Materials Science and Engineering Commons^™

Growth And Characterization Of Nanoscale Thin Films, Erik Thomas Wolter

Honors Program Theses

Thin manganese films were grown by thermal evaporation in high vacuum. The growth rate was varied to determine how the growth rate affects the continuity of ultra-thin films. The resistance was measured with the two-point method in situ and the data was recorded digitally. The resistance was converted to resistivity and this was plotted against thickness. It was found that resistivity decreases exponentially as the film begins to form in islands. The film reaches a critical thickness as the islands coalesce and the data can then be fitted with Fuchs’ equation. The resistivity continues to decrease but the minimum resistivity …

Development Of Thermo-Regulating Fabric Using Phase Change Material (Pcm), Prasad S. Bhatkhande

Master's Theses and Doctoral Dissertations

This research study concentrates on use of phase change material (PCM) in textiles which can produce thermo-regulating characteristics to control body temperature useful for various daily wear and technical textiles. The latent heat which is released or absorbed during the process of phase change is studied and discussed in this research. The PCMs are encapsulated into tiny microcapsules to protect from washing out or abrasion. These microcapsules are bounded onto the fabric surface by using a binder. The microcapsules and their effectiveness are tested by using SEM, Optical Microscope, DSC and Comfort tester. The testing is further extended to the …

Synthesis And Characterization Of Carbon Magnetic Nanoparticles, Sunilsingh Gusain

Material Science and Engineering Theses - Archive

Carbon incorporated iron nanoparticles (Fe-CNPs) were successfully synthesized using ultrasonic cavitation in Benzene. This novel method of carbon nanoparticle (CNP) synthesis is a very cost-effective and versatile as one can easily tune the microstructure and magnetic properties by varying few parameters, for e.g. voltage. The Fe-CNP complexes are produced due to the electric plasma discharge generated between the electrodes in an ultrasonic cavitation field of liquid benzene. The constituent of the CNPs can be easily modified by different choice of electrode materials- iron and graphite. The resultant Fe-CNPs were characterized by high-resolution transmission electron microscopy and X-ray photoelectron spectroscopy to …

Stabilisation Of Linear-Cavity Fibre Laser Using A Saturable Absorber, David Michel, Feng Xiao, Kamal Alameh

Research outputs 2011

We investigate the optimisation of the length of an un-pumped erbium doped fibre (EDF) in order to suppress amplifier noise in a linear-cavity fibre laser structure. The experimental results demonstrate the existence of an optimum length of the un-pumped EDF which eliminates noise due to high optical pumping powers, thus leading to a stable laser output.

Garnet Multilayer Thin Film Structure With Magnetostatically-Altered And Improved Magnetic Properties Prepared By Rf Magnetron Sputtering, Mohammad Nur-E-Alam, Mikhail Vasiliev, Viacheslav Kotov, Kamal Alameh

Research outputs 2011

We prepare an all-garnet multilayer film structure by sandwiching a magneto-soft garnet material in between two magneto-hard garnet materials with high bismuth substitution levels using RF magnetron sputtering technique and investigate the microstructure and the effects of magnetostatic inter-layer coupling on magnetic properties. Both types of the Bi-substituted magneto-optic garnet materials used possess excellent optical, magnetic and magneto-optical properties suitable for the application in different new and emerging technologies in optics and photonics. Garnet layers of composition type Bi2Dy1Fe4Ga1O12 have strong perpendicular magnetic anisotropy and Bi1.8Lu1.2Fe3.6Al1.4O12 magneto-soft layer features magnetization behavior similar to that of in-plane magnetized films. The all-garnet …

Stress Corrosion Cracking Evaluation Of Candidate High Strength Stainless Steels For Prestressed Concrete, Joseph Rogelio Fernandez

USF Tampa Graduate Theses and Dissertations

Prestressed concrete piles are commonly used to support over-water highway bridges in marine environments. The reinforcing steel within will ultimately be degraded via corrosion damage due to the penetration of chloride ions from sea water. The service life of these structures is, in part, dictated by the time required to diffuse chloride ions through the concrete cover and subsequently corrode the steel. Therefore, by slowing the rate of diffusion or increasing the chloride threshold of the steel (or both) an increased service life can be expected. This thesis focuses on the latter whereby stainless steel reinforcing alternatives were investigated to …

Growth And Characterization Of Thermoelectric Ba8Ga16Ge30 Type-I Clathrate Thin-Films Deposited By Pulsed Dual-Laser Ablation, Robert Harry Hyde

USF Tampa Graduate Theses and Dissertations

The on-going interest in thermoelectric (TE) materials, in the form of bulk and films, motivates investigation of materials that exhibit low thermal conductivity and good electrical conductivity. Such materials are phonon-glass electron-crystals (PGEC), and the multi-component type-I clathrate Ba₈Ga₁₆Ge₃₀ is in this category. This work reports the first investigation of Ba₈Ga₁₆Ge₃₀ films grown by pulsed laser deposition (PLD).

