Stochastic Model For High Temperature Oxidation Of Cr–Ni Austenitic Steels Assisted By Spallation,
2022
Missouri University of Science and Technology
Stochastic Model For High Temperature Oxidation Of Cr–Ni Austenitic Steels Assisted By Spallation, Simon N. Lekakh, Oleg Neroslavsky, Mei Li, Larry Godlevski
Materials Science and Engineering Faculty Research & Creative Works
Cr–Ni austenitic steels offer significant high temperature corrosion protection by forming a surface oxide layer. However, above critical service conditions (temperature, atmosphere, thermal cycling), oxidized surface can experience intensive degradation because of scale spallation, which could be detrimental to the in-service life. To predict the effect of scale spallation on oxidation kinetics, a simulation was implemented using a stochastic model. The model considers topological parameters and intensity of spallation which can occur, while delivering a true oxidation constant. The experimental procedure identified the amount of formed spalled scale and topology of spallation based on the use of element mapping of …
Investigation Of Adhesion, Deformation Mechanics, And Electrical Properties Of Ag/Sio2/Pdms Tri-Layers For Stretchable Electronic Applications,
2022
Rowan University
Investigation Of Adhesion, Deformation Mechanics, And Electrical Properties Of Ag/Sio2/Pdms Tri-Layers For Stretchable Electronic Applications, Rhandy Joe Paladines
Theses and Dissertations
The motivation behind this research is to improve the interfacial layer bonding of metallic thin films to PDMS substrates with the aid of a buffer layer. The physical vapor deposition (PVD) technique of sputtering was used to deposit bilayer thin films of silver (Ag) and silicon dioxide (SiO2) on PDMS. Two chamber pressures were used in this work, 5 and 20 mTorr, to investigate the role of this parameter in determining the interfacial adhesion and the role in determining the resistance sensitivity. Studies of the surface energy and increased bonding strength for metallization are carried out. Surface characterization using atomic …
Pulsed Lased Deposition Of Single-Crystalline (001) Oriented Pb(Zr0.5t0.5)O3 Thin Film On Prsco3 Substrate,
2022
Department of Mechanical and Industrial Engineering, University of Dar es Salaam, P.O. Box 35131, Tanzania
Pulsed Lased Deposition Of Single-Crystalline (001) Oriented Pb(Zr0.5t0.5)O3 Thin Film On Prsco3 Substrate, Mahamudu H. Mtebwa, Nava Setter
Tanzania Journal of Science
High quality thin films are important for domain engineering applications such as on-volatile memory applications. Single crystalline (001) oriented Pb (Zr0.5T0.5)O3 thin films have been grown by pulsed laser deposition on PrScO3 with strontium ruthenate (SRO) electrodes. Thin films were prepared from PZT ceramic targets with 15% excess PbO to compensate for lead loss at high deposition temperature. Layer by layer/step flow growth mode observed on AFM images has been realised by using a single terminated PrScO3 substrate as well as optimized deposition parameters. XRD measurements have confirmed the highly (001) oriented tetragonal symmetry. Furthermore, analysis conducted using piezoresponse force …
Effects Of Multilayer Structure On The Microstructure And Optical Properties Of The Dc Sputtered Chromium Thin Films For Selective Solar Absorber Applications,
2022
Physics Department, University of Dar es Salaam, P.O. Box 35063, Dar es Salaam Tanzania
Effects Of Multilayer Structure On The Microstructure And Optical Properties Of The Dc Sputtered Chromium Thin Films For Selective Solar Absorber Applications, Justine J. Tibaijuka, Margaret E. Samiji, Mmantsae Diale, Nuru R. Mlyuka
Tanzania Journal of Science
Chromium thin films exhibit several properties that make them potential for solar thermal applications. In this work the effect of film thickness and sputtering power based multilayer structure on the optical properties of DC sputtered chromium thin films is reported. The structural, topological, and optical properties of these films were determined by X-ray diffractometer, Atomic Force Microscopy, and Ultraviolet-Visible-Near Infrared spectrophotometer, respectively. XRD spectra revealed a single peak with preferential orientation of (200) and (210) for single layer and multilayer chromium films, respectively. The grain size and roughness were relatively higher for the multilayer compared to single layer Chromium films. …
