Materials Science and Engineering Commons^™

Formation Of Chromium-Iron Carbide By Carbon Diffusion In Alₓcocrfenicu High-Entropy Alloys, Mohsen Beyramali Kivy, Caitlin S. Kriewall, Mohsen Asle Zaeem

Materials Science and Engineering Faculty Research & Creative Works

Effect of the addition of carbon on phase formations in Al_xCoCrFeNiCu (x = 0.3, 1.5, 2.8) high-entropy alloys (HEAs) was studied. Free diffusion of carbon from graphite crucible resulted in the partitioning of the entire Cr from the matrix and the formation of the (Cr,Fe)₂₃C₆ phase in all HEAs. No other metal-carbide phase was detected. The formation of (Cr,Fe)₂₃C₆ enhanced the overall hardness of the HEAs. By increasing the amount of Al, the Cr amount decreased resulting in the reduction of carbon diffusion and volume fraction of the (Cr,Fe)₂₃C_{6 …}

Analysis Of The Low-Cycle Fatigue Behavior Of Silicone Rubber For Biomedical Balloons, Chase Cooper

Materials Engineering

The development of a medical drug delivery device that allows for the deployment drugs into the adventitial tissue of blood vessels requires the inflation of a silicone elastomer. The inflated silicone must be able to consistently endure multiple loading cycles without failing so that the device can operate reliably. There are multiple methods of processing the silicone for the device and the goal of this study is to examine the effect of the various processing methods on the characteristics of the silicone. The Dynamic Mechanical Analysis Machine (DMA) is used to model the conditions of the device’s application by performing …

Exploring The Relationship Between Cellular Structure And Mechanical Properties Of Polymer Foams, Timothy Lee Tan

Materials Engineering

Polymer foams are the material of choice for applications that require comfort, cushioning, and high energy absorption. While popular, the relationship between their microstructure and their mechanical properties is not yet strongly predictable. The aim of this project is to look at the different relationships between the area or volume occupied by pores compared to the amount of solid material and determine which method of quantifying this relationship will provide the best prediction of mechanical properties. To examine this relationship, foams of various densities made from either ethylene-co-vinyl acetate or thermoplastic polyurethane were first physically characterized through three methods: (1) …

Silicon Based Uncooled Microbolometer, Asahel Banobre

Dissertations

During the last decade, uncooled microbolometer infrared detectors have attracted the attention of military and civilian infrared detection and imaging industry due to their significant advantages. In actuality, infrared imaging systems play a critical role in sectors such as thermography (predictive maintenance and building inspection), commercial and civilian applications (vision automotive, surveillance, navigation and fire-fighting), and defense industry (thermal weapon sight, soldier vision and vehicle vision enhancer). Compared with the cryogenically cooled infrared photon detectors, uncooled infrared imaging technology offers advantages such as operation at room temperature, light weight and size, reduced power consumption, easy integration with read-out electronics and …

Structural Studies To Determine The Mechanisms Supporting Multiferroic And Ferroelectric Properties Of Complex Oxides, Han Zhang

Dissertations

Multiferroics are a class of materials which possess both magnetic and electrical polarization with possible coupling between them. They show promise to enable new sensors and data storage devices with novel features, such as the possibility of writing polarization bits with magnetic fields at low power. The coexisting magnetic and ferroelectric order parameters are usually weakly coupled, preventing practical use. The development and study of new classes of materials with large magnetoelectric couplings is of high importance. Understanding the structure of these materials is key to this effort.

As one class of these systems, the RX3(BO₃)₄ has …

A Biodegradable Piezoelectric Composite Scaffold Containing Zinc Oxide For Cartilage Repair Applications, Ateka Mohd Arabi Khader

Dissertations

Osteoarthritis (OA) affects 27 million adults in the United States. OA causes degeneration of articular cartilage and subchondral bone. Articular cartilage has limited ability to regenerate and repair. Bone and cartilage tissues have known piezoelectric properties, which means they can generate electrical activity in response to mechanical deformation. Using a biomimetic approach, zinc oxide (ZnO), which has known piezoelectric properties, is fabricated into a flexible three-dimensional fibrous scaffold by embedding ZnO nanoparticles into slow degrading polycaprolactone (PCL). Zinc ions can be released from the fibrous scaffold over time, which also may be beneficial for cell function since zinc has well-known …

Stretchable Methyl Ammonium Lead Iodide Perovskite Solar Cells For Photovoltaic And Piezoelectric Energy Harvesting, William Tait

University Scholar Projects

The goal of this work was to fabricate an inverse planar perovskite solar cell (PSC) that was stretchable in one dimension and completely solution-processible. Perovskites are a material that have attracted much attention in recent years due to their appealing characteristics, such as being photovoltaic and piezoelectric. PSCs have been the focus of many studies in the solar cell area, as they are solution-processible and have shown high efficiencies relative to the amount of time they have been studied. Fabricating a PSC on a stretchable substrate would be beneficial, as a bendable, stretchable PSC would likely have more applications than …