This dissertation details the in-situ growth of polycrystalline type-I clathrate Ba₈Ga₁₆Ge₃₀ thin-films by pulsed laser ablation. Films deposited using conventional laser ablation produced films that contained a …

Oxygen Diffusion Characterization Of Frp Composites Used In Concrete Repair And Rehabilitation, Chandra K. Khoe

USF Tampa Graduate Theses and Dissertations

Many independent studies have conclusively demonstrated that fiber reinforced polymers (FRP) slow down chloride-induced corrosion of steel in concrete. The mechanism for this slow down is not well understood but it has been hypothesized that FRP serves as a barrier to the ingress of chloride, moisture, and oxygen that sustain electrochemical corrosion of steel.

This dissertation presents results from an experimental study that determined the oxygen permeation rates of materials used in infrastructure repair. In the study, the oxygen permeation constants for epoxy, carbon and glass fiber laminates, concrete, epoxy-concrete and FRP-concrete systems were determined and a method developed to …

Novel Magnetic Materials For Sensing And Cooling Applications, Anurag Chaturvedi

USF Tampa Graduate Theses and Dissertations

The overall goals of the present PhD research are to explore the giant magnetoimpedance (GMI) and giant magnetocaloric (GMC) effects in functional magnetic materials and provide guidance on the optimization of the material properties for use in advanced magnetic sensor and refrigeration applications.

GMI has attracted growing interest due to its promising applications in high-performance magnetic sensors. Research in this field is focused on the development of new materials with properties appropriate for practical GMI sensor applications. In this project, we have successfully set up a new magneto-impedance measurement system in the Functional Materials Laboratory at USF. We have established, …

Rate-Dependent Stiffening And Strain Localization In Physically Associating Solutions, Kendra Erk, Kenneth R. Shull

School of Materials Engineering Faculty Publications

Model physically associating solutions of acrylic triblock copolymer molecules in a midblock-selective solvent displayed non-linear strain-stiffening behavior which transitioned to rapid strain softening during shear start-up experiments at reduced rates spanning almost four orders of magnitude. Softening was believed to result from the shear-induced formation of highly localized regions of deformation in the macromolecular network. This behavior was accurately captured by a model that incorporated the strain energy and relaxation behavior of individual network strands in the solution. Flow curves predicted from the model were non-monotonic, consistent with the onset of flow instabilities at high shear rates. The non-linear stress …

Density Functional Theory Study On The Electronic Structure Of N- And P-Type Doped Srtio3 At Anodic Solid Oxide Fuel Cell Conditions, S. Suthirakun, Salai Cheettu Ammal, G. Xiao, Fanglin Chen, Hans-Conrad Zur Loye, Andreas Heyden

Faculty Publications

The electronic conductivity and thermodynamic stability of mixed n-type and p-type doped SrTiO3 have been investigated at anodic solid oxide fuel cell (SOFC) conditions using density functional theory (DFT) calculations. In particular, constrained ab initio thermodynamic calculations have been performed to evaluate the phase stability and reducibility of various Nb- and Ga-doped SrTiO3 at synthesized and anodic SOFC conditions. The density of states (DOS) of these materials was analyzed to study the effects of n- and p-doping on the electronic conductivity. In agreement with experimental observations, we find that the transformation from 20% Nb-doped Sr-deficient SrTiO3 to a non-Sr-deficient phase …

A Comparison Of Two Engineering Outreach Programs For Adolescents, Louis S. Nadelson, Janet M. Callahan

Materials Science and Engineering Faculty Publications and Presentations

There is continued growth and development of outreach programs designed to increase pre-college students’ awareness and understanding of engineering as a profession and as a career. These outreach programs vary in format and in the groups targeted for participation but maintain the same fundamental goal of increasing participant knowledge of engineering. Many of these outreach programs also maintain the implicit goal of increasing the participants' knowledge and attitudes toward college. The additional resources and funding that are commonly allocated to support outreach programs frequently involve documenting accountability which motivates evaluation of program impact. Therefore, many outreach events include program evaluation …

Mse News 2011, Department Of Materials Science And Engineering, Michigan Technological University

Department of Materials Science and Engineering Annual Reports

Table of Contents

• New Fund and Center: a Challenge, an Opportunity, and an Appeal from Chair Mark Plichta
• MSE Scientist: Positioned for Success with Unique Program
• Student Accomplishments and Awards
• Department News
• Alumni Updates

Electronically Enhanced Surface Diffusion During Ge Growth On Si(100), Ali Orguz Er, Hani E. Elsayed-Ali

