Materials Science and Engineering Commons^™

Investigation Of Gaas Double Heterostructures For Photonic Heat Engines, Nathan Giannini-Hutchin

Optical Science and Engineering ETDs

The creation of a laser cooled semiconductor device has been a long sought achievement. GaAs-based devices have emerged as a promising candidate for the realization of this goal. Efforts to improve the efficiency of such devices have enabled the material to exhibit external quantum efficiencies (EQE, a measure of the probability that an excitation leads to the emission of a photon) of 99.5\%. Despite this impressive feat, a laser coolable device remains elusive.

To investigate the obstacles to such a device, the material characteristics of GaAs-based double heterostructures (DHS) are theoretically and experimentally examined. Through this study, a GaAs $\vert$ …

Exploring The Effect Of Environmental Degradation On The Shape Memory Properties Of Polymers, Jorge Mario Avila

Open Access Theses & Dissertations

A key detriment of the use of polymers by our society is the negative effect this material class has had on the environment. A category of polymers known as shape memory polymers (SMP)s have the ability to return to a programmed original shape form after deformation to a temporary shape by using stimuli such as temperature, electrical pulses and even magnetism. The shape memory effect allows for some polymers to heal if they are damaged. This ability to heal means that components made from these materials can be reused rather than thrown away if they are damaged. The work presented …

The Living Breakwaters Pdr Efforts Econcrete Resource Analysis, Guianina Ferrari, Shervon Stephens, Calvin O. Walters Jr.

Publications and Research

On October 29, 2012, Superstorm Sandy impacted 443,000 people and caused nearly $19 billion (about $58 per person in the US) worth of damage within New York City. As part of the New York City infrastructure reparation plan, the Living Breakwaters project in Tottenville addressed coastal resilience, allocating $100M of public funds to a series of artificial breakwaters by the southwest coast of Staten Island. Each breakwater is constructed and designed to mitigate water flow in storm events. ECOncrete, a primary element of the breakwater, is a specialty cast cementitious product that is marine organism-friendly that encourages biocalcification and photosynthesis. …

Low-Cost, Low-Weight Test Rig Design For A Laboratory-Scale Twin Rotor Wind Turbine, Ahmed Ayoub, Ahmed Elzeedy, Mahmoud Elkordy, Eslam Ayad, Mohamed Waleed, Amira Elkodama, Amr Ismaiel

Future Engineering Journal

Multi-Rotor Wind Turbine (MRWT) has been proven advantageous over Single-Rotor Wind Turbine (SRWT) in many aspects. In order to study the performance of MRWT over SRWT, this work presents a low-cost and low-weight design for a test rig for laboratory-scale wind turbine configurations. The configurations under study are a single-rotor, and a twin-rotor of the same size with a diameter of 30 cm. Aerodynamic loads have been calculated using the Blade Element Momentum (BEM) method, then the loads were used for stress analysis over the test rig proposed. The test rig is designed on Solidworks and the aerodynamic and inertial …

Study On Predictive Maintenance Of V-Belt In Milling Machines Using Machine Learning, Reza Aulia Rahman, Mohammad Faishol Erikyatna, Achmad Fauzan Hery Soegiharto

Journal of Mechanical Engineering Science and Technology (JMEST)

Towards industry 4.0, monitoring the degradation of machine tools’ components becomes a key feature so that smooth productivity is achieved. To preserve the functionality and performance of the machine tools, proper maintenance activities must be planned and carried out. V-belt is important component in machine tools that transmits power from the electric motor spindle in order to machine to work and cut desired material properly. The purpose of this research is to develop a predictive maintenance system for v-belt milling machine Krisbow 31N2F using machine learning. The machine learning algorithm models using multiple and simple linear regression algorithm was developed …

True Stress-Strain Behavior Of Al-Based Cast Automotive Alloy Under Different Ageing Conditions And The Effect Of Trace Zr, Mashiur Rahman Shoummo, Akib Abdullah Khan, Mohammad Salim Kaiser

Journal of Mechanical Engineering Science and Technology (JMEST)

