Environmental Engineering Commons^™

Evaluating Stormwater & Carbon Benefits Of Urban Street Trees, Anthony J. Rodriguez Diaz

Theses

Urban areas experience a multitude of environmental challenges, including flooding and air pollution. In response to these pressures, urban forests have emerged as an essential nature-based strategy to enhance resilience and reduce climate-related risks. The implementation and expansion of urban street trees further contribute to this effort by mitigating stormwater runoff and reducing atmospheric carbon emissions.

Fortunately, advances in environmental modeling have made it increasingly possible to quantify these ecosystem services using specialized software. The United States Department of Agriculture (USDA) Forest Service's i-Tree suite exemplifies this progress. The software provides a comprehensive set of tools designed to quantify environmental …

An Inquiry Into The Physics Of Mixing And Floc Filtration, Andrew P. Pennock

Dissertations

Flocculation and clarification are two essential processes to deliver safe water at a reasonable cost to consumers. There are two major thrusts to the research presented in this dissertation. The first is to better characterize the physics and mixing parameters used for the design of hydraulic flocculators in the context of drinking water treatment plants. The second major thrust is to investigate floc filtration as a mechanism for the removal of primary particles during floc blanket clarification.

The intensity of mixing in environmental and chemical engineering applications is often characterized by the Camp and Stein velocity gradient. This parameter has …

Electrified Membrane For Water Treatment And Resource Recovery: Advancing Multiscale Strategies In Gas-Involving Reactions, Jianan Gao

Dissertations

Multifunctional, modular, and scalable water treatment technologies that operate without chemical additives are crucial for addressing global water pollution challenges. While traditional membrane-based separation processes are crucial for ensuring clean water supplies, they primarily focus on pollutant removal rather than on the upcycling of pollutants into valuable resources. Electrified membrane filtration presents a robust alternative, utilizing minimal or no chemical additives and harnessing electrical power to directly reduce contaminants or produce reactive oxidants or reductants on-site.

This dissertation is dedicated to the development of innovative electrochemically reactive membranes designed to address three major challenges: (1) the engineering of electrocatalysts with …

Microwave Catalysis-Enabled Membrane Processes For Microbial Inactivation, Fangzhou Liu

Dissertations

The COVID-19 pandemic has highlighted the urgent need for advanced technologies to combat virus transmission. Traditional membrane filtration technologies primarily serve as physical barriers, capturing pollutants but failing to inactivate microbial agents such as bacteria and viruses. These membranes typically target larger particles but are ineffective against sub-micrometer viral particles. Thus, there's a critical demand for membrane filtration processes that combine robust filtration with antifouling and reaction -enabled functions for efficient pathogen disinfection. This research explores a novel microwave-assisted membrane filtration process incorporating catalytic reactions to enhance microbial disinfection and prevent membrane fouling, offering a groundbreaking solution to global challenges …

A Molecular Dynamics Study On The Destruction Mechanism Of Per And Polyfluoroalkyl Substances Due To Ultrasound Technology, Bruno Bezerra De Souza

Dissertations

Per- and polyfluoroalkyl substances (PFAS) are a group of stable synthetic chemicals that are highly persistent and harmful pollutants to the environment and human health. PFAS have caused a strong public and regulatory response due to their ubiquitous presence in the environment and toxicity to humans. The application of ultrasound is one of the most effective treatment technologies for the mineralization of PFAS in contaminated water. However, this technology is treated as a black box causing the inability to be optimized. Therefore, there is a pressing need to investigate the intricate dynamics of PFAS degradation under ultrasound to unlock its …

Microplastic Abundance And Removal In Stormwater Using Green Infrastructure, Meghana Parameswarappa Jayalakshmamma

Dissertations

Microplastics (MPs) are increasingly recognized as a pervasive environmental contaminant, conveying other contaminants, accumulating in aquatic organisms, and posing ecological risks. The existing research has primarily focused on MPs in wastewater treatment plant effluents in surface waters. However, the role of stormwater systems in MP transport has been less explored. Given the rise in MPs from urban sources, stormwater runoff from urban areas may serve as a critical conduit for transporting land-based MPs into aquatic environments. Green infrastructures (GIs) have been recognized for mitigating flooding and improving water quality from minor storms by trapping stormwater pollutants. Yet, the capability of …

Development Of Super Hydrophobic Membranes And Their Applications, Sumona Paul

Dissertations

Effective liquid phase separation is vital across industries, especially in aviation, chemicals, fuels, and textiles. Membrane technology offers advantages over traditional methods like distillation, with low energy consumption and protection for heat-sensitive molecules. Membrane performance is assessed based on factors such as materials, surface modification, and interactions. This research targets superhydrophobic membranes for liquid-liquid filtration and antiwetting omniphobic membranes for membrane distillation, focusing on properties like contact angle and thermal resistance.

