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Articles 931 - 960 of 6110

Full-Text Articles in Environmental Engineering

Photochemical Formation Mechanisms And Applications Of Mn Oxide Nanomaterials, Zhenwei Gao Aug 2022

Photochemical Formation Mechanisms And Applications Of Mn Oxide Nanomaterials, Zhenwei Gao

McKelvey School of Engineering Graduate Student Theses & Dissertations

Manganese (Mn) oxides are ubiquitous in aquatic and terrestrial environments, and the rich redox chemistry of manganese is of interest in engineered systems, such as batteries and water oxidation catalysts. Mn oxides have large surface areas and are highly active in adsorption and redox reactions. Our research group recently reported photochemically-assisted abiotic inorganic oxidation of Mn2+(aq) to δ-MnO2 nanosheets in the presence of nitrate and without a microorganism, demonstrating that abiotic Mn oxidation processes are not negligible. My doctoral work focuses on investigating the effects of various aquatic chemistry parameters, including reactive oxygen species (ROS), peroxyl radical (ROO•), reactive halogen …


Nano-Bio Interactions: Implications And Applications, Anushree Ghosh Aug 2022

Nano-Bio Interactions: Implications And Applications, Anushree Ghosh

McKelvey School of Engineering Graduate Student Theses & Dissertations

Rapid expansion of technology development at the nanoscale has underpinned a promising industry. Towards this, there remain significant information gaps which are critical with regard to decision making processes and ultimate industrial sustainability. From an implication point of view, understanding how common biological macromolecules, including glycolipids and/or biopolymers produced by bacteria and fungi, which are ubiquitous in the environment, is fundamental to predicting the behavior of released/produced nanoparticles. Conversely, other bio-based tailored macromolecules, including mussel foot protein (MFP), have significant potential as functional material coatings for advanced applications.This PhD thesis is focused on interfacial processes related to superparamagnetic iron oxide …


Calcium Bearing Mineral-Hydrogel Composites For Phosphate Removal And Recovery, Albern Xuan-Wei Tan Aug 2022

Calcium Bearing Mineral-Hydrogel Composites For Phosphate Removal And Recovery, Albern Xuan-Wei Tan

McKelvey School of Engineering Graduate Student Theses & Dissertations

The millions of tons of phosphate rock ore mined every year for use as phosphorus fertilizer have created two challenges. First, phosphate rock is a mined, non-renewable resource that is also heavily geographically concentrated, raising concerns about the long-term sustainability and availability of phosphorus. Second, after it is applied as a fertilizer, phosphorus will also be released to the broader environment. There, it contributes to harmful algal blooms and eutrophication, which threaten surface water quality and can harm aquatic ecosystems and the communities and industries that rely on them. These considerations motivate the coupled development of techniques for removing and …


Evaluation Of Flood Damage On Cross Laminated Timber Wall Configurations, Mustafa Nezih Kaya Aug 2022

Evaluation Of Flood Damage On Cross Laminated Timber Wall Configurations, Mustafa Nezih Kaya

Theses and Dissertations

Greenhouse gas emissions are one of the critical factors that affect climate change, increasing flooding risk and threatening human life. The use of traditional construction materials is responsible for a higher percentage of global greenhouse gas emissions when compared to the use of sustainable materials in the construction industry. The substitution of current building materials with sustainable materials is essential to reduce greenhouse gas emissions and positively influence climate change when the current construction demand in the world is considered. Wood is one of the primary environmentally friendly construction materials in regard to high carbon storage and low carbon emissions. …


An Evaluation Of Energy Consumption Comparing Conventional Water Treatment Plants To Microfiltration And Ultrafiltration Water Treatment Plants, Danielle Larsen Aug 2022

An Evaluation Of Energy Consumption Comparing Conventional Water Treatment Plants To Microfiltration And Ultrafiltration Water Treatment Plants, Danielle Larsen