Towards Environmentally Sustainable, High-Performance, Lightweight Composites For Automotive Applications,
2022
Rowan University
Towards Environmentally Sustainable, High-Performance, Lightweight Composites For Automotive Applications, Jasmin Zamudio Vasquez
Theses and Dissertations
The increasing public demand in the world automotive industry to improve the environmental sustainability of their manufactured vehicles without sacrificing drivers' comfort and safety and the high cost of lightweight materials have driven researchers to reconsider materials used in the automotive application. Thus, this work aims toward the production of environmentally sustainable, high-performance, lightweight composites, utilizing recycled carbon fibers (RCFs) and pyrolyzed tire particles (PTPs) reclaimed from pyro-gasification of CFRP wastes and end-of-life tires (ELTs), respectively, as reinforcements for cardanol-based epoxy resins. The fabricated composites exhibited rubbery-like behavior at 25 °C. Spectroscopic, rheological, physical, thermal, thermomechanical, and mechanical characterizations were …
Preface To Special Issue On Water Electrolysis For Hydrogen Production,
2022
1. School of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 400044;
Preface To Special Issue On Water Electrolysis For Hydrogen Production, Li Li, Jin-Song Hu, Zi-Dong Wei
Journal of Electrochemistry
No abstract provided.
Perovskite-Type Water Oxidation Electrocatalysts,
2022
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry,Jilin University, Changchun 130012, P. R. China;
Perovskite-Type Water Oxidation Electrocatalysts, Xiao Liang, Ke-Xin Zhang, Yu-Cheng Shen, Ke Sun, Lei Shi, Hui Chen, Ke-Yan Zheng, Xiao-Xin Zou
Journal of Electrochemistry
The development of energy conversion/storage technologies can achieve the reliable and stable renewable energy supply, and bring us a sustainable future. As the core half-reaction of many energy-related systems, water oxidation is the bottleneck due to its sluggish kinetics of the four-concerted proton-electron transfer (CPET) process. This necessitates the exploitation of low cost, highly active and stable water oxidation electrocatalysts. Perovskite-type oxides possess diverse crystal structures, flexible compositions and unique electronic properties, enabling them ideal material platform for the optimization of catalytic performance. In this review, we provide a comprehensive summary for the crystal structures, electronic structures and synthetic methods …
Self-Supporting Nife Ldhs@Co-Oh-Co3 Nanorod Array Electrode For Alkaline Anion Exchange Membrane Water Electrolyzer,
2022
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, China;
Self-Supporting Nife Ldhs@Co-Oh-Co3 Nanorod Array Electrode For Alkaline Anion Exchange Membrane Water Electrolyzer, Dan-Dan Guo, Hong-Mei Yu, Jun Chi, Zhi-Gang Shao
Journal of Electrochemistry
The development of efficient and durable electrodes for anion exchange membrane water electrolyzers (AEMWEs) is essential for hydrogen production. In this work, 2D NiFe layered double hydroxides (NiFe LDHs) nanosheets were grown on the 1D cobaltous carbonate hydroxide nanowires array (Co-OH-CO3) and the unique 3D layered self-supporting nanorod array (NiFe LDHs@Co-OH-CO3/NF) electrode was obtained. Importantly, we demonstrated an efficient and durable self-supporting NiFe LDHs@Co-OH-CO3/NF electrode for oxygen evolution reaction (OER) and as the anode of the AEMWE. In a three-electrode system, the self-supporting NiFe LDHs@Co-OH-CO3/NF electrode showed excellent catalytic activity for OER, …
The Rapid Preparation Of Efficient Mofeco-Based Bifunctional Electrocatalysts Via Joule Heating For Overall Water Splitting,
2022