This study presents a highly hydrophobic membrane achieved by immobilizing carbon nanotubes (CNTs) onto a PTFE microfiltration membrane. It's designed for dewatering organic-water mixtures with trace water content via …

Assessing The Feasibility And Mechanism Of Destructive Removal Of Per- And Polyfluoroalkyl Substances (Pfas) From Water, Kaushik Vinaykumar Londhe

Dissertations

One of the most pertinent challenges faced by the drinking water community is the widespread contamination of per- and polyfluoroalkyl substances (PFAS). These anthropogenic chemicals have been ubiquitously used in everyday products such as carpets, stain repellents, dyes, shampoos, non-stick cookware as well as in aqueous firefighting foams. PFAS are linked with adverse health effects in humans such as thyroid disease, obesity, immunological and reproductive disorders and linked to cancer in adults and low birth weight and developmental defects in infants.

Conventional water treatment technologies have proven to be largely ineffective in PFAS remediation, due to their extreme stability and …

Colloidal Behavior Of Nanobubbles And Their Application In Enhancing Plant Growth: Mechanisms Of Nanobubble Interactions With Microbial And Soil Species, Shan Xue

Dissertations

Climate change has resulted in increasing uncertainties of water resources and disturbance on agricultural activities. For example, the shortage of water resources, land erosion and pollution from runoff significantly affect agricultural sustainability. This dissertation research focuses on the fundamental studies of nanobubble (NB) water and explores the benefits for irrigation to enhance plant germination and growth. Unlike bulk bubbles, NBs exhibit prolonged stability in water and possess large surface areas that facilitate efficient mass transfer and potential tailored reactions (e.g., disinfection). However, the enhancement mechanisms for NBs on seed germination and plant growth remain elusive.

This research first evaluated the …

Faceted Nanomaterial Synthesis, Characterizations And Applications In Reactive Electrochemical Membrane Filtration, Qingquan Ma

Dissertations

Facet engineering of nanomaterials, especially metals and metal oxides has become an important strategy for tuning catalytic properties and functions from heterogeneous catalysis to electrochemical catalysis, photocatalysis, biomedicine, fuel cells, and gas sensors. The catalytic properties are highly related to the surface electronic structures, surface electron transport characteristics, and active center structures of catalysts, which can be tailored by surface facet control. The aim of this doctoral dissertation research is to study the facet-dependent properties of metal or metal oxide nanoparticles using multiple advanced characterization techniques. Specifically, the novel atomic force microscope-scanning electrochemical microscope (AFM-SECM) and density functional theory (DFT) …

Bioremediation Of Petroleum Hydrocarbons In Coastal Sediments, Charbel Abou Khalil

Dissertations

The biodegradation of dispersed crude oil in the ocean is relatively rapid (a half-life of a few weeks). However, it is often much slower on shorelines, usually attributed to low moisture content, nutrient limitation, and higher oil concentrations in beaches than in dispersed plumes. Another factor may be the increased salinity of the upper intertidal and supratidal zones since these parts of the beach are potentially subject to prolonged evaporation and only intermittent inundation. Therefore, two laboratory experiments are conducted to investigate whether such an increase in porewater salinity results in additional inhibitory effects on oil biodegradation in seashores.

