Effects Of Specimen Size And Yttria Concentration On Mechanical Properties Of Single Crystalline Yttria-Stabilized Tetragonal Zirconia Nanopillars,
2017
Missouri University of Science and Technology
Effects Of Specimen Size And Yttria Concentration On Mechanical Properties Of Single Crystalline Yttria-Stabilized Tetragonal Zirconia Nanopillars, Ning Zhang, Mohsen Asle Zaeem
Materials Science and Engineering Faculty Research & Creative Works
The nanoscale plastic deformation of yttria-stabilized tetragonal zirconia (YSTZ) is highly dependent on the crystallographic orientations, i.e., dislocation is induced when the loading direction is 45° tilted to {111} and {101} slip planes, while tetragonal to monoclinic phase transformation dominates the plastic deformation when loading direction is perpendicular to the slip planes. This study investigates the effects of specimen size and yttria concentration on the mechanical response of single crystalline YSTZ nanopillars. Through uniaxial compression test, the smaller-is-stronger phenomenon is revealed in nanopillars deformed through a dislocation motion mechanism. Serrated stacking faults are observed in the smallest nanopillar, while neat …
Elastic Properties Of Superconductors And Materials With Weakly Correlated Spins,
2017
University of Nebraska-Lincoln
Elastic Properties Of Superconductors And Materials With Weakly Correlated Spins, Christian Binek
Christian Binek Publications
It is shown that in the ergodic regime, the temperature dependence of Young’s modulus is solely determined by the magnetic properties of a material. For the large class of materials with paramagnetic or diamagnetic response, simple functional forms of the temperature derivative of Young’s modulus are derived and compared with experimental data and empirical results. Superconducting materials in the Meissner phase are ideal diamagnets. As such, they display remarkable elastic properties. Constant diamagnetic susceptibility gives rise to a temperature independent elastic modulus for ceramic and single crystalline superconductors alike. The thermodynamic approach established in this report, paves the way to …
Solvent Based 3d Printing Of Biopolymer/Bioactive Glass Composite And Hydrogel For Tissue Engineering Applications,
2017
Missouri University of Science and Technology
Solvent Based 3d Printing Of Biopolymer/Bioactive Glass Composite And Hydrogel For Tissue Engineering Applications, Krishna Kolan, Yong Liu, Jakeb Baldridge, Caroline Murphy, Julie A. Semon, D. E. Day, Ming-Chuan Leu
Biological Sciences Faculty Research & Creative Works
Three-dimensional (3D) bioprinting is an emerging technology in which scaffolding materials and cell-laden hydrogels may be deposited in a pre-determined fashion to create 3D porous constructs. A major challenge in 3D bioprinting is the slow degradation of melt deposited biopolymer. In this paper, we describe a new method for printing poly-caprolactone (PCL)/bioactive borate glass composite as a scaffolding material and Pluronic F127 hydrogel as a cell suspension medium. Bioactive borate glass was added to a mixture of PCL and organic solvent to make an extrudable paste using one syringe while hydrogel was extruded and deposited in between the PCL/borate glass …
A Study In The Use Of Elastic Materials In Expandable Containment Units,
2017
Liberty University
A Study In The Use Of Elastic Materials In Expandable Containment Units, Andrew J. Eisenman, Joby Anthony Iii, David Satagaj
Montview Journal of Research & Scholarship
