Physical Sciences and Mathematics Commons^™

Formulation Of Colloidal Suspensions Of 3-Mercaptopropionic Acid Capped Pbs Quantum Dots As Solution Processable Qd "Inks" For Optoelectronic Applications, Chase Collier Reinhart

Dissertations and Theses

The use of colloidal quantum dots (QDs) for photovoltaic energy conversion is a nascent field that has been dominated for well over a decade by the use of 3-mercaptopropionic acid (3-MPA) capped PbS QDs. These QDs are routinely deposited via an in situ solid state ligand exchange process that displaces the native oleate ligand on the PbS QD surface. This ligand exchange procedure is wasteful of material and has been demonstrated to leave numerous impurities that limit electronic performance of the as-deposited QD devices. Until the last few years there was very little understanding in chemical literature as to many …

Algorithm For Premature Ventricular Contraction Detection From A Subcutaneous Electrocardiogram Signal, Iris Lynn Shelly

Dissertations and Theses

Cardiac arrhythmias occur when the normal pattern of electrical signals in the heart breaks down. A premature ventricular contraction (PVC) is a common type of arrhythmia that occurs when a heartbeat originates from an ectopic focus within the ventricles rather than from the sinus node in the right atrium. This and other arrhythmias are often diagnosed with the help of an electrocardiogram, or ECG, which records the electrical activity of the heart using electrodes placed on the skin. In an ECG signal, a PVC is characterized by both timing and morphological differences from a normal sinus beat.

An implantable cardiac …

Geothermometry Of Two Cascade Geothermal Systems, Donnel Alexander Malkemus

Dissertations and Theses

For this thesis I applied classical and multi-component geothermometry techniques to new water chemistry data from Breitenbush Hot Springs, Oregon and the Wind River Valley, Washington. A total of 20 well, spring, and stream samples from Breitenbush Hot Springs and 4 spring samples from the Wind River Valley were collected and analyzed for major, minor, and select trace anions and cations, as well as stable oxygen and hydrogen isotopes. I used two computer programs, GeoT and RTEst, to conduct multi-component geothermometry reservoir condition estimation on each water sample. Water chemistry data from Breitenbush Hot Springs indicates a range of thermal, …

Investigations Into The Effects Of Water Exchange And The Structure Of Lanthanide Chelates, Katherine Marie Payne

Dissertations and Theses

Lanthanide chelates are effective agents for improving contrast in MR images. Optimizing the relaxation of inner sphere water molecules is a common focus of research in this field. However, the efforts to design an optimal contrast agent have commonly over-looked the relationship of water position and water exchange kinetics. This work explores structural conformation, the impact of very fast water exchange kinetics on hydration, and differing tumbling rates for regioisomers of a number of lanthanide chelates. We have grown crystals of LnDOTMA and obtained structural data by X-ray diffraction that provide a picture of the chelate during water exchange and …

The Effects Of Anthropogenic Stressors On Mercury Concentrations And Community Composition Of Freshwater Zooplankton, Meredith Powers Jordan

Dissertations and Theses

Methylmercury (MeHg) bioaccumulation in freshwater aquatic systems is impacted by anthropogenic stressors, including climate change and excess nutrients. The goal of this study was to determine how warmer water temperatures and excess nutrients would impact zooplankton communities and phytoplankton concentrations, and in turn increase or decrease MeHg concentrations in freshwater zooplankton. I used a 2x2 factorial design to determine if the interaction of temperature and nutrients would impact plankton metrics and zooplankton MeHg concentrations. Mesocosms were filled with Hg-contaminated water and plankton from Cottage Grove Reservoir, Oregon, a waterbody that has experienced decades of elevated MeHg concentrations and corresponding fish …

Sedimentologic Changes In The Deposits Of An Evolving Lahar-Flood In 2006, Hood River Basin, Mount Hood, Oregon, Matthew Ray Poole

Dissertations and Theses

Over a span of six days from November 2-7, 2006 approximately 43 cm of precipitation fell over the Hood River Basin in Oregon. A lahar was initiated on the Eliot Branch of the Middle Fork Hood River by two or more landslides that occurred on the lateral moraines of the Eliot Glacier on the early part of November 7th, 2006. The Eliot Branch lahar was embedded within the larger regional flood that was occurring in the Hood River Basin and traveled a total of 48 km from the initiation points on the north flank of Mount Hood to the Hood …

