Other Mechanical Engineering Commons^™

Ligand Assisted Growth Of Perovskite Single Crystals With Low Defect Density, Ye Liu, Xiaopeng Zheng, Yanjun Fang, Ying Zhou, Zhenyi Ni, Xun Xiao, Shangshang Chen, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

A low defect density in metal halide perovskite single crystals is critical to achieve high performance optoelectronic devices. Here we show the reduction of defect density in per[1]ovskite single crystals grown by a ligand-assisted solution process with 3‐(decyldimethy[1]lammonio)‐propane‐sulfonate inner salt (DPSI) as an additive. DPSI ligands anchoring with lead ions on perovskite crystal surfaces not only suppress nucleation in solution, but also regulate the addition of proper ions to the growing surface, which greatly enhances the crystal quality. The grown CH₃NH₃PbI₃ crystals show better crystallinity and a 23-fold smaller trap density of 7 × 10 …

Social Connectedness And Negative Affect Uniquely Explain Individual Differences In Response To Emotional Ambiguity, Maital Neta, Rebecca L. Brock

Department of Mechanical and Materials Engineering: Faculty Publications

Negativity bias is not only central to mood and anxiety disorders, but can powerfully impact our decision-making across domains (e.g., financial, medical, social). This project builds on previous work examining negativity bias using dual-valence ambiguity. Specifically, although some facial expressions have a relatively clear negative (angry) or positive valence (happy), surprised expressions are interpreted negatively by some and positively by others, providing insight into one’s valence bias. Here, we examine putative sources of variability that distinguish individuals with a more negative versus positive valence bias using structural equation modeling. Our model reveals that one’s propensity toward negativity (operationalized as temperamental …

Direct Numerical Simulation Of A Pulsatile Flow In A Stenotic Channel Using Immersed Boundary Method, Siamak Mirfendereski, Jae Sung Park

Department of Mechanical and Materials Engineering: Faculty Publications

A three-dimensional direct numerical simulation model coupled with the immersed boundary method has been developed to simulate a pulsatile flow in a planar channel with single and double one-sided semicircular constrictions. For relevance to blood flow in large arteries, simulations have been performed at Reynolds numbers of 750 and 1000. Flow physics and resultant wall shear stress (WSS)-based hemodynamic parameters are presented. The instantaneous vortex dynamics, mean flow characteristics, and turbulent energy spectra are evaluated for flow physics. Subsequently, three WSS-based parameters, namely the time-averaged WSS, oscillatory shear index, and relative residence time, are calculated over the stenotic wall and …

Large-Scale Synthesis Of Compressible And Re-Expandable Three-Dimensional Nanofiber Matrices, Alec Mccarthy, Lorenzo Saldana, Daniel Mcgoldrick, Johnson V. John, Mitchell Kuss, Shixuan Chen, Bin Duan, Mark A. Carlson, Jingwei Xie

Department of Mechanical and Materials Engineering: Faculty Publications

Due to their biomimetic properties, electrospun nanofibers have shown great potential in many biomedical fields. However, traditionally-produced nanofibers are typically two-dimensional (2D) membranes limiting their applications. Herein, we report a large-scale synthesis of compressible and reexpandable three-dimensional (3D) nanofiber matrices for potential biomedical applications. The reproducible mass production of such matrices is achieved using a multiple-emitter electrospinning machine with a controlled environment (e.g., temperature, humidity, and air flow rate) followed by an innovative gas-foaming expansion. The modified 20-emitter circular array with 3D-printed needle caps is capable of maintaining stable Taylor cones under extremely high flow rates. The introduction of such …

Assembly Of Close-Packed Ferroelectric Polymer Nanowires Via Interface-Epitaxy With Res2, Dawei Li, Shuo Sun, Kun Wang, Zahra Ahmadi, Jeffrey E. Shield, Stephen Ducharme, Xia Hong

