Engineering Commons^™

Varying Current Electro-Synthesis Of Glyoxalic Acid In Pairs In The Fixed-Bed Electrolytic Cell, Yin-Sheng Chen, Xin-Sheng Zhang, Ying-Chun Dai, Wei-Kang Yuan

Journal of Electrochemistry

As for the process of the electro oxidation of glyoxal to glyoxalic acid, the electrolytic result of either fixed bed electrolytic cell or varying current electrolysis was better than that of either flat plate electrolytic cell or constant current electrolysis. The average current density of varying current electro synthesis of glyoxalic acid in pairs was 1535 A/m² and the current efficiency were 85.3% and 86.7% and the selectivity were 93.9% and 94.0% for the anodic oxidation and cathodal reduction respectively. The initial composition of anodic electrolyte was 7% glyoxal and 8% hydrochloric acid (W/W) and the cathodal electrolyte consisted …

Electrochemical Synthesis And Characterization Of The Nickel Electropolyurushiol Coordination Polymer, Feng Gao, Guo-Cai Shen, Jie-Yuan Tang, Wen-Gong Zhang

Journal of Electrochemistry

The nickel electropolyurushiol coordination polymer (EPU Ni²⁺) was obtained by the reaction between nickel chloride isopropyl alcohol solution with electropolyurushiol (EPU). The electrochemical polymerization of urushiol and the preparation of nickel electropolyurushiol coordination polymer were investigated. The coordination polymer was characterized by XPS, FT-IR, DMTA and AES methods, and its composition and structure were determined.The content of Ni²⁺ reached up to 7.5%. It was shown that there was certain coordination between Ni²⁺ and electropolyurushiol in the coordination polymer, thus cross-inks were formed. Therefore the glass transition temperature of the coordination polymer increased and heat resistance was …

Electrosynthesis Of Glyoxylic Acid In A Packed Bed Reactor, Jin-Hong Fan, Jun Li, Yu-Zhong Su, Hao-Qi Gao

Journal of Electrochemistry

Glyoxylic acid was produced by electroreduction of oxalic acid in a packed bed reator. The cathodic and anodic electrolytes were super-saturated oxalic and hydrochloric acid aqueous solutions separated by a super-acid ion-exchange membrane. The current efficiency and yield of glyoxylic acid were studied under different structured packed bed reactors and different electrode materials, temperatures and current densities. The results indicated that the current efficiency of synthsis of glyoxylic acid was over 66.2% and the concentration of glyoxylic acid could reach 2.02% after 45min electrolysis with cathode of lead particles and anode of graphite board under conditions of temperature 32 ℃, …

Photoelectrochemistry Of La3+ Doped Semiconductor Porous Films Sensitized By Ru(Bpy)2(Ncs)2 Dye, Li Zhang, Yan-Jie Ren, Sheng-Min Cai

Journal of Electrochemistry

The La³⁺-doped TiO₂ nanoparticles were prepared with hydrothermal method.The photoelectrochemical properties of La³⁺-doped TiO₂ nanoporous-film electrode sensitized by Ru(bpy)₂(NCS)₂ were studied. The conversion efficiency of light to electricity and the energy conversion efficiencies were ineased with the depth of La³⁺-doped TiO₂ nanoporous-film electrode.

Preliminary Study On Direct Ethanol Fuel Cell, Shu-Qin Song, Li-Kang Chen, Jian-Guo Liu, Zhao-Bin Wei, Qin Xin

Journal of Electrochemistry

The performance of a direct ethanol fuel cell based on Nafion115 was reported.PtRu/C and Pt/C were used as ethanol anode and oxygen cathode catalysts in a single cell of size 9 cm² .The effects of temperature, oxygen pressure, the flow rate of ethanol, and oxygen, and ethanol concentration were tentatively studied. The experimental results showed that the cell open circuit voltage 0.608 V, the cell voltage 0.329 V at 50 mA/cm², and the peak power density 19.25 mW/cm² were reached under the conditions of T_cell =85 ℃, P_O2 =0.5 MPa, C_ethanol =1.0 mol/L …

Information Efficiency In Hyperspectral Imaging Systems, Stephen E. Reichenbach, Luyin Cao, Ram M. Narayanan

Department of Electrical and Computer Engineering: Faculty Publications

In this work we develop a method for assessing the information density and efficiency of hyperspectral imaging systems that have spectral bands of non-uniform width. Imaging system designs with spectral bands of nonuniform width can efficiently gather information about a scene by allocating bandwidth among the bands according to their information content. The information efficiency is the ratio of information density to data density and is a function of the scene’s spectral radiance, hyperspectral system design, and signal-to-noise ratio. The assessment can be used to produce an efficient system design. For example, one approach to determining the number and width …

