An Efficient Palladium-Thiourea Catalysed Heck Cross-Coupling Reaction For Molecular Electronic Interest,
2017
School of Fundamental Science, Universiti Malaysia Terengganu, 21030 Kuala Terengganu, Terengganu, Malaysia
An Efficient Palladium-Thiourea Catalysed Heck Cross-Coupling Reaction For Molecular Electronic Interest, Wan M. Khairul, Mohd Shahrul Shahmi Md Shariff, Rafizah Rahamathullah, Adibah Izzati Daud, Mustaffa Shamsuddin, Siti Kamilah Che Soh
Makara Journal of Technology
The synthesis and utilization of C-C bonds formation are concerned about the key steps for the building of several conducting molecular electronics involving many asymmetric catalysts approached, which is an essential task that most researchers would ignore in preparing these materials to enhance the production yield of cross-coupling materials. Despite the enormous progress, there still remains a great demand for economic and practicable cross-coupling processes involving ultra-low catalyst loadings with high turnover numbers due to the employment of conventional metal catalyst. Thus, there has been an excessive interest to cultivate non-phosphine palladium catalysts for excellent achievement of activity, stability, and …
A Study On Dielectric Properties Of The Cellulose Derivative-Nh4br-Glycerol- Based The Solid Polymer Electrolyte System,
2017
Advanced Materials Cluster, Faculty of Industrial Sciences & Technology, Universiti Malaysia Pahang, Lebuhraya Tun Razak, Gambang 26300, Kuantan, Pahang, Malaysia
A Study On Dielectric Properties Of The Cellulose Derivative-Nh4br-Glycerol- Based The Solid Polymer Electrolyte System, Nur Muhitul Jalilah Rasali, Saifful Kamaluddin Muzakir, Ahmad Salihin Samsudin
Makara Journal of Technology
The characterization of biopolymer-based solid polymer electrolytes (SPEs) has been carried out in this present work. Cellulose derivative was chosen due to its superior physical attributes. In this work, NH4Br-doped glycerol plasticized carboxyl methylcellulose-based SPEs were successfully prepared via the solution casting method. The conductivity and dielectric properties of the prepared films were investigated using the impedance analysis which presented ~1.91×10-3 Scm-1 (with addition of 6 wt% of glycerol). In addition, the studied SPE system shows a non-Debye behaviour without a single relaxation time. The findings of the research indicate that the complexes of NH4Br and glycerol in the cellulose …
Physical And Mechanical Properties Of Palm Kernel Oil-Based Polyester Polyurethane/Multi-Walled Carbon Nanotube Composites,
2017
School of Fundamental Science, Universiti Malaysia Terengganu, 21030 Kuala Terengganu, Terengganu, Malaysia
Physical And Mechanical Properties Of Palm Kernel Oil-Based Polyester Polyurethane/Multi-Walled Carbon Nanotube Composites, Khairul Anuar Mat Amin, Muhammad Alif Zailani, Nurul Nabilah Zulkifli, Khairiah Haji Badri
Makara Journal of Technology
In this study, polyurethane (PU) films from palm kernel oil-based polyester (PKO-p) incorporated multi-walled carbon nanotubes (MWNTs) are prepared via a evaporative casting method. Nanoparticle fluid dispersions containing 0.02%, 0.03%, and 0.05% wt. of MWNTs are added into PKO-p based resin and mixed by digital probe sonicator for 30 min followed by mixing with isocyanate to produce PU-MWNTs composite films. The mechanical properties, swelling, water vapour transmission rate (WVTR) and conductivity of the PU-MWNTs composite films are examined. Results show that the toughness (T) or flexibility, the tensile strength (TS), and Young’s modulus (YM) values of PU-MWNTs composite films increase …
Spectroscopic Contrast Of Diarylethene Molecules On Octanethiol Monolayer,
2017
Physics of Nanodevices, Zernike Institute for Advanced Materials, University of Groningen, Groningen, NL-9747 AG, The Netherlands
Spectroscopic Contrast Of Diarylethene Molecules On Octanethiol Monolayer, Arramel Arramel, Tibor Kudernac, Nathalie Katsonis, Bernard Lucas Feringa, Bart Jan Van Wees
Makara Journal of Technology
We present a systematic scanning tunneling microscopy (STM) study of bias-dependent imaging of disulfur diarylethene (2S-DE) molecules on octanethiol (C8) monolayer at room temperature. In a rigid confinement of the C8 matrix, we did not observe any significant variation in the appearance of the 2S-DE. On the contrary, a reversal in the apparent height of the 2S-DE was present when the molecule was situated on a gold vacancy island. We attributed this finding to the presence of a new electronic state that became accessible for a tunneling event. In addition, the C8 surface structure underwent a reversible phase transformation from …
The Mechanism Of Radiation-Induced Nanocluster Evolution In Oxide Dispersion Strengthened And Ferritic-Martensitic Alloys,
