Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons™

Open Access. Powered by Scholars. Published by Universities.®

Theses/Dissertations

2016

University of Massachusetts Amherst

Articles 1 - 30 of 81

Full-Text Articles in Physical Sciences and Mathematics

Applications Of Sampling And Estimation On Networks, Fabricio Murai Ferreira Nov 2016

Applications Of Sampling And Estimation On Networks, Fabricio Murai Ferreira

Doctoral Dissertations

Networks or graphs are fundamental abstractions that allow us to study many important real systems, such as the Web, social networks and scientific collaboration. It is impossible to completely understand these systems and answer fundamental questions related to them without considering the way their components are connected, i.e., their topology. However, topology is not the only relevant aspect of networks. Nodes often have information associated with them, which can be regarded as node attributes or labels. An important problem is then how to characterize a network w.r.t. topology and node label distributions. Another important problem is how to design efficient …

Go to article

Detecting Anomalously Similar Entities In Unlabeled Data, Lisa D. Friedland Nov 2016

Detecting Anomalously Similar Entities In Unlabeled Data, Lisa D. Friedland

Doctoral Dissertations

In this work, the goal is to detect closely-linked entities within a data set. The entities of interest have a tie causing them to be similar, such as a shared origin or a channel of influence. Given a collection of people or other entities with their attributes or behavior, we identify unusually similar pairs, and we pose the question: Are these two people linked, or can their similarity be explained by chance? Computing similarities is a core operation in many domains, but two constraints differentiate our version of the problem. First, the score assigned to a pair should account for …

Go to article

Chasing New Physics: From Electroweak Baryogenesis To Dark Matter, Huaike Guo Nov 2016

Chasing New Physics: From Electroweak Baryogenesis To Dark Matter, Huaike Guo

Doctoral Dissertations

The origin of the baryon asymmetry in the universe and the nature of the dark matter remain mysteries and addressing these cosmological puzzles requires physics beyond the standard model. Electroweak baryogenesis remains a highly testable framework for explaining the baryon asymmetry and is employed in this work to study the capability of baryon generation for beyond standard model physics models and to explore new physics discovery potential in high energy and precision frontier. Weakly interacting massive particles as cold dark matter are also studied in this work featuring loop induced direct detection signals and novel nuclear responses within the recently …

Go to article

Application-Aware Resource Management For Cloud Platforms, Xin He Nov 2016

Application-Aware Resource Management For Cloud Platforms, Xin He

Doctoral Dissertations

Cloud computing has become increasingly popular in recent years. The benefits of cloud platforms include ease of application deployment, a pay-as-you-go model, and the ability to scale resources up or down based on an application's workload. Today's cloud platforms are being used to host increasingly complex distributed and parallel applications. The main premise of this thesis is that application-aware resource management techniques are better suited for distributed cloud applications over a systems-level one-size-fits-all approach. In this thesis, I study the cloud-based resource management techniques with a particular emphasis on how application-aware approaches can be used to improve system resource utilization …

Go to article

Study Of Charge Transport Mechanism In Microbial Nanowires, Ramesh Adhikari Nov 2016

Study Of Charge Transport Mechanism In Microbial Nanowires, Ramesh Adhikari

Doctoral Dissertations

Conductivity of an individual proteinaceous filaments, called pili or microbial nanowires, produced by wild type Geobacter sulfurreducens was measured using a low-noise electrical transport technique. It was shown that the conductivity is diminished if aromatic amino acid residues are removed from the pili. It was demonstrated that the conductivity of G. sulfurreducens pili is similar to that of synthetic organic polymers and is related to the respiration rate of the bacteria. Conductivity measurements were performed on microbial nanowires produced by other species of Geobacter with a different aromatic amino acid distribution along the wire. Also, measurements on a mutated pili …

