Environmental Engineering Commons^™

Treatment Of Vegetable Oil Refining Wastes, D. Kaya, Yung-Tse Hung

Civil and Environmental Engineering Faculty Publications

The common vegetable oils are soybean, sesame, sunflower, corn, canola, and cotton seeds. Their yields, compositions and physical and chemical properties determine their usefulness in various applications aside edible uses. Crude oils obtained by pressing of such vegetable seeds are not usually considered to be edible before the removal of various nonglyceride compounds through operations known as refining. The refining processes remove undesirable materials such as phospholipids, monoacylglycerols, diacylglycerols, free fatty acids, colour and pigments, oxidised materials, etc., but, may also remove valuable minor components such as antioxidants and vitamins (carotenes and tocopherols). The major steps involved in chemical refining …

Physical And Biological Factors Affecting Oxygen Transfer In The Activated Sludge Wastewater Treatment Process, Kenneth A. Campbell

Doctoral Dissertations

“The activated sludge (AS) process is widely utilized for wastewater treatment due to its versatility and general resiliency, but is energy intensive, requiring aeration and mixing energy inputs to maintain the biochemical reaction and optimize treatment performance. This study is focused on determining different factors that influence oxygen transfer and consequently its energy demand.

AS morphology, as described by the d₁₀, d₂₀, d₃₂, specific filament length (SFL), 30 min settleability (SV₃₀), etc., does influence the OTE. Filamentous organisms increase the hydrodynamic radius of suspended particles, which dilates mixed liquor apparent viscosity (µ …

Cationic Surfactant Analysis With Good Laboratory Practice, Lawrence K. Wang, Mu-Hao Sung Wang, Nazih K. Shammas, Valerie Renak, Yung-Tse Hung

Civil and Environmental Engineering Faculty Publications

The objectives of this research are to: (a) demonstrate how to select an organic solvent (such as 1,1,1-trichloroethane) for spectrophotometric determination of cationic surfactant in water and wastewater, (b) investigate and recommend possible better organic solvents for surfactant analysis; and (c) introduce good laboratory practice for personal protection, laboratory protection and hazardous waste management. Specifically this research involves selection of alternate less toxic and greener organic solvent for use in a methyl orange method for colorimetric determination of cationic surfactants in the 0.2 to 2.0 mg/L range. The principles, steps and management of the methyl orange method include: (a) complexation …

Data Driven Synthetic Load Modeling For Smart City Energy Management Studies, Fernando Bereta Dos Reis

Electronic Theses and Dissertations

The primary aim of this dissertation is to provide synthetic residential load models with granular level information on the customers having information about the appliances that constitute each individual residential customer through time. The synthetic load model is capable of being widely utilized by the power system research community since only publicly available data is utilized for its generation. This gives researcher’s access to how the synthetic load was made and also how accurate the model is in representing real power system regions. As the title of the dissertation suggests, the synthetic residential load models are intended for smart city …

Initial Transformation Of Photo-Viable Free Amino Acids In The Presence Of Surrogate And Standard Dissolved Organic Matter Under Sunlit Irradiation, Ryan J. Kibler

Dissertations, Master's Theses and Master's Reports

With more than half of the nation’s drinking water affected by wastewater discharge from upstream and more indirect and direct reuse of treated wastewater, human health and ecotoxicological impacts resulting from effluent organic material (EfOM) will increase. Dissolved free amino acids (DFAAs), nitrogen components of EfOM, are essential nitrogen sources for microorganisms and play important roles in global N-cycling in natural aquatic environments. Several DFAAs including histidine, methionine, and tyrosine in sunlit surface waters are susceptible to direct and indirect photochemical transformation with reactive oxygen species. In this study, we investigated the reaction kinetics and initial reaction mechanisms involved in …

A Field Study Of Bioaccessible Lead In Detroit Soils: Insight Into The Effectiveness Of Phosphate-Based Lead Sequestration, Sabrina R. Good

Wayne State University Theses

Historical and contemporary use of lead (Pb) in gasoline, paints, and industry have caused lead to be ubiquitous in the urban soil environment, disproportionately affecting low-income minority children. As soil is a major exposure pathway for children, an effective remediation technique for lead-contaminated soil is urgently needed. Common remediation techniques, such as excavation or soil capping, are expensive and environmentally destructive, especially on a city-wide residential basis. Decreasing the bioavailability of lead, or the fraction which is retained by the human body, may be a more economically and environmentally conscious option for remediating lead in urban environments.

