Environmental Engineering Commons^™

Photocatalytic Nanoparticle Treatment Of Cyanotoxins In Harmful Algal Blooms, Brian Baird

Civil Engineering Undergraduate Honors Theses

Harmful Algal Blooms (HAB) have the ability to cause detriment to water bodies, ecosystems, and human health. Furthermore, current evidence suggests that these events are becoming increasingly common due to factors such as increased pollution and global warming. While there are current methods to treat water that is negatively impacted by the bacteria and toxins associated with HABs, these methods are often costly and inefficient. The purpose of this research is to explore a potential treatment option that uses titanium dioxide photocatalytic nanoparticles attached to a retractable net to treat toxins produced by HABs in situ. Specifically, the toxin …

Sustainability And Health Impacts Of Pulse Crops In The United States Using Life Cycle Assessment, Prathamesh A. Bandekar

Graduate Theses and Dissertations

Environmental sustainability and human health impact of pulses produced and consumed in the United States was assessed using life cycle assessment (LCA). The study included three objectives 1) to estimate environmental impact of current production and consumption practices in the United States using attributional LCA; 2) to estimate environmental and human health impact of iso-caloric diets containing varying amounts of pulses using Hybrid-LCA and Combined Nutritional and Environmental-LCA (CONE-LCA); and 3) to estimate environmental impact of increased demand for pulses using consequential LCA. Scope of the study varied for each objective with system boundary encompassing cradle-to-grave activities for objective 1 …

A Snapshot Of Sars-Cov-2 In Wastewater Treatment Plants In Northwest Arkansas, Katie Loethen

Biological and Agricultural Engineering Undergraduate Honors Theses

Because SARS-CoV-2, a coronavirus, is released in the fecal shedding of covid-positive patients, the virus enters the municipal waste stream and flows to wastewater treatment plants (WWTPs). The goal of this research is to quantify the effectiveness of wastewater treatment processes at removing SARS-CoV-2 from wastewater and preventing its release into the environment. Sampling at Paul R. Noland and West Side WWTPs in Fayetteville, Arkansas, took place from August 2020 to May 2021, and samples were tested for the presence of SARS-CoV-2 using N1 and N2 primers via RT-qPCR. Sampling days which returned positive detection of one or both of …

Port Infrastructure Resilience Through Combined Wind-Surge Demand Characterization, Kaley Callaway

Graduate Theses and Dissertations

The United States economy is reliant on maritime transportation for 70% of imports and exports. Structures that are integral to the operation of ports, such as cranes, are jeopardized when tropical storms approach land. While wind is the only environmental load used to design dockside container cranes, storm surge often accompanies severe wind events and can create large structural loads. This study focuses on determining coupled storm-surge demands and the effect of waves on dockside container cranes. A damage index prediction tool that considers both maximum wind speed and storm surge height is developed and applied to historical hurricane data …

Sustainability In Construction Practices As Emphasis On Environmental Investing In Esg Model Grows, Maddie Heal

Management Undergraduate Honors Theses

The purpose of this research is to emphasize the importance of growing investment on environmental initiatives in business ESG models in regard to sustainable practices in construction. The ESG acronym is known as the environmental, social, and governance efforts that businesses strive to incorporate in their models to increase the responsibility of operations.

Investors continue to seek out responsible businesses when choosing which ventures to pursue. The analysis of the current construction crisis, current investments in the right direction of Eco-friendly design regarding construction, and the threats and benefits incentivizing those investments elucidates the need to emphasize socially responsible investment …

Community Transportation Needs And Willingness To Use Shared Micromobility: A Case Study Of Fort Smith, Arkansas, Anthony Michael Kammerer

Civil Engineering Undergraduate Honors Theses

Shared micromobility is utilized in “targeted service areas with the usage generally intended for short trips such as "first- and last-mile" connections to complete trips made via other modes, including transit” (Price et al., 2021). In the United States, this practice has especially taken off with the implementation of sharing-based systems. This is evidenced by ridership numbers in the United States growing from 84 million riders nationwide in 2018 to 136 million riders in 2019 (NACTO, 2020). Users often use their smart phone or another similar device to unlock the vehicle after paying a fee on the device through their …

The Effect Of Changing Land Use On Streamflow Statistics And Flood Flows Across Select Gages In Northwest Arkansas, Timothy Mcmullen