Go to article

Elastic Resource Management In Distributed Clouds, Tian Guo Nov 2016

Elastic Resource Management In Distributed Clouds, Tian Guo

Doctoral Dissertations

The ubiquitous nature of computing devices and their increasing reliance on remote resources have driven and shaped public cloud platforms into unprecedented large-scale, distributed data centers. Concurrently, a plethora of cloud-based applications are experiencing multi-dimensional workload dynamics---workload volumes that vary along both time and space axes and with higher frequency. The interplay of diverse workload characteristics and distributed clouds raises several key challenges for efficiently and dynamically managing server resources. First, current cloud platforms impose certain restrictions that might hinder some resource management tasks. Second, an application-agnostic approach might not entail appropriate performance goals, therefore, requires numerous specific methods. Third, …

Go to article

A Period Examination Through Contemporary Energy Analysis Of Kevin Roche’S Fine Arts Center At University Of Massachusetts-Amherst, L Carl Fiocchi Jr Nov 2016

A Period Examination Through Contemporary Energy Analysis Of Kevin Roche’S Fine Arts Center At University Of Massachusetts-Amherst, L Carl Fiocchi Jr

Doctoral Dissertations

Studies of buildings belonging to a subset of Modernist architecture, Brutalism, have included discussions pertaining to social and architectural history, critical reception, tectonic form and geometry inspirations, material property selections, period technology limitations, and migration of public perceptions. Evaluations of Brutalist buildings’ energy related performances have been restricted to anecdotal observations with particular focus on the building type’s poor thermal performance, a result of the preferred construction method, i.e. monolithic reinforced concrete used as structure, interior finish and exterior finish. A valid criticism, but one that served to dismiss discussion that the possibility of other positive design strategies limiting energy …

Go to article

X-Ray Characterization Of Mesophases And Phase Transitions Of Dna Analogues In Solutions, Mustafa Selcuk Yasar Nov 2016

X-Ray Characterization Of Mesophases And Phase Transitions Of Dna Analogues In Solutions, Mustafa Selcuk Yasar

Doctoral Dissertations

We think of DNA as double-stranded helices (duplex), but the polymer exists in many conformations. Several triplex and quadruplex DNA structures can be formed in laboratory settings and exist in nature. This thesis first provides a brief description of the nature of the order in arrays of duplex DNA under biologically relevant molecular crowding conditions. Then we compare the duplex DNA mesophases with the corresponding liquid crystalline phase behavior of the triplex and quadruplex DNA analogues. In particular, we focus on G-quadruplexes. Observed in the folds of guanine-rich oligonucleotides, G-quadruplex structures are based on G-quartets formed by hydrogen bonding and …

Go to article

Evaporation Induced Self-Assembly And Characterization Of Nanoparticulate Films: A New Route To Bulk Heterojunctions, Yipeng Yang Nov 2016

Evaporation Induced Self-Assembly And Characterization Of Nanoparticulate Films: A New Route To Bulk Heterojunctions, Yipeng Yang

Doctoral Dissertations

Polymer-based semiconducting materials are promising candidates for large-scale, low-cost photovoltaic devices. To date, the efficiency of these devices has been low in part because of the challenge of optimizing molecular packing while also obtaining a bicontinuous structure with a characteristic length comparable to the exciton diffusion length of 10 to 20 nm. In this dissertation we developed an innovative evaporation-induced nanoparticle self-assembly technique, which could be an effective approach to fabricate uniform, densely packed, smooth thin films with cm-scale area from home-made P3HT nanoparticles. Unlike the previous reports of nanoparticle-based film formation, we use a mixture of two solvents so …

Go to article

Intrinsic Functions For Securing Cmos Computation: Variability, Modeling And Noise Sensitivity, Xiaolin Xu Nov 2016

Intrinsic Functions For Securing Cmos Computation: Variability, Modeling And Noise Sensitivity, Xiaolin Xu

