Environmental Engineering Commons^™

Application Of Passive Samplers For Exploring Remedial Progress In The Torch Lake Aoc And Interlake Variability Of Pcbs, Cailin B. Bishop

Dissertations, Master's Theses and Master's Reports

This study evaluates changes in dissolved polychlorinated biphenyl (PCB) concentrations in Torch Lake, Michigan, an Area of Concern shaped by decades of legacy contamination and evolving restoration policy. Passive samplers deployed across sites and seasons (2024–2025) show total PCB concentrations ranging from below detection to 110 pg/L (mean = 16.8 pg/L), representing an approximate 90% decline since 2005. Comparisons with regional reference lakes indicate no statistically significant difference (p = 0.84), suggesting concentrations may approach background atmospheric levels despite continued variability. Congener profiles indicate a shift toward lower-chlorinated PCBs, though interpretation of higher-chlorinated congeners is limited by slow sorption kinetics. …

Life Cycle Assessment Of Renewable Hydrocarbon Fuels Produced By The New Cool Gas To Liquid (Cool Gtl) Process, Elochukwu Okoye

Dissertations, Master's Theses and Master's Reports

The Cool Gas-to-Liquid (Cool GTL) process converts biogas and captured CO₂ into renewable hydrocarbon fuels, contributing to GHG emissions reduction in transportation. This report explains a Life Cycle Assessment (LCA) study that was completed to evaluate the environmental impact of different feedstocks, hydrogen sources, and electricity inputs. The analysis considers biogas from food waste, manure, and landfill sources, as well as biogenic, fossil, and direct air capture (DAC) CO₂ feedstocks. Results show that biogas pathways provide the greatest GHG reductions, with the best case (food and manure biogas + solar hydrogen + solar electricity) achieving a net-negative GWP …

Life Cycle Assessment And Life Cycle Cost Assessment Of A Floating Treatment Wetland In A Wastewater Lagoon Located In Copper Harbor, Michigan, Erin Browne

Dissertations, Master's Theses and Master's Reports

A full-scale floating treatment wetland was implemented in a wastewater treatment lagoon in Copper Harbor, Michigan. Copper Harbor is a small, rural community located in a cold climate. Many studies have focused on the performance of floating treatment wetlands in mesocosm studies in warmer climates, but there is not a lot of research conducted on the feasibility and performance of full-scale floating treatment wetlands in wastewater lagoons, specifically in cold climates. The 2024 treatment season was the first season with the floating treatment wetland implemented in the wastewater lagoon. A preliminary assessment of the cost and environmental impacts of a …

Direct Methane Capture Via Aerobic Methanotrophs, Waaseyaaban Landgren

Dissertations, Master's Theses and Master's Reports

Methane, a greenhouse gas with global warming potential 80 times greater than carbon dioxide, heavily contributes to global warming. Removing 1 Gt of atmospheric methane by 2050 would limit global temperature increase from reaching 1.5°C. Currently, biotrickling filter systems for removing atmospheric methane via methanotrophs exist, but not for very low methane concentrations (< 1 v%). Current research work at the University of Washington isolated and engineered a microbe strain which thrives at 500 ppmv methane, solving one obstacle in making this technology feasible. In this thesis, techno-economic analysis and environmental life cycle assessment conducted on this process have assessed its economic feasibility, greenhouse gas reduction potential, and possible areas of improvement. Study results show that at 500 ppmv methane, this process could remove atmospheric methane at a cost of $3,992-5,224 per tCH₄. The ideal case also produces annual net reduction in warming potential by 276-311 tCO₂e per process unit deployed.