Research has demonstrated …

Water Reclamation Using Functionalized Forward Osmosis Membrane, Fnu Joshua

Electronic Theses and Dissertations, 2020-2023

This study investigated water reclamation from an impaired-quality water using forward osmosis (FO) membrane functionalized by nano zero valent iron (nZVI) loaded polyelectrolyte multilayer films. Stormwater runoff was selected as the impaired-quality water, which served as a feed solution (FS) and a NaCl salt solution at a concentration representing reverse osmosis (RO) concentrate was used a draw solution (DS). RO concentrate is another impaired-quality water that is discharged to the environmental with little or no treatment. A commercial cellulose triacetate (CTA) FO membrane was modified using poly allylamine hydrochloride (PAH) (a polycation) and poly acrylic acid (PAA) (a polyanion) following …

Removal Of Chemicals Of Emerging Concern And Mass Transfer Modeling In A Nanofiltration Membrane Process, Carlyn Higgins

Electronic Theses and Dissertations, 2020-2023

An investigation of 1,4-dioxane and enantiomeric ibuprofen mass transfer in a nanofiltration (NF) membrane process has been completed. Pilot-scale experiments using a 267 gallon per minute (gpm) split-feed, center-port NF process treating pH 6.5 groundwater revealed a consistent 12 percent removal of 1,4-dioxane despite the variable feed concentration (180 nanograms per liter (ng/L) to 38,400 ng/L) when the water flux and temperature were held constant. Bench-scale, flat-sheet NF membrane experiments treating pH 4.0 synthetic water displayed a 34.5 to 49.5 percent removal of racemic ibuprofen. Removal values were dependent on feedwater concentration (1 to 1,500 microgram per liter (µg/L)), pH, …

Improving Air Pollution Exposure Estimation Using Cell Phone Location Data And Low-Cost Sensors, Xiaonan Yu

Electronic Theses and Dissertations, 2020-2023

Human exposure estimation to air pollution plays an important role in epidemiological studies which are designed to reveal correlations between human exposures to certain air pollutants and certain diseases, such as asthma, cardiovascular disease and reproductive diseases. Traditionally, when people's mobile data is hard to get, home location is used to estimate people's exposures assuming that people stay at home all the time. Whereas, people move and it is more accurate to estimate people's exposures including people's mobility. In our study, we showcased two methods to obtain people's mobile data: Google Maps location history (GMLH) data and Call Detailed Record …

Recovery Of Ethyl Lactate From Washing Solution Originating From Drill Cuttings Treatment By Adsorption Process, Theary Peng Orng

Chulalongkorn University Theses and Dissertations (Chula ETD)

The purpose of this study was to recover the washing solutions generated from drill cuttings washing process using an adsorption technology. Ethyl lactate (EL) was selected as an extracting agent for drill cuttings washing throughout the work. Various washing parameters including liquid-to-solid (L/S) ratio, washing time, mixing speed, rinse-to-solid (R/S) ratio, and rinsing time were studied with the aid of response surface methodology. Once the optimal washing conditions were obtained, the recovery of washing solutions, i.e., spent EL and rinsed water using the commercial granular activated carbon (GAC) and kapok fiber (KF) were investigated. Finally, the adsorbent modification and validation …

Soil-Water-Energy Nexus Of Green Roofs, Katherine Ann Bartels

Masters Theses

"As the urban landscape continues to sprawl into previously undeveloped land to accommodate population growth, the need to design cities that effectively manage urban stormwater is imperative for a sustainable future. Green roofs use rain-harvesting techniques to reduce urban stormwater discharge while simultaneously providing traditional roof services as well as several ecosystem services. However, green roof media design varies greatly among commercial applications, and little guidance is available to engineers when selecting the media for prospective green roofs. Efforts to maximize stormwater retention and enhance urban heat island mitigation capabilities of green roofs while concurrently reducing nutrient loading were examined …

An Evaluation Of Ground-Freezing Methods In The Zone Of Discontinuous Permafrost, Northwest Territories, Elzbieta Mastej Ms

Theses and Dissertations (Comprehensive)

Northwestern Canada is one of the most rapidly warming regions on Earth. The southern limit of the discontinuous permafrost zone is highly sensitive to small climatic fluctuations and presently experiencing a rapid landscape change due to accelerated permafrost thaw, which is further exacerbated by anthropogenic disturbances such as seismic exploration. Recent research has begun to examine both natural and mechanical approaches to minimize permafrost loss, although the utility of such methods in peatland environments is not well understood. This study explored the efficiency of natural and artificial ground cooling processes in a peatland environment by evaluating snow exclusion and thermosyphon …