Investigation Of Jet Dynamics In Cross-Flow: Quantifying Volcanic Plume Behavior, Graham Freedland

Dissertations and Theses

Volcanic eruption columns inject high concentrations of ash into the atmosphere. Some of this ash is carried downwind forming ash clouds in the atmosphere that are hazardous for private and commercial aviation. Current models rely on inputs such as plume height, duration, eruption rate, and meteorological wind fields. Eruption rate is estimated from plume height using relations that depend on the rate of air entrainment into the plume, which is not well quantified. A wind tunnel experiment has been designed to investigate these models by injecting a vertical air jet into a cross-flow. The ratio of the cross-flow and jet …

From Drought Monitoring To Forecasting: A Combined Dynamical-Statistical Modeling Framework, Hongxiang Yan

Dissertations and Theses

Drought is the most costly hazard among all natural disasters. Despite the significant improvements in drought modeling over the last decade, accurate provisions of drought conditions in a timely manner is still one of the major research challenges. In order to improve the current drought monitoring and forecasting skills, this study presents a hybrid system with a combination of remotely sensed data assimilation based on particle filtering and a probabilistic drought forecasting model. Besides the proposed drought monitoring system through land data assimilation, another novel aspect of this dissertation is to seek the use of data assimilation to quantify land …

Effects Of Antibiotic Mixtures Across Marine Intertidal Trophic Levels: Examining Environmentally-Relevant Contaminant Concentrations, Jaclyn Rebecca Teixeira

Dissertations and Theses

Approximately 48% of Americans use prescription drugs within each 30-day period, and there are signs this trend is increasing. Although many studies track pharmaceuticals’ fates in contaminating waterways, only fairly recent efforts have examined the potential impacts of these drugs on non-target organisms. The antibiotics sulfamethoxazole and trimethoprim, often prescribed together to treat bacterial infections, have been detected worldwide in marine and estuarine environments at concentrations up to 700-800 ng/L each. Toxic effects of these drugs have been identified in freshwater organisms, with synergistic effects observed in short-term studies of mixtures of the two; however, little research has examined possible …

Image Stitching: Handling Parallax, Stereopsis, And Video, Fan Zhang

Dissertations and Theses

Panorama stitching increases the field of view in an image by assembling multiple views together. Traditional stitching techniques are proven to be effective only when dealing with parallax-free monocular images. Many challenges that remain unsolved in the stitching research area include how to stitch monocular images with large parallax, how to stitch stereoscopic images to maintain their stereoscopic consistency and original disparity distribution, and how to create panoramic videos with temporally coherent content. To provide more powerful stitching techniques with more universality, we first develop a parallax-tolerant image stitching technique. With the help of it, we then effectively extend the …

The Application Of Electrochemical Impedance Spectroscopy To Immediately Diagnose The Protective Quality Of Coatings On Artistic And Architectural Metalwork, Kathryn Nicole Hosbein

Dissertations and Theses

Corrosion is a spontaneous process that causes irreversible damage to nearly all metals, which has world-wide implications for architectural and artistic metalwork, such as bridges, buildings, airplanes and sculptures. Protective coatings such as wax, paint, or polymeric clear coatings are used to prolong the lifetime of metals such as steel and bronze. Unfortunately, these coatings fail over time due to oxidative damage by UV rays and by failure to exclude water that can carry salts and pollutants that cause corrosion of the underlying substrate. The current method of coating assessment is visual inspection but when coating failure is detected at …

Hydrogeochemical Evaluation Of The Uinta Formation And Green River Formation, Piceance Creek Basin, Northwestern Colorado, Usa, Megan E. Masterson

Dissertations and Theses

The Piceance Creek Basin in northwestern Colorado contains extensive oil shale deposits that produce natural gas and which could potentially yield ~1.5 trillion barrels of shale oil. However, much of the oil shale lies at depths too great for traditional mining practices and various innovative approaches for in situ conversion of kerogen to oil have been proposed. A firm understanding of the existing hydrogeochemistry is needed as resulting mineralogical changes or rock-fluid reactions may affect rock porosity and permeability. Using an existing database complied by the USGS, the water chemistry of 267 surface and groundwater samples in the Piceance Creek …

