Physical Sciences and Mathematics Commons^™

Single Particle Tracking: Analysis Techniques For Live Cell Nanoscopy., Peter K. Relich

Physics & Astronomy ETDs

Single molecule experiments are a set of experiments designed specifically to study the properties of individual molecules. It has only been in the last three decades where single molecule experiments have been applied to the life sciences; where they have been successfully implemented in systems biology for probing the behaviors of sub-cellular mechanisms. The advent and growth of super-resolution techniques in single molecule experiments has made the fundamental behaviors of light and the associated nano-probes a necessary concern among life scientists wishing to advance the state of human knowledge in biology. This dissertation disseminates some of the practices learned in …

Analysis Of 3d Cone-Beam Ct Image Reconstruction Performance On A Fpga, Devin Held

Electronic Thesis and Dissertation Repository

Efficient and accurate tomographic image reconstruction has been an intensive topic of research due to the increasing everyday usage in areas such as radiology, biology, and materials science. Computed tomography (CT) scans are used to analyze internal structures through capture of x-ray images. Cone-beam CT scans project a cone-shaped x-ray to capture 2D image data from a single focal point, rotating around the object. CT scans are prone to multiple artifacts, including motion blur, streaks, and pixel irregularities, therefore must be run through image reconstruction software to reduce visual artifacts. The most common algorithm used is the Feldkamp, Davis, and …

Natural Burial: Being Green In Life, Now In Death Too, Brandon C. Shaik

Capstones

Nearly 80 million baby boomers are approaching the end of their lives. Being more environmentally conscious than previous generations, the environmentally minded individuals are increasingly choosing natural burial as the next progression of sustainability — reducing an individual impact even after death. A 2015 poll conducted by Harris Poll on behalf of the Funeral and Memorial Information Council found that 64 percent of adults over the age of 40 were interested in natural burial, up from 21 percent in 2010. Individuals who have chosen natural burial indicate the environmental benefit as a primary reason for their decision. There are currently …

A Green Oasis: What Makes Community Gardens Worth Saving? While Researchers Amass Evidence Of Benefits, Advocates Develop New Strategy To Prove Their Value., Joel Wolfram

Capstones

Green Valley Community Garden in Brownsville, Brooklyn, is one of about a dozen gardens on land owned by the New York City Department of Housing Preservation and Development that are being uprooted by plans to build affordable housing. The gardeners are fighting back to prevent the garden’s destruction, saying that the food-producing green space is a source of healthy eating in a community with high rates of health problems, like diabetes and obesity. Researchers are attempting to tease out the public health benefits of community gardens as one metric of their value, but the science is still catching up with …

Zirconium Diboride, Hexagonal Boron Nitride, And Amorphous Alumina Thin Films For High Temperature Applications, David Murdock Stewart

Electronic Theses and Dissertations

The use of microelectronic sensors and actuators in harsh, high temperature environments, such as power plants, turbine engines, and industrial manufacturing, could greatly improve the safety, reliability, and energy efficiency of these processes. The primary challenge in implementing this technology is the breakdown and degradation of thin films used in fabricating these devices when exposed to high temperatures >800 °C and oxidizing atmospheres. Zirconium diboride, hexagonal boron nitride, and amorphous alumina are candidate materials for use as thin film sensor components due to their high melting temperatures and stable phases. Zirconium diboride thin films have metallic-like electrical conductivity and remain …

Sperner's Lemma, The Brouwer Fixed Point Theorem, The Kakutani Fixed Point Theorem, And Their Applications In Social Sciences, Ayesha Maliwal

Electronic Theses and Dissertations

Can a cake be divided amongst people in such a manner that each individual is content with their share? In a game, is there a combination of strategies where no player is motivated to change their approach? Is there a price where the demand for goods is entirely met by the supply in the economy and there is no tendency for anything to change? In this paper, we will prove the existence of envy-free cake divisions, equilibrium game strategies and equilibrium prices in the economy, as well as discuss what brings them together under one heading.