Development Of Amine-Functionalized Mesoporous Alumina For Radioiodine Removal From Water, Mansour Mohammed Alsalbokh

Masters Theses

“Radioactive materials have spread due to careless disposal and nuclear disasters. Some radionuclides can exist in an aqueous media, like radioactive iodine. As a result, in this work amine-functionalized mesoporous alumina was developed to adsorb radioactive iodine from the liquid phase. Bismuth was incorporated, using a wet impregnation method, to test it as a possible silver replacement. Amine grafting was used to functionalize the surface of the mesoporous alumina. All materials prepared in this work were characterized by N₂ physisorption, FTIR and TGA to determine the textural properties, surface functionality, and amine loading. The synthesized materials were tested for …

Fluvial Sediment Organic Matter Degradation Identified With Elemental And Isotopic Fate During Laboratory Incubation, Brenden Riddle

Theses and Dissertations--Civil Engineering

Fluvial sediment is well recognized as a critical factor in both carbon and nutrient budgets within stream systems. However, we find very few studies of reactivity and isotope enrichment for stream water from agricultural and urban streams and the class of substrate known as fluvial sediment organic matter. This study investigated the hypothesis that fluvial sediment is subject to degradation even though many previous studies have considered this class of substrate generally inert. Therefore we qualify that elemental and isotopic signatures of fluvial sediment organic matter should be considered potentially non-conservative when used in tracer studies. Methods applied to this …

Probabilistic Approach To Water, Sediment, And Nutrient Connectivity For Advancing Watershed Modelling, David Tyler Mahoney

Theses and Dissertations--Civil Engineering

The goal of this dissertation is to represent the spatial and temporal domains of water, sediment, and nutrient flux and pathways within fluvial and watershed settings. To complete this goal, we integrate connectivity theory into watershed model structures to simulate water, sediment, and nutrient movement at the fundamental unit they occur. Fluvial-based sediment and nutrient flux is an important driver of global sediment and nutrient budgets, and the quantification of which serves as an ongoing challenge to limnologists, engineers, and watershed managers. Watershed models have been richly developed over the past century, but are currently restrained by problems related to …

A Modeling Approach To Understanding Glyphosate Transport In The Belize River Watershed, Barbara Anmei Astmann

Theses and Dissertations--Civil Engineering

Glyphosate is the most widely used herbicide worldwide and is often transported from application areas to surface water when solubilized in runoff or sorbed to eroded sediment. There is evidence that suggests both glyphosate and its main metabolite aminomethylphosphonic acid (AMPA) may pose a risk to human health, as well as cause adverse effects in the environment. However, consistent monitoring data is still limited, especially in developing countries. Belize is a developing nation with agriculture being a major sector of its economy and is heavily reliant on glyphosate. The widespread use of glyphosate in Belize may be resulting in glyphosate …

Variance Decomposition Of Forecasted Water Budget And Sediment Processes Under Changing Climate In Fluvial And Fluviokarst Systems, Nabil Al Aamery

Theses and Dissertations--Civil Engineering

Variance decomposition is the partitioning of different factors affecting the variance structure of a response variable. The present research focuses on future streamflow and sediment transport processes projections as the response variables. The authors propose using numerous climate factors and hydrological modeling factors that can cause any response variable to vary from historic to future conditions in any given watershed system. The climate modeling factors include global climate model, downscaling method, emission scenario, project phase, bias correction. The hydrological modeling factor includes hydrological model parametrization, and meteorological variable inclusion in the analysis. This research uses a wide spectrum of data, …

Investigation Into The Presence, Persistence, And Fate Of S. Aureus, And Its Mobile Genetic Elements, In Wastewater And The Surrounding Environment, Atena Amirsoleimani

Theses and Dissertations--Civil Engineering

Currently, the world is engaged in a battle against very small parts of our environment that develop and share genes for resistance to multiple environmental conditions. Pathogenic infections caused by antibiotic-resistant bacteria have been impacting animal and human health and life. Increasing incidences of methicillin- resistant Staphylococcus aureus (MRSA) infections transmitted through the environment are rising faster than the discovery of new antibiotics. Multi-drug resistant S. aureus infections in healthy individuals without prior hospitalization have been increasing all around the world.