The rigidity of materials in conjunction with the aspect of elasticity has been a concern of modern technologies and construction in recent centuries because of the advantages that expandable storage would bring to the fields of containment units with respect to population growth and space exploration. The world population is currently growing at an exponential rate, and as our population grows, the more important it will become to have containment units that can both contain large volumes of material as well as minuscule amounts of material without wasting space. In order accomplish this, we will need a new type of …
Wastewater Treatment Process Based On Microbial Electrochemistry: Opportunities And Challenges,
2017
State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, No.73 Huanghe Road, Nangang District, Harbin 150090, P.R.China;
Wastewater Treatment Process Based On Microbial Electrochemistry: Opportunities And Challenges, Wei-Hua He, Jia Liu, Hai-Man Wang, Yu-Jie Feng
Journal of Electrochemistry
Microbial electrochemical technology (MET) has drawn great attention for its characteristics of synergetic pollution removal and energy recovery of wastewater. In the last decade, significant developments in microbial electrochemical system (MES) have been made in the aspects of electron transfer mechanism, microbial community analysis, function expansion, low-cost electrode materials and scaled-up constructions. However, the feasibility of MET as a wastewater treatment process has been controversial so far. In this paper, the characteristics of MET were systematically compared with anaerobic and aerobic processes from the application point of view in the aspects of pollution degradation and energy recovery processes. The MET-based …
Ionic Liquid-Supported Tempo/Polymeric Ionic-Liquid/Carbon Black Ternary Composites: Preparations And Applications In Electrochemical Oxidation Of Alcohols,
2017
School of Chemistry, biology & Materials Science, East China University of Technology, Nanchang 330013;
Ionic Liquid-Supported Tempo/Polymeric Ionic-Liquid/Carbon Black Ternary Composites: Preparations And Applications In Electrochemical Oxidation Of Alcohols, Xin Lin, Cao-Cao Sun, Zhi-Rong Liu, Cheng-Chu Zeng
Journal of Electrochemistry
To effectively recover redox catalyst and supporting electrolyte, a novel ternary composite consisting of ionic liquid-supported TEMPO, polymeric ionic-liquid and carbon black was prepared. The ionic-liquid supported redox catalyst TEMPO-IL-BF4 was firstly synthesized from 4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl, and followed by the reaction of polydimethyldiallylammonium chloride (PDDA) and bis(trifluoromethane)sulfonimide lithium salt (LiTFSI) to form poly[diallyldimethylammonium bis(trifluoromethanesulfonyl)imide] (PDDA(Tf2N)). A combination of the above mentioned two synthesized materials and carbon black afforded to obtain the ternary composite, which was used as the recoverable supporting electrolyte and mediator for the electrochemical oxidation of alcohol. The results indicate that various alcohols could be oxidized …
Electrochemical Synthesis Of Homoallylic Alcohols And Homoallylic Amines,
2017
Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510641, China;
Electrochemical Synthesis Of Homoallylic Alcohols And Homoallylic Amines, Wei-Qiang Zhong, Xiang-Hui Liang, Jing-Mei Huang
Journal of Electrochemistry
Electrochemical technique has been widely applied in the organic synthesis. This review focuses on the electrochemical synthesis of homoallylic alcohols and homoallylic amines from the allylation of carbonyl compounds and imines. This method has been developed impressively, especially in the field of electrochemical allylation in a green solvent of aqueous media. Improvement of the efficiency of the electricity, regio-selectivity and chiral synthesis are expected.