Leveraging Product And Process Characteristics Across The Concrete Pavement Life Cycle To Integrate Global Warming Potential Into Project Procurement Processes, Michelle Annette Cooper

Dissertations, Master's Theses and Master's Reports

The objective of this research is to support sustainable procurement of concrete pavements by linking materials-level global warming potential (GWP) to the project-level. Infrastructure owners require reliable environmental product declarations (EPDs) and methodologies for integrating GWP into the procurement process to ensure equitable decision-making. This work provides insights into current EPD reliability by assessing the sensitivity of concrete GWP to materials-level contributors to recommend a level of supply chain specificity needed to effectively communicate GWP. A benchmarking methodology was developed and implemented to establish reference values for procuring sustainable products. Having provided evidence towards EPD reliability, this work presents a …

Dam It All: A Multi-Scalar Investigation Into The Ecological Role And Function Of Beaver Dams, Kenneth Larsen

Dissertations, Master's Theses and Master's Reports

The central theme of this dissertation is ecological scaling, which examines how small, localized features, such as beaver ponds, contribute to large-scale watershed processes and how different modeling approaches at various scales reveal distinct insights. Through a combination of probabilistic modeling and high-resolution empirical research, this work demonstrates that small ponded systems, particularly those created by beavers (Castor canadensis), serve as critical biogeochemical control points, whose contributions to sediment and nutrient dynamics have been historically underestimated.

In Chapter 1, I contextualize this research within the broader fields of freshwater ecology, watershed modeling, and ecological restoration. I introduce the …

Sustainable Materials For Environment − Multifunctional Material Made From Dead Leaves And Nanostructured Materials For Antibiotic Degradation, Siyuan Fang

Dissertations, Master's Theses and Master's Reports

As environmental pollution from industrial processes and human activities continues to rise, finding efficient approaches to recycle waste materials and degrade persistent contaminants becomes increasingly critical. Dead leaves, an abundant but underutilized biomass, present an opportunity for creating value-added materials if their biocomponents can be preserved and transformed. Simultaneously, antibiotics such as tetracycline are widely found in water bodies but pose serious ecological and health risks, necessitating effective degradation methods. This dissertation addresses these challenges by leveraging natural and nanostructured materials to develop multifunctional products and advanced photocatalytic processes.

Chapter 3 of this dissertation addresses the challenge of converting waste …

Interplay Of Discharge Rates, Slope, And Sediment Size In River Meandering Dynamics: Insights From Experimental Studies, Yifan Zhang

Dissertations, Master's Theses and Master's Reports

Sinuosity is an important concept in various fields including hydrology, geomorphology, and ecology. It not only presents the degree of curviness of a river channel but also reflects the ecological sustaining ability. By studying the sinuosity of a stream or river channel, important implications could also be found including the transportation and deposition of the sediments, the habitats of the riverbanks, and the types of species that are able to live on the watershed and river. To study the factors that could heavily affect the sinuosity of a river channel, a full set of laboratory experiments was designed to perform …

Aluminum Critical Mineral Production Feasibility Via Landfill Mining: Preliminary Study Of Potential Project Locations And Co-Benefits, Anabel M. Needham

Dissertations, Master's Theses and Master's Reports

In 2022, aluminum was named a critical mineral by the United States Geological Survey (USGS) and the global demand for aluminum is projected to increase by 40% from 2020 to 2030 (Aleksić 2023). There are currently no large-scale bauxite mines in the United States to contribute to aluminum production, and this study aims to investigate the feasibility of aluminum landfill mining in the United States to produce secondary aluminum. The feasibility of landfill mining for the purpose of recovering materials and energy is a relatively new technology, and often co-benefits are required to make these projects economically viable. Publicly available …

Assessing Wave Dynamics Induced Coastal Flooding Along The Southern Shores Of Lake Superior, Saumik Mallik

Dissertations, Master's Theses and Master's Reports

This study provides a comprehensive assessment of coastal hazards along the southern shores of Lake Superior, encompassing the interplay of static water levels, surges, and the amplifying effects of wave dynamics. Employing 51 years of historical water level data from five gauge stations in the US portion of Lake Superior, the study conducts extreme value analysis to estimate return levels over various return periods (25, 50, 100, and 500 years) for static water levels and surges. In parallel, Significant Wave Heights (SWH) data generated from the Simulating Waves Nearshore (SWAN) model is calibrated through a multi-step procedure based on historical …