A thorough investigation has been carried out on the Al-12Si-1Mg-1Cu-1Ni automotive alloy considering different properties, specially mechanical properties associated with true stress and true strain with Zr addition of trace amount. A commercially available piston is melted to produce the alloy, and trace amount of Zr is added to make another. The base alloy along with the Zr added alloy had been applied to homogenization, solution treatment, quenching, and ageing in order to get the age-hardening response. The alloys have been heat-treated at 25 ºC, 200 ºC, and 300 ºC, respectively, for four hours for attaining the under, peak and …

Effect Of Graphene Addition On Bacterial Cellulose-Based Nanocomposite, Jibril Maulana, Heru Suryanto, Aminnudin Aminnudin

Journal of Mechanical Engineering Science and Technology (JMEST)

Bacterial cellulose (BC) is a widespread, low-cost biopolymer that has generally been produced from plants and biomass waste. A method for improving the range of applications for bacterial cellulose is adding graphene material. It has an outstanding feature that can increase the performance of nanocomposite materials. The research aims to observe the effect of graphene on the surface morphology, crystallinity, chemical bonding, and tensile strength of BC/CuO nanocomposite. For this study's synthesis, BC was synthesized by fermenting pineapple peel extract for 10 to 14 days. The produced BC was crushed, homogenized with a nano homogenizer machine, and filtered. Filtered BC, …

The Effect Of Nozzle Temperature, Infill Geometry, Layer Height And Fan Speed On Roughness Surface In Petg Filament, Doohan Taqdissillah, Aris Zainul Mutaqqin, Mahros Darsin, Dedi Dwilaksana, Nasrul Ilminnafik

Journal of Mechanical Engineering Science and Technology (JMEST)

3D printing is a process of making three-dimensional solid objects from a digital file process created by laying down successive layers of material until the object is created. Many filaments can be used in 3D printing, one of which is PETG (PolyEthylene Terephthalate Glycol). PETG is a modification of PET (PolyEthylene Terephthalate) with added glycol at a molecular level to offer different chemical properties that provide significant chemical resistance, durability, and excellent formability for manufacturing. This study aims to find the most optimal parameter of surface roughness of PETG with different parameters of nozzle temperature, infill geometry, layer height and …

Backpack Effects On Two-Dimensional Gait Spatiotemporal And Kinematic Parameters, Nardo Rizaldy, Alvin Alvin, Wirawan Lingga, Ethan B.W. Goeij, F. Ferryanto

Journal of Mechanical Engineering Science and Technology (JMEST)

Loads could affect the body gait in various ways. Backpacks, sling bags, suitcases, and even trolleys could hugely affect human gait without us realizing it. The effects of these loads have been scientifically researched in biomechanics and sports science for the past few years. For instance, the comparison of walking with and without a backpack could easily reveal significant differences in body segments, which could be utilized for therapy and medicine development. The aim of this research is to determine the differences of the spatiotemporal kinematic parameters between a conventional human gait and a backpackloaded gait. Some parameters to be …

Investigate The Potential Renewable Energy Of Microalgae Spirulina Sp Using Proximate Analyzer, Sem-Edx, And Thermogravimetry, Yahya Zakaria, Sukarni Sukarni, Poppy Puspitasari, Nandang Mufti, Samsudin Anis, Anwar Johari

Journal of Mechanical Engineering Science and Technology (JMEST)

Microalgae Spirulina sp which has been cultivated by the Brackishwater Aquaculture Development Center, Situbondo Indonesia were tested for their potential energy performance using proximate analyzer, SEMEDX, and thermogravimetry. The proximate analyzer showed volatile matter (VM), fixed carbon (FC), moisture, ash content (AC), total sulfur of microalgae Spirulina sp 68.15, 12.57, 11.22, 8.06, and 0.67 (wt%, ar), respectively, and the gross calorific value (GCV) is 4971 kcal/kg (dry basis). SEM-EDX test showed the morphology and chemical content of Spirulina sp. The content of microalgae Spirulina sp is dominated by carbon (C) and oxygen (O), then followed by chlorine (Cl), sodium (Na), …

Characterization Of Materials Properties In Additively Manufactured Aisi-420 Martensitic Steel Deposited By Laser Engineered Net Shaping, Md Mehadi Hassan