Preparations And Applications Of Irsnox Electrode In Electrochemical Synthesis Of 2,5-Dichlorophenol,
2017
Department of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, China;Department of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051 Jiangsu, China;
Preparations And Applications Of Irsnox Electrode In Electrochemical Synthesis Of 2,5-Dichlorophenol, Xiang-Yu Ma, Xu-Guo Tu, Rui-Nan He, Ya Chen, Gui-Sheng Zhu, Shou-Yan Shao, Song Chen
Journal of Electrochemistry
The electrodes of titanium based iridium tin oxides (IrSnOx) have been prepared by traditional thermal decomposition method and further applied to the electrosynthsis of 2,5-dichlorophenol in order to explore a green and high efficient synthesis route. The results showed that the electrode surface existed apparent cracks, while the intermediate layer prepared with Sn:Sb=94:6 existed less cracks and longer life time. The main products of the electrolytic reaction were 2,5-dichlorophenol, p-chlorophenol, and 1,2,4-trichlorobenzene. The electrosynthsis yield of 2,5-dichlorophenol reached 57% and the selectivity of 2,5-dichlorophenol was as high as 93% by using the IrSnOx as an anode, which is obviously better …
Electrocatalysis Of Nanotin Dioxide In The Battery Reaction Of Zinc-Nitrobenzene,
2017
Department of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, China;Department of Chemistry and Chemical Engineering, Yancheng Institute of Technology,Yancheng 224051, Jiangsu, China;
Electrocatalysis Of Nanotin Dioxide In The Battery Reaction Of Zinc-Nitrobenzene, Xu-Guo Tu, Xiang-Yu Ma, Rui-Nan He, Xiao-Juan Wang, Chen Ling, Yun-Xia Sun, Song Chen
Journal of Electrochemistry
The tin dioxide (SnO2) nanoparticles were synthesized by using a simple hydrothermal route in the presence of tetrapropyl ammonium bromide (TPAB) as a surfactant. Accordingly, the titanium mesh based SnO2 catalyst electrode was prepared. The morphologies and structures of SnO2 nanostructures were characterized by scanning electron microscopy and X-ray diffraction spectrometry. The influences of reactant concentration, reaction temperature and time on the morphology of the products were investigated in detail. The electrocatalytic performance of SnO2 for the reduction of nitrobenzene with zinc was studied. Possible formation process and growth mechanism for such hierarchical SnO2 …
Selective Direct Electro-Oxidation Of C-H Bond,
2017
State Key Laboratory Breeding Base ofGreen Chemistry Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310032 Zhejiang China
Selective Direct Electro-Oxidation Of C-H Bond, Yan-Mei Liao, Qian-Qian Wu, An-Lun Zhang, Ying-Hong Zhu, Chun-An Ma
Journal of Electrochemistry
Carbon-hydrogen (C-H) bond is the most basic chemical bond in organic compounds. The activation and direct conversion of C-H bond are the effective methodology for synthesis of different kinds of organic compounds from alkane compounds. The oxidative activation and functionalization of C-H bonds constitute an important and challenging area of investigation. The electro-oxidative activation of C-H bonds to form new C-O, C-C and C-N bonds has proven to be interesting and important in organic chemistry using the clean electron as the oxidant. The target C-O, C-C and C-N compounds could be selectively achieved by choosing the appropriate electrode, supporting electrolyte …
Electrocarboxylation: An Effective Process For Fixation Of Co2 Into Organic Carboxylic Acids,
2017
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China;
Electrocarboxylation: An Effective Process For Fixation Of Co2 Into Organic Carboxylic Acids, Huan Wang, Jia-Xing Lu
Journal of Electrochemistry
Conversion and utilization of greenhouse gas carbon dioxide (CO2) have become more and more significant to the sustainable development of the global economy. Among them, electrocarboxylation of organic substrates is an effective process. Under mild conditions such as ambient temperature and pressure, carbocations generated by electroreduction of organic substrates can react with CO2 into corresponding carboxylic acids. This paper introduces the recent progress of our group in electrochemical carboxylation, including electrocarboxylation of varies active organic substrates and asymmetric electrocarboxylation.