Department of Mechanical and Materials Engineering: Faculty Publications

The flexible, transparent, and low-weight nature of ferroelectric polymers makes them promising for wearable electronic and optical applications. To reach the full potential of the polarization-enabled device functionalities, large-scale fabrication of polymer thin films with well-controlled polar directions is called for, which remains a central challenge. The widely exploited Langmuir–Blodgett, spin-coating, and electrospinning methods only yield polymorphous or polycrystalline films, where the net polarization is compromised. Here, an easily scalable approach is reported to achieve poly(vinylidene fluoride-trifluoroethylene) P(VDF-TrFE) thin films composed of close-packed crystalline nanowires via interface-epitaxy with 1T′-ReS₂. Upon controlled thermal treatment, uniform P(VDF-TrFE) films restructure into …

Reducing Corrosion Of Additive Manufactured Magnesium Alloys By Interlayer Ultrasonic Peening, M. P. Sealy, R. Karunakaran, S. Ortgies, G. Madireddy, A. P. Malshe, K. P. Rajurkar

Department of Mechanical and Materials Engineering: Faculty Publications

Additive manufad (AM) magn alloys corrode rapidly due to tensile stress and coarse microstructures. Cyclically combining (hybridizing) additive manufacturing with interlayer ultrasonic peening was proposed as a solution to improve corrosion resistance of additive manufactured magnesium WE43 alloy through strengthening mechanisms and compressive residual stress. Applying interlayer peening work hardened discrete layers and formed a glocal integrity of regional grain refinement and subsurface compressive residual stress barriers. Tensile residual stress that typically accelerates corrosion decreased 90%. Results showed time-resolved control over corrosion was attainable by interlayer peening, and local corrosion within print cells decreased 57% with respect to as-printed WE43.

Ultra-Fast Charging In Aluminum-Ion Batteries: Electric Double Layers On Active Anode, Xuejing Shen, Tao Sun, Lei Yang, Alexey Krasnoslobodtsev, Renat F. Sabirianov, Michael P. Sealy, Wai-Ning Mei, Zhanjun Wu, Li Tan

Department of Mechanical and Materials Engineering: Faculty Publications

With the rapid iteration of portable electronics and electric vehicles, developing high-capacity batteries with ultra-fast charging capability has become a holy grail. Here we report rechargeable aluminum-ion batteries capable of reaching a high specific capacity of 200 mAh g^−1. When liquid metal is further used to lower the energy barrier from the anode, fastest charging rate of 10⁴ C (duration of 0.35 s to reach a full capacity) and 500% more specific capacity under high-rate conditions are achieved. Phase boundaries from the active anode are believed to encourage a high-flux charge transfer through the electric double layers. As …

Twinning-Assisted Dynamic Adjustment Of Grain Boundary Mobility, Qishan Huang, Qi Zhu, Yingbin Chen, Mingyu Gong, Jixue Li, Ze Zhang, Wei Yang, Jian Wang, Haofei Zhou, Jiangwei Wang

Department of Mechanical and Materials Engineering: Faculty Publications

Grain boundary (GB) plasticity dominates the mechanical behaviours of nanocrystalline materials. Under mechanical loading, GB configuration and its local deformation geometry change dynamically with the deformation; the dynamic variation of GB deformability, however, remains largely elusive, especially regarding its relation with the frequently-observed GB-associated deformation twins in nanocrystalline materials. Attention here is focused on the GB dynamics in metallic nanocrystals, by means of well-designed in situ nanomechanical testing integrated with molecular dynamics simulations. GBs with low mobility are found to dynamically adjust their configurations and local deformation geometries via crystallographic twinning, which instantly changes the GB dynamics and enhances the …

Electron Microscopy Observation Of Electric Field-Assisted Sintering Of Stainless Steel Nanoparticles, Fei Wang, Qin Zhou, Xing-Zhong Li, Yongchul Yoo, Michael Nastasi, Bai Cui

Department of Mechanical and Materials Engineering: Faculty Publications

The intrinsic role of electrical current on the electric field-assisted sintering (EFAS) process of stainless steel 316L nanoparticles has been revealed by both ex situ and in situ experiments. A novel device on the Si chip has been designed and fabricated to fit into the sample holder of a transmission electron microscope for these experiments. The evolution of nanoparticle morphology and microstructures during the EFAS process has been studied using scanning electron microscopy and transmission electron microscopy, which has been combined with the simultaneous measurement of the electric voltage and current changes. A preliminary four-stage mechanism for the EFAS process …