On The Use Of Linda As A Framework For Distributed Database Systems, Madhan M. Thirukonda, Ronaldo Menezes

Electrical Engineering and Computer Science Faculty Publications

Linda is a coordination language capable of solving issues in distributed computing environments that relate to process synchronization, communication and creation. The expressiveness of Linda in distributed systems is such that researchers are proposing novel applications using Linda as a primary means of coordination. The examples range from peer-to-peer to groupware computing, from simple chat applications to control systems. Surprisingly, Linda has not been used in the field of distributed databases, although Linda can be helpful in solving coordination issues in a distributed database system. In this paper, we look at a possibility of using Linda in the context of …

Modeling, Fabrication, And Optimization Of Niobium Cavities – Phase I: Quarterly Progress Report November 20, 2001 - February 20, 2002, Robert A. Schill Jr., Mohamed Trabia

Transmutation Sciences Materials (TRP)

Multipacting is one of the major loss mechanisms in RF superconductivity cavities for accelerators. This loss mechanism limits the maximum amount of energy/power supported by the cavities. Optimal designs have been identified in others’ studies. In practice, these designs are not easily manufactured. Chemical etching processes used to polish the cavity walls result in a nonuniform surface etch. A nonuniform surface etch will leave some unclean areas with contaminants and micron size particles. These significantly affect multipacting. Further, a nonuniform etch will leave areas with damaged grain structure, which is not good for superconducting properties. Typically, the depth of chemical …

Nanostructures With Small- And Large-Scale Periodic And Random Rough Surfaces And Lateral Fluctuations In The Permittivity And Permeability-Scattered Near Fields, Ezekiel Bahar

Department of Electrical and Computer Engineering: Faculty Publications

The scattered electromagnetic near fields due to fluctuations in the surface height and/or lateral variations in the electromagnetic medium parameters are evaluated using a full-wave approach. Since the scales of the height and medium fluctuations considered could be significantly smaller or larger than the electromagnetic wavelengths, the familiar perturbation and physical/geometrical optics solutions cannot be used nor is it possible to investigate subwave length features based on far-field measurements. The full-wave approach employs complete field expansion that includes propagating and evanescent waves as well as lateral waves and surface waves, which are not accounted for in the perturbation and physical …

Two Mechanisms Of Blueshift Of Edge Emission In Ingan-Based Epilayers And Multiple Quantum Wells, E. Kuokstis, J. W. Yang, Grigory Simin, M. Asif Khan, R. Gaska, M. S. Shur

Faculty Publications

We present the results of a comparative photoluminescence(PL) study of GaN and InGaN-based epilayers, and InGaN/GaN multiple quantum wells(MQWs). Room-temperature PL spectra were measured for a very broad range of optical excitation from 10 mW/cm² up to 1 MW/cm². In contrast to GaN epilayers, all In-containing samples exhibited an excitation-induced blueshift of the peak emission. In addition, the blueshift of the emission in the InGaN epilayers with the same composition as the quantum well was significantly smaller. The comparison of the blueshift in the “bulk” InGaN and in the MQWs allowed us to separate two different mechanisms …

Experimental Study Of Streamers In Pure N2 And N2/O2 Mixtures And A ≈13 Cm Gap, Won J. Yi, P. F. Williams

P. F. (Paul Frazer) Williams Publications

Empirical data on streamer formation and propagation in near-atmospheric pressure N₂ and N₂/O₂mixtures are presented. The data were obtained primarily from high-speed, high-sensitivity shutter and streak photography of streamers produced in a ≈13 cm gap. The streamer propagation velocity as a function of applied voltage, polarity, total pressure, and O₂ concentration are provided. In addition, information on streamer bifurcation, and streamer shape and size is included.