2017
Boise State University
The Mechanism Of Radiation-Induced Nanocluster Evolution In Oxide Dispersion Strengthened And Ferritic-Martensitic Alloys, Matthew John Swenson
Boise State University Theses and Dissertations
The objective of this study is to evaluate the mechanism of irradiation-induced nanoparticle evolution in a model Fe-9%Cr oxide dispersion strengthened steel and commercial ferritic-martensitic alloys HCM12A and HT9. Each alloy is irradiated with Fe2+ ions, protons, or neutrons to doses ranging from 1-100 displacements per atoms at 500°C. The morphology of nanoclusters are characterized using atom probe tomography. The evolution of clusters in each alloy are notably different with each irradiating particle, and the competing effects of ballistic dissolution and radiation-enhanced, diffusion-driven growth are attributed to the respective differences in cluster evolution. A phase evolution model, originally theorized …
Analysis And Modeling Of The Growth Of Intermetallic Compounds In Aluminum–Steel Joints,
2017
Lanzhou University of Technology, China
Analysis And Modeling Of The Growth Of Intermetallic Compounds In Aluminum–Steel Joints, Gang Zhang, Manjiao Chen, Yu Shi, Jiankang Huang, Fuqian Yang
Chemical and Materials Engineering Faculty Publications
In this work, we experimentally and numerically studied the microstructures and growth of intermetallic compounds (IMCs) formed in Al–Fe (aluminum–steel) joints welded by a pulsed double electrode gas metal arc welding (DE-GMAW)-brazing method. The IMCs consist of Fe2Al5 and FeAl3, with Fe2Al5 being the main compound in the joints. The thickness of an IMC layer increases with an increase of the welding current (heat input) into the base metal. EBSD measurement suggests that the preferred crystal orientation of the Fe2Al5 IMC likely provides the necessary path for Al atoms …
Characterization Of Slm Printed 316l Stainless Steel And Investigation Of Microlattice Geometry,
2017
California Polytechnic State University, San Luis Obispo
Characterization Of Slm Printed 316l Stainless Steel And Investigation Of Microlattice Geometry, Finley H. Marbury
Materials Engineering
The goal of this project was firstly to characterize Cal Poly’s SLM printed 316L stainless steel. SEM analysis showed Cal Poly’s as-printed 316L material to have a cellular dendritic microstructure containing mostly austenite and a small amount of δ-ferrite. After being heat treated to eliminate warp, its yeild and ultimate tensile strength were on par with the literature, however higher modulus and lower elongation were observed. XRD analysis confirmed residual stresses in the material, and that grains are preferentially oriented in both heat treated and non heat treated samples. The amount of porosity in the material was found to be …
Characterization Of The 15-5 Stainless Steel Electric Discharge Machining Recast Layer,
2017
California Polytechnic State University, San Luis Obispo
Characterization Of The 15-5 Stainless Steel Electric Discharge Machining Recast Layer, Julian R. Lohser, Rhys W. Gilmore
Materials Engineering
Electric discharge machining (EDM) is a non-conventional machining process that is used for tough, hard materials or materials that require no tool force. Wire EDM produces a recast layer and heat-affected zone as a result of rapid melting and quenching at the surface of the cut. A secondary machining operation has been required to remove this layer. Previous estimates of the depth of the recast layer are likely too conservative due to improvements in the technology; therefore, the goal of this study is to characterize and more accurately investigate the size of the layer. Two EDM machine parameters, voltage and …
Tensile Properties Of High-Strength Connecting Rod Bolts,
2017
California Polytechnic State University, San Luis Obispo
Tensile Properties Of High-Strength Connecting Rod Bolts, Leland K. Lam
Materials Engineering
Oliver Racing Parts (ORP) is looking to optimize the manufacturing process for high-strength connecting rod bolts. A high yield strength is desired for the bolts because deformation would result in a loss of engine performance. A high tensile strength is also necessary to prevent catastrophic failure if deformation occurs. A high ductility as a proxy for toughness is attractive for resisting crack nucleation and growth during cyclic loading. Bolts were made of MP35N, a nickel-cobalt multiphase alloy; MLX-17, a precipitation hardenable stainless steel; 8740, a low alloy steel; and H11, a chromium hot-work tool steel. The temperature of the most …
Straightening Of Investment Casting Ni-Based Superalloys,
2017
California Polytechnic State University, San Luis Obispo
Straightening Of Investment Casting Ni-Based Superalloys, Silvia Squillaci, Janessa Cabrera