Civil Engineering Undergraduate Honors Theses

Since 1901, heavy rainfall events have increased in the United States in both intensity and frequency, and population in the United States has increased, resulting in significant land use changes. Both of these trends could explain an increase in observed flood magnitude and frequency. In order to determine if a relationship exists between land use/land cover and changing stream flows in northwest Arkansas, this study analyzed temporal changes in various flow statistics for fourteen stream gages and compared the rates of change in flow statistics from gages on streams with watersheds that have varying land uses, i.e. urban, agricultural, and …

Exploring The Effects Of Varied Land Use On Elemental Concentrations Within Streams, Logan Jennings

Biological and Agricultural Engineering Undergraduate Honors Theses

It is well documented that human activity influences the chemistry of surrounding waters. As such, it is possible that there is a link between land use within a watershed and the chemical composition of the stream. The objectives of this study are to determine if varied land use does affect the concentrations of macronutrients and trace elements present in the streams of Northwest Arkansas, and if so, to determine what extent urban and agricultural development are responsible for these changes. Water samples were collected across 19 streams in the Northwest Arkansas region between January and March of 2022. Water samples …

Formation Of Reactive Nitrogen Species During Dichloramine Decay And Their Impact On N Nitrosodimethylamine Formation Under Drinking Water Conditions, Huong Thu Pham

Graduate Theses and Dissertations

NDMA occurrence and formation pathways in drinking water systems are reviewed and NDMA yields are compared on the basis of disinfectant type, water chemistry, and precursor category. In chloramination, despite monochloramine being the predominant species between pH 7-9, evidence suggests that dichloramine is the primary species involved in NDMA formation. This is somewhat confounding as NDMA yields are maximal at pH 9, yet at pH 9 dichloramine decays faster than it forms and hence is present at trace levels; additionally, the proposed mechanism involves a spin-forbidden incorporation of dissolved oxygen as a triplet, which is presumably kinetically slow. This review …

Identification Of Phosphorous Loading Point Source Facilities To 303(D) Listed Nutrient Impaired Waters Through Watershed Delineation Using Arcgis For Life Cycle Assessment Applications, John Zimmerman

Chemical Engineering Undergraduate Honors Theses

The work done for this project is part of a larger “life cycle assessment (LCA) of novel electrochemical phosphorus recovery technology at the wastewater treatment plant and U.S. watershed scales” (Morrissey 2019). The goal of that LCA is to determine “environmental impacts of implementing electrochemical struvite recovery at the wastewater treatment plant, U.S watershed, and global scales” (Morrissey 2019). This project’s goal is to identify locations deemed more sensitive to eutrophication impacts. The results will be used as part of the life cycle inventory (LCI) accounting for geographically explicit phosphorus flows. The waters identified as impaired were sourced from the …

Comparison Of The Resistance Of Belitic Calcium Sulfoaluminate Cement And Portland Cement To Sulfate Attack And Sulfuric Acid, Rilye Dillard

Graduate Theses and Dissertations

Microbially induced corrosion (MIC) is a fairly common concrete deterioration mechanism with many negative effects. MIC is a complex chemical and biological process that occurs in sewage systems and is nearly impossible to replicate in a laboratory setting. For this study, sulfate and sulfuric acid attack on concrete were studied to mimic two stages of the MIC process. The ASTM C1012, Standard Test Method for Length Change of Hydraulic-Cement Mortars Exposed to a Sulfate Solution and a modified ASTM C1012 accelerated method were used to compare the sulfate resistance of belitic calcium sulfoaluminate (BCSA) cement, portland cement (PC), and PC-fly …

Analysis Of Shear-Strength In Weathered Shale Strata Along A Highway Slope Failure Site In Northwest Arkansas, Olivia Overton

Civil Engineering Undergraduate Honors Theses

Slope failures cost millions of dollars per year to repair and can be deadly. Accurate modeling of slope conditions, including soil parameters, water table locations, and depth to bedrock, are essential to determining the overall stability of a slope. This project is a continuation of the work completed in 2019 by a former University of Arkansas researcher, Vanessa LeBow. LeBow RocScience used Slide2 modeling software to model two highway embankment slopes in Northwest Arkansas that experienced slope movement to determine whether increased use of geophysical data could increase the accuracy of slope stability models. A parametric study of shear strengths …