In …

Formation Of Oil Particle Aggregates And The Impact On The Fate Of Oil, Wen Ji

Dissertations

Spilled oil slicks are likely to break into droplets offshore due to wave energy. The fate and transport of such droplets are affected by suspended particles in local marine environment, through forming oil particle aggregates (OPAs). OPA formation is affected by various factors, including the properties of the particles and oil, the mixing energy and duration, etc. To investigate the impact of these factors, lab scale experiments are conducted by using seawater (both artificial and natural) and kaolinite and silica to simulate the formation of OPAs in baffled flasks. In the first experiment, 9 gm and 3 gm spherical silica …

Understanding The Interfacial Processes Of Reactive Nanobubbles Toward Agricultural Applications, Xiaonan Shi

Dissertations

There is a growing interest in nanobubble (NB) technology because of its diverse applications (e.g., detergent-free cleaning, water aeration, ultra-sound imaging and intracellular drug delivery, and mineral processing). NBs have a higher efficiency of mass transfer compared to bulk scale bubbles due to the high specific surface areas. The high specific surface also facilitates physical adsorption and chemical reactions in the gas liquid interface. Furthermore, the collapse of NBs creates shock waves and the formation of hydroxyl radicals (OH).

However, it remains elusive why or how NBs are stabilized in water and particularly, the states of internal pressures of NBs …

Reactive Iron Mineral Coatings In Redox Transition Zones Of A Site With Historical Contamination: Abiotic Attenuation, Xin Yin

Dissertations

Reactive iron mineral coatings are found throughout reduction-oxidation (redox) transition zones and play a significant role in contaminant transformation processes. In this study, an 18.3-meter core is collected, subsampled, and preserved under anoxic conditions to maintain its original redox state. Screening analyses are conducted at sampling increments of 5.08 cm in depth for the following: elemental concentrations with X-ray fluorescence (XRF), sediment pH, sediment oxidation-reduction potential (ORP), total volatile organic carbon (TVOC) in the sample headspace, and abundant bacteria (16S rRNA sequencing). Using the Fe and S gradients correlated with microbial data, five RTZs are delineated. To characterize iron mineral …

The Role Of Microorganisms In Rare Earth Elements Bioaccumulation, Maedeh Soleimanifar

Dissertations

Rare earth elements (REE) are valuable raw materials in our modern life. Extensive REE application from electronic devices to medical instruments and wind turbines, and non-uniform distribution of these resources around the world, make them strategically and economically important for countries. Current REE physical and chemical mining and recycling methods could have negative environmental consequences, and biologically-mediated techniques could be applied to overcome this issue.

In this research, the first objective is to investigate the bioextraction of cerium oxide and neodymium oxide nanoparticles (REE-NP) by a pure culture Methylobacterium extorquens AM1 (ATCC®14718™). Results show that adding up to 1,000 ppm …

Characterizing Reactive Iron Mineral Coatings And Their Roles In Natural Attenuation At A Site With Historical Contamination, Han Hua

Dissertations

Reactive iron mineral coatings in redox transition zones play an important role in contaminant attenuation. These mineral coatings include poorly crystalline to crystalline iron sulfides, carbonates, and oxyhydroxides, and are a signature of the biogeochemical processes occurring. To better understand these processes, reactive iron mineral coatings are characterized in an 18-m Anaerobic Core collected from a contaminated industrial site. This study targets redox transition zones uncovered in the core. A suite of complementary analyses is applied to distinguish the surface coating mineralogy using X-ray Diffraction, X-ray fluorescence, and field-emission scanning electron microscopy (FESEM) with energy dispersive X-ray analyzer (EDX). In …

The Stability Of Nanobubbles And Its Application In Contaminated Sediment Treatment, Shaini Dilsha Aluthgun Hewage

Dissertations

This dissertation consists of two sections. First, nanobubbles' stability and behavior are studied using experimental and theoretical approaches. Second, nanobubbles application combined with ultrasound to remediate contaminated sediments is discussed.

The stability study consists of four sections. (i). Laboratory investigation to determine bubble size distributions and zeta potentials for different gases, pH levels, temperatures, and salt conditions. (ii). A theoretical study based on the diffused double layer theory to explain nanobubbles' behavior in different NaCl concentrations. (iii). Nanobubbles' stability in electrolyte solutions under different ion valencies using deionized water, NaCl, Na₂SO₄, Na₃PO₄, …

Compound Flooding In Coastal Areas Emanating From Inland And Offshore Events, Hamed Behzad Koochaksaraii

Dissertations

The vulnerability of urban populations to natural hazards and climate change is a major theme in many reports on coastal cities with flooding ranking highly among the climate change concerns. Flooding could occur as a result of runoff for inland rainfall that accumulates at the mouth of the estuary to the sea or it could occur due to a storm surge emanating from the ocean. The techniques for modeling the flooding from these events are very different, as they were developed in different scientific fields: hydrology and hydraulic engineering for inland rainfall versus coastal oceanography and coastal engineering for offshore …