On The Improvements Of Boundary-Layer Representation For High Resolution Weather Forecasting In Costal-Urban Environments, David Melecio-Vazquez

Dissertations and Theses

As large urban centers around the world become more densely populated, the global conversion from natural to man-made land surfaces will only increase. These land-use changes affect the urban surface energy budget which in turn changes the structure of the planetary boundary layer (PBL) above. With current high-performance computing systems, meteorological and built environment information can be better utilized to quantify the anthropogenic effects of these modifications. Although these systems have improved forecasting near-surface weather conditions, a comprehensive approach to represent urban impacts on the PBL is still limited. Improved PBL representation can lead to better weather and climate forecasts, …

The Diffuse Bounce Back Lattice Boltzmann Method And Its Applications On The Study Of Fluid-Particle Interactions, Geng Liu

Dissertations and Theses

Fluid-structure interaction is very broadly seen and widely used in many industrial, engineering and environmental processes. The lattice Boltzmann method has been preferred for simulating particulate flows due to its advantages of easy implementation, micro- and mesoscopic physical insights and parallel algorithm. Both sharp and diffuse boundary treatments are studied to recover curved and moving boundaries on structured orthogonal grids for the lattice Boltzmann method. These methods can describe curved boundaries more accurately and more smoothly than the naive staircase approximation. However, to improve the order of velocity accuracy and to reduce the fluctuation of force, either interpolation or additional …

Impact Dynamics Of Surfactant-Laden Droplets On Non-Wettable Coatings, Amir Esmaeili

Theses and Dissertations

Owing to their excellent water repellency, non-wettable (superhydrophobic) coatings have gained tremendous attention in the past couple of decades. Alkyl ketene dimer (AKD), an inexpensive polymer frequently used in paper industry as a sizing agent, has shown potentials to become superhydrophobic. The formation of a porous structure after curing the solidified AKD for an extra-long time (4–6 days) results in superhydrophobicity, i.e., a static contact angle with water of >150° and a roll-off angle of <10°. In this work, a facile and low-cost method was used to turn the surface of AKD superhydrophobic in a very short period of time by briefly treating the coatings, obtained from isothermally heated molten AKD at 40 °C for 3 min, with ethanol. The resulting superhydrophobicity is due to the formation of porous, entangled irregular micro/nano textures that create air cushions on the surface leading to droplet state transition from Wenzel to Cassie. As a proof of concept, the same material was applied to the co-sputtered nickel-tungsten thin films, commonly used in micro/nano-electro-mechanical systems, to improve their hydrophobicity. According to the results, at least 20% increase was observed in the dynamic contact angles of the treated substrates.

In addition, this work presents a detailed high-speed imaging analysis of the influence of the molecular weight, concentration and ionic nature of surfactants on droplet …

Performance And Economical Analysis Of Different Insulating Materials Used To Reduce The Heat Load Of An Existing Residential Building, Radwa A. El-Awadly, Ahmed A. Abdel-Rehim

Mechanical Engineering

The energy consumption from the residential sector is an important element which has an impact on the total energy consumption in any country. The heating and air conditioning loads can be reduced through many means. Using thermal insulation in buildings does not only contribute in reducing the required air conditioning system size, but also in reducing the annual energy cost for the whole building. In this case, the energy saving varies according to the building type, the climatic conditions at which the building is located as well as the type of the insulating material used. In the present study, an …

A Combined Study Of Heat Transfer And Temperature Distribution Inside Heated Double-Wall Infant Incubator Using Cfd, Hesham Safwat

Mechanical Engineering

What will be the answer if someone tried walking on the street and asking ten mothers in which pregnancy month their child had been born? The answer will be shocking because according to World Health organization (WHO 2012) at least one out of those ten mothers will answer that her kid was born earlier than his/her time! There are more than 15 million premature babies in the world having their first breath every year earlier than their times and more than 1.1 million of them the first few breaths unfortunately become their last. Moreover, if this question is asked to …

Cfd Investigation Of The Optimal Ventilation System For A Single-Family Room Neonatal Intensive Care Unit, Hesham Safwat, Ahmed Elbaz

