques for the specific characterization of *H in NitRR, with clear definitions of each technique's "detectable targets, quantitative accuracy, and …
Microwave-Assisted Synthesis Of Core-Shell Structured Pd@Pdptcufe Recessed Truncated Octahedral Nanocrystals For Multifunctional Electrocatalysis, De-Zhong Hu, Wen-Dan Jiang, Wei Keat Ng, Jun Yang, Xiong-Wu Kang
Microwave-Assisted Synthesis Of Core-Shell Structured Pd@Pdptcufe Recessed Truncated Octahedral Nanocrystals For Multifunctional Electrocatalysis, De-Zhong Hu, Wen-Dan Jiang, Wei Keat Ng, Jun Yang, Xiong-Wu Kang
Journal of Electrochemistry
Developing cost-efficient and durable multifunctional electrocatalysts of hydrogen evolution reaction, oxygen reduction reaction and oxygen evolution reaction is crucial for improving energy conversion efficiency in electrolytic water splitting electrolyzer and advancing rechargeable zinc-air batteries. Polyhedral shaped nanocrystals with well-defined crystal facets represent a type of model catalysts that enables the exploration of structure-activity relationships. However, it is still very challenging to prepare alloy nanocrystals with multiple metal components due to their complicated redox potentials and mixing enthalpy. Herein, we report a rapid microwave-assisted polyol reduction method for syntheses of core-shell Pd@PdPtCu, Pd@PdPtCuNi, Pd@PdPtCuCo and Pd@PdPtCuZn octahedral nanocrystals, and recessed truncated-octahedral …
Neural Network Driven By Electrochemical Performance Data For Predicting The Discharge Termination Time Of Seawater Electrolyte-Based Metal-Air Batteries, Peng-Peng Shen, Yi-Chi Pan, Yu-Rong Liu, Lu-Dan Zhang, Ning Niu, Guan-Jun Wang, De-Kun Yang, Xin-Long Tian, Peng Rao
Neural Network Driven By Electrochemical Performance Data For Predicting The Discharge Termination Time Of Seawater Electrolyte-Based Metal-Air Batteries, Peng-Peng Shen, Yi-Chi Pan, Yu-Rong Liu, Lu-Dan Zhang, Ning Niu, Guan-Jun Wang, De-Kun Yang, Xin-Long Tian, Peng Rao
Journal of Electrochemistry
Seawater electrolyte-based metal-air batteries exhibit great promise for marine energy supply systems. However, conventional statistical analysis methods, though applicable to seawater metal-air battery lifetime prediction, have inherent limitations of insufficient prediction accuracy and large error. Herein, a deep time-series regression framework based on InceptionTime and incorporating prior-biased attention pooling is proposed to construct a nonlinear mapping between electrochemical performance sequences and the discharge termination time of catalysts. Specifically, chronoamperometric profiles are employed to extract long-term stability features, while prior knowledge derived from linear sweep voltammetry is introduced to strengthen the attention weighting over critical potential regions. Under a nested leave-one-catalyst-out …
Unveiling Cuo-Doped Mwcnts Incorporated Polycaprolactone As Effective Photocatalytic Nanomembranes For Sequestrating Toxic Dyes From Industrial Wastewater And Antibacterial Applications, Hesham Moustafa, Mohamed Mousa, Mohamed Morsy, Gotdon Price, Mohamed H. Hemida, Samah A. Mohamed, Ahmed Helal
Unveiling Cuo-Doped Mwcnts Incorporated Polycaprolactone As Effective Photocatalytic Nanomembranes For Sequestrating Toxic Dyes From Industrial Wastewater And Antibacterial Applications, Hesham Moustafa, Mohamed Mousa, Mohamed Morsy, Gotdon Price, Mohamed H. Hemida, Samah A. Mohamed, Ahmed Helal
Nanotechnology Research Centre
Organic dyes, such as methylene blue (MB), are widely used in the textile and dyestuff industries, which can be released into the environment as major dye pollutants in wastewater, thereby causing serious environmental hazards. The present research aimed to synthesize effective CuO-doped multi-walled carbon nanotubes (MWCNTs) and incorporated into a renewable polycaprolactone (PCL) polymer at varied dosages (i.e., 3, 7, and 10 wt%) to fabricate photocatalytic nanomembranes for toxic dye sequestration. XRD, SEM and FTIR analysis were employed to characterize the structure, morphology and composition of prepared nanoparticles and PCL nanomembranes. The mechanical properties and antibacterial performance of prepared nanomembranes …
