Electrodeposited Epitaxial Cobalt Oxides And Copper Metal,
2018
Missouri University of Science and Technology
Electrodeposited Epitaxial Cobalt Oxides And Copper Metal, Caleb M. Hull
Doctoral Dissertations
"Electrochemical deposition methods are presented for the deposition of Co(OH)2 and Cu metal. Paper I shows the deposition of β-Co(OH)2 on Ti through electrochemical reduction of [Co(en)3]3+ to [Co(en)3]2+ in 2M NaOH. The catalytic properties of the deposited Co(OH)2 towards water oxidation is found comparable to Co3O4, with the surface of the Co(OH)2 converting to CoOOH during the reaction. Paper II gives the conditions suitable for epitaxial growth of Co(OH)2 on Au(100), Au(110), and Au(111) following the same reduction mechanism as described in Paper I. …
Soy-Based Polyurethane Foam For Insulation And Structural Applications,
2018
Missouri University of Science and Technology
Soy-Based Polyurethane Foam For Insulation And Structural Applications, Gurjot S. Dhaliwal
Doctoral Dissertations
"Polyurethane (PU) foams are widely used as insulation materials due to their high insulation properties and low cost compared to conventional materials such as styrene and mineral wool. PU foams are traditionally fabricated with petroleum-based precursors. However, high crude price and higher carbon footprint has lead interest of researchers to synthesis PU foams using plant-based raw materials, that are inexpensive and renewable. In this dissertation, PU foams were fabricated using soy-based polyol and its thermal and mechanical properties were investigated. In the first part, of PU foam samples with different formulations were fabricated using soy-based polyol HB230, and varying amounts …
Functionalized Nanoporous Carbon Scaffolds For Hydrogen Storage Applications,
2018
Missouri University of Science and Technology
Functionalized Nanoporous Carbon Scaffolds For Hydrogen Storage Applications, Christopher L. Carr
Doctoral Dissertations
"Recent efforts have demonstrated confinement in porous scaffolds at the nanoscale can alter the hydrogen sorption properties of metal hydrides, though not to an extent feasible for use in onboard hydrogen storage applications, proposing the need for a method allowing further modifications. The work presented here explores how the functionalization of nanoporous carbon scaffold surfaces with heteroatoms can modify the hydrogen sorption properties of confined metal hydrides in relation to non-functionalized scaffolds (FS). Investigations of nanoconfined LiBH4 and NaAlH4 indicate functionalizing the carbon scaffold surface with nitrogen can shift the activation energy of hydrogen desorption in excess of …
Chemistry, Design, And Processing Of Two-Stage Trip Steel,
2018
Missouri University of Science and Technology
Chemistry, Design, And Processing Of Two-Stage Trip Steel, Daniel M. Field
Doctoral Dissertations
"A regular solution model was developed to calculate the chemical driving force for α-martensite formation, ΔGλ→ αChem. A model for the strain energy, ΔGλ→αstr, was formulated utilizing the Young’s modulus (E), lattice misfit squared (δ²), and molar volume (Ω) which opposed the chemical driving force for α-martensite formation. The MαS was determined at a temperature at which ΔGλ→αChem + ΔGλ→αstr = 0. In conjunction with a previously developed ε-martensite model, a means of predicting the volume fraction of λ-austenite was determined; and it was shown that for values …
Multi-Scale Investigation Of Microstructure, Fiber-Matrix Bond, And Mechanical Properties Of Ultra-High Performance Concrete,
2018
Missouri University of Science and Technology
Multi-Scale Investigation Of Microstructure, Fiber-Matrix Bond, And Mechanical Properties Of Ultra-High Performance Concrete, Zemei Wu
Doctoral Dissertations
"The main objective of this study is to provide new insights into enhancing fiber-matrix bond and mechanical properties of ultra-high performance concrete (UHPC). Three main strategies were investigated: 1) use of supplementary cementitious materials; 2) use of nano-particles; and 3) use of deformed fibers. A multi-scale investigation involving the evaluation of non-fibrous UHPC mortar phase (matrix), fiber-matrix interface phase, and then UHPC composite material was undertaken to determine microstructural characteristics, fiber bond to matrix, and key mechanical properties of the UHPC matrix and UHPC. Test results indicate that the incorporation of 10%-20% silica fume effectively improved the fiber-matrix bond and …
Material Thermal Property Estimation Of Fibrous Insulation: Heat Transfer Modeling And The Continuous Genetic Algorithm,
2018
Virginia Commonwealth University
Material Thermal Property Estimation Of Fibrous Insulation: Heat Transfer Modeling And The Continuous Genetic Algorithm, Elora Frye
Theses and Dissertations
Material thermal properties are highly sought after to better understand the performance of a material under particular conditions. As new materials are created, their physical properties will determine their performance for various applications. These properties have been estimated using many techniques including experimental testing, numerical modeling, and a combination of both. Existing methods can be time consuming, thus, a time-efficient and precise method to estimate these thermal properties was desired. A one-dimensional finite difference numerical model was developed to replicate the heat transfer through an experimental apparatus. A combination of this numerical model and the Continuous Genetic Algorithm optimization technique …