This paper examines three …

An Analysis Of Gulf Of Maine Cod Metapopulation Structure And Localized Stability, With Application To Area-Based Fisheries Management, Derek Olson

Electronic Theses and Dissertations

The complex metapopulation structure of groundfish stocks in the Gulf of Maine, particularly Atlantic cod (Gadus morhua), is largely ignored under the current system of broad-scale stock assessment and management. This mismatch of biological and administrative scales has contributed to severe overall stock decline and localized serial depletion of Gulf of Maine cod. Such chronic management failure has led to growing calls for a more area-based, finer-scale approach to managing groundfish in the Gulf of Maine. A primary difficulty hindering the development of finer-scale groundfish management has been the challenge of estimating fishing mortality upon local stock components. …

Nanoscale Thermal And Electronic Properties Of Thin Films Of Graphene And Organic Polyradicals, Sabastine Chukwuemeka Ezugwu

Electronic Thesis and Dissertation Repository

Ultrathin film materials have attracted significant attention in light of their potential applications in very large scale integrated electronics and data storage. For instance, the amount of data that can be addressed and stored in a memory device scales inversely with the thinness of the active layer of these components. In our thesis, we have developed a suite of scanning-probe and nano-optical techniques focused on understanding the electronic surface properties and the thermal conductivity of ultrathin materials. We discuss a few specific examples in which we applied these techniques towards improved performance of thin films of graphene and organic polyradicals …

Roles Of Siphon Flows In Suspension Feeding, Kevin Du Clos

Electronic Theses and Dissertations

Benthic marine suspension feeders provide an important link between benthic and pelagic ecosystems. The strength of this link is determined by suspension-feeding rates. Many studies have measured suspension-feeding rates using indirect clearance-rate methods, which are based on the depletion of suspended particles. Direct methods that measure the flow of water itself are less common, but they can be more broadly applied because clearance-rate measurements are affected by properties of the cleared particles. We present pumping rates for three species of suspension feeders, the clams Mya arenaria and Mercenaria mercenaria and the tunicate Ciona intestinalis, calculated using a direct method …

Effect Of Small-Scale Continental Shelf Bathymetry On Storm Surge Generation, Sunni A. Siqueira

University of New Orleans Theses and Dissertations

Idealized bathymetries were subjected to idealized cyclones in order to measure the storm surge response to a range of bathymetry features, under various storm conditions. Ten bathymetries were considered, including eight shoals, one pit, and a featureless reference domain. Six storms (two different sizes/intensities and three different landfall directions) were used as meteorological forcing. The bathymetry features influenced local surge response during pre- and post-peak surge conditions. However, peak surge and surge at the coast were not meaningfully affected by the presence of the bathymetry features considered. The effect of three bathymetry feature parameters on surge response was analyzed (i.e. …

The Synthesis And Characterization Of Photoluminescent Conjugated Frameworks Containing Silicon And Germanium, Douglas William Hammerstroem

Dissertations

Siloles and 9-heterofluorenes (Si, Ge) are conjugated π-electron systems containing Group 14 atoms which demonstrate unique properties such as high electron affinity, mobility, and bathochromically shifted optical spectra relative to their all-carbon analogs. This is due to their low-lying lowest-unoccupied molecular orbital (LUMO) which is resultant of the σ*-π* conjugation between the exocyclic groups at the Group 14 center and the butadiene unit of the ring. As a consequence, they have received considerable attention for their use as components for a wide variety of optical and electronic applications such as organic light emitting diodes (OLEDs), photovoltaic devices, field-effect transistors (FETs), …

Scatterometry Of 50 Nm Half Pitch Features, Ruichao Zhu

Optical Science and Engineering ETDs

Metrology technologies are an essential adjunct to Integrated Circuit (I.C.) Semiconductor manufacturing. Scatterometry, an optical metrology, was chosen to measure 50 nm half pitch feature structures. A bread-board scatterometry system has been assembled to provide a non-contact, non-destructive, accurate and flexible measurement. A real-time, on-line scatterometry system has also been demonstrated and proven to provide a high throughput measurement.