Perovskite Solar Cells Fabricated Via Scalable Dip Coating Methods, Joseph F. Iannello

Theses and Dissertations

Perovskite solar cells present the possibility for less expensive electricity generation, through the use of low cost materials and fabrication methods relative to current silicon-based technology. Many current methods of fabricating thin film perovskite solar cells focus on spin-coating, which inherently lacks scalability due to particle conglomeration, poor uniformity over a larger area, and safety concerns. Dip-coating, an alternative to spin-coating, which is explored here addresses these issues which limit scalability. Each individual layer can be separately synthesized, deposited, and characterized, which leads towards scalability. Choosing only the best results from each independent layer allowed progress to the creation of …

Direct Synthesis Of Graphene On Niobium And Niobium Nitride, Robin Ekeya, Otto Zietz

Maseeh Summer Undergraduate Research Experience

Since its isolation by mechanical exfoliation in 2004, graphene has attracted enormous interest from the scientific community not the least because of its unique physical and electronic properties. Among these, graphene’s ballistic electron transport and proximity induced superconductivity make graphene-superconductor (GS) hybrid structures a scientifically promising area.

Three Speed 3d Printed Magnetic Gear, Robert J. Rutherford

Maseeh Summer Undergraduate Research Experience

Power transmission is traditionally achieved with a mechanical gear. Mechanical gears require maintenance, cause vibration, and have no overload protection. Magnetic gears offer an innovative solution to these drawbacks as they do not require regular maintenance, have no need for lubrication, create very little acoustic noise, have built in overload protection and as a result of these advantages, have a longer lifetime of operation. This research focused upon the design, assembly and demonstration of the magnetic gear concept. The research used a solid works design, 3D printed ABS plastic housing, and use of neodymium magnets and ferromagnetic iron segments.

This …

A Comparative Analysis Of Integrated Optical Waveguide Isolators With Magneto-Optic Layers, Reyhane Oztekin

Electrical Engineering Theses and Dissertations

The objective of this study is to theoretically devise an on-chip optical isolator which is monolithically integrated with a semiconductor waveguide layer yielding low loss. The optical properties of iron are modeled for the use of optical waveguide isolators by improving the Brendel-Bormann model. Our model for iron shows excellent fit with the optical data up to 30 electronvolts (eV). The semiconductor optical waveguide isolator with magneto-optic layers based on non-reciprocal loss shift is developed in this study. Fe, Co, and Ni metals as well as cerium-substituted yttrium iron garnet (Ce:YIG) have been used as magneto-optic layers. We have shown …

Soft-Microrobotics: The Manipulation Of Alginate Artificial Cells, Samuel Sheckman

Mechanical Engineering Research Theses and Dissertations

In this work, the approach to the manipulation of alginate artificial cell soft-microrobots, both individually and in swarms is shown. Fabrication of these artificial cells were completed through centrifugation, producing large volumes of artificial cells, encapsulated with superparamagnetic iron oxide nanoparticles; these artificial cells can be then externally stimulated by an applied magnetic field. The construction of a Permeant Magnet Stage (PMS) was produced to manipulate the artificial cells individually and in swarms. The stage functionalizes the permanent magnet in the 2D xy-plane. Once the PMS was completed, Parallel self-assembly (Object Particle Computation) using swarms of artificial cells in complex …

Investigation Of The Effects Of Harmful Radiation On Type-Ii Strained Layer Superlattice Focal Plane Arrays Operated In The Long Wave Infrared, Patrick Fumo

Electrical Engineering Theses and Dissertations

In-situ exposure of InAs/InAsSb strained layer superlattice focal plane arrays to gamma-rays revealed the possibility of a detector capable of imaging through a total ionizing dose event. Two long wave infrared focal plane arrays were exposed to a Co⁶⁰ source at dose rates of 60 Rads/s and 70 Rads/s in incremental steps up to a total accumulated dose of 30 kRads. The first device showed no degradation in dark current density with accumulated dose while the second device tested showed a small increase up to 1 kRad and minimal increases with subsequent dose steps. The primary imaging defect in …

Ii-Vi Semiconductor Nanowire Array Sensors Based On Piezotronic, Piezo-Phototronic And Piezo-Photo-Magnetotronic Effects, Shuke Yan

LSU New Orleans Theses and Dissertations

With the rapid progress of nanotechnologies, there are two developing trends for the next generation of sensors: miniaturization and multi-functionality. Device miniaturization requires less power consumption, or even self-powered system. Multi-functional devices are usually based on multi-property coupling effects. Piezoelectric semiconductors have been considered to be potential candidates for self-powered/multi-functional devices due to their piezotronic coupling effect. In this dissertation, ZnO and CdSe nanowire arrays have been synthesized as the piezoelectric semiconductor materials to develop the following self-powered/multi-functional sensors: (1) self-powered gas sensors of ZnO/SnO₂, ZnO/In₂O₃, ZnO/WO₃ and CdSe nanowire arrays have been …

