Environmental Engineering Commons^™

Trihalomethane, Dihaloacetonitrile, And Total N-Nitrosamine Precursor Adsorption By Carbon Nanotubes: The Importance Of Surface Oxides And Pore Volume, Erin Needham

Graduate Theses and Dissertations

As drinking water sources become increasingly impaired, enhanced removal of natural organic matter (NOM) may be required to curb formation of disinfection byproducts (DBPs) upon chlor(am)ination. While carbon nanotubes (CNTs) can adsorb NOM, their properties for DBP precursor adsorption have not been elucidated. Nine types of CNTs were assessed for trihalomethane (THM), dihaloacetonitrile (DHAN), and total N-nitrosamine (TONO) precursor adsorption. Batch isotherm experiments were completed with lake water and, to simulate an impaired condition, effluent from a wastewater treatment plant (WWTP). Adsorption varied with CNT type and dose, with TONO precursors having the highest percent removals from WWTP effluent (up …

Understanding N-Nitrosodimethylamine Formation In Water: Chloramine Chemistry, Kinetics, And A Proposed Reaction Pathway, Huong Thu Pham

Graduate Theses and Dissertations

The formation of N-nitrosodimethylamine (NDMA) in drinking water systems is a concern because of its potential carcinogenicity and occurrence at toxicologically relevant levels. The postulated mechanism for NDMA formation involves a substitution between dichloramine and amine-based precursors to form an unsymmetrical dimethylhydrazine (UDMH), which is then oxidized by ground-state molecular oxygen to form NDMA. However, this latter reaction is spin forbidden, thus likely occurs at a slow rate. It is hypothesized that the reaction between monochloramine and hydroxylamine (a nitrification product) may form an intermediate, which is involved in the NDMA formation pathway. This intermediate may also be generated from …

Impact Of Rfid Information-Sharing Coordination Over A Supply Chain With Reverse Logistics, Juan Jose Nativi Nicolau

Open Access Dissertations

Companies have adopted environmental practices such as reverse logistics over the past few decades. However, studies show that aligning partners inside the green supply chain can be a substantial problem. This lack of coordination can increase overall supply chain cost. Information technology such as Radio Frequency Identification (RFID) has the potential to enable decentralized supply chain coordinate their information. Even though there are research that address RFID on traditional supply chain, few researches address how to coordinate RFID information sharing in a green supply chain. We study, through simulation experiments, two types of RFID information-sharing coordination under different configurations related …

Evaluating The Two-Stage Ditch As A New Best Management Practice, Andi Hodaj

Open Access Dissertations

A two-stage ditch involves modifications of a traditional drainage ditch to resemble more the features of a natural stream. The idea is to create or simulate extended benches on both sides of the ditch that would develop naturally over a period of time in a stream because of geomorphological processes. Previous research in Indiana and Ohio has shown that two-stage ditches offer the potential to reduce sediment load and extend the interaction time between water and vegetation on the benches allowing larger uptake of nutrients from the vegetation on the extended benches, and increasing the denitrification rates in the bench …

Reactions Of Graphene Oxide And Buckminsterfullerene In The Aquatic Environment, Yingcan Zhao

Open Access Dissertations

Due to unique physical and chemical properties, carbon-based nanomaterials, including C60 and graphene oxide, now being used in an increasing number of applications. Considering their widespread use, nanoparticles will inevitably find their way to the natural environment. However, their environmental fate and transport have not been intensively explored, resulting in a general lack of knowledge regarding their risk assessment and life cycle exposure concentrations. To this end, this study has investigated: (i) the photo mineralization of aqu/nC60 clusters under photo irradiation, and (ii) environmental transformation of graphene oxide in the aquatic environment. This study shows that CO2 was produced from …

Mapping And Analyzing Energy Use And Efficiency In A Modified Hydroponic Shipping Container, Rachel E. Sparks

Open Access Theses

In urban centers today, vertical farming is becoming a popular alternative to conventional agriculture in an effort to increase local food production and improve urban food security by growing crops using hydroponic methods in controlled environment spaces. More specifically, one vertical method involves growing crops inside refurbished shipping containers, or a “farm-in-a-box” concept, which offers a flexible, mobile, and scalable means of year-round food production in a variety of climates. Despite benefits of producing food locally, some of the concerns associated with these vertical farming systems include high energy consumption from climate control and electric lighting systems as well as …