Three different types of samples have been measured using the scatterometry setup. The wire-grid polarizer (WGP) sample has been made by Jet and Flash Nanoimprint Lithography with ~100 nm pitch and ~50 nm wide ~200 nm tall Al gratings on fused …

Web-Based Integrated Development Environment, Hien T. Vu

Master's Projects

As tablets become more powerful and more economical, students are attracted to them and are moving away from desktops and laptops. Their compact size and easy to use Graphical User Interface (GUI) reduce the learning and adoption barriers for new users. This also changes the environment in which undergraduate Computer Science students learn how to program. Popular Integrated Development Environments (IDE) such as Eclipse and NetBeans require disk space for local installations as well as an external compiler. These requirements cannot be met by current tablets and thus drive the need for a web-based IDE. There are also many other …

Biogenetically Inspired Total Synthesis Of Lingzhiol. Design And Synthesis Of Axially Chiral N-Heterocyclic Carbene Catalysts., Krishna Sharmah Gautam

Arts & Sciences Electronic Theses and Dissertations

A stereo- and enantio-selective synthesis of lingzhiol has been achieved, mimicking a proposed biogenetic pathway via Brønsted acid-catalyzed semipinacol rearrangement of a 2,3-epoxy alcohol. A new and improved method was developed for alkylation of anilines using a domestic microwave oven. The resulting racemic chiral anilines were resolved via classical resolution and transformed into axially chiral thiazolylidene-based NHC organocatalysts, which were applied to asymmetric benzoin condensation.

Effects Of Temperature On Activity Of Aquatic Hyphomycetes: A Microcosm Study, Kyra Harrington‌‌

Honors Theses

Predicted increases in temperature under climate change scenarios are expected to affect not only atmospheric and water temperatures, but also the rate of heterotrophic activity and carbon dynamics and retention in ecosystems. The magnitude of the increase in metabolic activity of living organisms with increased temperature can be predicted by the Metabolic Theory of Ecology, however, multiple factors can cause deviations from simple predictions. The goal of this study is to assess the temperature sensitivity of aquatic hyphomycetes and fungi-mediated leaf litter decomposition by following responses to temperature of fungal biomass accrual, respiration and decomposition rates in laboratory microcosms simulating …

New Insights Into The Martian Crust And Angrite Parent Body Through Meteorites, Alison R. Santos

Earth and Planetary Sciences ETDs

Petrologic studies of two new, unique meteorites were conducted in order to characterize the samples and provide insights into their parent bodies. The first sample, Northwest Africa 7034, is the first martian meteorite breccia to be discovered. In an effort to understand the martian crustal materials sampled by the breccia, we developed a classification scheme for the breccia clasts based on their texture, mineralogy, and chemistry. We then further investigated two clast groups which contained trends in mineralogy and chemistry that suggested a possible genetic relationship between the two. Our findings suggest they are not related by a simple igneous …

Synthesis Of Metal-Containing Phosphines And Their Use In Coordination, Polymer, And Materials Chemistry, Amir Rabiee Kenaree

Electronic Thesis and Dissertation Repository

This thesis describes the investigation of a novel strategy for the synthesis of metal-containing small molecules, polymers, and nanomaterials. In this context, a new family of air-stable, homo- and heterometallic primary, secondary, and tertiary phosphines were prepared via the radical-initiated hydrophosphination reaction of PH₃ with vinylferrocene and/or vinylruthenocene. The full characterization of the phosphines confirmed their targeted structures and proved that the properties of the starting metallocenes are reflected in those of the resulting phosphines.

To study the coordination behavior of this family of phosphines, primary, secondary, and tertiary ethylferrocene phosphines were reacted with Group 6 metal carbonyl adducts …

Separation Of Nitrito- And Nitropentamminecobalt (Iii) Chloride By High Performance Liquid Chromatography, Tisha Hutchinson

Seton Hall University Dissertations and Theses (ETDs)

Reversed phase high performance liquid chromatography, chosen because of its ability to collect many data points over a long period of time with minimal involvement, was used to separate pentaamminenitritocobalt(III) chloride and pentaamminenitrocobalt(III) chloride. Pentaamminenitritocobalt(III) chloride was prepared, made into a concentrated solution, divided into aliquots and allowed to isomerize to pentaamminenitrocobalt(III) chloride over a period of twelve to eighteen hours. An injection was made approximately every forty-five minutes. The samples were analyzed at three wavelengths, 254 nm, 460 nm and 490 nm. The absorbance was collected and was used to determine the kinetics of the reaction.

