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Fate Of Conductive Ink Pigments During Recycling And Landfill Deposition Of Paper-Based Printed Electronics, James Edward Atkinson 2017 Western Michigan University

Fate Of Conductive Ink Pigments During Recycling And Landfill Deposition Of Paper-Based Printed Electronics, James Edward Atkinson

Dissertations

Printed electronics (PE) are being developed as an alternative to traditional electronics, due to the more efficient use of materials and lower cost of production. The overall goal of this study was to understand how metallic pigments in conductive inks in PE are partitioned during landfill disposal and paper recycling conditions. The purpose is to assess the potential environmental impacts of PE landfilling in terms of metal leaching and to help develop new strategies for sequestering metallic ink components while paper-based PE are subjected to conventional paper recycling methods. The objective of this research is to study the fate of …


Mitigation Of Corrosion Under Insulation (Cui) Of Carbon Steel Of Different Insulating Materials: A Literature Review And Testing Analysis, Michael Alexander Lowes 2017 California Polytechnic State University, San Luis Obispo

Mitigation Of Corrosion Under Insulation (Cui) Of Carbon Steel Of Different Insulating Materials: A Literature Review And Testing Analysis, Michael Alexander Lowes

Materials Engineering

Equipment often found in refineries may be enveloped in insulation and weathering jackets to maintain internal processing temperatures. In many cases moisture from the environment will penetrate the weathering jacket and infiltrate the insulation, leaching corrosive ions to the surface of metal equipment, effectively creating a corrosion cell. The goal of this project is to investigate different insulating materials for their ability to inhibit corrosion under insulation (CUI). The inhibiting mechanism utilizes water ingress that leaches ions from the insulator to bond with the surface metal and create a passive layer, inhibiting any further corrosion. This study will follow ASTM …


Preliminary Investigations Into Selective Laser Melting, David Takeo Otsu 2017 California Polytechnic State University, San Luis Obispo

Preliminary Investigations Into Selective Laser Melting, David Takeo Otsu

Master's Theses

Selective laser melting is a promising metallic additive manufacturing process with many potential applications in a variety of industries. Through a gracious donation made by Lawrence Livermore National Laboratory, California Polytechnic State University received and installed an SLM 125 HL selective laser melting machine in February 2017. As part of the initial setup effort, a preliminary machine verification study was conducted to evaluate the general print quality of the machine with default parameter settings. Coincidentally, the as-printed microstructure of SLM components was evaluated through nil strength fracture surface examination, an alternative to conventional polish-and-etch metallography. A diverse set of components …


Kinked Tensile Behavior Of Cold Worked Nitinol, Grant R. Caraway, Samuel J. Canovas 2017 California Polytechnic State University, San Luis Obispo

Kinked Tensile Behavior Of Cold Worked Nitinol, Grant R. Caraway, Samuel J. Canovas

Materials Engineering

To characterize the decrease in ductility caused by an induced stress concentration as a function of various levels of cold work and heat treatment, Nitinol medical guide wires with a .004″ diameter were tested using both a standard, straight tensile test and a modified, bent tensile test. The ratio of the two break loads (bent:straight) for identically processed samples was used as a proxy for measuring the ductility of the guide wires: the higher the ratio, the more ductile the sample. The average break load ratio as a function of increased cold work, decreased from 1.27 to 0.91 for the …


Effect Of Composition And Build Direction On Additively Manufactured Hastelloy X Alloys, Justin A. Spitzer, Jeffrey T. Schloetter, Sarah Zerga 2017 California Polytechnic State University, San Luis Obispo

Effect Of Composition And Build Direction On Additively Manufactured Hastelloy X Alloys, Justin A. Spitzer, Jeffrey T. Schloetter, Sarah Zerga

Materials Engineering

Microcracking has caused premature failure and reduction in properties in additively manufactured (AM) Hastelloy X. The purpose of this research is to meet or exceed the mechanical properties of wrought Hastelloy X by modifying the composition and build direction of Hastelloy X manufactured using Direct Metal Deposition (DMD). Tensile testing, scanning electron microscopy (SEM), and metallography were performed on the samples. ANOVA was used to analyze the dependence that the properties had on build direction and composition. The nominal composition wrought samples had a yield strength of 310.1 MPa and a 60.79% Elongation. Alloy P60-X18 in a horizontal build had …