1. Fuel Cell System and Engineering Laboratory, Key Laboratory of Fuel Cells & Hybrid Power Sources, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;2. University of Chinese Academy of Sciences, Beijing, 100049, China;
The Rapid Preparation Of Efficient Mofeco-Based Bifunctional Electrocatalysts Via Joule Heating For Overall Water Splitting, Ao Zhou, Wei-Jian Guo, Yue-Qing Wang, Jin-Tao Zhang
Journal of Electrochemistry
Water electrolysis is an available way to obtain green hydrogen. The development of highly efficient electrocatalysts is a current research hotspot for water splitting, but it remains challenging. Herein, we demonstrate the synthesis of a robust bifunctional multi-metal electrocatalysts toward water splitting via the rapid Joule-heating conversion of metal precursors. The composition and morphology were well regulated via altering the ratio of metal precursors. In particular, the trimetal MoC/FeO/CoO/carbon cloth (CC) electrode revealed the outstanding bifunctional electrocatalytic performance due to the unique composition and large electrochemical active surface area. Typically, the MoC/FeO/CoO/CC catalyst needed low overpotentials of 121 and 268 …
Recent Development Of Low Iridium Electrocatalysts Toward Efficient Water Oxidation,
2022
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry,Jilin University, Changchun 130012, P. R. China;
Recent Development Of Low Iridium Electrocatalysts Toward Efficient Water Oxidation, Jing Ni, Zhao-Ping Shi, Xian Wang, Yi-Bo Wang, Hong-Xiang Wu, Chang-Peng Liu, Jun-Jie Ge, Wei Xing
Journal of Electrochemistry
Developing high-performance and low-cost electrocatalysts for oxygen evolution reaction (OER) is the key to implementing polymer electrolyte membrane water electrolyzer (PEMWE) for hydrogen production. To date, iridium (Ir) is the state-of-the-art OER catalyst, but still suffers from the insufficient activity and scarce earth abundance, which results in high cost both in stack and electricity. Design low-Ir catalysts with enhanced activity and stability that can match the requirements of high current and long-term operation in PEMWE is thus highly desired, which necessitate a deep understanding of acidic OER mechanisms, unique insights of material design strategies, and reliable performance evaluation norm, especially …
A Co Porphyrin With Electron-Withdrawing And Hydrophilic Substituents For Improved Electrocatalytic Oxygen Reduction,
2022
Key Laboratory for Colloid and Interface Chemistry Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, China;
A Co Porphyrin With Electron-Withdrawing And Hydrophilic Substituents For Improved Electrocatalytic Oxygen Reduction, Hong-Bo Guo, Ya-Ni Wang, Kai Guo, Hai-Tao Lei, Zuo-Zhong Liang, Xue-Peng Zhang, Rui Cao
Journal of Electrochemistry
Understanding factors that influence the catalyst activity for oxygen reduction reaction (ORR) is essential for the rational design of efficient ORR catalysts. Regulating catalyst electronic structure is commonly used to fine-tune electrocatalytic ORR activity. However, modifying the hydrophilicity of catalysts has been rarely reported to improve ORR, which happens at the liquid/gas/solid interface. Herein, we report on two Co porphyrins, namely, NO2-CoP (Co complex of 5,10,15,20-tetrakis(4-nitrophenyl)porphyrin) and 5F-CoP (Co complex of 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin), and their electrocatalytic ORR features. By simultaneously controlling the electronic structure and hydrophilic property of the meso-substituents, the NO2-CoP showed higher electrocatalytic activity than …
Surface Structure Engineering Of Feni-Based Pre-Catalyst For Oxygen Evolution Reaction: A Mini Review,
2022
1. State Key Laboratory of Electroanalytic Chemistry, Jilin Province Key Laboratory of Low Carbon Chemistry Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences,Changchun 130022, China;2. School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China;
Surface Structure Engineering Of Feni-Based Pre-Catalyst For Oxygen Evolution Reaction: A Mini Review, Jia-Xin Li, Li-Gang Feng