Evaluation Of The Effect Of Tack Coat Type, Application Rate, And Surface Type On Interlayer Shear Strength,
2018
South Dakota State University
Evaluation Of The Effect Of Tack Coat Type, Application Rate, And Surface Type On Interlayer Shear Strength, Chamika Prashan Dharmarathna
Electronic Theses and Dissertations
Tack coat is an asphaltic material applied between asphalt pavement layers. Since pavement is a multilayered structure, it is highly important to make proper bond between the layers to achieve a monolithic behavior. Hence, inadequate bond due to application of inadequate amount of tack coat may lead to poor structural behavior and premature failure. Also, applying excessive amount of tack coat may lead to layer slippage and binder migration. Therefore, it is highly important to apply an optimum amount of tack coat between layers. Over the past decades several studies have been conducted to determine the optimum tack coat application …
Thickness Dependence Of Electrical Conductivity In A Thin Film Thermoelectric Composite,
2018
University of Nevada, Las Vegas
Thickness Dependence Of Electrical Conductivity In A Thin Film Thermoelectric Composite, David Zagaceta, William Rogers, Andres Breucop, Brian Herrera
Math 365 Class Projects
In this work we utilize the Van Der Pauw method for measuring and calculating the electrical conductivity of a composite material in relation to its thickness.
Development Of Sorption Technology For Extracting Rare Earth Elements From Coal Fly Ash,
2018
Wayne State University
Development Of Sorption Technology For Extracting Rare Earth Elements From Coal Fly Ash, Bilal Syed
Research Opportunities for Engineering Undergraduates (ROEU) Program 2017-18
Rare Earth Elements (REEs) are elements with many high tech uses (e.g., smartphones, electric cars, advanced weaponry) and have been identified by the DOE to be critical to the US economy. Currently, China supplies over 85% of REEs resulting in an undiversified market and susceptibility to supply shock and economic insecurity. To address this susceptibility, this research aims to develop an economic and environmentally-friendly method of extracting REEs from nascent, plentiful sources such as coal and coal by-products like fly ash.
Effects Of Build Parameters On The Mechanical And Di-Electrical Properties Of Am Parts,
2018
University of Texas at Arlington
Effects Of Build Parameters On The Mechanical And Di-Electrical Properties Of Am Parts, Sai Sri Munaganuru, Muthu Ram Prabhu Elenchezhian, Vamsee Vadlamudi, Rauhon Ahmed Shaik, Hari K. Adluru, Rassel Raihan
Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive
Additive manufacturing (AM) revolutionized many industries, i.e., Automotive, Biomedical, Aerospace and Defense. As opposed to traditional manufacturing methods, a part is manufactured layer by layer from 3D CAD models in AM. Though the vision of AM is impressive, there are many challenges that are hindering the widespread use of these complex parts. One of the challenges in these materials is defects grow and their orientation during the manufacturing process. In this paper we are going to investigate the effect of Build Parameters and their effects on the mechanical and electrical properties of the additively manufactured heterogeneous material system. We will …
Manufacturing A Composite Wheel Prototype Using 3d Printed Molds,
2018
Minnesota State University, Mankato
Manufacturing A Composite Wheel Prototype Using 3d Printed Molds, Steven Thuening
All Graduate Theses, Dissertations, and Other Capstone Projects
Throughout the evolution of high performance racing, a large emphasis has been on reducing the weight of the vehicle in order to improve its performance. Over the years, new designs and materials have been introduced reducing weight in a variety of different locations. Comparing weight reduced in different areas has shown that some areas are more valuable to reduce than others are. Perhaps one of the most beneficial locations are the wheels. This is because the mass of the wheel is considered unsprung and rotational. Because of this, large improvements towards the reduction of wheel mass have been developed in …
Technology Development For Detection Of Circulating Disease Biomarkers From Liquid Biopsies Using Multifunctional Nanomaterials,
2018
University at Albany, State University of New York
Technology Development For Detection Of Circulating Disease Biomarkers From Liquid Biopsies Using Multifunctional Nanomaterials, Mustafa Balcioglu
Legacy Theses & Dissertations (2009 - 2024)
Despite the advance health care, devastating health conditions such as cancer and infectious diseases that affect populations worldwide are too often not diagnosed until morbid symptoms become apparent in the late phase. Obtaining an early and accurate diagnosis that reveal a hidden lethal threat before the disease becomes complicated may dramatically reduce the severity of its impact on the patient’s life and increase the probability of survival. For example, in the case of ovarian cancer, which is the fifth most common malignancy and the fifth leading cause of cancer mortality in women in the US, the 5-year relative survival is …