Materials Engineering
Samples belonging to four different designs of afterburner flaps, available in the as-cast, solutionized and aged conditions, underwent 4-point bend testing to fracture to investigate straightening. The average maximum load values of the second design samples in the as-cast, solutionized and aged conditions were respectively 33 kN, 29 kN and 27 kN. Regarding the fourth design samples, the average maximum load for the as-cast, solutionized and aged conditions were respectively 23 kN, 28 kN, and 25 kN. The other parameter measured during testing was the maximum extension at fracture. All as-cast samples belonging to the second design fractured at values …
Comparison Of Intrusive And Non-Intrusive Methods For Corrosion Monitoring Of Fuel Processing Systems,
2017
California Polytechnic State University, San Luis Obispo
Comparison Of Intrusive And Non-Intrusive Methods For Corrosion Monitoring Of Fuel Processing Systems, Armando Jacob Espinoza, Thomas Conner Field
Materials Engineering
This presentation contains an assessment of the best overall corrosion monitoring device, intrusive or non-intrusive, for use in the petrochemical industry. Corrosion in the petrochemical industry is a large issue because it causes a deterioration of pipe integrity in fuel processing systems. A reduction of pipe wall integrity due to corrosion could result in a leak or an explosion of fuel processing lines since those systems function at high pressures. The use of corrosion monitoring systems in the petrochemical industry helps to detect early signs of corrosion prior to failure so that proper maintenance can be performed to prevent catastrophe. …
Predicting Service Life Of 347 Stainless Steel Pipes By Carburization Rate Measurement,
2017
California Polytechnic State University, San Luis Obispo
Predicting Service Life Of 347 Stainless Steel Pipes By Carburization Rate Measurement, Tyler L. Sura
Materials Engineering
Chevron Corporation and other refiners face challenges predicting the service life of piping in coker furnaces. This is largely due to a build up coke on a single surface of the piping. This coke build up results in carbon penetration into the surface of the 347 stainless steel used for the pipes. Carbon penetration can lead to degradation of the surface and ultimately, the failure of the pipe. Current modeling software has difficulty predicting the influence of sulfur on the carbon penetration rate. This study aims to provide a baseline for further study into the subject. The carbon penetration rate …
Development Of Low Cost Braze Alloys For Aerospace Applications,
2017
California Polytechnic State University, San Luis Obispo
Development Of Low Cost Braze Alloys For Aerospace Applications, Alyssa M. Elliott, Sandy Babich, Blake Whitmee
Materials Engineering
Non-precious metal braze alloys can help lower the cost of brazing, which is a commonly-used joining process in the aerospace industry. A-286, a stainless steel superalloy, and Inconel© 718, a nickel-based superalloy, are both commonly used alloys at Aerojet Rocketdyne. Both alloys were brazed into butt joints using nickel-based braze alloys: AMS 4776, 4777, and 4778. The brazed samples were machined into a modified version of the ASTM E8 subsize specimen samples and tensile tested to compare the strength and calculated elongation of the brazed samples to the base metals’ properties. All of the brazed samples fractured at the joint, …
Preliminary Investigations Into Selective Laser Melting,
2017
California Polytechnic State University, San Luis Obispo
Preliminary Investigations Into Selective Laser Melting, David Takeo Otsu
Master's Theses
Selective laser melting is a promising metallic additive manufacturing process with many potential applications in a variety of industries. Through a gracious donation made by Lawrence Livermore National Laboratory, California Polytechnic State University received and installed an SLM 125 HL selective laser melting machine in February 2017. As part of the initial setup effort, a preliminary machine verification study was conducted to evaluate the general print quality of the machine with default parameter settings. Coincidentally, the as-printed microstructure of SLM components was evaluated through nil strength fracture surface examination, an alternative to conventional polish-and-etch metallography. A diverse set of components …
Kinked Tensile Behavior Of Cold Worked Nitinol,
2017
California Polytechnic State University, San Luis Obispo
Kinked Tensile Behavior Of Cold Worked Nitinol, Grant R. Caraway, Samuel J. Canovas
Materials Engineering