The breakdown process has two phases: a fast phase featuring the propagation of streamers, and much slower phase involving the heating of the gas to form the spark …

Forces On Permeable Conductors In Magnetic Fields, Lee W. Casperson

Electrical and Computer Engineering Faculty Publications and Presentations

It is often implied that the force density formula dF/dV = JXB is all that is required to calculate the force that would be experienced by any stationary current-carrying medium in a region of space containing a magnetic field. However, representations of this formula are not all compatible, and the methods of applying such formulas when the conductor or surrounding medium have permeabilities different from vacuum are not widely known. The simplest case that one might consider is that of a current-carrying wire in an otherwise uniform field. It appears that the experimental measurements corresponding to such a situation have …

High-Performance Inter-Pcb Connectors: Analysis Of Emi Characteristics, Xiaoning Ye, James L. Drewniak, Jim Nadolny, David M. Hockanson

Electrical and Computer Engineering Faculty Research & Creative Works

Electromagnetic interference (EMI) coupling associated with inter-board connection is investigated. Two experimental techniques, based on |S₂₁| measurements, including both common-mode current and near-field measurements, are reported. Both methods, as well as finite difference time domain (FDTD) modeling, were used as experimental and numerical tools for inter-printed-circuit-board (inter-PCB) connector evaluation. The EMI performance of a lab-constructed stacked-card connector, and a commercially available module-on-backplane connector were studied. EMI characteristics of the connectors are demonstrated by investigating a few aspects of the design: type of shield/ground blade for signal return, number and length of ground pins, signal pin designation, etc. Good …

On Performance Analysis And Implementation Issues Of Iterative Decoding For Graph Based Codes, Xuefei Wei

Dissertations

There is no doubt that long random-like code has the potential to achieve good performance because of its excellent distance spectrum. However, these codes remain useless in practical applications due to the lack of decoders rendering good performance at an acceptable complexity. The invention of turbo code marks a milestone progress in channel coding theory in that it achieves near Shannon limit performance by using an elegant iterative decoding algorithm. This great success stimulated intensive research oil long compound codes sharing the same decoding mechanism. Among these long codes are low-density parity-check (LDPC) code and product code, which render brilliant …

On The Data Hiding Theory And Multimedia Content Security Applications, Litao Gang

Dissertations

This dissertation is a comprehensive study of digital steganography for multimedia content protection. With the increasing development of Internet technology, protection and enforcement of multimedia property rights has become a great concern to multimedia authors and distributors. Watermarking technologies provide a possible solution for this problem.

The dissertation first briefly introduces the current watermarking schemes, including their applications in video,, image and audio. Most available embedding schemes are based on direct Spread Sequence (SS) modulation. A small value pseudo random signature sequence is embedded into the host signal and the information is extracted via correlation. The correlation detection problem is …

Renegotiation Based Dynamic Bandwidth Allocation For Selfsimilar Vbr Traffic, Zafer Sahinoglu

Dissertations

The provision of QoS to applications traffic depends heavily on how different traffic types are categorized and classified, and how the prioritization of these applications are managed. Bandwidth is the most scarce network resource. Therefore, there is a need for a method or system that distributes an available bandwidth in a network among different applications in such a way that each class or type of traffic receives their constraint QoS requirements.

In this dissertation, a new renegotiation based dynamic resource allocation method for variable bit rate (VBR) traffic is presented. First, pros and cons of available off-line methods that are …

Qos Routing Source Routing Problems And Solutions, Ye Tian

Theses

The notion of Quality-of-Service has been proposed to capture qualitatively or quantitatively defined performance contracts between the service provider and the user applications. Integrated network services are designed to support Quality-of-Service (QoS). One of the primary goals for the integrated network services is to find the paths that satisfy given QoS requirements, namely QoS routing. The challenging issue in this area is to route packets subjected to multiple uncorrelated constraints because the problem is inherently NP-complete. This thesis studies the source routing heuristic approaches that bring the time complexity down to the polynomial-time for the multi-constrained path (MCP) problem. A …

Hyperbolic Position Location Estimator With Tdoas From Four Stations, Sreeram Potluri

Theses

This thesis presents a detailed derivation of a set of equations needed to locate the three dimensional position of a mobile given the locations of four fixed stations (like a global positioning system (GPS) satellite or a base station in a cell) and the signal time of arrival (TOA) from the mobile to each station. From these derived equations, a synthesizable VHDL model was developed and simulated using IEEE numen*c_std package. All the inputs and outputs were described by 32 bit vectors. From the simulations, it was observed that in the best case the mobile position was off by I …

Cxquery: A Novel Xml Query Language, Peter Revesz, Yi Chen

School of Computing: Conference and Workshop Papers

XML is becoming the data exchange standard on the Internet. Previously proposed XML query languages, such as XQuery, Quilt, YALT, Lorel, and XML-QL, lack schema definition of the query result; therefore, they are limited for defining views, integrating data, updating, and further querying, all of which are often needed in e-Business applications. We propose a novel XML query language called CXQuery, which defines the schema of the query results explicitly and can easily define views, and integrate, update, and query XML data. In addition, CXQuery can express spatial and spatio-temporal queries using a constraint-based querying approach.

