Materials Science and Engineering Commons^™

Electro-Magnetic Responsive Ni0.5zn0.5fe2o4 Nano-Particle Composite, Jaiprakash Kanagaraj

Electronic Theses and Dissertations

The purpose of this study is to simulate and synthesize a Radar (or Radiation) Absorbent Material (RAM) by using polymers and nickel zinc ferrite (Ni0.5Zn0.5Fe2O4) magnetic nanoparticles. There is an ardent desire in military, space and electronics for lighter, faster, cheaper and widespread bandwidth providing RAM materials. Electromagnetic property such as magnetic permeability and electric permittivity play a major in controlling the radiation. The appropriate combination of permeability and permittivity properties is acquired for the synthesis of RAM providing wide-ranging bandwidth. The apt property is achieved by rule of mixture, mixing of particular composition of epoxy polymer having low permeability …

Analysis Of 3d Printed Cylindrical Members, Salvador Caballero

Electronic Theses and Dissertations

Compressive analysis of a structural member is the determination of the axial capacity of the member when it is undergoing a load causing the member to fail in either a buckling or a crushing mode. 3D printed plastic columns have not been characterized and analyzed yet. However, this research characterizes 3D-printed PLA columns and provides parameters for future researchers to investigate. The literature describes the different industries that utilize 3D-printing. In this research, we introduce an innovative approach to investigate the stresses produced in a 3D printed composite member, made of PLA and locally available soil. The compressive testing will …

Photoluminescence From Gan Co-Doped With C And Si, Mykhailo Vorobiov

Theses and Dissertations

This thesis devoted to the experimental studies of yellow and blue luminescence (YL and BL relatively) bands in Gallium Nitride samples doped with C and Si. The band BL_C was at first observed in the steady-state photoluminescence spectrum under high excitation intensities and discerned from BL1 and BL2 bands appearing in the same region of the spectrum. Using the time-resolved photoluminescence spectrum, we were able to determine the shape of the BL_C and its position at 2.87 eV. Internal quantum efficiency of the YL band was estimated to be 90\%. The hole capture coefficient of the BL_{C …}

Mechanical Annealing Of Model Glasses: Effects Of Strain Amplitude And Temperature, Nikolai V. Priezjev

Mechanical and Materials Engineering Faculty Publications

Molecular dynamics simulations are performed to examine the dynamic response of amorphous solids to oscillatory shear at finite temperatures. The data were collected from a poorly annealed binary glass, which was deformed periodically in the elastic regime during several hundred shear cycles. We found that the characteristic time required to reach a steady state with a minimum potential energy is longer at higher temperatures and larger strain amplitudes. With decreasing strain amplitude, the asymptotic value of the potential energy increases but it remains lower than in quiescent samples. The transient decay of the potential energy correlates well with a gradual …

Corrosion Performance Of Zirconium-Based Passivations On Electroplated Zinc Nickel, Madison Morgan Reed

Masters Theses

“Performance requirements for Department of Defense (DoD) electrical components include corrosion and electrical contact resistance. Historically, electroplated cadmium with a chromate conversion coating (CrCC) has been used to meet corrosion and contact resistance standards. However, replacements are needed for these materials because they are toxic and carcinogenic. Electroplated γ-ZnNi has been identified as an acceptable alternative to Cd. This study evaluated commercially available Zr-based thin films and sealers as passivations for potential replacement of CrCCs. Ten different passivations were tested and compared with bare γ-ZnNi. X-Bond and Zircobond passivations were found to provide some improvement to the bare ZnNi corrosion …

Grain Refinement Of High Alloy Stainless Steels In Sand And Directionally Solidified Castings, Dustin Alan Arvola

Masters Theses

"The goal of this research project is to develop an industrially viable melting process that will control the crystallization macrostructure of austenitic grades of cast steels. Titanium nitride (TiN) has proven to be an effective grain refiner of austenite. Theoretical simulation and experimental application has led to the development of a repeatable grain refining melt process for austenitic stainless steel alloys.

Grain refinement of the as-cast structure of Cr-Ni stainless steel alloys solidified with primary FCC, BCC and dual FCC/BCC phases was studied experimentally. Refinement was achieved in both cast ferritic and austenitic grades. Dual solidification of …

Research And Development Of Optically Transparent Join With Low Processing Temperatures, Eric Kevin Muskovin

Masters Theses

The purpose of this study was to investigate durable solar cell cover glass joins produced by diffusion bonding with deep eutectic solvents (DES) and to develop a novel process of joining optically transparent materials at low temperatures. A joined PV cell-glass specimen was characterized using Raman, μ-FTIR, SEM-EDS, and thin-film XRD. DESs were created with malonic acid (MAL) and choline chloride (ChCl) of varying composition factors (CF; CF=MAL/ChCl). Joining borosilicate glass coupons was attempted using DESs with CF = 0.65 and 1 at temperatures between 100-150 °C for 20 hours. Joining the glass coupons failed at all temperatures and oxygen …