Low Impact Development: Low-Maintenance Design To Encourage Residential Adoption Of Sustainable Systems, Haley Ellis

Biological and Agricultural Engineering Undergraduate Honors Theses

Residential adoption of low-impact development (LID) technology can positively impact downstream watershed hydrology by reducing total volumetric discharge from the residential site. This reduction can provide economic, environmental, and social benefits for the residents as well as the community at large. Additionally, homeowners are often affected by stormwater related issues, like flooding or washout, that could be easily mitigated with a sustainably engineered LID structure or network. Engineering for sustainability often includes the blending of several objectives to provide greater overall benefit. This thesis compares the outflow characteristics of three low-maintenance residential LID design scenarios differing in rain garden soil …

Moisture Monitoring Of A Clt Structure In A Southern Climate, Elizabeth Poblete

Graduate Theses and Dissertations

Understanding of moisture behavior in cross laminated timber (CLT) is critical to the widespread use of CLT in construction in the United States. Currently, very little data exists on the long-term impact of moisture on CLT. The objective of this research is to collect data regarding the long-term moisture variation in the CLT panel at the University of Arkansas Adohi Hall residence hall. The climate of Northwest Arkansas is different from previously monitored buildings, as they were in the Pacific Northwest. Comparatively, Northwest Arkansas has a warmer climate with higher average annual precipitation. Waterproofing efforts are usually employed to prevent …

Surface Modified Polypropylene Membranes For Treating Hydraulic Fracturing Produced Waters By Membrane Distillation, Tharaka Hawpe Gamage

Graduate Theses and Dissertations

Membrane distillation is an emerging technology for treating hydraulic fracturing flowback and produced waters. Suppression of membrane fouling by inorganic and polar and non-polar organic compounds is a challenge. Here polyhydroxyethyl methacrylate, polyacrylic acid, polvinylallyl imidazolium bromide and polyvinylhexyl imidazolium bromide chains have been grafted from the membrane surface. Fouling is initially due to adsorption of organic compounds followed by scale formation. When challenged with produced water, membranes modified with polvinylallyl imidazolium bromide chains provided the greatest resistance to fouling. For EC pretreated produced water and synthetic produced water that contained mainly inorganic species, the flux decline was much less.

Irrigation Design In Montana: Accommodating Varying Water Accessibility Across The Continental Divide., John Garrett Lampson

Biological and Agricultural Engineering Undergraduate Honors Theses

The design work performed in this project was conducted over two summers (2018, 2019) of internship experience with the Natural Resources Conservation Service (NRCS) across the state of Montana. The first summer’s design work was based out of Glendive, MT, in Dawson County, approximately 50 kilometers from the North Dakota border. The second summer was in Missoula, MT, in Missoula County, near the Idaho border. The two areas differ significantly in topography, weather, and water availability with the main separating geographic influence being the Rocky Mountains.

This paper focuses on the design process and requirements for two farms located outside …

Discovering Synergies Among Sustainable Rating Systems In Green Roof Analysis, Kanaan Hardaway

Biological and Agricultural Engineering Undergraduate Honors Theses

As awareness has grown of the impacts the built environment has on the natural environment and the human psyche, methods to create more sustainable living environment have been developed. Green infrastructure is well-known for its environmental benefits. Emerging literature suggests green infrastructure have aesthetic qualities conducive to mental restoration, as well. To analyze the multi-benefits of green infrastructure, a green roof is studied for its aesthetic qualities and its impact on LEED, SITES, and WELL certification. A questionnaire was administered to individuals on the University of Arkansas campus to quantify human perceptions and attitudes toward a green roof on a …

Cytotoxicity And Mutagenicity Of Disinfection Byproduct Mixtures Formulated Using Free Chlorine And Monochloramine, Yonas Ghebremedhin

Graduate Theses and Dissertations

Bioassays have been used extensively to assess various toxicity endpoints of drinking water disinfection byproducts (DBPs), but an emphasis on single compounds prevails. In this research, DBP mixtures were assessed using a cytotoxicity test with Chinese Hamster Ovary (CHO) cells and an Ames fluctuation test with Salmonella typhimurium TA-98 and TA-100 with and without S9 rat liver homogenate. Seven whole mixture DBP concentrates were formulated using reconstituted natural organic matter (NOM) extracts from the Upper Mississippi River using scaled disinfectant dosing protocols with free chlorine and monochloramine in the presence and absence of added bromide. DBPs were identified by gas …