Mini High Temperature Test Unit Final Design Report, Kevin Liu, Juan P. Castillo 2017 California Polytechnic State University, San Luis Obispo

Mini High Temperature Test Unit Final Design Report, Kevin Liu, Juan P. Castillo

Mechanical Engineering

Lawrence Livermore National Laboratory has invested considerable effort to develop new standard for nuclear grade HEPA filters that can withstand high temperatures along with methods to optimally test not only the experimental filter media, but also new frame seals and media binders. Therefore, LLNL in collaboration with Cal Poly has designed and built a Mini High Temperature Testing Unit (MHTTU) to recreate conditions observed during a fire and to test different materials in an effective, inexpensive, regulated and reliable method. The existing prototype was unable to achieve the ideal testing conditions of 1000°F air at the low flow rates of …


Bear Minimum: Ultralight Composite Bear Canister, Rama B. Adajian, Adam C. Eisenbarth 2017 California Polytechnic State University, San Luis Obispo

Bear Minimum: Ultralight Composite Bear Canister, Rama B. Adajian, Adam C. Eisenbarth

Mechanical Engineering

The ultralight backpacking community needs a strong, easy to use, safe bear canister that is lighter than current market products for trekking in the backcountry. A full design of the lid for the bear canister is to be completed. This includes the locking mechanism to ensure it is bear proof, the interface between the lid and the canister, and the structure of the lid so it passes the strength and weight specifications. The lid, along with the already designed canister body, is to be manufactured with formal documentation. The lid will initially be tested separately and then with the canister …


The Magnetic, Electrical And Structural Properties Of Copper-Permalloy Alloys, Makram A. Qader, A. Vishina, Lei Yu, Cougar Garcia, Rakesh K. Singh, Nicholas D. Rizzo, Mengchu Huang, Ralph Chamberlin, Kirill Belashchenko, Mark van Schilfgaarde, N. Newman 2017 Arizona State University

The Magnetic, Electrical And Structural Properties Of Copper-Permalloy Alloys, Makram A. Qader, A. Vishina, Lei Yu, Cougar Garcia, Rakesh K. Singh, Nicholas D. Rizzo, Mengchu Huang, Ralph Chamberlin, Kirill Belashchenko, Mark Van Schilfgaarde, N. Newman

Kirill Belashchenko Publications

Copper-permalloy [Cu1–x(Ni80Fe20)x] alloy films were deposited by co-sputtering and their chemical, structural, magnetic, and electrical properties were characterized. These films are found to have favorable weak ferromagnetic properties for low temperature magnetoelectronic applications. Our results show that by varying the composition, the saturation magnetization (Ms) can be tuned from 700 emu/cm3 to 0 and the Curie temperature (Tc), can be adjusted from 900 K to 0 K. The Ms and Tc are found to scale linearly between x = 25% and 100%. Electronic structure calculations …


Memorizing Chromic Response To Pressure, Maulik Kiritkumar Padh 2017 New Jersey Institute of Technology

Memorizing Chromic Response To Pressure, Maulik Kiritkumar Padh

Theses

Almost all appliances are prone to mechanical stress in one form or the other. An increasing dependence on machines in daily life calls for a need to increase their maintenance quality. Various materials, methods and configurations to observe mechanical pressure have been devised and this paper discusses one such technique. The use of gold nanoparticles in its one dimensional array causes plasmonic coupling between the nanoparticles, which when disrupted creates a plasmonic shift in its assembly. Such a film, when casted on a polymer with a known elastic limit, causes deformation by an application of stress. This forces the film …


Corrosion Studies Of Stainless Steel Blades, Dhruv S. Kothari 2017 New Jersey Institute of Technology

Corrosion Studies Of Stainless Steel Blades, Dhruv S. Kothari

Theses

Corrosion is a subject of interest to interdisciplinary research communities that includes fields of materials science, chemistry, physics, metallurgy and chemical engineering. In order to understand the mechanisms of corrosion and the function of corrosion inhibitors, the reactions at the interfaces between the corrosive electrolyte and a steel surface, particularly at the initial stages of the corrosion process, need to be described. Naturally, these reactions are strongly affected by the nature and properties of the steel surfaces. It is however seen that the majority of recent corrosion and corrosion-inhibition investigations are limited to electrochemical testing, with ex situ analysis of …


Smart Polymeric Temperature Sensors – For Biological Systems, Greenee Anilkumar Sinha 2017 New Jersey Institute of Technology