Designed Extrudate For Ceramic Additive Manufacturing, Devin Mcmillen

Masters Theses

"The objective of this thesis work was to design ceramic paste systems that assist in achieving a high theoretical density ( > 95%) after deposition by a novel additive manufacturing process, i.e. Ceramic On-Demand Extrusion (CODE). The work is encompassed in five main sections: Sections 1 and 2 provide an introduction and literature review of relevant topics for the following sections of experimentation. Section 3 provides an analysis of a reaction chemistry to identify three discrete materials that could be combined via CODE and result in zirconium diboride (ZrB₂) post-sintering. Section 4 describes the development of a high solids …

Effect Of Microstructural Features On Steel Machinability, Mark C. Emmendorfer

Masters Theses

Non-metallic inclusions can have a tremendous impact on the machinability of steel. Some oxide inclusions such as alumina, spinel, and other refractory abrasive oxide inclusions can have a detrimental effect on machinability. Modification of oxide inclusions by calcium treatment can promote the formation of low melting point oxides such as anorthite and gehlenite inclusions that can assist in chip formation and form a lubricating layer on the rake surface of the machine tool. MnS is known to be beneficial to improving the machinability of steel. They assist in chip formation by being heavily deformed in the primary shear zone. Sulfide …

Modulated Photothermal Radiometry: Detector Sensitivity Study And Experimental Setup, Jessica Nicole Seals

Masters Theses

"This thesis outlines the development of a system used for determining the surface thermal diffusivity of both non-irradiated and irradiated materials. The motivation for this work is to establish a modulated photothermal radiometry (PTR) system on the campus of Missouri University of Science and Technology. One of the main efforts described in this thesis is the design and construction of the physical apparatus. Along the way, it was necessary to perform a detailed sensitivity analysis of the system to determine whether the expected signal emitted from the sample falls within the bounds of detectivity for the HgCdTe (MCT) detector used …

High Temperature Polymer Composites Using Out-Of-Autoclave Processing, Sudharshan Anandan

Doctoral Dissertations

"High performance polymer composites possess high strength-to-weight ratio, corrosion resistance, and have design flexibility. Carbon/epoxy composites are commonly used aerospace materials. Bismaleimide based composites are used as a replacement for epoxy systems at higher service temperatures. Aerospace composites are usually manufactured, under high pressure, in an autoclave which requires high capital investments and operating costs. In contrast, out-of-autoclave manufacturing, specifically vacuum-bag-only prepreg process, is capable of producing low cost and high performance composites. In the current study, out-of-autoclave processing of high temperature carbon/bismaleimide composites was evaluated. The cure and process parameters were optimized. The properties of out-of-autoclave cured laminates compared …

Data Driven Composites: The Challenge And Paths Forwards, Muthu Ram Prabhu Elenchezhian, Vamsee Vadlamudi, Rassel Raihan, Kenneth Reifsnider

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

The concept of “data driven” grew out of the general subject of data analytics, especially in the business world. The classical sequence proposed by Dykes (2010) shown below illustrates the general contents of the concept. Indeed, the idea of “predictive modeling” of the future behavior of a system has strong roots in the business community. In general, for engineering and other fields, the data driven challenge is to use the past with information from the present to predict the future behavior of a system. In turn, the user must pay for collection and processing, hosting and maintenance of the data, …

State Variable Methods Of Assessment, Prognosis, And Control Of Composite And Bonded Structures, Kenneth Reifsnider, Rassel Raihan, Vamsee Vadlamudi, Muthu Ram Prabhu Elenchezhian

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

It is generally recognized that the determination of material state is the baseline foundation for the assessment and prognosis of current and future performance of structural materials in which distributed damage leads to progressive property degradation. Many classes of composite materials, both naturally occurring and engineering designs, are governed by such behavior. However, finding appropriate measureable physical variables to make such assessments, especially for as-manufactured and subsequent real-time assessment and prognosis conditions is challenging. Measurement and analysis of multiple single defect initiation, interaction, and collective effects is the most rigorous current methodology, and is the foundation for certification and quality …

Global Prediction Of Discrete Local Damage Interactions Using Broadband Dielectric Spectroscopy, Vamsee Vadlamudi, Muthu Ram Prabhu Elenchezhian, Rauhon Ahmed Shaik, Aishwarya Nandini, Rassel Raihan, Kenneth Reifsnider