Joint Probability Analysis Of Extreme Precipitation And Water Level For Chicago, Illinois, Anna Li Holey

Dissertations, Master's Theses and Master's Reports

A compound flooding event occurs when there is a combination of two or more extreme factors that happen simultaneously or in quick succession and can lead to flooding. In the Great Lakes region, it is common for a compound flooding event to occur with a high lake water level and heavy rainfall. With the potential of increasing water levels and an increase in precipitation under climate change, the Great Lakes coastal regions could be at risk for more frequent and severe flooding. The City of Chicago which is located on Lake Michigan has a high population and dense infrastructure and …

Eutrophication On Twin Lakes: Applying A Phosphorus Budget And Shoreline Surveys To Assess Current & Historical Lake Health, Tyler K. Lemahieu

Dissertations, Master's Theses and Master's Reports

The Twin Lakes system, a series of lakes including Lake Gerald and Lake Roland, was historically categorized as oligotrophic but is now mesotrophic having experienced cultural eutrophication. A mass balance phosphorus budget model was constructed for the Twin Lakes system in Houghton, Co. Michigan for the 2022 stratified season. Additional spatial insights were gleaned through a survey of shoreline water quality, which corroborated the model results. The lakes currently experience substantial depletion of hypolimnetic dissolved oxygen during late summer stratification. A budget reveals approximately 22% (6.6 kg) of the current 29.5 kg total phosphorus inputs to Twin Lakes (during the …

Bioaccumulation Of Polychlorinated Biphenyl Compounds And Mercury In A Mining Impacted Aquatic Ecosystem, Michelle Bollini

Dissertations, Master's Theses and Master's Reports

The Keweenaw area continues to be influenced by the century of copper mining that ended nearly 50 years ago. This project is focused on Torch Lake, an aquatic ecosystem that has been heavily impacted by mining waste disposal. The watershed has been impaired by mine discharge and tailings, smelter and smokestack plumes, and poor waste disposal practices. The lake is listed as a Great Lakes Area of Concern with beneficial use impairments of restrictions on fish consumption and a degraded benthic community. Polychlorinated biphenyl compounds (PCBs) and methylmercury (MeHg) are persistent, bioaccumulative, and toxic substances (PBTs). These contaminants pose threats …

Treating Contaminated Water: Predicting Reactivities Of Aqueous Organic Contaminants With Hydrated Electrons, And Development Of A Biogarden To Manage Greywater Discharge In Monteverde, Costa Rica, Rose C. Daily

Dissertations, Master's Theses and Master's Reports

Advanced reduction processes (ARPs) that generate highly reactive solvated electrons (e^-_aq) are a promising method for the destruction of conventional and emerging aqueous organic contaminants. While there is a large database of contaminant reactivity with e^-_aq in the literature, there is little information on the detailed elementary mechanisms for reduction of multifunctional group compounds and the impact of those functional groups on reactivity. As it is difficult to determine specific mechanisms through experiments and time consuming to measure reactivity, the development of computational approaches to elucidate mechanisms and predict reactivity is becoming increasingly important. In …

Predicting The Reactivities And Reaction Mechanisms Of Photochemically Produced Reactive Intermediates, Benjamin Barrios Cerda

Dissertations, Master's Theses and Master's Reports

Photochemically produced reactive intermediates (PPRIs) such as the hydroxyl radical, carbonate radical (CO₃^•-) singlet oxygen (¹O₂) and triplet state of chromophoric dissolved organic matter (³CDOM^*) are formed in sunlit natural waters upon photoexcitation of chromophoric dissolved organic matter (CDOM). PPRIs react with the organic compounds involved in key environmental processes, resulting in transformation products of smaller molecular weight than their parent compounds. Photochemical transformation of these key water constituents due to their reactions with PPRIs may pose potential effects on human and aquatic ecosystems. Consequently, there is a need …