Two Charge States Of Dominant Acceptor In Unintentionally Doped Gan: Evidence From Photoluminescence Study, Michael A. Reshchikov, Hadis Morkoç, S. S. Park, K. Y. Lee

Electrical and Computer Engineering Publications

Photoluminescence of the dominant deep-level acceptor in high-purity freestanding GaN is studied over a wide range of excitation intensities. A yellow luminescence (YL) band at about 2.2 eV saturates with increasing excitation intensity, whereas a green luminescence (GL) band at about 2.5 eV increases as a square of the excitation intensity. The YL and GL bands are attributed to two charge states of the same defect, presumably a gallium vacancy-oxygen complex.

Backilluminated Gan/Algan Heterojunction Ultraviolet Photodetector With High Internal Gain, S. K. Zhang, W. B. Wang, I. Shtau, F. Yun, L. He, Hadis Morkoç, X. Zhou, M. Tamargo, R. R. Alfano

Electrical and Computer Engineering Publications

We report on a backilluminated GaN/Al0.18Ga0.82Nheterojunction ultraviolet (UV)photodetector with high internal gain based on metal-semiconductor-metal structures. A narrow band pass spectral response between 365 and 343 nm was achieved. When operating in dc mode, the responsivity reaches up to the order of 102 A/W under weak UVillumination, which is due to enormous internal gain up to 103. The linear dependence of photocurrent on bias and its square root dependence on optical power are found and explained by a trapping and recombination model. The high photocurrent gain is attributed to trapping and recombination centers with an acceptor character induced by dislocations …

Backilluminated Ultraviolet Photodetector Based On Gan/Algan Multiple Quantum Wells, S. K. Zhang, W. B. Wang, F. Yun, L. He, Hadis Morkoç, X. Zhou, M. Tamargo, R. R. Alfano

Electrical and Computer Engineering Publications

The operation of backilluminated ultraviolet (UV)photodetector based on GaN/Al0.27Ga0.73Nmultiple quantum wells(MQWs) is reported. The MQW structure was deposited on a 1-μm-thick Al0.35Ga0.65Nbuffer layer which was epitaxied on a sapphire substrate. Coplanar Ohmic contacts were made on the top side of the MQW structure. By illuminating the Ohmic contact positions from the backside of the detector, a flat and narrow band spectral response is achieved in the UV wavelength range from 297 nm to 352 nm. The electron-heavy hole absorption in the MQW region produces the sharp long-wavelength cutoff at 352 nm and the band-to-band absorption of the Al0.35Ga0.65Nbuffer layer introduces …

Growth Of Gan Films On Porous Sic Substrate By Molecular-Beam Epitaxy, F. Yun, Michael A. Reshchikov, L. He, Hadis Morkoç, C. K. Inoki, T. S. Kuan

Electrical and Computer Engineering Publications

Porous SiC (PSiC) substrates were used for the growth of GaN by reactive molecular-beam epitaxy with ammonia as the nitrogen source. Improved quality of GaNfilms has been demonstrated for growth on PSiC substrates, as compared to that on standard 6H–SiC substrates. Cross-sectional transmission electron microscopy and electron diffraction showed a reduction in dislocation density and a higher degree of lattice and thermal relaxation in the GaNfilmsgrown on porous substrates. The submicron GaNfilms exhibit a rocking curve linewidth of 3.3 arcmin for (0002) diffraction and 13.7 arcmin for (101̄2) diffraction. Low-temperature photoluminescence showed an excitonic transition with a full width at …

Defect Reduction With Quantum Dots In Gan Grown On Sapphire Substrates By Molecular Beam Epitaxy, D. Huang, Michael A. Reshchikov, F. Yun, T. King, A. A. Baski, Hadis Morkoç

Electrical and Computer Engineering Publications

The GaN films grown on buffer layers containing quantum dots by molecular beam epitaxy on sapphire substrates were investigated. The density of the dislocations in the films was determined by wet chemical etching and atomic force microscopy. It was found that the insertion of a set of multiple GaN quantum-dot layers in the buffer layer effectively reduces the density of the dislocations in the epitaxial layers. As compared to the dislocation density of ∼1010 cm−2in the typical GaN films grown on AlNbuffer layer, a density of ∼3×107 cm−2 was demonstrated in the GaN films grown with quantum dot layers.