The isomerization from …

The Paradox Of Social Media Security: A Study Of It Students’ Perceptions Versus Behavior On Using Facebook, Zahra Y. Alqubaiti

Master of Science in Information Technology Theses

Social media plays an essential role in the modern society, enabling people to be better connected to each other and creating new opportunities for businesses. At the same time, social networking sites have become major targets for cyber-security attacks due to their massive user base. Many studies investigated the security vulnerabilities and privacy issues of social networking sites and made recommendations on how to mitigate security risks. Users are an integral part of any security mix. In this thesis, we explore the relationship between users’ security perceptions and their actual behavior on social networking sites. Protection motivation theory (PMT), initially …

Regulatory Compliance-Oriented Impediments And Associated Effort Estimation Metrics In Requirements Engineering For Contractual Systems Engineering Projects, Md Rashed I. Nekvi

Electronic Thesis and Dissertation Repository

Large-scale contractual systems engineering projects often need to comply with a myriad of government regulations and standards as part of contractual fulfillment. A key activity in the requirements engineering (RE) process for such a project is to elicit appropriate requirements from the regulations and standards that apply to the target system. However, there are impediments in achieving compliance due to such factors as: the voluminous contract and its high-level specifications, large number of regulatory documents, and multiple domains of the system. Little empirical research has been conducted on developing a shared understanding of the compliance-oriented complexities involved in such projects, …

Formulation Of Colloidal Suspensions Of 3-Mercaptopropionic Acid Capped Pbs Quantum Dots As Solution Processable Qd "Inks" For Optoelectronic Applications, Chase Collier Reinhart

Dissertations and Theses

The use of colloidal quantum dots (QDs) for photovoltaic energy conversion is a nascent field that has been dominated for well over a decade by the use of 3-mercaptopropionic acid (3-MPA) capped PbS QDs. These QDs are routinely deposited via an in situ solid state ligand exchange process that displaces the native oleate ligand on the PbS QD surface. This ligand exchange procedure is wasteful of material and has been demonstrated to leave numerous impurities that limit electronic performance of the as-deposited QD devices. Until the last few years there was very little understanding in chemical literature as to many …

X-Ray Absorption And Emission Studies Of Anodic Titania Nanostructures, Jun Li

Electronic Thesis and Dissertation Repository

One-dimensional (1D) TiO₂ nanomaterials with ordered structure have been extensively applied in various fields, such as photocatalysts, solar cells, supercapacitors and rechargeable batteries, due to the unique structural and functional properties compared to the disordered nanoparticulate forms. Nevertheless, intrinsic disadvantages of TiO₂, such as its large band gap (~3 eV), fast recombination rate of photoexcited electron–hole pairs and insufficient ionic conductivity, severely limit the development of 1D TiO₂ nanomaterials for practical applications. To address the above issues, the scope of this thesis focus on the fundamental understandings of the electronic structure of highly ordered TiO_{2 …}

How Shape Of Simulated Graphene Sheets Affects Debye Scattering Patterns, Lindsay Lesh

Honors Projects

This research is about understanding the structure of a subset of graphitic stardust found in primitive meteorites (e.g. the Murchison meteorite). The carbon grains of interest exhibit a core-rim structure, where the core – with a density less than that of the graphitic rim – comprises the majority of the grain. Previous studies have shown that the cores are comprised primarily of unlayered graphene, and it has been hypothesized that the cores are the result of the rapid freezing (quenching) of a liquid carbon droplet. Electron diffraction is sensitive to small differences in crystal structure and simulated electron diffraction powder …

Bgsu Minecraft Initiative Website, Jacob Gusching

Honors Projects

A website for the BGSU Minecraft Initiative, a program that uses Minecraft as an educational tool to engage younger students to learn. This website is a communication tool to showcase the work of BGSU students and to spread the knowledge and lesson to plans to interested parties.