Mechanical Engineering

Newborns are immunocompromised, and they are more susceptible to get infected than elders, hence, they should be kept in an aseptic environment that is almost free of microorganisms. A neonatal intensive care unit (NICU) is intended for caring for ill, premature and low-birth-weight infants. There are 2 main types of NICUs: the open-bay (OBA) NICU and single-family room (SFR) NICU. Researches have proved that the SFR NICUs have many advantages as compared with the OBA NICUs ,hence, SFR NICUs are predominant worldwide since 1994. The ventilation system has a crucial role in the infection prevention and control (IPC) program, as …

Investigating Nox Vs Co2 Tradeoff In Heavy Duty Emissions Through The Years Under The Scope Of Carb’S 3-Bin Moving Average Window Method, Ghadi Sadek

Graduate Theses, Dissertations, and Problem Reports (ETD)

With the rise in urban pollution level over the last few years, regulatory agencies around the world have taken multiple steps to ensure engine exhaust pollutant are well monitored and properly regulated. Yet there exists a significant difference in emissions rates in various operating conditions between US and European products which currently uses a Moving average window (MAW) approach for their in-use compliance testing and certification program. Using WVU’s vehicle data collected using PEMS devices, this study aims at investigating the NOx versus CO2 tradeoff found in heavy duty diesel engines equipped with different aftertreatment technologies, under the scope of …

On The Improvement Of The Indirect Quantification Of Methane Emissions: A Stationary Single Sensor Approach, Robert Scott Heltzel

Graduate Theses, Dissertations, and Problem Reports (ETD)

There is a need for improved indirect quantification of methane emissions, particularly from the natural gas industry. Natural gas production continues to increase along with the number of wells and production sites. These production sites have the potential to contribute significant levels of methane emissions. Methane is a potent greenhouse gas and the primary component of natural gas. A more complete understanding of emissions through improved quantification will lead to enhanced mitigation. Emissions have historically been quantified with both direct and indirect methods, with varying results. Emissions have been shown to be both temporally and spatially variable. These facts have …

Development Of Synthetic Coal Char Simulant For Microwave Conversion Studies: A Computationally-Driven Approach, Kevin A. Hager

Graduate Theses, Dissertations, and Problem Reports (ETD)

Recent experimental demonstration of new reaction windows for coal char/methane reactions that are less energy-intensive, provides innovation for modular reactors. However, the correlation of the exact mechanism for the enhancement of these reaction windows is not certain. This study investigates the simplification of these experimental studies by developing a well-characterized coal char simulant. The approach involves using a computational approach to screen macroscopic composition to replicate the dielectric and compositional response of actual char. This study is focused on PRB coal char. A discrete element method (DEM) technique was used to simulate the packing of coal chars to give the …

A Road Grade Based Weighting System For Calculating On-Road Distance-Specific Oxides Of Nitrogen Emissions Of Light-Duty Diesel Vehicles, Jason D. Bolyard

Graduate Theses, Dissertations, and Problem Reports (ETD)

Light-duty diesel vehicles have received significant public and governmental scrutiny recently for violating emissions regulations. Similar to the heavy-duty diesel manufacturers during the late 1990’s, some light-duty manufacturers were implementing different control strategies between laboratory certification tests and customer on-road operation. These devices allowed the vehicle to pass certification tests but then use alternative operation on the road during normal use. The alternative operation would allow for better fuel economy but higher oxides of nitrogen (NOx) emissions. Light-duty vehicles are currently certified in the US using chassis dynamometer testing. The effects of all on-road driving conditions are not mimicked in …

Predictive Maintenance Of Bearing Machinery Using Simulation- A Bibliometric Study, Karan Gulati Mr., Keshav Basandrai Mr., Shubham Tiwari Mr., Pooja Kamat Prof., Satish Kumar Dr.

Library Philosophy and Practice (e-journal)

Modelling is a way of constructing a virtual representation of software and hardware that involves a real-world device. We will discover the behaviour of the system if the software elements of this model are guided by mathematical relationships. For testing conditions that may be difficult to replicate with hardware prototypes alone, modelling and simulation are particularly useful, especially in the early phase of the design process when hardware might not be available. Model-based approach in MATLAB-Simulink can be useful for predictive maintenance of machines as it can reduce unplanned downtimes and maintenance costs when industrial equipment breaks. Through this bibliometric …