Modeling Of Historic Columbia River Flood Impacts Based On Delft 3d Simulations, Lumas Terence Helaire

Dissertations and Theses

Natural and anthropogenic processes over the past 150 years have altered the bathymetry of the Lower Columbia River (LCR) and have changed the long wave propagation of tides and floods. Possible causes for the increase in tidal amplitudes (+7% in tidal range in Astoria) are decreases in river discharge, lengthening of the river channel due to the construction of jetties at the mouth, dredging and deepening of the shipping channel, and reduction of the tidal prism due to the filling and diking of tidal wetlands. In this study, changes in the characteristics of long waves are elucidated by developing two …

Use Of Water Indices Derived From Landsat Oli Imagery And Gis To Estimate The Hydrologic Connectivity Of Wetlands In The Tualatin River National Wildlife Refuge, Debra Sue Blackmore

Dissertations and Theses

This study compared two remote sensing water indices: the Normalized Difference Water Index (NDWI) and the Modified NDWI (MNDWI). Both indices were calculated using publically-available data from the Landsat 8 Operational Land Imager (OLI). The research goal was to determine whether the indices are effective in locating open water and measuring surface soil moisture. To demonstrate the application of water indices, analysis was conducted for freshwater wetlands in the Tualatin River Basin in northwestern Oregon to estimate hydrologic connectivity and hydrological permanence between these wetlands and nearby water bodies. Remote sensing techniques have been used to study wetlands in recent …

A Landscape Approach To Determining And Predicting Juvenile Coho Salmon (Oncorhynchus Kisutch) Movement Timing And Growth Patterns Prior To Ocean Entry, Amelia Lee Johnson

Dissertations and Theses

Coho salmon (Oncorhynchus kisutch) rely on unique habitats during the winter season, which may dictate how much individuals may grow and when migration from freshwater rearing habitat to the ocean occurs. Here I analyze movement timing and growth patterns for coho salmon through a field-based study and a literature review. For the field portion, I examined hatchery-stocked juvenile coho salmon across four stream basins in the Russian River watershed, California to determine the relative importance of climate, landscape, and fish size metrics in predicting movement and growth patterns over a winter rearing and spring smolt outmigration time period …

Watershed Response To Climate Change And Fire-Burns In The Upper Umatilla River Basin Using The Precipitation Runoff Modeling System, Kimberly Crystal Yazzie

Dissertations and Theses

This study provides an analysis of watershed response to climate change and forest fire impacts, to better understand the hydrologic budget and inform water management decisions for present and future needs. The study site is 2,365 km², located in the upper Umatilla River Basin (URB) in northeastern Oregon. The Precipitation Runoff Modeling System, a distributed-parameter, physical-process watershed model, was used in this study. Model calibration yielded a Nash Sutcliffe Model Efficiency of 0.73 for both calibration (1995-2010) and validation (2010-2014) of daily streamflow. Ten Global Climate Models using Coupled Model Intercomparison Project Phase 5 experiments with Representative Concentration …

Use Of Distance Weighted Metrics To Investigate Landscape-Stream Temperature Relationships Across Different Temporal Scales, Eric Craig Watson

Dissertations and Theses

Stream ecosystems have experienced significant negative impacts from land use, resource exploitation, and urban development. Statistical models allow researchers to explore the relationships between these landscape variables and stream conditions. Weighting the relevant landscape variables based on hydrologically defined distances offers a potential method of increasing the predictive capacity of statistical models. Using observations from three grouped watersheds in the Portland Metro Area (n=66), I have explored the use of three different weighting schemes against the standard method of taking an areal average. These four different model groups were applied to four stream temperature metrics: mean seven-day moving average maximum …

Orthomorphisms Of Boolean Groups, Nichole Louise Schimanski

Dissertations and Theses

An orthomorphism, π, of a group, (G, +), is a permutation of G with the property that the map x → -x + π(x) is also a permutation. In this paper, we consider orthomorphisms of the additive group of binary n-tuples, Zⁿ₂. We use known orthomorphism preserving functions to prove a uniformity in the cycle types of orthomorphisms that extend certain partial orthomorphisms, and prove that extensions of particular sizes of partial orthomorphisms exist. Further, in studying the action of conjugating orthomorphisms by automorphisms, we find several symmetries within the orbits and stabilizers of this action, and …