Many people carry S. aureus in their nose and on their skin, common niches for the bacteria to co-grow …

Soil Bulk Density Effects On Runoff Estimation, Colton Pugh

Theses and Dissertations--Biosystems and Agricultural Engineering

Urbanization has long been a major factor in the hydrology of surrounding areas. Engineers are commonly tasked with mitigating the extra runoff that urbanization brings with it. The NRCS Curve Number (CN) method is a commonly-used approach to predicting the amount of runoff that will be experienced from a given area. However, this method is known to be highly simplified in model of the processes involved. This study focused on determining the relationships between soil bulk density, simulated rainfall events, hydrologic soil group (HSG) and runoff estimation (specifically via the NRCS CN method). It was determined that soil bulk density …

Quantifying Nitrogen Fate In Karst Agroecosystem Streams Of Central Kentucky: Development And Application Of Numerical Modeling And Insight From High-Resolution Sensors, Nolan Lewis Bunnell

Theses and Dissertations--Biosystems and Agricultural Engineering

In-stream fate of nutrients in karst agroecosystems remains poorly understood, despite the known impact of karst on water resources at local to global scales. In the Inner-Bluegrass region of central Kentucky, heterogeneity of karst maturity, flow pathways, and nutrient sources adds to the complexity of quantifying nutrient dynamics, thus requiring novel monitoring and modeling approaches. The significance of these streams is recognized given spring/surface water confluences have been identified as hotspots for biogeochemical transformations. In slow-moving streams high in dissolved inorganic nutrients (particularly dissolved inorganic nitrogen (DIN) and dissolved reactive phosphorus (DRP)), benthic and floating aquatic macrophytes are recognized to …

Systems Analysis For Sustainability Assessment Of Biogas And Bio-Ch4 Production From Food Waste And Dairy Manure Mixtures In The Us, Sharath Kumar Ankathi

Dissertations, Master's Theses and Master's Reports

The purpose of the dissertation is to relate systems analysis for bioenergy to identify optimum configurations for improved scenarios and to make better decisions in a systems perspective.

Chapter 1 is a review of the literature to identify the state of the knowledge in terms of systems analysis for anaerobic digestion (AD) bioenergy systems. The key outcomes from this review showed that anaerobic digestion of mixtures of food waste and animal manure has great potential to achieve economic and environmental benefits compared to other treatments of organic waste materials, such as landfilling or conventional manure management.

Chapter 2 focuses on …

Life Cycle Information Models With Parameter Uncertainty Analysis To Facilitate The Use Of Life-Cycle Assessment Outcomes In Pavement Design Decision-Making, Chaitanya Ganesh Bhat

Dissertations, Master's Theses and Master's Reports

The objective of this dissertation is to develop Life Cycle Information Models (LCIMs) to promote consistent and credible communication of potential environmental impacts quantified through Life-Cycle Assessment (LCA) methodology. The introduction of Life Cycle Information Models (LCIMs) will shift the focus of pavement LCA stakeholders to collect reliable foreground data and adapt to consistent background data present within LCIMs. LCA methodology requires significant Life Cycle Inventory (LCI) data to model real world systems and quantify potential environmental impacts. The lack of guidance in ISO standards on consistently compiling LCI data and defining protocols for modeling lowers the reliability of LCA …

Modeling The Effects Of Wastewater Infrastructure Options On Water Quality In Greater Cleveland, Ohio, Mike Foster

Dissertations, Master's Theses and Master's Reports

The city of Cleveland, OH, and the Northeast Ohio Regional Sewer District are in the process of an ambitious engineering project designed to reduce the amount of untreated wastewater that is discharged into Lake Erie and its tributaries. The project involves the construction of seven tunnels that will intercept combined sewer overflows for transport to wastewater treatment plants, along with upgrades to the treatment capacity of these plants. This report will examine the water quality impacts of this project, as well as the impact of six additional proposed management options, on the streams of Greater Cleveland and the Lake Erie …

Using Ftir-Atr To Predict Saccharification From Enzymatic Hydrolysis Of Physically Pretreated Lignocellulosic Biomass, Rajasri Alaparthi

Master’s Theses

Producing biofuels from lignocellulosic biomass (i.e., non-edible plants) can reduce greenhouse gas emissions. The main challenge in converting lignocellulose to fuel, however, lies in the bioconversion process of biomass to sugars. To overcome the recalcitrance of the plant cell walls, pretreatment (e.g., ball milling) can be coupled with enzymatic hydrolysis to produce sugar monomers (e.g., glucose and xylose). The research question in this thesis study was “Can Fourier Transform Infrared Spectroscopy Attenuated Total Reflectance (FTIR-ATR) applied to untreated and physically pretreated lignocellulosic biomasses coupled with chemometric analysis predict sugar yields from enzymatic hydrolysis?” PLS models were constructed by correlating the …

Site-Specific Irrigation Management In A Sub-Humid Climate Using A Spatial Evapotranspiration Model With Satellite And Airborne Imagery, Sandeep Bhatti, Derek M. Heeren, J. Burdette Barker, Christopher M. U. Neale, Wayne Woldt, Mitchell S. Maguire, Daran Rudnick