Silver-Based Microbial Check Valve For Spacecraft Potable Water Systems, Tanner Burns

Chemical Engineering Undergraduate Honors Theses

As human space exploration increases, the development of a more efficient potable water treatment system suited for spacecraft becomes crucial. This Waste-management Education Research Consortium (WERC) challenge was designed to explore the viability of microbial control through the utilization of silver ions as a biocide for possible integration into the Tranquility Node 3 water purification system aboard the International Space Station (ISS). Current systems using iodine risk causing hyperthyroidism from overexposure; however, silver can be safely ingested without this side effect. After researching silver delivery methods including electrochemical ion production, controlled release, or a combination of the two, our team …

Development Of A Multimode Instrument For Remote Measurements Of Unsaturated Soil Properties, Sean Elliott Salazar

Graduate Theses and Dissertations

The hydromechanical behavior of soil is governed by parameters that include the moisture content, soil matric potential, texture, and the mineralogical composition of the soil. Remote characterization of these and other key properties of the soil offers advantages over conventional in situ or laboratory-based measurements: information may be acquired rapidly over large, or inaccessible areas; samples do not need to be collected; and the measurements are non-destructive. A field-deployable, ground-based remote sensor, designated the Soil Observation Laser Absorption Spectrometer (SOLAS), was developed to infer parameters of bare soils and other natural surfaces over intermediate (100 m) and long (1,000 m) …

Recovery Of Water And Salts From Hyper-Saline Mine Water Using Freeze Crystallization, Miriam Gonzalez

Chemical Engineering Undergraduate Honors Theses

In the mining industry, usage of large volumes of water enables mines to conduct multiple processes within one location. Hypersaline brine waters exit the processes of the mine to be utilized for other roles; some of these roles include leaching, recirculation, and extraction operations. These waters are highly concentrated with salt components and are released to different sections of the mine. The salts of highest concentration in the brine are aluminum sulfate and magnesium sulfate heptahydrate, along with low concentrations of many other elements. There are multiple ways to recover purified water from the brine solution: freeze crystallization, evaporative processes, …

Removal And Reuse Of Phosphorus As A Fertilizer From Cafo Runoff, Hannah Young

Chemical Engineering Undergraduate Honors Theses

Eutrophication is the process in which nutrient saturated waters promote algal blooms on the surface of the water. This limits the amount of dissolved oxygen content in the water, effectively limiting the range of species that can survive in a body of water. Concentrated animal feeding operations (CAFO) can contribute to this issue. The animals in a CAFO produce large amounts of nutrient-rich waste streams that can enter natural waterways if not properly managed and increase the problem of eutrophication. The ability to treat these waste streams and recover the excess nutrients would allow for not only the reduction of …

Silver-Based Microbial Check Valve For Spacecraft Potable Water Systems, Rogelio E. Garcia

Chemical Engineering Undergraduate Honors Theses

As human space exploration increases, the development of a more efficient potable water treatment system suited for spacecraft becomes crucial. This Waste-management Education Research Consortium (WERC) challenge was designed to explore the viability of microbial control through the utilization of silver ions as a biocide for possible integration into the Tranquility Node 3 water purification system aboard the International Space Station (ISS). Current systems using iodine risk causing hyperthyroidism from overexposure; however, silver can be safely ingested without this side effect. After researching silver delivery methods including electrochemical ion production, controlled release, or a combination of the two, our team …

Internal Design Of A Hydroponics Greenhouse For Tri Cycle Farms, Sarah Gould

Biological and Agricultural Engineering Undergraduate Honors Theses

Hydroponics is the agricultural technique of growing plants without soil, using other growing media and added nutrients in a solvent. It is an attractive agricultural method over conventional agriculture because it is more water efficient, is less labor intensive, yields higher quality crops in less time, and is easier to control. According to the Digital Journal, “hydroponics crop value is anticipated to grow to USD 27.29 Billion by 2022 at an estimated CAGR of 6.39% from 2015 to 2020” (Sawant, 2016). Alongside this growing market acceptance for hydroponics, there is also a local demand that requires only a small transportation …