Journal of Electrochemistry
Nitrite, a widespread raw material, is harmful to human health for long-term consumption. At present, the detection methods of nitrite mainly include chemical analysis, fluorescence, ultraviolet spectrophotometry and chromatography. These methods have ideal sensitivity and selectivity, but also have some characteristics: cumbersome operation, expensive equipment and professional personnel. Therefore, the development of a simple and sensitive nitrite assay is of great significance. In this paper, the Au/rGO/FeOOH composite materials, which revealed good synergistic catalytic performance among the three elements in the composite, were prepared by simple hydrothermal method and reduction method for the first time with large specific surface area …
Development Of High-Performance Fiber Cement: A Case Study In The Integration Of Circular Economy In Product Design,
2022
Kasetsart University
Development Of High-Performance Fiber Cement: A Case Study In The Integration Of Circular Economy In Product Design, Parinya Chakartnarodom, Sarunya Wanpen, Wichit Prakaypan, Edward A. Laitila, Nuntaporn Kongkajun
Michigan Tech Publications, Part 1
A new fiber cement (FC) is designed with the integration of circular economy (CE) concepts, in particular a product that is recyclable yet maintains performance. The FC samples were prepared from the mixtures of ordinary Portland cement (OPC), sand, and cellulose fibers, and required an inclusion compound (IC) and water. From the heat of hydration tests, the most effective IC, IC1, was prepared from lithium silicate, sodium thiocyanate, alkylbenzene sulfonate, and hydrochloric acid. The FC samples were recycled by crushing and grinding, then used as sand replacement in varying amounts to produce new FC samples. The results from the mechanical …
Effect Of Degradation Of Methylene Blue Dye (Mb) By Using Erbium Oxide (Er2o3) Nps,
2022
Al-Esraa University College, Dept. of Biomedical Engineering, Baghdad / Iraq
Effect Of Degradation Of Methylene Blue Dye (Mb) By Using Erbium Oxide (Er2o3) Nps, Hind Ahmed Jasim, Farah Farman Abbass, Sarah A. Hamood, Hind Mohammed Hassan, Mohammed Sellab Hamza
Al-Esraa University College Journal for Engineering Sciences
In an experiment investigating the photo catalytic degradation of methylene blue using varied concentrations of Er2O3 nanoparticles, different conditions were tested including with and without sunshine, as well as in the absence of a UV source. The presence of a UV source was also considered in the research. UV-Visible spectroscopy was utilized to characterize the catalysts. The degradation of methylene blue dye was monitored by spectrophotometry by tracking dye absorbance at regular time intervals and adjusting the dye concentration. The results indicated that the most effective degradation of methylene blue dye occurred during a 5-hour irradiation time and in the …
Architecture Between Development And Ability Programs,
2022
University of Technology
Department of Architectural Engineering
Baghdad / Iraq
Architecture Between Development And Ability Programs, Allaa Ahmed Rasheed, Ibrahim Jawad Kadhim
Al-Esraa University College Journal for Engineering Sciences
The development of architecture and its pursuit of perfection can only be achieved through society to reach a specific result when meeting new desires that arise as a result of human development, expanding individual and societal needs, and deepening their relationships in multifaceted ways. The research focuses on development as it requires a clear cumulative vision of the integrative relationship between practice and participation in interpreting the act (effect) from the force (influence). It emphasizes that the power of capabilities is understood through learning and education in describing the capabilities of architecture. This involves adopting new ideas and intellectual premises …
The Designing Of Contemporary Teaching- Learning Spaces According To Interactive Flow Action Local School Spaces-A Case Study,
2022
Ministry of Education, Dept. of School Building, Baghdad / Iraq.