Enhanced Removal Of Perfluorooctanoic Acid (Pfoa) Via Microwave-Fenton-Reactive Membrane Filtration, Fangzhou Liu

Theses

Perfluorooctanoic Acid (PFOA), one of the common per- and poly fluorinated alkylated substances (PFASs), is increasingly detected in the environment due to the diverse industrial applications and high resistance to degradation processes. This study evaluated degradation of PFOA in microwave-assistant catalytic membrane filtration, a process that integrates microwave catalytic reactions into a ceramic membrane filtration. First, water permeation of the pristine and catalyst-coated membranes were examined under the influence of microwave irradiation to analyse the impacts of the coating layer and water temperature increase on permeate flux, which were well interpreted by three models. Then, the PFOA removal was first …

Electrochemically Reactive Membranes For Efficient Biomass Recovery, Pollutant Degradation And Commercialization, Likun Hua

Dissertations

Micropollution in natural waters such as rivers and groundwater aquifers is a widespread problem that prevents these potentially potable sources from being used as drinking water. In the United States, approximately two-thirds of the over 1,200 most serious hazardous waste sites in the nation are contaminated with trichloroethylene (TCE), a potentially carcinogenic compound. Other emerging and environmentally persistent organic micropollutants include polyromantic hydrocarbons (PAHs), organophosphate flame retardants, endocrine disrupting compounds (EDCs), pesticides, herbicides, pharmaceuticals and personal care products (PPCPs). Membrane filtration is one of the most efficient separation processes widely used for water treatment and pollutant removal. However, traditional membrane …

Fouling And Aging In Membrane Filtration : Hybrid Afm-Based Characterization, Modelling And Reactive Membrane Design, Wanyi Fu

Dissertations

Membrane filtration has been extensively used in water and wastewater treatment, desalination, dairy making, and biomass/water separation. However, membrane fouling, aging and insufficient removal efficiency for dissolved organic matters remain major challenges for wider industrial applications. In order to tackle these challenges, this doctoral dissertation investigates mechanisms of membrane fouling and development of antifouling membrane filtration technologies. Specifically, four major research areas are explored: (i) nanoscale physicochemical characterization of the chemically modified polymeric membranes; (ii) quantitative modelling between membrane properties and membrane fouling and defouling kinetics; (iii) development of quantitative structure-activity relationships for membranes that undergo thermal and chemical aging …

Methods To Improve The Remediation Of Polycyclic Aromatic Hydrocarbons (Pahs) In Aerobic And Anaerobic Environments, Brian Wartell

Dissertations

Oil spills occur regularly in terrestrial environments and crude oil can contain many compounds that are highly resistant to degradation. Among these compounds are high levels of polycyclic aromatic hydrocarbons (PAHs) which are not only toxic but can also be carcinogenic and/or mutagenic. The first chapter of this dissertation includes an extensive review chapter on the variables affecting the anaerobic degradation of hydrocarbons, with a particular focus on PAHs. Electron acceptors, electron donors, temperature, salinity, pH all play key roles in determining the possibility effective of effective degradation occurring. Thus, by addressing solutions, such as biostimulation, improving environmental variables for …

Experimental And Numerical Characterization Of Multiphase Subsurface Oil Release, Feng Gao

Dissertations

Subsurface oil release is commonly encountered in the natural environment and engineering applications and has received the substantial attention of researchers after the disastrous Deepwater Horizon Blowout oil spill in 2009. The main focus on the present research is to systematically study the hydrodynamics of underwater oil jet under a variety of conditions, including the effect of dispersant and different gas to oil ratios (GOR) by using experimental measurement as well as a Computational Fluid Dynamics (CFD) approach, from which the measured turbulent characteristics (e.g., velocity, turbulent kinetic energy, turbulence dissipation rate, etc.) of underwater oil jet are thoroughly examined …

Estimating Vehicles Emissions At Signalized Intersections In The Highway Capacity Manual, Yuanyuan Fan

Dissertations

Over the past decades, motor vehicle volumes have continued to increase at a high rate. As a result, engineers in the transportation field not only need more robust knowledge of traffic operation control and transportation planning, but more attention is also needed to understand and estimate the influences that this increasing volume of vehicles has on the environment, especially the influence on air quality. The EPA has stated that reducing carbon monoxide (CO) from vehicle emissions is the most significant way to control air pollution from the transportation sector.