Silicic Volcanism At The Northern And Western Extent Of The Columbia River Basalt Rhyolite Flare-Up: Rhyolites Of Buchanan Volcanic Complex And Dooley Mountain Volcanic Complex, Oregon, Adam M. Large

Dissertations and Theses

Two mid-Miocene (16.5-15 Ma) rhyolite volcanic centers in eastern Oregon, the Buchanan rhyolite complex and Dooley Mountain rhyolite complex, were investigated to characterize eruptive units through field and laboratory analysis. Results of petrographic and geochemical analysis add to field observations to differentiate and discriminate the eruptive units. Additionally, new geochemical data are used to correlate stratigraphically younger and older basalt and ash-flow tuff units with regional eruptive units to constrain the eruptive periods with modern Ar-Ar age dates.

Previous work at the Buchanan rhyolite complex was limited to regional mapping (Piper et al., 1939; Greene et al., 1972) and brief …

Quef And Quef-Like: Diverse Chemistries In A Common Fold, Adriana Bon Ramos

Dissertations and Theses

The tunneling fold (T-Fold) superfamily is a small superfamily of enzymes found in organisms encompassing all kingdoms of life. Seven members have been identified thus far. Despite sharing a common three-dimensional structure these enzymes perform very diverse chemistries.

QueF is a bacterial NADPH-dependent oxidoreductase that catalyzes the reduction of the nitrile group of 7-cyano-7-deazaguanine (preQ₀) to a primary amine (preQ₁) in the queuosine biosynthetic pathway. Previous work on this enzyme has revealed the mechanism of reaction but the cofactor binding residues remain unknown. The experiments discussed herein aim to elucidate the role of residues lysine 80, …

Thermal Decomposition Of Electronic Cigarette Liquids, Robert Paul Jensen

Dissertations and Theses

Electronic cigarette liquid (e-liquid) is a solution of propylene glycol and/or glycerol with varying concentrations of nicotine and flavorants. Inhalation of vaporized e-liquid is a method of nicotine delivery that is growing in popularity and is commonly regarded as safe relative to smoking traditional tobacco products. The thermal decomposition of glycerol and propylene glycol is typical of alcohols and has been investigated, although not exhaustively. In this work, samples of propylene glycol and glycerol were vaporized using an electronic cigarette (e-cigarette) and were analyzed for evidence of decomposition using nuclear magnetic resonance (NMR) spectroscopy. E-cigarettes are shown to degrade glycerol …

Improving The Roadside Environment Through Integrating Air Quality And Traffic-Related Data, Christine M. Kendrick

Dissertations and Theses

Urban arterial corridors are landscapes that give rise to short and long-term exposures to transportation-related pollution. With high traffic volumes, congestion, and a wide mix of road users and land uses at the road edge, urban arterial environments are important targets for improved exposure assessment to traffic-related pollution. Applying transportation management strategies to reduce emissions along arterial corridors could be enhanced if the ability to quantify and evaluate such actions was improved. However, arterial roadsides are under-sampled in terms of air pollution measurements in the United States and using observational data to assess such effects has many challenges such as …

Molecular Probes For Pancreatic Cancer Imaging, Lei Wang

Dissertations and Theses

Pancreatic ductal adenocarcinoma (PDAC) has the poorest five-year survival rate of any cancer. Currently, there are no effective diagnostics or chemotherapeutics. Surgical resection is the only curative therapy. However, most patients experience recurrence due largely to challenges in assessing tumor margin status in the operating room. Molecular probes that selectively highlight pancreatic cancer tissue, having the potential to improve PDAC margin assessment intraoperatively, are urgently needed. In this work, a series of red and near-infrared fluorescent probes is reported. Two were found to distribute to normal pancreas following systemic administration. One selectively accumulates in genetically modified mouse models of PDAC, …

Groundwater-Surface Water Interactions Near Mosier, Oregon, Cullen Brandon Jones

Dissertations and Theses

The town of Mosier, Oregon, is located near the east, dry end of the Columbia River Gorge, and the local area is known for cherry orchards that rely heavily on groundwater for irrigation. The CRBG groundwater system in Mosier has experienced groundwater declines of up to 60 meters due to over-pumping and or commingling. Declining groundwater levels have led to concerns over the sustainability of the resource, as it is the principle water source for irrigation and domestic use. Despite numerous previous studies of groundwater flow in CRBG aquifers here and elsewhere in the Columbia River basin, an aspect that …