Properties Of Alxga1−Xn Layers Grown By Plasma-Assisted Molecular-Beam Epitaxy Under Ga-Rich Conditions, L. He, Michael A. Reshchikov, F. Yun, D. Huang, T. King, Hadis Morkoç

Electrical and Computer Engineering Publications

AlxGa1−xN films were grown by plasma-assisted molecular-beam epitaxy on (0001)sapphire substrates under Ga-rich conditions. To control the AlxGa1−xN composition over the entire range, the Al and Ga arrival rates were fixed while the nitrogen arrival rate was varied. We have found that the Al fraction increased with decreasing N flow due to preferentially favorable bonding of Al and N over Ga and N. Consequently, the growth rate decreased as the Al mole fraction increased. A photoluminescence quantum efficiency at 15 K was markedly higher for the AlxGa1−xN layers grown under Ga-rich conditions (3%–48%) compared to the layers grown under N-rich …

Room-Temperature Single-Electron Charging In Electrochemically Synthesized Semiconductor Quantum Dot And Wire Array, N. Kouklin, L. Menon, Supriyo Bandyopadhyay

Electrical and Computer Engineering Publications

Cylindrical quantum dots of diameter ∼8 nm and height 3–10 nm, and wires of diameter 50 nm and height 500–1000 nm, were self-assembled by electrodepositing semiconductors in the nanometer-sized pores of anodic alumina films. Current–voltage characteristics of both wires and dots show Coulomb blockade at room temperature, while the wires also show a Coulomb staircase when exposed to infrared radiation. These results establish that electrochemicalself-assembly is a viable technique for producing nanostructures that have potential uses in room-temperature single electronics.

Energy Band Bowing Parameter In Alxga1-Xn Alloys, Feng Yun, Michael A. Reshchikov, Lei He, Thomas King, Hadis Morkoç, Steve W. Novak, Luncun Wei

Electrical and Computer Engineering Publications

Molecular-beam epitaxy grown AlxGa1−xN alloys covering the entire range of alloy compositions, 0⩽x⩽1, have been used to determine the alloy band gap dependence on its composition. The Alchemical composition was deduced from secondary ion mass spectroscopy and Rutherford backscattering. The composition was also inferred from x-ray diffraction. The band gap of the alloy was extracted from low temperature optical reflectance measurements which are relatively more accurate than photoluminescence. Fitting of the band gap data resulted in a bowing parameter of b=1.0 eV over the entire composition range. The improved accuracy of the composition and band gap determination …

Implementation Of A Si/Sic Hybrid Optically Controlled High-Power Switching Device, Prashant Bhadri, Kuntao Ye, Elena A. Guliants, Fred R. Beyette Jr.

Electrical and Computer Engineering Faculty Publications

The ever-increasing performance and economy of operation requirements placed on commercial and military transport aircraft are resulting in very complex systems. As a result, the use of fiber optic component technology has lead to high data throughput, immunity to EMI, reduced certification and maintenance costs and reduced weight features. In particular, in avionic systems, data integrity and high data rates are necessary for stable flight control. Fly-by-Light systems that use optical signals to actuate the flight control surfaces of an aircraft have been suggested as a solution to the EMI problem in avionic systems. Current fly-by-light systems are limited by …

Translation Of 'Balika Badhu: A Selected Anthology Of Bengali Short Stories', Monish Ranjan Chatterjee

Electrical and Computer Engineering Faculty Publications

This project, which began with the desire to render into English a rather long tale by Bimal Kar about five years ago, eventually grew into a considerably more extended compilation of Bengali short stories by 10 of the most well-known practitioners of that art since the heyday of Rabindranath Tagore. The collection is limited in many ways, not the least of which being that no woman writer has been included, and that it contains only a baker's dozen stories (if we count Bonophool's micro-stories collectively as one ) — a number pitifully small considering the vast and prolific field of …

Discontinuities And Continuities: A New Way To Understand Virtual Work, Mary Beth Watson-Manheim, Kevin Crowston, Katherine M. Chudoba

School of Information Studies - Faculty Scholarship

“Virtual” is a potent buzzword, freely applied to many situations, with many meanings. In this exploratory study, we develop a more precise understanding of "virtual" to describe changing work environments. Specifically, we propose a framework to classify work environments based on the type of discontinuities involved. Discontinuities are gaps or a lack of coherence in aspects of work. The framework allows us to compare research across different topics and work settings. We use the framework to classify 75 published articles on virtual work environments or earlier, related research streams. We observed that many studies were simultaneously addressing existing or emerging …