Removal And Reuse Of Phosphorus As A Fertilizer From Cafo Runoff, Kristin Moore

Chemical Engineering Undergraduate Honors Theses

Eutrophication is the process in which nutrient saturated waters promote algal blooms on the surface of the water. This limits the amount of dissolved oxygen content in the water, effectively limiting the range of species that can survive in a body of water. Concentrated animal feeding operations (CAFO) can contribute to this issue. The animals in a CAFO produce large amounts of nutrient-rich waste streams that can enter natural waterways if not properly managed and increase the problem of eutrophication. The ability to treat these waste streams and recover the excess nutrients would allow for not only the reduction of …

Effectiveness Of Titanium And Iron Nanoparticles In Treating M. Aeruginosa For Harmful Algal Bloom Remediation, Natalie Von Tress

Biological and Agricultural Engineering Undergraduate Honors Theses

Harmful Algal Blooms (HABs) are a growing issue worldwide, posing harm to both aquatic ecosystems and drinking water quality. This issue could be potentially mitigated using nanoparticle (NP) treatment, simultaneously removing cyanobacteria and associated cyanotoxins in HABs. This research seeks to discern the effectiveness of using titanium dioxide and iron (III) oxide NP treatment at removing cyanobacteria via flocculation and sedimentation. Each NP at 25 mg/L and 50 mg/L were used to treat suspended culture of Microcystis aeruginosa, the representative cyanobacteria, up to 72 hours. Cell concentration and morphology in the supernatant were measured via a Coulter counter and …

Ecological Co2 Flux Of A Green Roof Ecosystem And A Typical Grassland Ecosystem, Madeline Oxner

Biological and Agricultural Engineering Undergraduate Honors Theses

The Hillside Auditorium Green Roof is a low impact development feature on the University of Arkansas campus. It retains storm water and allows plants living on the roof to take up and transpire the water. Green roofs work to mimic natural ecosystems in urban environments. A key property is ecosystem respiration, which plays a large role in the global carbon cycle and is an important biologic activity indicator. The ecosystem respiration of Hillside Auditorium Green Roof was compared to a typical grassland ecosystem at the University of Arkansas farm to determine how closely the green roof is able to mimic …

Towards Environmentally Sustainable And Cost-Effective Food Distribution In The U.S., Jasmina Burek

Graduate Theses and Dissertations

Distribution centers (DCs) and supermarkets have an important role in food sustainability, but no previous research has accounted for their environmental impact. The purpose of this research was to assess environmental sustainability of grocery, perishables, and general merchandise DCs; to estimate food storing and retailing impact; and to provide cost-effective strategies to reduce DCs’ environmental impacts. The importance and relevance of the research is threefold: improving sustainability of DCs, food storing, and food retailing. The main method used in this research was the life cycle assessment (LCA) method. An initial study calculated environmental impacts of the Wal-Mart Stores, Inc. DCs, …

Accumulation Of Lead By Biofilms In Drinking Water Distribution Systems, Kaleb Oren Belcher

Graduate Theses and Dissertations

Recent crises, such as the one in Flint, MI, indicate that lead exposure from drinking water is a major health concern in the United States. Over six million lead service lines are still in use in the United States, and a universal protocol to safely remove these lead service lines from drinking water distribution systems has not yet been established. This paper calls to attention the potential hazard that biofilms pose as a source of lead in distribution systems, even after the removal of lead pipes. This study used a simulated water distribution system containing a lead source pipe and …

Assessing Biofiltration Without Ozonation For Removal Of Trihalomethane Precursors In Drinking Water At The Beaver Water District Drinking Water Treatment Plant, Sana Ajaz

Graduate Theses and Dissertations

Biofiltration without pre-ozonation has the capability to remove natural organic matter (NOM) fractions that serve as precursors of disinfection byproducts (DBPs), which include the four regulated trihalomethanes (THMs) and dichloroacetonitrile (DCAN). Rapid small-scale column tests (RSSCTs) and Pilot Plant filters operated at empty-bed contact times (EBCTs) of 4, 8, and 16 minutes were used to evaluate the performance of nutrient-amended (free ammonia and phosphorus) biofiltration for THM and DCAN precursor removal, as measured using formation potential (FP) tests. NOM surrogates – which include dissolved organic carbon (DOC), specific ultraviolet absorbance (SUVA254) and fluorescence-PARAFAC components – were measured weekly throughout the …