Physics Faculty Publications

The effect of nanosecond pulsed laser excitation on surface diffusion during the growth of Ge on Si(100) at 250 °C was studied. In situ reflection high-energy electron diffraction was used to measure the surface diffusion coefficient while ex situ atomic force microscopy was used to probe the structure and morphology of the grown quantum dots. The results show that laser excitation of the substrate increases the surface diffusion during the growth of Ge on Si(100), changes the growth morphology, improves the crystalline structure of the grown quantum dots, and decreases their size distribution. A purely electronic mechanism of enhanced surface …

Tof-Sims Analysis Of Hydrogen In Niobium, From 160°K To 475°K, P. Maheshwari, G. R. Myneni, G. Ciovati, C. Zhou, F. A. Stevie, J. M. Rigsbee, D. P. Griffis, A. D. Batchelor

Physics Faculty Publications

Niobium (Nb) is the material of choice for superconducting radio frequency (SRF) cavities due to its high critical temperature and critical magnetic field. Interstitial impurity elements such as H directly influence the efficiency of these cavities. Quantification of H in Nb is difficult since H is extremely mobile in Nb with a very high diffusion coefficient even at room temperature. In the presented work, Time of Flight Secondary Ion Mass Spectrometry (TOF-SIMS) was used to characterize H in Nb over a wide temperature range (160°K to 475°K) in situ to check for changes in mobility. Multiple experiments showed that as …

Effect Of Nickel On Castability Of Chromium Molybdenum Steel & The Dynamic Fracture Toughness Of Hy-130, Abhilash Dash

Masters Theses

"The fill lengths of Ni alloyed Cr-Mo steels obtained from fluidity studies (Paper 1) varied linearly with superheat. A 5% Ni steel showed a maximum fill length compared to other steels tested. Ni decreased the liquidus, solidus, and dendritic coherency temperature, but it did not have any significant effect on volume fraction (0.27-0.31) of the solid phase at the dendrite coherency point. The filling time obtained experimentally at 150 C⁰ superheat for 5% Ni steel (HY 130) was close to 1.4 s. For similar conditions, the predicted fill time using a Magmasoft model was close to 1.9 s. Modeling results …

Thermo-Physical Properties Measurement And Steel - Ceramic Shell Interactions In Investment Casting, Chirag Mahimkar

Masters Theses

"Investment casting is a process in which a ceramic shell is prepared on a wax or foam pattern. The wax is melted out or the foam is burnt out and the shell is sintered to have sufficient strength to withstand casting conditions. The investment casting process is very important as it produces near net shape castings which reduce the need for subsequent operations of castings like machining etc. Investment casting shells are subjected to a number of heating cycles during pattern removal, firing, preheating before pouring and finally during solidification. The thermo-physical properties of the shell play an important role …

The Effect Of Cr, Si And B On The Oxidation Behavior On Three Nb-Based Alloys, David Alvarez

Open Access Theses & Dissertations

Nb-based alloys are of particular interest to replace the current Ni-based superalloys for high-temperature structural applications. One important limitation to improve the efficiency of gas-turbine engines is the temperature limit of current materials being used. By allowing the temperature to increase, the efficiency will increase. Nb-based alloys have high melting points and adequate mechanical properties but the oxidation resistance is still inadequate.

This research focuses on the oxidation behavior of three Nb-based alloys to study the effect of Cr and Si variation and look at the effect of Boron. Boron can form a glassy borosilicate which is viscous at high …

Fabrication And Characterization Of Nanocrystalline Yttrium Oxide Thin Films For Electronic Device Applications, Mudavakkat Vikas Haridas

Open Access Theses & Dissertations

This thesis presents the optimization of growth conditions for fabricating nanocrystalline Yttrium Oxide (Y2O3) thin films on silicon and optical grade, high quality quartz substrates in order to study its structural, optical and electrical properties for electronic device applications.

Commercially Y2O3 has proven to be difficult to fabricate at high quality due to its high temperature growth requirements and the need to alter established fabrication methods for electronic devices. A high temperature requirement for high quality poses a problem for research and analysis. This calls upon for an optimization of the growth conditions to facilitate fabrication of thin films for …

Preparation And Characterization Of Iron Oxide And Hydroxide Based Nanomaterials, Guillermo Carbajal Franco

Open Access Theses & Dissertations

Iron (Fe) oxides and hydroxides are common and abundant materials. They exhibit diverse crystal structures, properties and phenomena by virtue of which they find a wide range of scientific and technological applications. Controlled growth and manipulation of the specific structure and electronic behavior to meet the requirements of a given application is a challenging problem in view of many possible phases and composition of the resulting materials. The preparation method and experimental conditions will, therefore, significantly affect the properties and performance of Fe oxides and hydroxides. The goal of the project is to obtain Fe-based oxide/hydroxide catalytic materials and to …