Influence Of Stormwater Control Measures On Watershed Hydrology And Biogeochemical Cycling, Colin D. Bell

Open Access Dissertations

Urban development replaces vegetation with impervious surfaces and natural drainage channels with pipe networks that quicken flow paths and alter hydrologic regimes. Additionally, the import of food, application of fertilizer to lawns and gardens, and heightened atmospheric deposition increases nutrient availability in urban landscapes. These excess nutrients are ultimately routed to streams through the pipe networks before it can be processed by the vegetation and microorganisms of the landscape. This combination of physical and chemical disturbances impacts stream ecosystems and degrades their ability to perform valuable services such as removal of nutrients, degradation of pollutants, and provision of recreational and …

The Role Of Organic Matter In The Fate And Transport Of Antibiotic Resistance, Metals, And Nutrients In The Karst Of Northwest Arkansas, Victor Lee Roland Ii

Graduate Theses and Dissertations

Organic matter (OM) in the environment acts as a nutrient, but may also act as a transport vector for harmful chemical compounds and bacteria. Acetate is a labile form of OM produced during fermentation in anaerobic lagoons used to store animal fecal-waste from concentrated animal feeding operations (CAFOs). Dry and liquid fertilizers from CAFOs pose a threat to groundwater by introducing excessive amounts of nutrients (e.g. OM, nitrate and ammonia), metals, and antibiotic compounds. In the epikarst of Northern Arkansas in the Buffalo River watershed additional input of labile dissolved organic carbon (DOC) from liquid CAFO waste-fertilizers was hypothesized to …

Nanofiltration Rejection Of Contaminants Of Emerging Concern From Municipal Water Resource Recovery Facility Secondary Effluents For Potable Reuse Applications, Steven Michael Jones

Graduate Theses and Dissertations

As reuse of municipal water resource recovery facility (WRRF) effluent becomes vital to augment diminishing fresh drinking water resources, concern exists that conventional barriers may prove deficient and the upcycling of contaminants of emerging concern (CECs) could prove harmful to human health and aquatic species if more effective and robust treatment barriers are not in place.

There are no federal Safe Drinking Water Act (SDWA) regulations in place specifically for direct potable reuse (DPR) of WRRF effluent. Out of necessity, some states are developing their own DPR reuse regulations. Currently, reverse osmosis (RO) is the default full advanced treatment (FAT) …

Simulation Of Conservation Practice Effects On Water Quality Under Current And Future Climate Scenarios, Carlington W. Wallace

Open Access Dissertations

Analysis of the effects of implementing different conservation practices, as well as increased levels of conservation practices under existing and projected future climate, will determine if current conservation practice recommendations will be sufficient to maintain soil and water resources. The Soil and Water Assessment Tool (SWAT) was used to study four watersheds of different sizes (CCW = 680 km2, F34 = 183 km2, AXL = 42 km 2 and ALG = 20 km2) located in Northeastern Indiana. The overarching goal of this study was to evaluate the effect of various agricultural practices on runoff and agricultural chemical losses under current …

High Voltage Rear Electric Drivetrain Design For A Parallelthrough-The-Road Plug-In Hybrid Electric Vehicle, Adam Garrett Fogarty

Open Access Theses

Purdue University was selected as one of 15 universities to participate in a three year Advanced Vehicle Technology Competition (AVTC) called EcoCar2: Plugging Into the Future. The vehicle built by the Purdue team was a Parallel-Through-The-Road Plug-in Hybrid Electric Vehicle (PTTR PHEV). The vehicle utilized a B20 diesel powertrain to power the front wheels, as well as a custom electric drivetrain to power the rear wheels. Using this vehicle during the final year of the competition, the team was successful in placing 4th overall as well as 2nd in the category of Well-To-Wheel (WTW) Greenhouse Gas Emissions. A stock 2013 …

Systematic Analysis Of Drainage Events In Free Draining And Managed Subsurface Drainage Systems, Guy Bou Lahdou

Open Access Theses

Understanding the hydrologic controls that regulate outflow from free and managed subsurface drainage systems during drainage events can offer improved insight on the overall functioning and effectiveness of the systems so that they can be better managed or retrofitted to increase their environmental benefits. This study used drainage, precipitation, water table, and soil moisture data from a monitoring site located in east central Indiana to investigate the event hydrology of 22 drainage events in free and managed subsurface drainage systems. Relationships between event drainage volume, drain flow hydrograph metrics, column soil moisture, water table depth, and precipitation characteristics were explored …