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Variable Rate Irrigation (VRI) considers spatial variability in soil and plant characteristics to optimize irrigation management in agricultural fields. The advent of unmanned aircraft systems (UAS) creates an opportunity to utilize high-resolution (spatial and temporal) imagery into irrigation management due to decreasing costs, ease of operation, and reduction of regulatory constraints. This research aimed to evaluate the use of UAS data for VRI, and to quantify the potential of VRI in terms of relative crop and water response. Irrigation treatments were: (1) VRI using Landsat imagery (VRI-L), (2) VRI using UAS imagery (VRI-U), (3) uniform (U), and (4) rainfed (R). …

Emulsion Characterization Study For Improved Bilgewater Treatment And Management, Daniela Diaz Hernandez

Electronic Theses and Dissertations, 2020-2023

The need for proper management of bilgewater to meet discharge regulations (e.g., 15 ppm oil) has revealed the necessity to expand the current understanding of bilgewater emulsions. This study proposed to evaluate emulsion stability under various environmental conditions and to identify governing parameters for emulsion formation. The stabilizing properties of eight-commercial cleaners and two-neat surfactants were evaluated. In situ characterization techniques were used for monitoring emulsion stability. Additionally, a needle-type pH microsensor and fluorescence spectroscopy were used for analyzing mass transfer at the oil-water interface. Water quality of extracted bilgewater showed to highly vary between vessels (e.g., conductivity: 1.74 -- …

Metalimnetic Oxygen Minimum In Green Lake, Wisconsin, Mahta Naziri Saeed

Dissertations, Master's Theses and Master's Reports

Green Lake, located in Green Lake County, Wisconsin, has been experiencing summer Metalimnetic Oxygen Minima (MOM). The severity of the MOM has increased in recent years and the lake was listed as impaired in 2014. To investigate the MOM, the lake was monitored during 2017 and 2018 at two sites using moored temperature and oxygen sensors recording at 1-hour intervals. Using these data, a hydrodynamic model (Simstrat) was configured for the lake. A new model was then developed to simulate the oxygen changes in the lake. Productivity, respiration, sediment oxygen demand (SOD) and fluxes were included, and hydrodynamics were driven …

Ground And Aerial Robots For Agricultural Production: Opportunities And Challenges, Santosh Pitla, Sreekala Bajwa, Santosh Bhusal, Tom Brumm, Tami M. Brown-Brandl, Dennis R. Buckmaster, Isabella Condotta, John Fulton, Todd J. Janzen, Manoj Karkee, Mario Lopez, Robert Moorhead, Michael Sama, Leon Schumacher, Scott Shearer, Alex Thomasson

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Crop and animal production techniques have changed significantly over the last century. In the early 1900s, animal power was replaced by tractor power that resulted in tremendous improvements in field productivity, which subsequently laid foundation for mechanized agriculture. While precision agriculture has enabled site-specific management of crop inputs for improved yields and quality, precision livestock farming has boosted efficiencies in animal and dairy industries. By 2020, highly automated systems are employed in crop and animal agriculture to increase input efficiency and agricultural output with reduced adverse impact on the environment. Ground and aerial robots combined with artificial intelligence (AI) techniques …

Implementation Of Real-Time Decision Support Technology At Akron Water Reclamation Facility, Hunter Durbin

Williams Honors College, Honors Research Projects

Advances in computer science, data analytics, hardware, and software are changing the way that sewer collection systems are able to operate. By combining these technologies into something called a Real-Time Decision Support System (RTDSS), operators of sewer collection systems can make operational decisions supported by data being recorded throughout the sewer system in real-time. A RTDSS has the potential to optimize the available capacity of a sewer collection system at a lower cost compared to traditional construction solutions. The City of Akron is in the process of implementing a RTDSS in their sewer collection system. This report analyzes how the …

Water Condensation Collection For Disaster Relief, Tyler Gaydosh

Williams Honors College, Honors Research Projects

Numerous populations experience sudden, unexpected circumstances where drinking water supply may be compromised. Current leading response strategies include the delivery of disposable water bottles, a simple and effective way of meeting the demand of fresh drinking water. The lack of reusability results in problems with waste and cost. Any response to provide drinking water to a population in these circumstances must consider a prolonged crisis and these limitations: minimal delivery opportunities, power supply, and waste management (e.g., aftereffects of Hurricane Maria in Puerto Rico). A review of alternatives for water collection was done to determine a viable collection method that …