Doctoral Dissertations

A basic premise behind modern secure computation is the demand for lightweight cryptographic primitives, like identifier or key generator. From a circuit perspective, the development of cryptographic modules has also been driven by the aggressive scalability of complementary metal-oxide-semiconductor (CMOS) technology. While advancing into nano-meter regime, one significant characteristic of today's CMOS design is the random nature of process variability, which limits the nominal circuit design. With the continuous scaling of CMOS technology, instead of mitigating the physical variability, leveraging such properties becomes a promising way. One of the famous products adhering to this double-edged sword philosophy is the Physically …

Go to article

Studies On Lattice Systems Motivated By Pt-Symmetry And Granular Crystals, Haitao Xu Nov 2016

Studies On Lattice Systems Motivated By Pt-Symmetry And Granular Crystals, Haitao Xu

Doctoral Dissertations

This dissertation aims to study some nonlinear lattice dynamical systems arising in various areas, especially in nonlinear optics and in granular crystals. At first, we study the 2-dimensional PT-symmetric square lattices (of the discrete non-linear Schr¨odinger (dNLS) type) and identify the existence, stability and dynamical evolu- tion of stationary states, including discrete solitons and vortex configurations. To enable the analytical study, we consider the so-called anti-continuum (AC) limit of lattices with uncoupled sites and apply the Lyapunov–Schmidt reduction. Numerical experiments will also be provided accordingly. Secondly, we investigate the nonlinear waves in the granular chains of elastically inter- acting (through …

Go to article

Stochastic Network Design: Models And Scalable Algorithms, Xiaojian Wu Nov 2016

Stochastic Network Design: Models And Scalable Algorithms, Xiaojian Wu

Doctoral Dissertations

Many natural and social phenomena occur in networks. Examples include the spread of information, ideas, and opinions through a social network, the propagation of an infectious disease among people, and the spread of species within an interconnected habitat network. The ability to modify a phenomenon towards some desired outcomes has widely recognized benefits to our society and the economy. The outcome of a phenomenon is largely determined by the topology or properties of its underlying network. A decision maker can take management actions to modify a network and, therefore, change the outcome of the phenomenon. A management action is an …

Go to article

Metamorphic And Structural Control Of Magnetism Within The Lower Continental Crust, Northern Saskatchewan, Canada, Jeffrey R. Webber Nov 2016

Metamorphic And Structural Control Of Magnetism Within The Lower Continental Crust, Northern Saskatchewan, Canada, Jeffrey R. Webber

Doctoral Dissertations

The linking of geophysical information to tectonometamorphic processes holds great potential for the surveying of vast remote areas of the planet and may allow for the transcendence of observational scales. Investigations concerning magnetic properties of the lower continental crust can reveal an incredible wealth of information concerning the conditions of metamorphism, regional extent of deformation, and controls on the magnetic architecture of the lithosphere. This dissertation presents three contributions aimed at the integration of petrology, structural geology, and rock magnetism in order to investigate the magnetic nature of the lower continental crust, constrain tectonometamorphic processes at the regional scale in …

Go to article

Spherical Tropicalization, Anastasios Vogiannou Nov 2016

Spherical Tropicalization, Anastasios Vogiannou

Doctoral Dissertations

In this thesis, I extend tropicalization of subvarieties of algebraic tori over a trivially valued algebraically closed field to subvarieties of spherical homogeneous spaces. I show the existence of tropical compactifications in a general setting. Given a tropical compactification of a closed subvariety of a spherical homogeneous space, I show that the support of the colored fan of the ambient spherical variety agrees with the tropicalization of the closed subvariety. I provide examples of tropicalization of subvarieties of GL(n), SL(n), and PGL(n).