Graphical Performance Measures For Practitioners To Identify Split Failures, Richard Scott Freije

Open Access Theses

Detector occupancy is commonly used to measure traffic signal performance. Despite improvements in controller computational power, there have been relatively few innovations in occupancy-based performance measures or integration with other data. This thesis introduces and demonstrates the use of graphical performance measures based on detector occupancy ratios to verify potential split failures and other signal timing shortcomings reported to practitioners by the public. The proposed performance measures combine detector occupancy during the green interval, detector occupancy during the first five seconds of the red interval, and phase termination cause (gap out or force off). These are summarized by time of …

Experimental And Numerical Study Of The Air Distribution In An Airliner Cabin, Wei Liu

Open Access Theses

Nowadays, more people, including those with impaired health or who are otherwise potentially sensitive to the cabin environment, are traveling by air than ever before. The flying public demands a higher comfort level and a cleaner environment because they encounter a combination of environmental factors including low humidity, low air pressure, and sometimes, exposure to air contaminants such as ozone, carbon monoxide, various organic chemicals, and biological agents. Moreover, international air travel has increased the potential risks associated with airborne disease transmission and the release, whether accidentally or intentionally, of noxious substances during flight. Many studies suggest that the risk …

Attached-Growth System For Nitrification At Low Temperature, Zhe Sun

Open Access Theses

Attached-growth biological treatment systems have potential to conduct nitrification in cold-temperature climates. In this research, in order to simulate the attached-growth nitrification process (using BOBBER biological reactor) at a real wastewater treatment facility, two laboratory-scale mini-BOBBER systems were installed in a temperature-controlled room and were operated for 101 days with pure ammonium chloride feed solution. Steady-state conditions were approached at 20°C, 15°C, 10°C, and 5°C. In addition, a series of batch experiments were conducted at temperatures of 20°C and 5°C to investigate the relationship between nitrification rate and ammonia-N concentration. Results from these experiments were analyzed and compared with the …

Effectiveness Of Air Sealing Measures And Other Energy Retrofit Measures In Lafayette Energy Improvement Program, Jia Ye

Open Access Theses

From September 2011 to March 2013, the City of Lafayette, IN implemented Lafayette Improvement Program. The goal of this project was to "increase energy efficiency of existing homes through retrofitting, thereby lowering the costs of home ownership within the Vinton and Glen Acres Neighborhood Target Area (The City of Lafayette, 2011)." Energy audit companies carried out before blower door test and after blower door test to identify air tightness of subjects. This paper finds out there was an improvement in air tightness in the population of 85 houses and the degree of improvement was between 16.85% and 17.85%.

Change point …

Assessing Trichloromethane Formation And Control In Algal-Stimulated Waters Amended With Nitrogen And Phosphorus, Clinton Mash

Graduate Theses and Dissertations

Nitrogen (N) and phosphorus (P) enrichments can stimulate algal growth in drinking water sources, which can cause increased production of disinfection byproduct (DBP) precursors. However, the effect of systematic N and P enrichments on DBP formation and control has not been adequately studied. In this work, we enriched samples from a drinking water source - sampled on April 5, May 30, and August 19, 2013 - with N and P to stimulate algal growth at N:P ratios covering almost five orders of magnitude (0.2-4,429). To simulate DBP-precursor removal processes at drinking water treatment plants (DWTPs), the samples were treated with …

Assessing The Impact Of Chlorine Residual On Trihalomethane And Haloacetonitrile Formation Under Chlorination And Chloramination Disinfection Regimes, Thien Duc Do

Graduate Theses and Dissertations

A disinfection byproduct (DBP) formation potential (FP) test can be used to indirectly measure the concentration of DBP precursors in natural waters, permitting assessment of various DBP-related treatment processes and control strategies. While these tests require a 7-day chlorine residual (CR) between 3-5 mg L^-1 as Cl², it is not well known if this recommended residual corresponds to the true DBPFP (i.e., the maximum concentrations) for trihalomethanes (THMs) and haloacetonitriles (HANs). In this study, THMs and HANs were quantified as a function of CR under three common disinfection regimes: (1) free chlorine at pH 7.0 (FC7), (2) …