Creating Functional Materials With Phosphorus, Tyler John Cuthbert

Electronic Thesis and Dissertation Repository

Understanding the relationship between small molecules or polymers and how they affect the properties of materials they compose is the basis of materials science. Using unique and versatile components can impart useful and interesting properties to materials. Here, we aimed to extend this understanding to phosphorus, and the known properties it possesses. This included the production of photopolymerizable coatings containing phosphonium molecules and polymers for antifouling and antibacterial applications. The synthesis and characterization of these phosphonium components was completed and materials were produced utilizing UV curing technology. Addition of these components produced coatings that could resist bacteria attachment and efficiently …

Algorithm For Premature Ventricular Contraction Detection From A Subcutaneous Electrocardiogram Signal, Iris Lynn Shelly

Dissertations and Theses

Cardiac arrhythmias occur when the normal pattern of electrical signals in the heart breaks down. A premature ventricular contraction (PVC) is a common type of arrhythmia that occurs when a heartbeat originates from an ectopic focus within the ventricles rather than from the sinus node in the right atrium. This and other arrhythmias are often diagnosed with the help of an electrocardiogram, or ECG, which records the electrical activity of the heart using electrodes placed on the skin. In an ECG signal, a PVC is characterized by both timing and morphological differences from a normal sinus beat.

An implantable cardiac …

Development Of An Hplc-Based Oligosaccharide Synthesizer, Salvatore Pistorio

Dissertations

Carbohydrates are the most abundant molecules on Earth. They are involved in a wide range of fundamental biological processes: anti-inflammation, immune response, joint lubrication, cell growth, antigenic determination. Carbohydrates are also held responsible for many damaging cellular processes, such as bacterial and viral infections, development of tumors, etc.. Therefore, the development of effective methods for the synthesis of complex carbohydrates has become a critical area of glycosciences. One challenge that stands out is the stereocontrol in the synthesis of glycosidic bonds, the linkage that serves as the only means to connect simple monosaccharides into complex oligomeric networks. Beyond this, the …

The Creation Of A Video Review Guide For The Free-Response Section Of The Advanced Placement Calculus Exam, Jeffrey Brown

Honors Theses

The Creation of a Video Review Guide for the Free-Response Section of the Advanced Placement Calculus Exam follows the creation of a resource to help students prepare for the College Board’s Advanced Placement Calculus Exam. This project originated out of the authors personal experiences in preparing for this exam. The goal of the project was to create an accessible resource that reviews content, provides insights into the Advanced Placement exam, and creates successful habits in student responses. This paper, chronologically, details the development of the resource and a reflection on the final product and future uses.

Using Gis To Predict Cetacean Strandings Related To Harmful Algal Blooms, Jessica L. Boyd

HCNSO Student Capstones

Exposure to harmful algal bloom (HAB) toxins, such as Karenia brevis, has been linked to cetacean strandings and mortalities. Biological and environmental data from a bottlenose dolphin (Tursiops truncatus) Unusual Mortality Event (UME) in 2004 are compared to those from pilot whale (Globicephala macrorhynchus) mass stranding events in 2013-2014 in western Florida. Geographical Information Systems (GIS) maps have been created by overlaying stranding locations and select K. brevis presence data in order to identify common spatial and temporal trends. Preliminary results indicate that elevated K. brevis levels (>10,000 cells/L) in Sarasota Bay during January-February and November may …

A Review Of Present And Alternative Lionfish Controls In The Western Atlantic, Adam Rittermann

HCNSO Student Capstones

Lionfish (Pterois volitans and Pterois miles) are the first recorded invasive piscivore in the Caribbean and have become a threat to native species. As generalist consumers, lionfish have a broad diet and reduce prey and competitor abundance and juvenile recruitment. To confront this problem, this paper serves to review all of the current and alternative future controls available to manage lionfish populations in the Western Atlantic and determine where focus is lacking. Derby and cull efforts are the only management efforts in place and are not effective in their current state as these local events have short-term benefits, …