The Photo-Transformation Of Free Methionine In The Presence Of Surrogate And Standard Isolate Dissolved Organic Matter Under Sunlit Irradiation, Benjamin J. Mohrhardt

Dissertations, Master's Theses and Master's Reports

Sulfur (S)-containing amino acids are key sources of carbon, nitrogen, and sulfur involved in protein synthesis, protein function, and providing energy for microbial growth. Dissolved free and combined methionine is one of two S-containing amino acids incorporated into proteins and has been attributed to their stability and function. The oxidation of methionine has received considerable attention given its ubiquitous presence in most biological systems and has been associated with losses in protein function and pathological disorders. In natural waters, methionine is rapidly and selectively taken up by microorganisms to achieve cellular requirements of carbon, nitrogen, and sulfur. The abiotic transformation …

Per- And Polyfluoroalkyl Substances Mitigation From Contaminated Groundwater Using Halophyte And Cow Bone Biochars, Bailey Papes

Dissertations, Master's Theses and Master's Reports

Per- and polyfluoroalkyl substances (PFAS) groundwater contamination is a growing concern for the Brackish Groundwater National Desalination Research Facility. Two of the four wells onsite are contaminated with perfluorooctanoic acid (PFOA), perfluorooctane sulfonic acid (PFOS), and perfluorohexane sulfonic acid (PFHxS). The removal of PFAS by adsorption onto powder activated carbon (PAC) is promising, but the production of PAC is energy intensive and expensive. A potential cost-effective alternative to PAC is biochar. This study quantified the capacities of two halophyte biochars, cow bone biochar and PAC to adsorb PFOA, PFOS, and PFHxS from brackish groundwater. The three biochars were ineffective at …

Simulating Groundwater Pollutant Transport For Remediation Design, Antrim County, Michigan, Abilynn Raetz

Dissertations, Master's Theses and Master's Reports

Located in Antrim County, Michigan between the coasts of Torch Lake and Lake Michigan is a hydrocarbon plume that has impacted surrounding residential wells. The plume is comprised of benzene, toluene, ethylbenzene, and xylenes (BTEX) and primarily resides in the shallowest groundwater aquifer. The plume is suspected of having originated from an underground storage container that was removed in 1979. A conceptual model was developed for the site, comprising of a simplified hydrogeological model. Groundwater modeling was performed using Aquaveo's groundwater modeling software (GMS). PEST parameter calibration was performed on the hydraulic conductivity and recharge values using data from surrounding …

Evaluation Of Production-Well Performance In Response To Formation Clogging And Rehabilitation For The Keweenaw Bay Tribal Fish Hatchery, Brock O. Howell

Dissertations, Master's Theses and Master's Reports

Temporally, the KBIC (Keweenaw Bay Indian Community) Hatchery wells have manifested general trends of declining specific capacity and higher energy consumption due to mineral precipitation in and around the production wells. Monitoring data, laboratory water analyses, and downhole video logging have confirmed that naturally occurring minerals are precipitating and clogging the screens and, likely, the surrounding formations. The reduction in fluid pressures in and around the well-screens from active pumping wells is typical but, ultimately alters the geochemical and physical conditions such that dissolved minerals precipitate on and around the well-screens, therefore, effectively clogging the well. The clogging from mineral …

Rebuilding Fish-Human Relationships By Quantifying Combined Toxicity And Evaluating Policy Related To Legacy Contamination, Emily Shaw

Dissertations, Master's Theses and Master's Reports

The central theme of this dissertation is relationships – building relationships as research partnerships, disrupting relationships through chemical contamination, and upholding existing relationships (i.e., responsibilities) to address industrial legacies. In partnership with the Keweenaw Bay Indian Community Lake Superior Band of Chippewa Indians (KBIC), this dissertation focuses on rebuilding fish-human relationships within the context of chemical contamination. By quantifying combined toxicity and evaluating the efficacy of cleaning up contamination, conclusions from this work help empower people to maintain practices and knowledges related to fish.