Dna Functionalized Nanoparticles In Nanobiosensor And Sensor Array Development For Molecular Diagnostics And In Vitro Identification Of Biomolecules,
2018
University at Albany, State University of New York
Dna Functionalized Nanoparticles In Nanobiosensor And Sensor Array Development For Molecular Diagnostics And In Vitro Identification Of Biomolecules, Mustafa Salih Hizir
Legacy Theses & Dissertations (2009 - 2024)
Nucleic acid technology along with vast variety of nanomaterials has demonstrated a great potential in many applications from biosensing studies to molecular diagnostics, from biomedical and bioanalytical research to environmental analysis. Especially short single stranded (ss) DNA molecules, called oligonucleotides, are extraordinary biopolymers featuring diverse functionality on the nanoparticles thanks to their high degree of programmability, target-specific binding or cleavage, molecular recognition ability, structure-switching capability, and unique interactions at the bio-nano interfaces. Among those, there have been many biosensing applications utilizing ss DNAs and numerous nanomaterials through various detection techniques such as fluorometric, colorimetric or electrochemical methods. Although many groundbreaking …
Genetically Engineered Polypeptides As Biomimetic Light Harvesting Optical Antenna,
2018
University at Albany, State University of New York
Genetically Engineered Polypeptides As Biomimetic Light Harvesting Optical Antenna, Jason P. Seeley
Legacy Theses & Dissertations (2009 - 2024)
Natural resources useful for the generation of energy are limited. The development of efficient materials capable of utilizing the abundant free solar radiation is of considerable interest. Utilization of otherwise wasted energy sources, including solar radiation, is a progressive step in the quest for sustainable energy. Solar radiation incident upon the earth’s surface exceeds current energy requirements and motivates scientists to investigate and develop functional devices and nanomaterials including light harvesting complexes (LHC) capable of capturing solar radiation for energy conversion and storage.
Direct Strength Approach To Predict The Flexural Strength Of Cold-Formed Z-Section Purlins On Sloped Roofs,
2018
Old Dominion University
Direct Strength Approach To Predict The Flexural Strength Of Cold-Formed Z-Section Purlins On Sloped Roofs, Ali Parva, Michael W. Seek
Engineering Technology Faculty Publications
In this study, the strength of cold-formed Z-section purlins is predicted considering the effects of roof slope in real roof systems. The study applies to simple span purlins with torsion restraints at support locations and at paired locations along the length of the member. A previously developed method has shown through comparisons to base tests that when the biaxial bending and torsion stresses are incorporated into the analysis, the Direct Strength Method can accurately predict the strength of a purlin. These stress distributions can deviate substantially from the constrained bending approximation typically assumed in analysis and therefore impacts the local …
Fe73.5si13.5b9cu1nb3 Metallic Glass: Rapid Activation Of Peroxymonosulfate Towards Ultrafast Eosin Y Degradation,
2018
Edith Cowan University
Fe73.5si13.5b9cu1nb3 Metallic Glass: Rapid Activation Of Peroxymonosulfate Towards Ultrafast Eosin Y Degradation, Jincheng Wang, Zhe Jia, Peng Qin, W. C. Zhang, M. D. Wang, T. B. Sercombe, Laichang Zhang
Research outputs 2014 to 2021
Discovering functional applications of metallic glasses (MGs) as heterogeneous catalysts is a fundamental and essential topic. This work reports the rapid production of sulfate radicals (SO4−) from peroxymonosulfate (PMS) using Fe73.5Si13.5B9Cu1Nb3 glassy ribbons as catalysts for Eosin Y (EY) dye wastewater treatment. The reaction rates (k) from the experimental data reveal that the EY degradation is well fitted with the pseudo-first-order kinetic model. The strong electron transfer ability is characterized by electrochemical methods, presenting an advanced catalytic performance for EY degradation. Various experimental parameters, including dye …
Photonic Crystal-Supported Long-Range Surface Plasmon-Polaritons Propagating Along High-Quality Silver Nanofilms,
2018
Edith Cowan University
Photonic Crystal-Supported Long-Range Surface Plasmon-Polaritons Propagating Along High-Quality Silver Nanofilms, Sergey K. Sekatskii, Anton Smirnov, Giovanni Dietler, Mohammad Nur E. Alam, Mikhail Vasiliev, Kamal Alameh
Research outputs 2014 to 2021
Long-range surface plasmon-polaritons (LRSPP) with a propagation length equal to 180 microns at the wavelength of 633 nm have been observed at the interface of 12.5 nm-thick silver nanofilm, coated by a 20 nm-thick protective ZnS layer, with air. Their propagation has been supported by a specially prepared 40-layer 1D Photonic Crystal designed in such a manner that silver layer has been deposited directly onto thin ZnS layer, earlier shown to be a non-oxide material most suitable for the preparation of high-quality thin silver nanofilms.