All Theses

The use of low-pressure, hollow fiber microfiltration (MF) and ultrafiltration (UF) membranes has become increasingly prominent in drinking water treatment plant configurations over the past 30 years. At the same time, the topics of energy efficiency and sustainability in industry are becoming progressively more important. Although MF and UF are highly successful in filtration, they are generally thought of as significant energy consumers; however, the data have not yet been available to compare multiple plants in various contexts to determine the factors that most affect energy use. This research compares the energy use of MF and UF treatment plants to …


Application Of A 14c-Assay To Assess Methanotrophic Biodegradation Of Tce In Low Ph Groundwater, Evan Groome Aug 2022

Application Of A 14c-Assay To Assess Methanotrophic Biodegradation Of Tce In Low Ph Groundwater, Evan Groome

All Theses

Current biological strategies for remediating trichloroethylene (TCE) in low pH aquifers (i.e., pH14C-TCE assay was developed to determine pseudo first-order rate constants for the degradation of TCE in microcosms containing soil and groundwater from the Boeing Michigan Aeronautical Research Center (BOMARC) superfund site, where the pH ranges from 4.1 to 4.9. The 14C-TCE assay was also adapted to calculate soil-normalized rate constants for data from this site, as well as data that Szwast21 collected from the Beltsville Agricultural Research Center (BARC). In addition to natural attenuation, biostimulation through amendments of methane and nutrients were also assessed. This treatment …


Fabrication Of Lab-Scale Polymeric And Silicon Dioxide Nanoparticle-Enabled Thin Film Composite Reverse Osmosis Membranes For Potable Reuse Applications, Timothy J. Dinh Aug 2022

Fabrication Of Lab-Scale Polymeric And Silicon Dioxide Nanoparticle-Enabled Thin Film Composite Reverse Osmosis Membranes For Potable Reuse Applications, Timothy J. Dinh

Master's Theses

Reverse osmosis (RO) is widely used for water reclamation and is one of the most feasible technologies for addressing water scarcity around the world. RO membrane fabrication procedures are continually being optimized and modified to enhance the treatment performance and efficacy of the RO process. A review of the existing literature published on membrane fabrication revealed that a detailed and reproducible methodology consistent among prior studies was not available. Therefore, the primary objective of this study was to utilize techniques from prior research to develop a reliable lab-scale membrane fabrication process for studying the potable reuse applications of TFC RO …


Implementation Of Secondary And Tertiary Treated Wastewater In Concrete Manufacturing, Amany G. Micheal Prof., Haidy Abdel Salam, Gouda Ghanem Aug 2022

Implementation Of Secondary And Tertiary Treated Wastewater In Concrete Manufacturing, Amany G. Micheal Prof., Haidy Abdel Salam, Gouda Ghanem

Civil Engineering

Water scarcity is a problem that faces many regions. In a developing and arid country like Egypt, the need for freshwater is exponentially increasing. This research is an evaluation of the recycled wastewater to be used in concrete manufacturing. The treated wastewater is blended with potable water with percentages of 25%, 50%, and 100%. The mixture of the two types of water is used in concrete mixing and curing. Control specimens with pure potable water are cast for comparison. The setting time for Ordinary Portland Cement is tested using the different water mixes. The hardened concrete is tested in compression …


Compound Flooding In Convergent Estuaries: Insights From An Analytical Model, Ramin Familkhalili, Stefan Talke, David A. Jay Aug 2022

Compound Flooding In Convergent Estuaries: Insights From An Analytical Model, Ramin Familkhalili, Stefan Talke, David A. Jay

Civil & Environmental Engineering Faculty Publications

We investigate here the effects of geometric properties (channel depth and cross-sectional convergence length), storm surge characteristics, friction, and river flow on the spatial and temporal variability of compound flooding along an idealized, meso-tidal coastal-plain estuary. An analytical model is developed that includes exponentially convergent geometry, tidal forcing, constant river flow, and a representation of storm surge as a combination of two sinusoidal waves. Nonlinear bed friction is treated using Chebyshev polynomials and trigonometric functions, and a multi-segment approach is used to increase accuracy. Model results show that river discharge increases the damping of surge amplitudes in an estuary, while …