The Highway Capacity Manual is a national and international resource that …

Biologically Active Filters: An Advanced Treatment Process For Pharmaceuticals And Personal Care Products, Shuangyi Zhang

Dissertations

With the increasing concern of pharmaceuticals and personal care products (PPCPs) in source water, this study examines the hypothesis that existing filters and adsorbents in water treatment plants can be converted to biologically active filters (BAFs) to treat these compounds. Removals through bench-scale BAFs are evaluated as a function of media, granular activated carbon (GAC) and dual-media, empty bed contact time (EBCT), and pre-ozonation. For GAC BAFs, greater oxygen consumption, increased pH drop, and greater DOC removal normalized to adenosine triphosphate (ATP) are observed indicating a different microbial community compared to dual-media BAFs. ATP concentrations in the upper portion of …

Effectiveness Of Water Quality Benefits Provided By Stormwater Management Facilities/Infiltration Basin, Vinicius Rodrigues De Mattos Barreto

Theses

Stormwater Best Management Practices (BMP) and devices are systems frequently built under assumed design performances, but rarely verified after construction. Their effectiveness in protecting the environment against pollutants carried by stormwater runoff has been extensively questioned and investigated. This research presents a case study of an infiltration basin in Medford, NJ to verify if the 80% expected Total Suspended Solids (TSS) removal as stated in the New Jersey Stormwater BMP Manual is actually achieved. A sampling pit was installed on the site and infiltrated water samples were collected during three rain events and TSS measurements were compared with the inflow. …

Fates Of Spilt Oil And Factors Affecting The Bio-Degradation Of Oil: A Review, Amogh-Ranganath Chakravarthy

Theses

The usage of crude oil and its products is increasing; in turn, the number of spills is also going up. The inland spills are the more recurrent spills in the U.S today. This review article deals with the weathering of oils, which commences just after oil spills into the environment with various processes such as evaporation, dissolution, photo-oxidation, dispersion, emulsification and bio-degradation along with other possible fates. Biodegradation is one of the most significant processes of weathering which depends on oil physical and chemical characteristics, environmental characteristics, pH, salinity and oil concentration. There is a range of oil concentration for …

Physical Controls On Water Flow And Solute Transport In Coastal Aquifers, Xiaolong Geng

Dissertations

Groundwater flow and associated subsurface solute fates have a significant impact on the structure and productivity of near-shore coastal ecosystems. For proper assessment and management of these coastal groundwater resources, it is quite essential to investigate the key factors (tides, waves, evaporation, and freshwater recharge etc.) affecting coastal groundwater systems. The main objective of this study is to examine and quantify two important physical control factors, oceanic waves and evaporation, on the groundwater flow and solute transport in near-shore aquifers. For the investigation of wave effects, a Computational Fluid Dynamics (CFD) modeling tool, Fluent, is used to simulate wave- induced …

Field Methods For Rapidly Characterizing Contaminant Mobility In Paint Waste During Bridge Rehabilitation, Zhan Shu

Dissertations

Currently, the New York State Department of Transportation (NYSDOT) uses a conservative approach of classifying all paint waste as hazardous from bridges undergoing rehabilitation which were constructed before 1989. This practice stems from the fact that there is no approved reliable, fast, and efficient method for classifying paint waste in-situ as non-hazardous. The main objective of this study was to develop a model that can predict the leachability of trace metals in paint waste generated during bridge rehabilitation. A statistically significant number of bridge sites were sampled based on hypothesis testing. Samples were then evaluated for total concentration of Resource …

Analyses Of Groundwater Contribution To A Riverine Wetland, Farzad Mahmoodinobar

Dissertations

Rainfall, runoff, overbank flow and groundwater, all contribute water to wetlands. Each transport element is associated with unique modeling approaches and uncertainties. Transpiration is perhaps the hardest to quantify as it is subject to all the variability of plant growth. Transpiration causes land area to lose moisture and the loss amount depends on precipitation incidence, the temperature and type and extent of vegetation. Plants can intercept virtually all recharge during the growing season and almost none from late fall to early spring in northeastern United States. Thus, an improvement in the transpiration element can contribute considerably to an improved groundwater …