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

With the increasing demand for composites in many modern applications, it is important to predict the initiation of failure events. Due to the heterogeneous nature of these materials, a single damage mode will not lead to final failure, hence detecting the initiation and growth of a single crack (defect) will not yield accurate predictions of the strength or the material state. It is important to capture the interaction of various damage modes that tend to change the material state leading to initiation of failure. To assess the material state, one needs to determine the appropriate global physical variables that can …

Molecular Dynamics For The Prediction Of The Interfacial Shear Stress And Interface Dielectric Properties Of Carbon Fiber Epoxy Composites, Rajni Chahal, Ashfaq Adnan, Kenneth Reifsnider, Rassel Raihan, Yuan Ting Wu, Vamsee Vadlamudi, Muthu Ram Prabhu Elenchezhian

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

The thermoset epoxy resin Diglycidyl ether of Bisphenol F (EPON 862), crosslinked with the Diethylene Toluene Diamine (DETDA) hardening agent, are utilized as the polymer matrix component in many graphite (carbon fiber) composites. Since it is difficult to experimentally characterize the interfacial region, computational molecular modeling is a necessary tool for understanding the influence of the interfacial molecular structure on bulk-level material properties. The purpose of this research is to evaluate and compare the interfacial shear stress and dipole moment for the pristine carbon fiber composite and the one with the moisture content at the interface. Molecular models are established …

Raman Spectroscopy Of The Skeleton Of The Coral Acropora Cervicornis, Zachary C. Shepard

Honors Undergraduate Theses

Coral reefs are an important element of marine ecosystem that are critical to maintain a healthy environment. Unfortunately, in recent years coral reefs are doing poorly and many in parts of the ocean are simply dying. Therefore, study of coral’s structural response to external loads could answer what will happen with their structures, while they exhibit different types of loading. Therefore, the proposition of using in-situ micro-Raman spectroscopy to study skeletons of Acropora cervicornis was used. Coral skeleton samples I subjected to mechanical loading studied their vibrational properties by exciting the material with 532nm visible light. A uniaxial compressive load …

Optimal Sintering Temperature Of Ceria-Doped Scandia Stabilized Zirconia For Use In Solid Oxide Fuel Cells, Amanda K. Assuncao

Honors Undergraduate Theses

Carbon emissions are known to cause decay of the Ozone layer in addition to creating pollutant, poisonous air. This has become a growing concern among scientists and engineers across the globe; if this issue is not addressed, it is likely that the Earth will suffer catastrophic consequences. One of the main culprits of these harmful carbon emissions is fuel combustion. Between vehicles, power plants, airplanes, and ships, the world consumes an extraordinary amount of oil and fuel which all contributes to the emissions problem. Therefore, it is crucial to develop alternative energy sources that minimize the impact on the environment. …

Regolith-Based Construction Materials For Lunar And Martian Colonies, Kevin Grossman

Electronic Theses and Dissertations

Humankind's ambitions of exploring our solar system and parts beyond depend heavily on our ability to collect resources from local environments at our destinations rather than bringing materials on the journey. This is a concept known as in-situ resource utilization (ISRU) and it is one that has been understood by every explorer and settler in the history of humankind. Regolith on the moon and Mars has been shown to be a particularly useful resource and has the ability to provide humans with resources including water, oxygen, construction material, fabric, radiation shielding, metals, and may more. This dissertation focuses on construction …

Influence Of Chitosan-Alginate Scaffold Stiffness On Bone Marrow Stromal Cell Differentiation, Isabel Arias Ponce

Electronic Theses and Dissertations

Tissue grafts are the gold standard for replacing large volume tissue defects. Yet, they present several risks, including infection, low functional outcomes, and reduced graft integrity. Tissue engineering (TE) combines cells and biomaterial scaffolds to foster tissue growth and remodeling. Bone marrow stromal cells (BMSCs) have been shown to respond to the stiffness of their microenvironment, resulting in differentiation into different lineages. 3D porous chitosan-alginate (CA) scaffolds have been previously demonstrated for bone TE with osteoblasts and BMSCs; however, only a single scaffold composition (4 wt%) was studied. Three CA scaffold compositions (2, 4, 6 wt% CA) were produced. Scanning …

Cell Printing: An Effective Advancement For The Creation Of Um Size Patterns For Integration Into Microfluidic Biomems Devices, Megan Aubin

Electronic Theses and Dissertations

The Body-on-a-Chip (BoaC) is a microfluidic BioMEMs project that aims to replicate major organs of the human body on a chip, providing an in vitro drug testing platform without the need to resort to animal model testing. Using a human model also provides significantly more accurate drug response data, and may even open the door to personalized drug treatments. Microelectrode arrays integrated with human neuronal or human cardiac cells that are positioned on the electrodes are essential components for BoaC systems. Fabricating these substrates relies heavily on chemically patterned surfaces to control the orientation and growth of the cells. Currently, …