Use Of A Trial Function Method To Semi-Analytically Simulate Matrix Diffusion In Heterogeneous And Fractured Media, Kien Trung Pham Aug 2022

Use Of A Trial Function Method To Semi-Analytically Simulate Matrix Diffusion In Heterogeneous And Fractured Media, Kien Trung Pham

All Dissertations

A semi-analytic trial function model is applied to simulate matrix diffusion in systems of parallel fractures, 2-D/3-D discrete fracture networks, and in 3-D heterogeneous media. The trial function model gives low normalized root mean square error (NRMSE) when compared to the parallel fracture analytical solution over a range of fracture spacing, with considerations for retardation and decay. The semi-analytic trial function model is efficient in time and maintains less than 6% NRMSE when it simulates matrix diffusive transport in 2-D/3-D discrete fracture networks (DFN). The model can predict DFN plume within a few meters of accuracy compared to fine-grid DFN …


Integration Of Techno-Economic Analysis (Tea) And Life Cycle Assessment (Lca) For Sustainable Process Design, Roksana Mahmud Aug 2022

Integration Of Techno-Economic Analysis (Tea) And Life Cycle Assessment (Lca) For Sustainable Process Design, Roksana Mahmud

All Dissertations

For sustainable design, technology developers need to consider not only technical and economic aspects but also potential environmental impacts while developing new technologies. Techno-economic analysis (TEA) evaluates the technical performance and economic feasibility of a technology. Life cycle assessment (LCA) evaluates the potential environmental impacts associated with a product system throughout its life cycle from raw material extraction to disposal. Generally, TEA and LCA are performed separately for technology assessment. Understanding of the trade-off between economic and environmental performances is crucial for sustainable process design, which is not fully available if TEA and LCA is performed separately. In contrast, integration …


A Snapshot Of Sars-Cov-2 In Wastewater Treatment Plants In Northwest Arkansas, Katie Loethen Aug 2022

A Snapshot Of Sars-Cov-2 In Wastewater Treatment Plants In Northwest Arkansas, Katie Loethen

Biological and Agricultural Engineering Undergraduate Honors Theses

Because SARS-CoV-2, a coronavirus, is released in the fecal shedding of covid-positive patients, the virus enters the municipal waste stream and flows to wastewater treatment plants (WWTPs). The goal of this research is to quantify the effectiveness of wastewater treatment processes at removing SARS-CoV-2 from wastewater and preventing its release into the environment. Sampling at Paul R. Noland and West Side WWTPs in Fayetteville, Arkansas, took place from August 2020 to May 2021, and samples were tested for the presence of SARS-CoV-2 using N1 and N2 primers via RT-qPCR. Sampling days which returned positive detection of one or both of …


Wind Flow Characteristics Of Multi-Vortex Tornadoes And Their Wind Effects On Residential Houses, Yi Zhao Aug 2022

Wind Flow Characteristics Of Multi-Vortex Tornadoes And Their Wind Effects On Residential Houses, Yi Zhao

Doctoral Dissertations

"Tornadoes strike the USA very frequently, with an average of 1200 reports per year, and the average annual tornado-induced property loss has reached $10B. The devastation from recent tornadoes have prompted a renewed interest in better understanding tornado dynamics, their interactions with the built environment, and the performance of civil structures during tornadoes. In the past, the wind effects caused by single-vortex tornadoes have been widely studied, while the multi-vortex tornadoes were rarely considered. In fact, many previous deadly, costly tornadoes involved multiple vortices. Therefore, it is important to understand the wind flow characteristics of multi-vortex tornadoes in order to …


Efficiency Of Bank Filtration In The Removal Of Cyanotoxins Under Different Levels Of Nutrients, Luke Walkenhorst Jul 2022

Efficiency Of Bank Filtration In The Removal Of Cyanotoxins Under Different Levels Of Nutrients, Luke Walkenhorst