Do Forest Commons Contribute To International Environmental Initiatives? A Socio-Ecological Analysis Of Nepalese Forest Commons In View Of Redd+, Harisharan Luintel

Dissertations and Theses

Forests in developing countries have the potential to contribute to global efforts to mitigate climate change, promote biodiversity and support the livelihoods of rural, local people. Approximately one-fourth of such forests are under the control of local communities, which primarily manage forests for subsistence and to meet their livelihood needs. The trend of bottom-up community control is increasing through the adoption of decentralization reforms over the last 40 years. In contrast, the United Nations has introduced the top-down program, Reducing Emissions from Deforestation and Forest Degradation (REDD+) for the conservation and enhancement of forest carbon and the sustainable management of …

Expanding The Versatility Of Nano Assembled Capsules As Platform Of Potential High Payload Mri Contrast Agents, Annah Farashishiko

Dissertations and Theses

Magnetic resonance imaging (MRI) has become a powerful clinical modality in diagnostic medicine. It is non-invasive and offers high spatial and temporal resolution. The goal of molecular imaging is to reveal the pathophysiology underlying the observed anatomy and diagnose diseases. The detection of pathological biomarkers can lead to early recognition of diseases and improved monitoring for recurrence. Clinically available contrast agents are limited in their discrimination of contrast between tissues and they tend to have very high detection limits. Because biomarkers are very low in concentration there is a need for high payload deposition of contrast agent (CA) and targeted …

Household Water Filter Use Characterization In Rural Rwanda: Signal Interpretation, Development And Validation, Sarita Lucia Tellez Sanchez

Dissertations and Theses

Access to safe drinking water is an important health factor in many developing countries. Studies have shown that unsafe drinking water and poor sanitation practices leads to diarrheal disease, which is one of the leading causes of death of children under five in developing countries. Provision and proper use of household water filters have been shown to effectively improve health.

This thesis is focused on the refinement and validation of algorithms for data collected from pressure transducer sensors that are used in household water filters (the Vestergaard Frandsen LifeStraw Family 2.0) deployed in Rwanda by the social enterprise DelAgua Health. …

Discovery And Characterization Of The Proteins Involved In The Synthesis Of N⁶-Threonylcarbamoyl Adenosine, A Nucleoside Modification Of Trna, Christopher Wayne Deutsch

Dissertations and Theses

N6-threonylcarbamoyl adenosine (t⁶A) is a universally conserved tRNA modification found at position 37 of tRNAs which decode ANN codons. Structural studies have implicated its presence as a requirement for the disruption of a U-turn motif in certain tRNAs, leading to the formation of properly structured anticodon stem loop. This structure is proposed to enhance the base pairing between U₃₆ of tRNA and A₁ of the codon which aids in translational frame maintenance.

Despite significant effort since its discovery in the 1970s the enzymes involved in its biosynthesis remained undiscovered. Bioinformatic analysis identified two proteins as likely …

Vision-Based Motion For A Humanoid Robot, Khalid Abdullah Alkhulayfi

Dissertations and Theses

The overall objective of this thesis is to build an integrated, inexpensive, human-sized humanoid robot from scratch that looks and behaves like a human. More specifically, my goal is to build an android robot called Marie Curie robot that can act like a human actor in the Portland Cyber Theater in the play Quantum Debate with a known script of every robot behavior. In order to achieve this goal, the humanoid robot need to has degrees of freedom (DOF) similar to human DOFs. Each part of the Curie robot was built to achieve the goal of building a complete humanoid …

Watershed Management And Private Lands: Moving Beyond Financial Incentives To Encourage Land Stewardship, Matthew Thomas Deangelo

Dissertations and Theses

Public water utilities are tasked with providing high quality, inexpensive water often sourced from watersheds representing a diverse mix of public and private land ownership. There is increasing recognition amongst water resource managers of the role that private landowners play in determining downstream water quality, but bringing together landowners with a wide variety of land management objectives under the umbrella of watershed stewardship has proven difficult. Recently, a large number of "Payment for Watershed Services" programs have aimed to engage private landowners in watershed stewardship initiatives by offering financial incentives for adopting watershed best management practices. However, a growing field …