Electrochemical Deposition Of Cr From Cr3+ In The Mixed Electrolyte Of [Bmim]Oac/H2O,
2017
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;
Electrochemical Deposition Of Cr From Cr3+ In The Mixed Electrolyte Of [Bmim]Oac/H2O, Wei Luo, Dong-Fang Niu, Rong-Bin Du, Jun-Wei Wang, Zhu-Qing Wang, Heng Xu, Xin-Sheng Zhang
Journal of Electrochemistry
The electrochemical reduction of trivalent chromium ion (Cr3+) to Cr in 1-butyl-3-methylimidazolium acetate ([BMIM]OAc)-H2O mixed electrolyte was investigated. The cyclic voltammograms showed that the electroreduction of Cr3+ in the mixed electrolyte occurred in a two-step process, namely, Cr3+ + e → Cr2+ and Cr2+ + 2e→ Cr0, controlled by the diffusion of Cr3+ to the electrode. The diffusion coefficient of Cr3+ was 1.2×10-8 cm2/s at 40 ℃ obtained by Rendle-Sevcik equation. The chronoamperomograms of the Cr3+ electrodeposition confirmed the three-dimensional instantaneous nucleation mechanism of …
Preparations And Characterizations Of Ti/Pbo2 Electrodes Modified With Rare Earth Of Praseodymium And Pvp In Electrochemical Degradation Of Organics,
2017
School of Chemistry and Material Engineering; Huainan Normal University; Huainan, Anhui 232038, P. R. China;
Preparations And Characterizations Of Ti/Pbo2 Electrodes Modified With Rare Earth Of Praseodymium And Pvp In Electrochemical Degradation Of Organics, Mai Xu, Feng-Wu Wang, Xian Liang, Yi-Jun Wei, Wen-Yan Fang, Chuan-Gao Zhu, Yun-Hu Hun
Journal of Electrochemistry
The titanium (Ti) based lead oxide (PbO2) electrodes doped with praseodymium oxide (Pr2O3) and polyvinylpyrrolidone (PVP) were prepared by electrodeposition. The surface morphologies and structures of the as-prepared thin films were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) technique, respectively. The results showed that the denser and more uniform coatings with smaller particles and larger surfaces were obtained by doping, which modified the micro-structure of the Ti/SnO2-Sb2O3/Pr2O3-PVP-PbO2 electrode. Cyclic voltammetry (CV) was also used to study the electrocatalytic activity of …
Listening And Negotiation Ii,
2017
Georgia Institute of Technology
Listening And Negotiation Ii, Adjo A. Amekudzi-Kennedy, Kevin D. Hall, Trevor Scott Harding, Amy J. Moll, Janet Callahan
Materials Science and Engineering Faculty Publications and Presentations
This paper is based on a panel held in June, 2017 in Columbus, Ohio, jointly sponsored by the Women in Engineering Division and by the Minorities in Engineering Division. It is focused on negotiation, with an emphasis on providing practical strategies that are relevant in an academic setting. The panel featured academic leaders at multiple levels, including professor, chair and dean, from diverse engineering institutions, ranging from teaching-centric to heavily research-focused. Panelists discussed strategies for negotiation, with an emphasis on an approach that meets the interests of both parties to the extent possible. The panel was administrated with an opening …
Establishing Doctoral Programs In Electrical Engineering, Materials Science And Engineering, And Computing In An Emerging Research Institution: Lessons Learned And Best Practices,
2017
Boise State University
Establishing Doctoral Programs In Electrical Engineering, Materials Science And Engineering, And Computing In An Emerging Research Institution: Lessons Learned And Best Practices, Janet Callahan, Cheryl B. Schrader, Darryl P. Butt, Timothy Anderson, Tammi Vacha-Hasse, Amy J. Moll
Materials Science and Engineering Faculty Publications and Presentations
Over the past decade, three doctoral programs have been launched at Boise State University. The first doctoral program established was in Electrical and Computer Engineering, selected because of the need for a trained workforce in the region. The other two doctoral programs, Materials Science and Engineering, and Computing, were from the start designed as interdisciplinary degree programs. That is, they were designed for the participation of not just program faculty within the division, but for the participation of program faculty with related research interests in other departments at the university. This paper presents the steps taken to launch the programs, …
Vertically Integrated Projects (Vip) Programs: Multidisciplinary Projects With Homes In Any Discipline,
2017
Boise State University
Vertically Integrated Projects (Vip) Programs: Multidisciplinary Projects With Homes In Any Discipline, Jocelyn B. S. Cullers, William L. Hughes, Donna C. Llewellyn
Materials Science and Engineering Faculty Publications and Presentations