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Harmful Algal Blooms (HABs) are an increasing concern not only in Nebraska, but across the world. Increasing global temperatures in conjunction with overuse of synthetic fertilizers are leading causes to the increasing frequency and concern of HABs. In the present work, the effectiveness of simulated bank filtration (BF), as an economical water treatment option, to remove cyanotoxins under different levels of nutrients (nitrates and phosphates) was investigated. Vertical flow-through columns pre-acclimated with two levels of nutrients (e.g., nitrate and phosphate—10 vs. 50 mg/L) were exposed to two different levels of cyanotoxins (10 vs. 75 μg/L). Results from the study confirmed …


Ds-Menet For The Classification Of Citrus Disease, Xuyao Liu, Yaowen Hu, Guoxiong Zhou, Weiwei Cai, Mingfang He, Jialei Zhan, Yahui Hu, Liujun Li Jul 2022

Ds-Menet For The Classification Of Citrus Disease, Xuyao Liu, Yaowen Hu, Guoxiong Zhou, Weiwei Cai, Mingfang He, Jialei Zhan, Yahui Hu, Liujun Li

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Affected by various environmental factors, citrus will frequently suffer from diseases during the growth process, which has brought huge obstacles to the development of agriculture. This paper proposes a new method for identifying and classifying citrus diseases. Firstly, this paper designs an image enhancement method based on the MSRCR algorithm and homomorphic filtering algorithm optimized by Laplacian (HFLF-MS) to highlight the disease characteristics of citrus. Secondly, we designed a new neural network DS-MENet based on the DenseNet-121 backbone structure. In DS-MENet, the regular convolution in Dense Block is replaced with depthwise separable convolution, which reduces the network parameters. The ReMish …


Construction And Operation Of A Pilot-Scale Odor Control Device, Brendan Bunker Jul 2022

Construction And Operation Of A Pilot-Scale Odor Control Device, Brendan Bunker

Department of Environmental Engineering: Theses and Other Student Research

Hydrogen sulfide (H2S) is a naturally occurring by-product of anaerobic digestion and causes an odor that can be a nuisance and a public health risk at higher concentrations. This compound can be treated through various means, but one of particular interest is a biotrickling filter (BTF). Such devices have excellent H2S treatment efficiencies, but start-up costs can be steep. The primary goal of this study is to explain the design and operation of a low-cost odor control device for improving environmental air quality in Nebraska using a BTF. This device has the potential for application as …


Wetland Soil Development Along Salinity And Hydrogeomorphic Gradients In Active And Inactive Deltaic Basins Of Coastal Louisiana, Amanda Fontenot Jul 2022

Wetland Soil Development Along Salinity And Hydrogeomorphic Gradients In Active And Inactive Deltaic Basins Of Coastal Louisiana, Amanda Fontenot

LSU Master's Theses

Coastal wetlands provide an abundance of ecosystem services that benefit society, such as essential habitat for commercial species, storm protection, nutrient cycling, and carbon storage. Louisiana faces rapid rates of relative sea level rise (natural subsidence and eustatic sea levels) that threaten wetland survival, which are amplified by a reduction of riverine sediment input. An important determining factor of marsh survival is the formation of wetland platform elevation, known as vertical accretion, which is determined by several processes including sediment deposition & erosion, below ground biomass (BGB) productivity, decomposition of organic matter, shallow & deep subsidence, and soil compaction. Feldspar …


Development An Edge-Computing Sensing Unit For Continuous Measurement Of Canopy Cover Percentage Of Dry Edible Beans, Wei-Zhen Liang, Joseph Oboamah, Xin Qiao, Yufeng Ge, Robert M. Harveson, Daran R. Rudnick, Jun Wang, Haishun Yang, Angie Gradiz Jul 2022

Development An Edge-Computing Sensing Unit For Continuous Measurement Of Canopy Cover Percentage Of Dry Edible Beans, Wei-Zhen Liang, Joseph Oboamah, Xin Qiao, Yufeng Ge, Robert M. Harveson, Daran R. Rudnick, Jun Wang, Haishun Yang, Angie Gradiz