To characterize the decrease in ductility caused by an induced stress concentration as a function of various levels of cold work and heat treatment, Nitinol medical guide wires with a .004″ diameter were tested using both a standard, straight tensile test and a modified, bent tensile test. The ratio of the two break loads (bent:straight) for identically processed samples was used as a proxy for measuring the ductility of the guide wires: the higher the ratio, the more ductile the sample. The average break load ratio as a function of increased cold work, decreased from 1.27 to 0.91 for the …
Effect Of Composition And Build Direction On Additively Manufactured Hastelloy X Alloys,
2017
California Polytechnic State University, San Luis Obispo
Effect Of Composition And Build Direction On Additively Manufactured Hastelloy X Alloys, Justin A. Spitzer, Jeffrey T. Schloetter, Sarah Zerga
Materials Engineering
Microcracking has caused premature failure and reduction in properties in additively manufactured (AM) Hastelloy X. The purpose of this research is to meet or exceed the mechanical properties of wrought Hastelloy X by modifying the composition and build direction of Hastelloy X manufactured using Direct Metal Deposition (DMD). Tensile testing, scanning electron microscopy (SEM), and metallography were performed on the samples. ANOVA was used to analyze the dependence that the properties had on build direction and composition. The nominal composition wrought samples had a yield strength of 310.1 MPa and a 60.79% Elongation. Alloy P60-X18 in a horizontal build had …
The Magnetic, Electrical And Structural Properties Of Copper-Permalloy Alloys,
2017
Arizona State University
The Magnetic, Electrical And Structural Properties Of Copper-Permalloy Alloys, Makram A. Qader, A. Vishina, Lei Yu, Cougar Garcia, Rakesh K. Singh, Nicholas D. Rizzo, Mengchu Huang, Ralph Chamberlin, Kirill Belashchenko, Mark Van Schilfgaarde, N. Newman
Kirill Belashchenko Publications
Copper-permalloy [Cu1–x(Ni80Fe20)x] alloy films were deposited by co-sputtering and their chemical, structural, magnetic, and electrical properties were characterized. These films are found to have favorable weak ferromagnetic properties for low temperature magnetoelectronic applications. Our results show that by varying the composition, the saturation magnetization (Ms) can be tuned from 700 emu/cm3 to 0 and the Curie temperature (Tc), can be adjusted from 900 K to 0 K. The Ms and Tc are found to scale linearly between x = 25% and 100%. Electronic structure calculations …
Process Development And Implementation For The Imaging Of Heat Treated A2 Steel For Consolidation Into An Atlas,
2017
James Madison University
Process Development And Implementation For The Imaging Of Heat Treated A2 Steel For Consolidation Into An Atlas, Jessica Roberts
Senior Honors Projects, 2010-2019
Material processes, properties, and microstructure are interconnected, often visualized as the points of a triangle. Changing the process a material goes through will in turn change the properties and microstructure of that material. In materials research and education (specifically with metals), comparison between research or experiment results and scholarly-accepted results is important. When reading textbooks addressing different properties of metals and the process of metal treatment, images are often shown of the various microstructures associated with each property or process stage. The difficulty comes in trying to compare the stages or properties to one another; often different materials and processes …
Characterization Of Plastic Deformation Evolution In Single Crystal And Nanocrystalline Cu During Shock By Atomistic Simulations,
2017
University of Arkansas, Fayetteville
Characterization Of Plastic Deformation Evolution In Single Crystal And Nanocrystalline Cu During Shock By Atomistic Simulations, Mehrdad Mirzaei Sichani
Graduate Theses and Dissertations
The objective of this dissertation is to characterize the evolution of plastic deformation mechanisms in single crystal and nanocrystalline Cu models during shock by atomistic simulations. Molecular dynamics (MD) simulations are performed for a range of particle velocities from 0.5 to 1.7 km/s and initial temperatures of 5, 300 and 600 K for single crystal models as well as particle velocities from 1.5 to 3.4 km/s for nanocrystalline models with grain diameters of 6, 11, 16 and 26 nm. For single crystal models, four different shock directions are selected, <100>, <110>, <111> and <321>, and dislocation density behind the shock wave …
Fabrication And Study Of The Structure And Magnetism Of Rare-Earth Free Nanoclusters,
2017
University of Nebraska-Lincoln
Fabrication And Study Of The Structure And Magnetism Of Rare-Earth Free Nanoclusters, Bhaskar Das
Department of Physics and Astronomy: Dissertations, Theses, and Student Research
No abstract provided.