Adaptive Targeting: Engaging Farmers To Assess Perceptions And Improve Watershed Modeling, Optimization, And Adoption Of Agricultural Conservation Practices, Margaret Mccahon Kalcic

Open Access Dissertations

Targeting agricultural conservation practices to farmland that has the greatest impact on surface water quality has received wide support from scientists and watershed managers. The targeting approach has, however, been politically contentious as many believe farmers will oppose the approach on grounds such as privacy invasion and unfair distribution of government incentives. Targeting conservation practices using complex optimization models has become common in the scientific community, and yet targeted results are underutilized in practice because of difficulties such as knowledge transfer and absence of a political framework for their use. For targeting to be successful, it must be politically supported …

Evaluation Of Broiler Litter Heat Production During Windrowing & Nitrogen Based Gas Emission Mitigation Using Biofilter, Min Lei

Graduate Theses and Dissertations

Ammonia emission from animal feeding operations (AFOs) has negative effects on environment and animals' health. Thus measuring and mitigating ammonia emission from AFOs is important for environmental protection. In chapter I, different ammonia measurements were discussed and a mitigation technology- biofilter was represented.

In-house windrowing of built-up litter has been used by broiler producers to reduce pathogen loads and rejuvenate litter for the next flock. When litter is piled up for an extended period during downtime, heat generated by the litter pile can become a substantial heat source due to the metabolism of microorganisms. In chapter II, heat production rates …

An Evaluation Of Spatial Variability Of Water Stress Index Across The United States: Implications Of Supply And Demand In The East Vs The West, Jennifer Ann Roath

Open Access Theses

In order to support both human and environmental needs, high quality fresh water must be available when and where it is required. As a metric for indicating unsustainable water usage, WSI is only useful when the values reflect accurate interactions between supply and demand; however, the complexity of temporal and spatial variability of available fresh water complicates the analysis of water stress.

The overall goal of this project was to investigate the spatial variability of water stress across the United States and the appropriate spatial scale for management decisions. To accomplish this, a national dataset describing spatial distribution and breakdown …

Product Characterization And Headspace Analysis Of Solar Irradiated Aqueous C60 Clusters, Dan Su

Open Access Theses

Buckminsterfullerene (C60) is an important fullerene material that has drawn much attention and is currently being applied in many different fields. It was discovered in 1985. As its production has largely increased to meet these industrial needs, it is obvious that its environmental occurrence, especially in aqueous systems, will occur. To further provide information for environmental toxicity studies and for its risk assessment, this thesis focuses on the photo transformation processes of aqueous C60 clusters (Aqu/nC60), with a particular interest in measuring any mineralization that occurs under different irradiation conditions. Two sets of experiments were conducted to test for CO2 …

Nutrient Recovery From Anaerobically-Digested Dairy Manure By Struvite Formation And Its Effect On Gas Releases, Zhong Qiao

Open Access Theses

Manure management practices such as anaerobic digestion and lagoon storage have become important issues for large dairy farms partially due to water quality and air quality concerns caused by excess nitrogen and phosphorus. Prior research efforts have proven that struvite formation is an effective method for nutrients recovery from both municipal and agricultural wastewaters. However, little is known about nutrient recovery through struvite formation from anaerobically-digested dairy manure effluents.The effects of struvite precipitation on the releases of gases such as NH3, H2S, and CO2 are also unclear.

In this thesis, both bench-scale tests and pilot-scale storage tests were conducted to …

A Watershed Scale Evaluation Of Selected Second Generation Biofeedstocks On Water Quality, Gurdeep Singh

Graduate Theses and Dissertations

This study compares a novel simulation approach to the conventional Soil and Water Assessment Tool (SWAT) modeler's approach for targeting biofuel crop production on marginal lands. In conventional SWAT modeling approach, non-spatial definition of hydrological response units (HRUs) results in the simulation of biofuel crops on both marginal and non-marginal land. This study provides an alternative approach in which a marginal-land raster was integrated into the land use and land cover (LULC) raster in such a way that the land uses were divided into marginal and non-marginal components. This modified LULC was used for model setup which resulted in marginal …

Effects Of Testing Time On Anaerobic Toxicity Assessment, Omolola Atinuke Akintomide

Graduate Theses and Dissertations

Anaerobic digestion has been widely used for wastewater treatment for decades. Several Anaerobic Toxicity tests have been developed to screen wastewater for toxicity and assess the treatability of such toxicants. However, past research and reviews on Biochemical Methane Potential (BMP) test and Anaerobic Toxicity Assay (ATA) were considered in this study.