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Canopy cover (CC) is an important indicator for crop development. Currently, CC can be estimated indirectly by measuring leaf area index (LAI), using commercially available hand-held meters. However, it does not capture the dynamics of CC. Continuous CC monitoring is essential for dry edible beans production since it can affect crop water use, weed, and disease control. It also helps growers to closely monitor “yellowness”, or senescence of dry beans to decide proper irrigation cutoff to allow the crop to dry down for harvest. The goal of this study was to develop a device – CanopyCAM, containing software and hardware …


Effect Of Bromoform And Linseed Oil On Greenhouse Gas Emissions From Stored Beef Manure, Andrew Ortiz Balsero, Mara Zelt, Amy Millmier Schmidt, Miguel Fudolig, Daniel N. Miller Jul 2022

Effect Of Bromoform And Linseed Oil On Greenhouse Gas Emissions From Stored Beef Manure, Andrew Ortiz Balsero, Mara Zelt, Amy Millmier Schmidt, Miguel Fudolig, Daniel N. Miller

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Emissions of carbon dioxide, methane, and nitrous oxide – potent greenhouse gases - from stored beef feedlot manure are a significant concern relative to climate change. Research on methane reduction strategies for enteric emissions has identified the application of organic additives, such as bromoform and linseed oil, to ruminant diets as potential solutions for reducing enteric emissions and pathogenic bacteria in excreted manure. The objective of this study was to determine the effect of bromoform and linseed oil on greenhouse gas emissions from beef feedlot manure, and on E. coli concentration in beef cattle manure, during a 5-week storage period. …


Elemental Sulfur And Metal Sulfide Minerals For Autotrophic Denitrification: Applications To Aquaculture, Groundwater Treatment, And Domestic Wastewater Treatment, Erica Amah Dasi Jul 2022

Elemental Sulfur And Metal Sulfide Minerals For Autotrophic Denitrification: Applications To Aquaculture, Groundwater Treatment, And Domestic Wastewater Treatment, Erica Amah Dasi

USF Tampa Graduate Theses and Dissertations

Nutrient pollution of waterways, from excess N and P, is a global concern that results in harmful impacts the environment, human health, and aquatic animals. This dissertation harnesses sulfur autotrophic denitrification to remove nutrients from groundwater, domestic wastewater, and wastewaters produced from marine recirculating aquaculture systems (RAS). Part 1 evaluates the denitrification performance of woodchips and elemental sulfur in cyclic denitrification filters (WS-CDFs) integrated into marine RAS operated under saline conditions. Part 2 investigates the use of metal sulfide minerals, with and without oyster shells, for supporting nutrient removal from groundwater in batch reactors. Part 3 assesses …


Learning From Machines: Insights In Forest Transpiration Using Machine Learning Methods, Morgan Thornwell Jul 2022

Learning From Machines: Insights In Forest Transpiration Using Machine Learning Methods, Morgan Thornwell

Dissertations and Theses

Machine learning has been used as a tool to model transpiration for individual sites, but few models are capable of generalizing to new locations without calibration to site data. Using the global SAPFLUXNET database, 95 tree sap flow data sites were grouped using three clustering strategies: by biome, by tree functional type, and through use of a k-means unsupervised clustering algorithm. Two supervised machine learning algorithms, a random forest algorithm and a neural network algorithm, were used to build machine learning models that predicted transpiration for each cluster. The performance and feature importance in each model were analyzed and compared …


Mdam-Drnet: Dual Channel Residual Network With Multi-Directional Attention Mechanism In Strawberry Leaf Diseases Detection, Tingjing Liao, Ruoli Yang, Peirui Zhao, Wenhua Zhou, Mingfang He, Liujun Li Jul 2022

Mdam-Drnet: Dual Channel Residual Network With Multi-Directional Attention Mechanism In Strawberry Leaf Diseases Detection, Tingjing Liao, Ruoli Yang, Peirui Zhao, Wenhua Zhou, Mingfang He, Liujun Li