Correlative In Situ Nonlinear Optical Characteriztion Of Plasmonic Colloidal Nanoparticle Growth Dynamics, Stena C. Peterson
Correlative In Situ Nonlinear Optical Characteriztion Of Plasmonic Colloidal Nanoparticle Growth Dynamics, Stena C. Peterson
LSU Doctoral Dissertations
Colloidal noble metal nanoparticles are of extreme interest as nanomaterials and for the wide variety of their possible applications in nanomedicine. The unique linear and nonlinear optical processes associated with these nanomaterials can be studied using a variety of spectroscopic techniques including extinction, second harmonic generation (SHG), and two-photon fluorescence (TPF) spectroscopy. In order to better understand and optimize these nanomaterials for their desired applications, it is important to investigate the growth and photophysical dynamics associated with gold nanoparticles, silver-gold core-shell (Ag-Au CS) nanoparticles, and gold-silver-gold core-shell-shell (Au-Ag-Au CSS) nanoparticles in addition to how their size, surface morphology, composition. and …
Synthesis, Thermal Stability, And Ionic Conductivity Of Phenyl-Extended Viologen Ditriflate Salts: Tailoring Properties Via Oxyethylene Chain Length, Seonghyeok L. Cox, Emily Moon, Si L. Chen, David King, Haesook Han, Pradip K. Bhowmik, Calvin Ng Yi Bin, Thamil Selvi Velayutham, Alfonso Martinez-Felipe
Synthesis, Thermal Stability, And Ionic Conductivity Of Phenyl-Extended Viologen Ditriflate Salts: Tailoring Properties Via Oxyethylene Chain Length, Seonghyeok L. Cox, Emily Moon, Si L. Chen, David King, Haesook Han, Pradip K. Bhowmik, Calvin Ng Yi Bin, Thamil Selvi Velayutham, Alfonso Martinez-Felipe
Chemistry and Biochemistry Faculty Research
Six new phenyl-extended viologen salts with oxyethylene groups paired with triflate anions (OTF) have been synthesized using anionic ring-opening and ring-closing reactions (ANRORC) and metathesis reactions with LiOTf salts. The salts, which contain terminal oxyethylene chains of varying lengths ((CH2CH2O)n, n = 1, 2, 3, 4, 5, and 7), are named PEOn-OTF. These materials exhibit a fluorescence response and possess high thermal stability, with processing windows up to approximately 300 °C, as confirmed by thermogravimetric analysis. While samples with short chain lengths (n = 1, 2, and 3) undergo crystallization observed …
Norman H. Cromwell, Unl Chemistry; Nu System Dean; Eppley Cancer Center Director, Norman H. Cromwell, Pete Boughn, Mark A. Griep
Norman H. Cromwell, Unl Chemistry; Nu System Dean; Eppley Cancer Center Director, Norman H. Cromwell, Pete Boughn, Mark A. Griep
UNL ORCA Interview Series
This 1980 interview of Normal Cromwell was done by Pete Boughn at the University of Nebraska Medical Center in Omaha. He asked about Cromwell’s history but mostly about his time as director of the Eppley Cancer Center. The interview is reproduced with permission from the UNMC McGoogan Library.
Cromwell was born in 1913 in Terre Haute, Indiana. In 1935, he earned a bachelor’s degree in chemical engineering from the Rose-Hulman Institute of Technology in his hometown. In 1939, three things happened: he earned a doctorate in organic chemistry from the University of Minnesota, he got married, and he was hired …
Techno-Economic Analysis Of Implementing Carbon Capture And Storage (Ccs) At The Punagaya 2×100 Mw Coal Power Plant, Ricky Andreas Kristianto Siringoringo, Rahma Muthia, Widodo Wahyu Purwanto
Techno-Economic Analysis Of Implementing Carbon Capture And Storage (Ccs) At The Punagaya 2×100 Mw Coal Power Plant, Ricky Andreas Kristianto Siringoringo, Rahma Muthia, Widodo Wahyu Purwanto
Journal of Materials Exploration and Findings
The increase in greenhouse gases due to the combustion of fossil fuels is one of the major drivers of global warming and consequently drives the development of low-carbon technologies such as Carbon Capture and Storage (CCS). The aim of this study is to evaluate the technical and economical feasibility of the implementation of CCS technology in the Punagaya Subcritical Coal-Fired Power Plant (CFPP) 2×100 MW as a part of the energy transition strategy towards Net Zero Emissions (NZE) 2060. The simulation was carried out using Aspen HYSYS software, including coal combustion, CO₂ capture through MDEA-PZ solvent, dehydration, transportation, and storage …