The Designing Of Contemporary Teaching- Learning Spaces According To Interactive Flow Action Local School Spaces-A Case Study, Aseel Jasem Al-Ataby, Anwar Subhi Ramadan Al-Qaraghuli
Al-Esraa University College Journal for Engineering Sciences
The world today faces many challenges related to environmental issues, as well as other social and economic challenges, and in light of intellectual, cognitive, and technical transformations, which led to the emergence of many new phenomena and concepts that correspond to them, including the concept of flow. This concept has been associated with many aspects of life, including architecture, whose importance has emerged recently in light of the challenge of the spread of the Corona virus and its effects on architecture with its residential, educational, and other spaces. This research focuses on the flow in the architectural space in general, …
A New Compact Triple-Band Micro-Strip Monopole Antenna Based On Minkowski Fractal Geometry,
2022
Department of Biomedical Engineering, Al-Esraa University College, Baghdad / Iraq
A New Compact Triple-Band Micro-Strip Monopole Antenna Based On Minkowski Fractal Geometry, Hayder S. Ahmed, Zahra' Salah Ahmed, Sarah A. Hamood, Mohammed Sellab Hamza, Taha A. Elwi
Al-Esraa University College Journal for Engineering Sciences
Wireless communication systems have made significant advancements in size reduction, with antenna terminals remaining a primary challenge for system compatibility. As a result, much of industrial research is focused on antenna miniaturization in wireless systems. In this work, a novel compact Triple-Band Fractal (TBF) antenna is proposed, utilizing three coupling fractal patches with varying iteration levels of Minkowski geometry to provide three resonant bands. The antenna design is implemented using an antenna substrate with a dielectric constant of 10.8 and a thickness of 1.27 mm within the CST Microwave Studio environment. The zero iteration patch resonator is responsible for the …
The Role Of Community Participation In The Architectural Production,
2022
University of Technology
Department of Architectural Engineering
Baghdad / Iraq
The Role Of Community Participation In The Architectural Production, Allaa Ahmed Rasheed, Ibrahim Jawad Kadhim
Al-Esraa University College Journal for Engineering Sciences
The role of community participation as a power in building architectural output at the level of the act of thinking in architecture and the design process in non-existence is related to power and presence with act. The research is concerned with expanding knowledge in the direction of the holistic language and searching for the role that builds the privacy of the architectural product versus the community's societal identity. It studies the concept of act within the limits of existence at the level of community participation since the act of architecture is the act of man to meet certain needs and …
The Communicative Deviation In Contemporary Architectural Production,
2022
Department of Architectural Engineering, University of Technology, Baghdad / Iraq
The Communicative Deviation In Contemporary Architectural Production, Haneen Hosham Abd-Alrahman, Panrizat Q. Hussein Fehmi
Al-Esraa University College Journal for Engineering Sciences
Deviation is one of the most important concepts discussed in various architectural and non-architectural theses when addressing the topic of creative production. It involves breaking away from the familiar and surpassing established architectural rules to create unique and excellent products that are characterized by their creativity and aesthetic appeal. Recognizing the significance of this concept in shaping contemporary architectural production, the research endeavors to explore the concept of connective displacement in architecture and delve into its essential aspects. The research identifies the research problem as the "cognitive deficiency surrounding connective displacement in the semantic structures embedded in architecture." The objective …
Developed Rc4 Algorithm With Double Reverse For Better Data Protect,
2022
Ministry of Higher Education and Scientific Research, Baghdad / Iraq
Developed Rc4 Algorithm With Double Reverse For Better Data Protect, Fouad Sahib Muhamed Alkhazraji
Al-Esraa University College Journal for Engineering Sciences
Computer security plays a crucial role in protecting users' data, and cryptographic techniques are commonly used for this purpose. Encryption is a method employed to ensure data confidentiality, whether it is stored on hard drives or transferred through various media. RC4 (Rivest Cipher 4) is a cryptographic algorithm that utilizes the same key for both encryption and decryption processes. It falls under the category of stream ciphers, which are widely utilized in numerous protocols due to their flexibility and speed. RC4 employs XOR (exclusive OR) function to implement its encryption and decryption steps. In this paper, a technique known as …