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The growth of strawberry plants is affected by a variety of strawberry leaf diseases. Yet, due to the complexity of these diseases' spots in terms of color and texture, their manual identification requires much time and energy. Developing a more efficient identification method could be imperative for improving the yield and quality of strawberry crops. To that end, here we proposed a detection framework for strawberry leaf diseases based on a dual-channel residual network with a multi-directional attention mechanism (MDAM-DRNet). (1) In order to fully extract the color features from images of diseased strawberry leaves, this paper constructed a color …


Investigating The Proper Use Of Litani River Basin Based On Water Quality, Mohamad Diab, Mohamad Soliman Jun 2022

Investigating The Proper Use Of Litani River Basin Based On Water Quality, Mohamad Diab, Mohamad Soliman

BAU Journal - Science and Technology

Litani River Basin (LRB) with a 170km length and annual river flow of 750 MCM is considered the most important water resource in Lebanon. Unfortunately, the river is facing water contamination as a result of human practices. Water Quality assessments was performed in the Litani River Basin using a combination of Principal Component Analysis method (PCA) and Water Quality Index method (WQI). Results revealed the improvement of the water quality significantly after passing lake Qaraoun. Moreover, according to WQI, Lower LRB water is ranked ‘’Good’’ for irrigation and ‘’BAD’ for drinking purposes. Microbial contamination is found to be the key …


Mechanical And Durability Properties Of Geopolymer Concrete – A Review, Lelian Elkhatib, Fadi Al Aridi, Adel Elkordi, Jamal Khatib Jun 2022

Mechanical And Durability Properties Of Geopolymer Concrete – A Review, Lelian Elkhatib, Fadi Al Aridi, Adel Elkordi, Jamal Khatib

BAU Journal - Science and Technology

Owing to the ongoing increase in human population, there is a need for more construction projects including residential buildings and other amenities. Concrete is by far the dominant material used in construction and cement is a main ingredient. Cement manufacture is an energy intensive process and emit large amounts of carbon dioxide into the atmosphere. A reduction in the amount of cement used in construction is greatly beneficial. The use of geopolymer or alkali activated materials can serve this purpose as it attempts to totally replace cement in concrete. Geopolymers are materials that consist mainly of silica and alumina materials …


Modified Biosand Filtration Using Aluminum Hydroxide Filter Media To Enhance Fluoride Removal, Joshelyn Guimaray Jun 2022

Modified Biosand Filtration Using Aluminum Hydroxide Filter Media To Enhance Fluoride Removal, Joshelyn Guimaray

USF Tampa Graduate Theses and Dissertations

There are over 20 countries whose citizens consume groundwater containing high levels of fluoride, including Nigeria, Mexico, India, China, and Ghana, which all have major health crises when it comes to the safety of their drinking water. Minerals like fluorite contain fluoride which is often found in groundwater aquifers. The minerals release fluoride into the groundwater. Per the World Health Organization (WHO) standard, the maximum contaminant limit for fluoride consumption should be less than 1.5 mg/L. Chronic exposure of elevated levels of fluoride can cause people to suffer debilitating health effects, such as dental and skeletal fluorosis. Dental fluorosis causes …


A Convergent Approach To Aqueous Lead (Pb) Mitigation Of A Supplemental Self-Supply Shallow Groundwater Source Accessed By Handpumps In Madagascar, Adaline Marie Buerck Jun 2022

A Convergent Approach To Aqueous Lead (Pb) Mitigation Of A Supplemental Self-Supply Shallow Groundwater Source Accessed By Handpumps In Madagascar, Adaline Marie Buerck

USF Tampa Graduate Theses and Dissertations

The World Health Organization (WHO) has consistently listed lead (Pb) as one of the ten chemicals of major public health concern. Though the toxic nature of lead has been known since the 20th century it is still utilized in a wide variety of products due to its favorable properties. Exposure to lead still accounts for approximately 900,000 deaths annually and disproportionately impacts those in low- and middle-income countries (LMIC) due to a variety of reasons such as poverty, malnutrition, and lack of knowledge on the toxic nature of lead. Lead exposure routes include air, soil, dust, diet, and water. Though …


Fragmentation Of Chemically Herded Oil Slicks By Obstacles: Visualizations, Flow Measurements, And Spatial Distributions, Ali Alshamrani Jun 2022