Voltage-Controlled Deposition Of Nanoparticles For Next Generation Electronic Materials, Subhodip Maulik

LSU Doctoral Dissertations

This work presents both a feasibility study and an investigation into the voltage-controlled spray deposition of different nanoparticles, namely, carbon nanotubes (CNTs), as well as molybdenum disulfide (MoS₂) and tungsten disulfide (WS₂) from the transition metal dichalcogenides (TMDCs) family of materials. The study considers five different types of substrates as per their potential application to next-generation device electronics. The substrates selected for this research were: 1) aluminum as a conducting substrate, 2) silicon as a semiconducting substrate, 3) glass, silicon dioxide (SiO₂), and syndiotactic poly methyl methacrylate (syndiotactic PMMA) as insulating substrates.

Since the …

Preliminary Investigation Of Tensile Strength And Impact Characterization Of Cementitious Composite Incorporating Carbon Nanotubes, Robabeh Jazaei

UNLV Theses, Dissertations, Professional Papers, and Capstones

Cement has been largely used in the construction industry, specifically as a matrix for concrete. Recently, a new generation of cement-based composite that greatly increases mechanical properties is replacing conventional concrete. With periodic advances in the field, researchers considered particles with high-aspect ratios such as Carbon Nanotubes (CNTs) to reinforce cement matrices. Although there is not much literature to draw upon in research, some research on improving the tensile strength of cementitious composite incorporating with CNTs does exist. However, there had been no evidence of investigation into impact strength until this study.

Most papers presented examined the effect of multi-walled …

Morphological And Energy Transport Optimization Of Spectrally-Selective Solar Absorber Coatings At Mesoscale, Dale Karas

UNLV Theses, Dissertations, Professional Papers, and Capstones

A special class of cuprous-based inorganic oxide materials, synthesized as nanoparticles via hydrothermal and co-precipitation methods, are portable to spectrally-selective absorber coatings with high solar-thermal energy conversion efficiency. Operating reliably at elevated temperatures when used in tandem with solar concentrators, these materials enable cost-competitive solar energy conversion technology that can be incorporated with thermal energy storage systems, supporting the viability of novel renewable power generation; notably, optimizing absorptive performance while mitigating thermal losses through re-radiated waste heat motivates sustainable energy production particular to desert climates, where water conservation and ecological sensitivity needs are paramount.

This work targets the chemical synthesis …

Numerical Study Of Oxidation In Stainless Steel Alloy Ep-823 By Liquid Lead-Bismuth Eutectic, Rajyalakshmi Palaparty

UNLV Theses, Dissertations, Professional Papers, and Capstones

The oxidation of stainless steel is influenced by the presence of oxygen in the surrounding medium; the oxygen reacts with the alloy to form an oxide. In certain environments, such as nuclear reactor coolant systems, minimal oxidation of the stainless steel containment functions as a protective shield from corrosive coolants such as liquid lead-bismuth eutectic.

In the current study, this minimal oxidation is evaluated for a system in which corrosion-resistant stainless steel alloy EP-823 is subject to an environment of flowing oxygenated liquid lead-bismuth eutectic at a temperature of 743 K, whereby the thickness of the forming oxide layer is …

A Novel Approach To Analyzing Strain Heterogeneity In Polycrystalline Quartz Specimens Deformed At High Pressure And Temperature, Nolan Ambrose Regis

UNLV Theses, Dissertations, Professional Papers, and Capstones

Rheological studies of rocks and minerals allow researchers to study the grain-scale deformation mechanisms that govern large-scale geologic processes from mountain building to mantle mixing. Deforming rock samples with high pressure and temperature apparatuses similar to the Griggs piston cylinder apparatus allows us to simulate deformation at depth. However, many apparatuses are limited to “cook-and-look” analysis and require modeling techniques to determine the evolution of deformation patterns found in experimental samples. A previous study used two-dimensional finite element models to analyze the development of stress and strain patterns in polycrystalline rocks. The study suggested rhythmic patterns in deformed rocks develop …

Ozone Removal Efficiency And Surface Analysis Of Green And White Roof Hvac Filters, Omed A. Abbass, David Sailor, Elliott T. Gall

Mechanical and Materials Engineering Faculty Publications and Presentations

Heating, ventilation, and air-conditioning ( HVAC ) system filters from a commercial building were tested for their ability to remove ozone from intake air. Filters were taken from rooftop HVAC systems installed for two months: one located on a white membrane roof and the other on a vegetated green roof. One new, unused filter sample was tested as a reference. Samples from these filters were exposed to ozonated air streams at 40 and 120 ppb and relative humidity levels of 30% and 70%. Filter surfaces were analyzed with a scanning electron microscope to observe the structure and composition of the …