Magneto-Optic Properties Of Ultrathin Nanocrystalline Ferrite Garnet Films In The 8k To 300k Temperature Interval,
2018
Edith Cowan University
Magneto-Optic Properties Of Ultrathin Nanocrystalline Ferrite Garnet Films In The 8k To 300k Temperature Interval, Viatcheslav Kotov, Vladimir Shavrov, A. Popkov, Mikhail Vasiliev, Kamal Alameh, Mohammad Alam, L. Alyabyeva, Dmitry Balabanov, Vladimir Burkov, M Virchenko
Research outputs 2014 to 2021
A study of the initial stages of crystallization in RF magnetron-sputtered ferrite garnet films is reported, in which a series of ultrathin Bi2Dy1Fe4Ga1O12 layers is fabricated and characterized. The spectral and temperature dependencies of magnetic circular dichroism (MCD) of these films are studied in the temperature range from 300 K down to 8 K. Measured magneto-optical properties are reported in the spectral range between 300 and 600 nm. In ultrathin garnets at temperatures below 160 K, we found that between 360 and 520 nm, the spectral MCD dependencies were typical of bismuth-substituted garnets with high levels of gallium dilution in …
Homogenization And Growth Behavior Of Second-Phase Particles In A Deformed Zr-Sn-Nb-Fe-Cu-Si-O Alloy,
2018
Edith Cowan University
Homogenization And Growth Behavior Of Second-Phase Particles In A Deformed Zr-Sn-Nb-Fe-Cu-Si-O Alloy, Liang-Yu Chen, Peng Sang, Lina Zhang, Dongpo Song, Yanqiu Chu, Linjiang Chai, Laichang Zhang
Research outputs 2014 to 2021
Homogeneous distribution of fine second-phase particles (SPPs) fabricated by cycles of deformation and annealing in zirconium alloys is a critical consideration for the corrosion resistance of fuel claddings. Different deformation degrees of zirconium alloys would result in distinctive microstructures, leading to a distinct growth of SPPs during subsequent annealing. Unfortunately, the homogenization and growth behavior of SPPs in deformed zirconium alloys have not been well studied. In this work, a β-quenched Zr–Sn–Nb–Fe–Cu–Si–O alloy was rolled and annealed at 580◦C or 680◦C. The morphologies, distributions, and sizes of SPPs resulting from the different processing procedures were investigated. A linear distribution of …
Effect Of High- And Low-Molecular-Weight Hyaluronic-Acid-Functionalized-Az31 Mg And Ti Alloys On Proliferation And Differentiation Of Osteoblast Cells,
2018
Technological University Dublin
Effect Of High- And Low-Molecular-Weight Hyaluronic-Acid-Functionalized-Az31 Mg And Ti Alloys On Proliferation And Differentiation Of Osteoblast Cells, Sankalp Agarwal, Brendan Duffy, James Curtin, Swarna Jaiswal
Articles
The quality of patient care has increased dramatically in recent years because of the development of lightweight orthopedic metal implants. The success of these orthopedic implants may be compromised by impaired cytocompatibility and osteointegration. Biomimetic surface engineering of metal implants using biomacromolecules including hyaluronic acid (HA) has been used an effective approach to provide conditions favorable for the growth of bone forming cells. To date, there have been limited studies on osteoblasts functions in response to metal substrates modified with the hyaluronic acid of different molecular weight for orthopedic applications. In this study, we evaluated the osteoblasts functions such as …