Fragmentation Of Chemically Herded Oil Slicks By Obstacles: Visualizations, Flow Measurements, And Spatial Distributions, Ali Alshamrani

USF Tampa Graduate Theses and Dissertations

Chemical herders are a promising technique for treatment of oil spills in icy waters at high latitudes. However, obstacles on the water surface such as floating ice affects or interferes with all spill response countermeasures including chemical herder operations by fracturing the contracting oil slick and trapping small oil patches. Chemical herders are likely to be especially useful in containing oil spills in remote, ice-infested Arctic waters, where using booms to contain an oil slick is difficult. Much of the previous research into chemical herder has focused on the effectiveness of different types of chemical herder agents to thicken oil …


Exploring Toluene Biosynthesis In Microbial Consortia Derived From Sediments And Superfund Site Groundwater, Raymond J. Poche Jun 2022

Exploring Toluene Biosynthesis In Microbial Consortia Derived From Sediments And Superfund Site Groundwater, Raymond J. Poche

LSU Master's Theses

While the aromatic hydrocarbon toluene is widely regarded as a contaminant associated with discharges of crude oil and refined petroleum products (e.g., gasoline), the enzyme phenylacetate decarboxylase catalyzes the decarboxylation of phenylacetate to yield toluene. Research described in this thesis further investigated toluene biosynthesis by a microbial consortium originating from chlorinated solvent-contaminated groundwater near Baton Rouge, Louisiana. In anoxic growth media supplemented with phenylacetate as a precursor, toluene accumulation was found to be maximal at near-neutral to slightly acidic pHs (toluene accumulation greater than 1 mg/L at pH in the range of 5.6 to 7.6, but was not observed for …


Evaluation Of Aluminum Dissolution, Current Density, And Pitting Patterns During Electrocoagulation, Monica Castro Carias Jun 2022

Evaluation Of Aluminum Dissolution, Current Density, And Pitting Patterns During Electrocoagulation, Monica Castro Carias

USF Tampa Graduate Theses and Dissertations

Electrocoagulation (EC) is a sustainable water treatment process involving the generation of coagulants on-site through the application of a voltage on metal (usually aluminum or iron alloys). The factors that impact EC system performance have been well researched, however further research is needed on the factors that impact anodic dissolution of aluminum electrodes, especially when the technology is transferred to full-scale applications. Electrode fouling is one of the factors that can impact dissolution of the anode during EC due to the formation of a protective oxide/hydroxide layer on the electrode surface. Previous studies have addressed electrode fouling by reversing polarity, …


Design And Commissioning Of An E-Beam Irradiation Beamline At The Upgraded Injector Test Facility At Jefferson Lab, Xi Li, Helmut Baumgart, Charles Bott, Gianluigi Ciovati, Shaun Gregory, Fay Hannon, Mike Mccaughan, Robert Pearce, Matthew Poelker, Hannes Vennekate, Shaoheng Wang Jun 2022

Design And Commissioning Of An E-Beam Irradiation Beamline At The Upgraded Injector Test Facility At Jefferson Lab, Xi Li, Helmut Baumgart, Charles Bott, Gianluigi Ciovati, Shaun Gregory, Fay Hannon, Mike Mccaughan, Robert Pearce, Matthew Poelker, Hannes Vennekate, Shaoheng Wang

Electrical & Computer Engineering Faculty Publications

The Upgraded Injector Test Facility (UITF) at Jefferson Lab is a continuous-wave superconducting linear accelerator capable of providing an electron beam with energy up to 10 MeV. A beamline for electron-beam irradiation has been designed, installed and successfully commissioned at this facility, aimed at the degradation study of 1,4-dioxane and per- and polyfluoroalkyl substances (PFAS) in wastewater treatment. A solenoid with a peak axial magnetic field of up to 0.28 T and a set of raster coils were used to obtain a Gaussian beam profile with a transverse standard deviation of ∼15.0 mm at the target location. Monte-Carlo simulations using …