Smart Polymeric Temperature Sensors – For Biological Systems, Greenee Anilkumar Sinha

Theses

The damaged brain is vulnerable to increase in brain temperature after a severe head injury. Continuous monitoring of intracranial temperature depicts functionality essential to the treatment of brain injury Many innovations have been made in the biomedical industry relying on electronic implants in treating condition such as traumatic brain injury (TBI) or other cerebral diseases. Hence, a methodical and reliable way to measure the temperature is crucial to assess the patient’s situation. In this investigation, an analysis of various approaches to detect the change in the temperature due to resistance, current-voltage characteristics with respect to time has been evaluated. Also, …


Operating Temperature Of A Solar Thermal Stirling Engine, Spencer Beck 2017 Linfield College

Operating Temperature Of A Solar Thermal Stirling Engine, Spencer Beck

Senior Theses

This paper explores the relationship between the operating temperature and electricity production of a simple heat engine. A Stirling engine was designed and constructed which runs on solar thermal energy collected by a Fresnel lens. The surface area of the solar collector was varied. This manipulated the operating temperature of the Stirling engine in order to measure power output. The mechanical energy from the engine was converted to electricity using a DC motor running in reverse, acting like a generator, in conjunction with an Arduino for data collection. Although adjustments must be made in order to improve the efficiency of …


Thin Film Thermal Deposition At Various Pressures, James Kela Yee Keen Grace 2017 Linfield College

Thin Film Thermal Deposition At Various Pressures, James Kela Yee Keen Grace

Senior Theses

This research was to verify the hypothesis that resistivity of metal's thin film deposited in a low-pressure environment is the same as its solid material. Thermal Evaporation is a thin film deposition technique in which metal inside a vacuum is evaporated, then deposited onto a surface. Higher quality metal films are deposited when the vacuum pressure is lower. At higher pressures, more air molecules are trapped within the layers of metal, thus increasing scattering sites and increasing the resistance. However, reaching a lower pressure requires more time and effort. In this research, films were deposited at various pressures and resistivities …


Are Solar Panels A Viable Power Source For A Green Energy Vehicle?, Mason C. Adams 2017 Linfield College

Are Solar Panels A Viable Power Source For A Green Energy Vehicle?, Mason C. Adams

Senior Theses

A solar cell powered go-kart has been built and tested. The result shows using solar energy alone cannot meet the requirement of running a regular passenger car. This is due to the limited surface area of the passenger car. This thesis also discusses the operating principles of solar panels, the physics of P type and N type semiconductors, and the formation of the PN junction, as well as the solar current. Modifications of an existing go-kart are described in detail in this thesis. Suggestions for making green vehicles are discussed as well.


Observing Orbital Angular Momentum Transfer From Electron Vortex Beams To Matter, Hannah DeVyldere 2017 Linfield College

Observing Orbital Angular Momentum Transfer From Electron Vortex Beams To Matter, Hannah Devyldere

Senior Theses

It is possible to produce electron beams with non-zero orbital angular momentum. Such beams, known as electron vortex beams, are theoretically able to transfer their orbital angular momenta to matter, causing the matter to rotate. Nanoparticles in an aqueous solution were observed with an electron vortex beam to detect the transfer of orbital angular momentum in a low-friction environment. Observing the transfer of orbital angular momentum to particles in solution is difficult due to the necessity of imaging the particles through a liquid and the random movement of particles in the solution. Thus, orbital angular momentum transfer to matter could …


Ferroelectric-Semiconductor Systems For New Generation Of Solar Cells, Rahmatollah Eskandari 2017 University of New Orleans, New Orleans

Ferroelectric-Semiconductor Systems For New Generation Of Solar Cells, Rahmatollah Eskandari

LSU New Orleans Theses and Dissertations

This dissertation includes two parts. In the first part the study is focused on the fabrication of multifunctional thin films for photovoltaic applications. There is no doubt about the importance of transforming world reliance from traditional energy resources, mainly fossil fuel, into renewable energies. Photovoltaic section still owns very small portion of the production, despite its fast growth and vast research investments. New methods and concepts are proposed in order to improve the efficiency of traditional solar cells or introduce new platforms. Recently, ferroelectric photovoltaics have gained interest among researchers. First objective in application of ferroelectric material is to utilize …