Nanoscience and Microsystems ETDs

Metal additive manufacturing (AM) is a disruptive technology enabling the fabrication of complex and near-net-shaped parts by adding material layer-wise. It offers reduced lead production time. AM processes are finding applications in many industrial sectors such as aerospace, automotive, biomedical, and mold tooling. Despite the tremendous advantages of AM, some challenges still prevent this technology's adoption in high-standard applications. Anisotropy and inhomogeneity in the mechanical properties of the as-built parts and the existence of pores and lack-of-fusion defects are considered the main issues in directed energy deposition (L-DED) parts. Laser-engineered net shaping LENS® offers excellent possibilities to fabricate metal tools …

Which Factor Dominates Battery Performance: Metal Ion Solvation Structure-Derived Interfacial Behavior Or Solid Electrolyte Interphase Layer?, Hao-Ran Cheng, Zheng Ma, Ying-Jun Guo, Chun-Sheng Sun, Qian Li, Jun Ming

Journal of Electrochemistry

Solid-electrolyte interphase (SEI) layer formed on the electrode by electrolyte decomposition has been considered to be one of the most important factors affecting the battery performance. We discover that the metal ion solvation structure can also influence the performance, particularly, it can elucidate many phenomena that the SEI cannot. In this review, we summarize the importance of the metal ion solvation structure and the derived metal ion de-solvation behaviors, by which we can build an interfacial model to show the relationship between the interfacial behavior and electrode performance, and then apply to different electrode and battery systems. We emphasize the …

Insight Into The Effects Of Cation Disorder And Surface Chemical Residues On The Initial Coulombic Efficiency Of Layered Oxide Cathode, Jin-Li Liu, Han-Feng Wu, Zhi-Bei Liu, Ying-Qiang Wu, Li Wang, Feng-Li Bei, Xiang-Ming He

Journal of Electrochemistry

Lithium layered oxide LiNi_0.6Co_0.2Mn_0.2O₂ (NCM622) is one of the most promising cathode materials in high-energy lithium-ion batteries for electric vehicles. However, one drawback for NCM622 is that its initial coulombic efficiency (ICE) is only about 87%, which is at least 6% lower than that of LiCoO₂ or LiFePO₄. In this work, we investigated the effects of surface chemical residues (e.g., LiOH and Li₂CO₃) and Li/Ni cation disorder resulted during the sintering on the ICE. We found that the ICE of the as-prepared samples could be boosted …

Efficient Interface Enabled By Nano-Hydroxyapatite@Porous Carbon For Lithium-Sulfur Batteries, Jia-Yu Wang, Xue-Feng Tong, Qi-Fan Peng, Yue-Peng Guan, Wei-Kun Wang, An-Bang Wang, Nai-Qiang Liu, Ya-Qin Huang

Journal of Electrochemistry

The dissolution and “shuttle effect” of lithium polysulfides (LiPSs) hinder the application of lithium-sulfur (Li-S) batteries. To solve those problems, inspired by natural materials, a nano-hydroxyapatite@porous carbon derived from chicken cartilage (nano-HA@CCPC) was fabricated by employing a simple pre-carbonization and carbonization method, and applied in Li-S batteries. The nano-HA@CCPC would provide a reactive interface that allows efficient LiPSs reduction. With a strong affinity for LiPSs and an excellent electronic conductive path for converting LiPSs, the shuttle effect of LiPSs was confined and the redox kinetics of LiPSs was substantially enhanced. Li-S batteries employing nano-HA@CCPC-modified separators exhibited long cycle life and …

Advances And Atomistic Insights Of Electrolytes For Lithium-Ion Batteries And Beyond, Tingzheng Hou, Xiang Chen, Lu Jiang, Cheng Tang