In chapter 1, I positioned myself, a white, American settler scholar, within the context of Indigenous …

Mapping Michigan's Historic Coastlines, Ryan A. Williams

Dissertations, Master's Theses and Master's Reports

This five-year project, sponsored by the Michigan Department of Environment, Great Lakes, and Energy, is working to map how Michigan’s Great Lakes shorelines have changed over the past 80+ years. Products of this project include publicly available digital, georeferenced, historic aerial photography datasets, as well as map layers depicting the locations of historic shorelines and bluff lines from 1938, 1980, 2009, 2016, 2018, and 2020. Additional products include bluff retreat risk areas, shoreline rate of change map layers, and tools to assist in the development of future Coastal Vulnerability Index projects for the Great Lakes. All products are available as …

Understanding The Weather- And Soil-Related Variability In Agricultural Water Footprints: Case Study Of Maize And Soybeans Grown In The St. Joseph Watershed, Karleigh M. Krieg

Dissertations, Master's Theses and Master's Reports

Introduced in 2002, the water footprint is a valuable tool for understanding the consumption of freshwater resources. The traditional approach to quantifying the water footprint is to sum the green, blue, and gray water footprint components. The green water footprint is the volume of water that comes from precipitation, is stored in the soil, and used by vegetation. The blue water footprint is the volume of surface or ground water that is withdrawn and applied to cultivated lands via irrigation. These components are based on the evapotranspiration of green and blue water resources, respectively. The gray water footprint is the …

Predicting The Impacts Of Climate Change On The Great Lakes Water Levels Using A Fully Coupled 3d Regional Modeling System, Miraj Kayastha

Dissertations, Master's Theses and Master's Reports

The Great Lakes of North America are the largest surface freshwater system in the world and many ecosystems, industries, and coastal processes are sensitive to the changes in their water levels. The recent changes in the Great Lakes climate and water levels have particularly highlighted the importance of water level prediction. The water levels of the Great Lakes are primarily governed by the net basin supplies (NBS) of each lake which are the sum of over-lake precipitation and basin runoff minus lake evaporation. Recent studies have utilized Regional Climate Models (RCMs) with a fully coupled one-dimensional (1D) lake model to …

Case Study Of Gravity-Fed Mountain Spring Tap System In Ha Leronti, Lesotho, Africa, Sarah Peterson

Dissertations, Master's Theses and Master's Reports

Water security has been declining rapidly in Lesotho, Africa in recent years. Lack of water has led to food insecurity, livestock deaths, and the spread of disease. Rural Basotho depend on rainfall to sustain their livelihoods; however, precipitation variability has recently increased due to climate change. For those who reside in the highlands of Lesotho, mountain springs can be a clean source of water. The tap system in the village of Ha Leronti relies on gravity to distribute water from two mountain springs to the ten village taps and nearby school campus. However, it is incapable of transporting the basic …

Initial Transformation Of Photo-Viable Free Amino Acids In The Presence Of Surrogate And Standard Dissolved Organic Matter Under Sunlit Irradiation, Ryan J. Kibler

Dissertations, Master's Theses and Master's Reports

With more than half of the nation’s drinking water affected by wastewater discharge from upstream and more indirect and direct reuse of treated wastewater, human health and ecotoxicological impacts resulting from effluent organic material (EfOM) will increase. Dissolved free amino acids (DFAAs), nitrogen components of EfOM, are essential nitrogen sources for microorganisms and play important roles in global N-cycling in natural aquatic environments. Several DFAAs including histidine, methionine, and tyrosine in sunlit surface waters are susceptible to direct and indirect photochemical transformation with reactive oxygen species. In this study, we investigated the reaction kinetics and initial reaction mechanisms involved in …