A survey of papers in the ASEE Multidisciplinary Engineering Division over the last three years shows three main areas of emphasis: individual courses; profiles of specific projects; and capstone design courses. However, propagating multidisciplinary education across the vast majority of disciplines offered at educational institutions with varying missions requires models that are independent of the disciplines, programs, and institutions in which they were originally conceived. Further, models that can propagate must be cost effective, scalable, and engage and benefit participating faculty. Since 2015, a consortium of twenty-four institutions has come together around one such model, the Vertically Integrated Projects (VIP) …
Ten Years Later: Where Are They Now?,
2017
Boise State University
Ten Years Later: Where Are They Now?, Janet Callahan, Donna C. Llewellyn, Vicki Stieha, Ann E. Delaney
Materials Science and Engineering Faculty Publications and Presentations
This paper explores the educational and career trajectories of the alumnae of an outreach activity for girls. The outreach activity was originally developed using an integrated marketing approach to attract girls into engineering programs.1 The program, a two day, overnight experience for rising 9th, 10th and 11th grade girls, focuses on showcasing engineering as an exciting, creative activity, including activities developed from that perspective. Started in 2005 and held annually since then, a total of over 500 girls have participated, with approximately 85% of them coming from Boise State University’s immediate metropolitan area. Facilitated by …
Symmetry Driven Control Of Optical Properties In Wo3 Films,
2017
Oak Ridge National Library
Symmetry Driven Control Of Optical Properties In Wo3 Films, Andreas Herklotz, Stefania Rus, Santosh Kc, Valentino Cooper, Amanda Huon, Er-Jia Guo, Thomas Ward
Faculty Publications
In this work, we demonstrate that the optical bandgap of WO3 films can be continuouslycontrolled through uniaxial strain induced by low-energy helium implantation.The insertion of He into epitaxially grown and coherently strained WO3 films canbe used to induce single axis out-of-plane lattice expansion of up to 2%. Ellipsometricspectroscopy reveals that the optical bandgap is reduced by about 0.18 eVper percent expansion of the out-of-plane unit cell length. Density functional theorycalculations show that this response is a direct result of changes in orbital degeneracydriven by changes in the octahedral rotations and tilts.
Effects Of Proton Irradiation On Structural And Electrochemical Charge Storage Properties Of Tio2 Nanotube Electrode For Lithium-Ion Batteries,
2017
Boise State University
Effects Of Proton Irradiation On Structural And Electrochemical Charge Storage Properties Of Tio2 Nanotube Electrode For Lithium-Ion Batteries, Kassiopeia A. Smith, Andreas I. Savva, Changjian Deng, Hui Xiong
Materials Science and Engineering Faculty Publications and Presentations
The effects of proton irradiation on nanostructured metal oxides have been investigated. Recent studies suggest that the presence of structural defects (e.g. vacancies and interstitials) in metal oxides may enhance the material’s electrochemical charge storage capacity. A new approach to introduce defects in electrode materials is to use ion irradiation as it can produce a supersaturation of point defects in the target material. In this work we report the effect of low-energy proton irradiation on amorphous TiO2 nanotube electrodes at both room temperature and high temperature (250 ˚C). Upon room temperature irradiation the nanotubes demonstrate an irradiation-induced phase transformation …
Photopolymerization Synthesis Of Magnetic Nanoparticle Embedded Nanogels For Targeted Biotherapeutic Delivery,
2017
University of South Florida
Photopolymerization Synthesis Of Magnetic Nanoparticle Embedded Nanogels For Targeted Biotherapeutic Delivery, Daniel Jonwal Denmark
USF Tampa Graduate Theses and Dissertations
Conventional therapeutic techniques treat the patient by delivering a biotherapeutic to the entire body rather than the target tissue. In the case of chemotherapy, the biotherapeutic is a drug that kills healthy and diseased cells indiscriminately which can lead to undesirable side effects. With targeted delivery, biotherapeutics can be delivered directly to the diseased tissue significantly reducing exposure to otherwise healthy tissue. Typical composite delivery devices are minimally composed of a stimuli responsive polymer, such as poly(N-isopropylacrylamide), allowing for triggered release when heated beyond approximately 32 °C, and magnetic nanoparticles which enable targeting as well as provide a mechanism for …