Journal of Electrochemistry

Electrolytes and the associated electrode-electrolyte interfaces are crucial for the development and application of high-capacity energy storage systems. Specifically, a variety of electrolyte properties, ranging from mechanical (compressibility, viscosity), thermal (heat conductivity and capacity), to chemical (solubility, activity, reactivity), transport, and electrochemical (interfacial and interphasial), are correlated to the performance of the resultant full energy storage device. In order to facilitate the operation of novel electrode materials, extensive experimental efforts have been devoted to improving these electrolyte properties by tuning the physical design and/or chemical composition. Meanwhile, the recent development of theoretical modeling methods is providing atomistic understandings of the …

Review On Oxygen-Free Vanadium-Based Cathodes For Aqueous Zinc-Ion Batteries, Xiao-Ru Yun, Yu-Fang Chen, Pei-Tao Xiao, Chun-Man Zheng

Journal of Electrochemistry

Aqueous zinc-ion batteries (AZIBs) are considered as one of the most promising next-generation electrochemical energy storage systems owing to their high-power density, environmental benign, intrinsic safety, and the low cost of the abundant zinc resources. However, their further development is still plagued by the inferior electrochemical performance of cathode materials. Though extensive research has been conducted to investigate various cathode materials (including manganese oxides, vanadium oxides, Prussian blues analogy, and organic materials), design of high-performance cathodes with satisfying capacity and long-term cycling stability still faces great challenges. Oxygen-free vanadium-based compounds, owing to their better conductivity, larger interlayer spacing, lower ion …

Effectiveness Of Clay Nanotube Blended Coating Materials For Thermal Insulation, Hawa Hashm

Doctoral Dissertations

Studies conducted by the U.S. Department of Energy reported that heating and cooling systems use nearly 60% of the total energy consumed in a building, while approximately 31% of that energy loss occurs through the improperly insulated floor, walls, and ceiling. Hot summers or severely cold weather can make these problems worse. The passing of conditioned air through these building materials is a substantial source of energy loss, which has driven significant investigation into new environmentally friendly, sustainable, and cost-effective solutions. The main objective of the research was to experimentally evaluate the thermal conductivity of paints blended with halloysite nanotubes …

Recent Progress In Two Dimensional Mxenes For Photocatalysis: A Critical Review, Tahir Haneef, Kashif Rasool, Jibran Iqbal, Rab Nawaz, Muhammad Raza Ul Mustafa, Khaled A Mahmoud, Tapati Sarkar, Asif Shahzad

All Works

Transition metal carbides and nitrides, generally known as MXenes have emerged as an alternative to improve photocatalytic performance in renewable energy and environmental remediation applications because of their high surface area, tunable chemistry, and easily adjustable elemental compositions. MXenes have many interlayer groups, surface group operations, and a flexible layer spacing that makes them ideal catalysts. Over 30 different members of the MXenes family have been explored and successfully utilized as catalysts. Particularly, MXenes have achieved success as a photocatalyst for carbon dioxide reduction, nitrogen fixation, hydrogen evolution, and photochemical degradation. The structure of MXenes and the presence of hydrophilic …

Fluid Droplet Spreading And Adhesion Studied With A Microbalance: A Review, Youhua Jiang, Jaroslaw Drelich

Michigan Tech Publications, Part 1

A contact angle observed for a liquid–solid system is not necessarily a unique value, and a few contact angles need to be considered carefully in relation to liquid spreading, adhesion and phase separation. Understanding of the significance of different contact angles has improved in the last few years through direct measurements of interactive forces between droplets/bubbles and solids together with the simultaneous visualization of the changes in their shapes. A microelectronic balance system is employed to measure the force of spreading after either liquid droplet or gas bubble attachment to a substrate surface and the droplet/bubble–substrate adhesion forces after droplet/bubble …

Transition-Metal Ions In Β-Ga2O3 Crystals: Identification Of Ni Acceptors, Timothy D. Gustafson, Nancy C. Giles, Brian C. Holloway, J. Jesenovec, B. L. Dutton, M. D. Mccluskey, Larry E. Halliburton

Faculty Publications

Excerpt: Transition-metal ions (Ni, Cu, and Zn) in β-Ga₂O₃ crystals form deep acceptor levels in the lower half of the bandgap. In the present study, we characterize the Ni acceptors in a Czochralski-grown crystal and find that their (0/−) level is approximately 1.40 eV above the maximum of the valence band.