Metalimnetic Oxygen Minimum In Green Lake, Wisconsin, Mahta Naziri Saeed

Dissertations, Master's Theses and Master's Reports

Green Lake, located in Green Lake County, Wisconsin, has been experiencing summer Metalimnetic Oxygen Minima (MOM). The severity of the MOM has increased in recent years and the lake was listed as impaired in 2014. To investigate the MOM, the lake was monitored during 2017 and 2018 at two sites using moored temperature and oxygen sensors recording at 1-hour intervals. Using these data, a hydrodynamic model (Simstrat) was configured for the lake. A new model was then developed to simulate the oxygen changes in the lake. Productivity, respiration, sediment oxygen demand (SOD) and fluxes were included, and hydrodynamics were driven …

Towards Efficient Water Treatment: Mechanism Of Colloidal Fouling Of Ultrafiltration Membranes, Ikenna Henry Ozofor

Dissertations, Master's Theses and Master's Reports

This research study first reviewed challenges of conventional and membrane separation systems for water treatment. Though membrane separation systems appeared superior to the conventional counterparts for water and wastewater treatment, wider applications of membrane systems have been limited by some factors, most notably is membrane fouling. Experimental studies were therefore conducted to achieve the goal of this research, which is to investigate how feed properties affect fouling of ultrafiltration (UF) membranes by colloids.

Feed salinity, pH, and nanoparticle concentration were the variables studied to unravel how different UF membranes are fouled by model silica colloids (with average diameter of 25nm). …

Systems Analysis For Sustainability Assessment Of Biogas And Bio-Ch4 Production From Food Waste And Dairy Manure Mixtures In The Us, Sharath Kumar Ankathi

Dissertations, Master's Theses and Master's Reports

The purpose of the dissertation is to relate systems analysis for bioenergy to identify optimum configurations for improved scenarios and to make better decisions in a systems perspective.

Chapter 1 is a review of the literature to identify the state of the knowledge in terms of systems analysis for anaerobic digestion (AD) bioenergy systems. The key outcomes from this review showed that anaerobic digestion of mixtures of food waste and animal manure has great potential to achieve economic and environmental benefits compared to other treatments of organic waste materials, such as landfilling or conventional manure management.

Chapter 2 focuses on …

Life Cycle Information Models With Parameter Uncertainty Analysis To Facilitate The Use Of Life-Cycle Assessment Outcomes In Pavement Design Decision-Making, Chaitanya Ganesh Bhat

Dissertations, Master's Theses and Master's Reports

The objective of this dissertation is to develop Life Cycle Information Models (LCIMs) to promote consistent and credible communication of potential environmental impacts quantified through Life-Cycle Assessment (LCA) methodology. The introduction of Life Cycle Information Models (LCIMs) will shift the focus of pavement LCA stakeholders to collect reliable foreground data and adapt to consistent background data present within LCIMs. LCA methodology requires significant Life Cycle Inventory (LCI) data to model real world systems and quantify potential environmental impacts. The lack of guidance in ISO standards on consistently compiling LCI data and defining protocols for modeling lowers the reliability of LCA …

Modeling The Effects Of Wastewater Infrastructure Options On Water Quality In Greater Cleveland, Ohio, Mike Foster

Dissertations, Master's Theses and Master's Reports

The city of Cleveland, OH, and the Northeast Ohio Regional Sewer District are in the process of an ambitious engineering project designed to reduce the amount of untreated wastewater that is discharged into Lake Erie and its tributaries. The project involves the construction of seven tunnels that will intercept combined sewer overflows for transport to wastewater treatment plants, along with upgrades to the treatment capacity of these plants. This report will examine the water quality impacts of this project, as well as the impact of six additional proposed management options, on the streams of Greater Cleveland and the Lake Erie …