Desulfination By 2′-Hydroxybiphenyl-2-Sulfinate Desulfinase Proceeds Via Electrophilic Aromatic Substitution By The Cysteine-27 Proton, Inacrist Geronimo, Shawn R. Nigam, Christina M. Payne 2017 University of Kentucky

Desulfination By 2′-Hydroxybiphenyl-2-Sulfinate Desulfinase Proceeds Via Electrophilic Aromatic Substitution By The Cysteine-27 Proton, Inacrist Geronimo, Shawn R. Nigam, Christina M. Payne

Chemical and Materials Engineering Faculty Publications

Biodesulfurization is an attractive option for enzymatically removing sulfur from the recalcitrant thiophenic derivatives that comprise the majority of organosulfur compounds remaining in hydrotreated petroleum products. Desulfurization in the bacteria Rhodococcus erythropolis follows a four-step pathway culminating in C–S bond cleavage in the 2′-hydroxybiphenyl-2-sulfinate (HBPS) intermediate to yield 2-hydroxybiphenyl and bisulfite. The reaction, catalyzed by 2′-hydroxybiphenyl-2-sulfinate desulfinase (DszB), is the rate-limiting step and also the least understood, as experimental evidence points to a mechanism unlike that of other desulfinases. On the basis of structural and biochemical evidence, two possible mechanisms have been proposed: nucleophilic addition and electrophilic aromatic substitution. Density …


Current Understanding And Future Research Directions At The Onset Of The Next Century Of Sintering Science And Technology, Rajendra K. Bordia, Suk-Joong L. Kang, Eugene A. Olevsky 2017 Clemson University

Current Understanding And Future Research Directions At The Onset Of The Next Century Of Sintering Science And Technology, Rajendra K. Bordia, Suk-Joong L. Kang, Eugene A. Olevsky

Publications

Sintering and accompanying microstructural evolution is inarguably the most important step in the processing of ceramics and hard metals. In this process, an ensemble of particles is converted into a coherent object of controlled density and microstructure at an elevated temperature (but below the melting point) due to the thermodynamic tendency of the particle system to decrease its total surface and interfacial energy. Building on a long development history as a major technological process, sintering remains among the most viable methods of fabricating novel ceramics, including high surface area structures, nanopowder-based systems, and tailored structural and functional materials. Developing new …


Nanostructured Dielectric Materials For High Energy Density Multi Layer Ceramic Capacitors, Fatih Dogan 2017 Missouri University of Science and Technology

Nanostructured Dielectric Materials For High Energy Density Multi Layer Ceramic Capacitors, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

A high energy density multilayer ceramic capacitor, having at least two electrode layers and at least one substantially dense polycrystalline dielectric layer positioned therebetween. The at polycrystalline dielectric layer has an average grain size of less than about 300 nanometers, a particle size distribution of between about 150 nanometers and about 3 micrometers, and a maximum porosity of about 1 percent. The dielectric layer is selected from the group including TiO2, BaTiO3, Al2O3, ZrO2, lead zirconium titanate, and combinations thereof and has a breakdown strength of at least about 1100 …


Pore Functionalized Pvdf Membranes With In-Situ Synthesized Metal Nanoparticles: Material Characterization, And Toxic Organic Degradation, Hongyi Wan, Nicolas J. Briot, Anthony Saad, Lindell E. Ormsbee, Dibakar Bhattacharyya 2017 University of Kentucky

Pore Functionalized Pvdf Membranes With In-Situ Synthesized Metal Nanoparticles: Material Characterization, And Toxic Organic Degradation, Hongyi Wan, Nicolas J. Briot, Anthony Saad, Lindell E. Ormsbee, Dibakar Bhattacharyya

Chemical and Materials Engineering Faculty Publications

Functionalized PVDF membrane platforms were developed for environmentally benign in-situ nanostructured Fe/Pd synthesis and remediation of chlorinated organic compounds. To prevent leaching and aggregation, nanoparticle catalysts were integrated into membrane domains functionalized with poly (acrylic acid). Nanoparticles of 16–19 nm were observed inside the membrane pores by using focused ion beam (FIB). This technique prevents mechanical deformation of the membrane, compared to the normal SEM preparation methods, thus providing a clean, smooth surface for nanoparticles characterization. This allowed quantification of nanoparticle properties (size and distribution) versus depth underneath the membrane surface (0–20 μm). The results showed that nanoparticles were uniformly …


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