The experimental tests included ammonium-nitrogen and sodium chloride toxicity tests with varied concentration and solid retention time. These tests were designed to demonstrate the impact of ammonia- nitrogen and sodium chloride on the biological degradation process. The anaerobic test set-up includes bench-scale test reactors and respirometers used for measuring …

The Development Of A High Performance Concrete To Store Thermal Energy For Concentrating Solar Power Plants, Emerson Esmond John

Graduate Theses and Dissertations

In recent years, due to rising energy costs as well as an increased awareness of the environmental effects of greenhouse gas emissions produced through traditional forms of energy production, there is great interest in developing alternative sources of energy. One of the most viable alternative energy sources is solar energy. In particular, concentrating solar power (CSP) technologies have been identified as an option for meeting utility needs in the U.S. Southwest. These systems are required to produce electricity not only during periods of high solar radiation but also during times of reduced radiation due to cloud cover, and even extend …

New Insights Into Disinfection Byproduct Formation And Control: Assessing Dissolved Organic Matter Diffusivity And Chemical Functionality, Ashley Pifer

Graduate Theses and Dissertations

Methods were developed for application of asymmetric flow field-flow fractionation (AF4) and fluorescence parallel factor (PARAFAC) analysis to raw and treated samples from drinking water sources to improve characterizations of dissolved organic matter (DOM) and discover DOM properties correlated to disinfection byproduct (DBP) formation potential (FP). Raw water samples were collected from a reservoir, adjusted to pH 6, 7, and 8 and subjected to (1) jar tests using aluminum sulfate (alum) and (2) treatment with magnetic ion exchange (MIEX^®) resin. Both treatments were followed by DBPFP tests at pH 7. AF4 was used to size DOM in raw …

Synergy Of Alum And Chlorine Dioxide For Curbing Disinfection Byproduct Formation Potential At Central Arkansas Water, Corey W. Granderson

Graduate Theses and Dissertations

Central Arkansas Water (CAW), the water utility for Little Rock, AR, draws their source water from Lake Maumelle and Lake Winona. To curb disinfection byproduct (DBP) formation, CAW has begun retrofitting their two plants to use chlorine dioxide as an alternative primary disinfectant followed by free chlorine secondary disinfection in the distribution system. In this study, fluorescence parallel factor (PARAFAC) analysis was combined with free chlorine simulated distribution system (SDS) tests and DBP formation potential (DBPFP) tests to study the benefit of chlorine dioxide primary disinfection (CDPD) with alum coagulation. Of the DBPs screened, trichloromethane (TCM) was formed in highest …

Mathematical Modeling Of Fluid Spills In Hydraulically Fractured Well Sites, Oluwafemi Michael Taiwo

Graduate Theses and Dissertations

Improved drilling technology and favorable energy prices have contributed to the rapid pace at which the exploitation of unconventional natural gas is taking place across the United States. As a natural gas well is being drilled, reserve pits are constructed to hold the drilling fluids and other materials returned from the drilling process. These reserve pits can fail, and when they do, plant and animal life of the surrounding area may be adversely affected. This project develops a screening tool for a suitable location for a reserve pit. This work will be a critical piece of the Infrastructure Placement Analysis …

Removal Of Disinfection By-Product Precursors Using Magnetic Ion Exchange (Miex(R)): The Effects Of Ph And Source Water Variability, Sarah Cousins

Graduate Theses and Dissertations

Disinfection by-products (DBPs) form as an unintended result of drinking water disinfection, from chemical reactions between disinfectants (e.g., free chlorine) and naturally occurring dissolved organic matter (DOM). At present, 11 DBPs are regulated in treated drinking waters due to potential adverse health effects, including four trihalomethanes (THMs). Despite nearly 40 years of DBP research, compliance with DBP regulations remains a challenge for many drinking water treatment plants (DWTPs), including the four DWTPs located on the Beaver Lake Reservoir in Northwest Arkansas. Due to the high net negative surface charge on DOM, anion exchange is one potentially viable method for removing …