Go to article

Specification And Analysis Of Resource Utilization Policies For Human-Intensive Systems, Seung Yeob Shin Nov 2016

Specification And Analysis Of Resource Utilization Policies For Human-Intensive Systems, Seung Yeob Shin

Doctoral Dissertations

Contemporary systems often require the effective support of many types of resources, each governed by complex utilization policies. Sound management of these resources plays a key role in assuring that these systems achieve their key goals. To help system developers make sound resource management decisions, I provide a resource utilization policy specification and analysis framework for (1) specifying very diverse kinds of resources and their potentially complex resource utilization policies, (2) dynamically evaluating the policies’ effects on the outcomes achieved by systems utilizing the resources, and (3) formally verifying various kinds of properties of these systems. Resource utilization policies range …

Go to article

Skein Theory And Algebraic Geometry For The Two-Variable Kauffman Invariant Of Links, Thomas Shelly Nov 2016

Skein Theory And Algebraic Geometry For The Two-Variable Kauffman Invariant Of Links, Thomas Shelly

Doctoral Dissertations

We conjecture a relationship between the Hilbert schemes of points on a singular plane curve and the Kauffman invariant of the link associated to the singularity. Specifcally, we conjecture that the generating function of certain weighted Euler characteristics of the Hilbert schemes is given by a normalized specialization of the difference between the Kauffman and HOMFLY polynomials of the link. We prove the conjecture for torus knots. We also develop some skein theory for computing the Kauffman polynomial of links associated to singular points on plane curves.

Go to article

Identifying Examinees Who Possess Distinct And Reliable Subscores When Added Value Is Lacking For The Total Sample, Joseph A. Rios Nov 2016

Identifying Examinees Who Possess Distinct And Reliable Subscores When Added Value Is Lacking For The Total Sample, Joseph A. Rios

Doctoral Dissertations

Research has demonstrated that although subdomain information may provide no added value beyond the total score, in some contexts such information is of utility to particular demographic subgroups (Sinharay & Haberman, 2014). However, it is argued that the utility of reporting subscores for an individual should not be based on one’s manifest characteristics (e.g., gender or ethnicity), but rather on individual needs for diagnostic information, which is driven by multidimensionality in subdomain scores. To improve the validity of diagnostic information, this study proposed the use of Mahalanobis Distance and HT indices to assess whether an individual’s data significantly departs …

Go to article

A Quantitative Measurement Of Structural Changes Of Rna Kissing Complexes Using Fluorescence Resonance Energy Transfer, Sheema Rahmanseresht Nov 2016

A Quantitative Measurement Of Structural Changes Of Rna Kissing Complexes Using Fluorescence Resonance Energy Transfer, Sheema Rahmanseresht

Doctoral Dissertations

Many RNA interactions in cells occur in the form of loop-loop interactions, also known as a "kissing complex". In the bacterial and viral systems discussed here, there are transiently bound proteins involved that modulate the function of kissing complex. These proteins either stabilize the kissing complex or facilitate its conversion to extended duplex. I studied R1inv-R2inv kissing complex (KC), derivatived from RNAI-RNAII complex of E.Coli. Rop protein is known to stabilize the bent R1inv-R2inv KC against dissociation. The goal was to study structural change of this kissing complex after binding of the stabilizing Rop protein. In this work for …

Go to article

Search For Long-Lived, Weakly Interacting Particles That Decay To Displaced Hadronic Jets In Proton-Proton Collisions At √S = 8 Tev With The Atlas Detector, Preema R. Pais Nov 2016

Search For Long-Lived, Weakly Interacting Particles That Decay To Displaced Hadronic Jets In Proton-Proton Collisions At √S = 8 Tev With The Atlas Detector, Preema R. Pais

Doctoral Dissertations

Many new physics models predict the existence of neutral, weakly interacting, long-lived particles that can decay within the detector volume, producing a distinctive experimental signature. A search is performed for a pair of such particles, using proton-proton collision data at √s = 8 TeV collected by the ATLAS detector in 2012, corresponding to a total integrated luminosity of 20.3 fb-1. Novel techniques are developed for the reconstruction of displaced decays to hadronic jets in the inner tracking detector and muon spectrometer. No significant deviation is found from the number of background events expected from Standard Model processes. The …

Go to article

Prospects For Infrared Quantum Gravity: From Cosmology To Black Holes, Basem K. Mahmoud El-Menoufi Nov 2016

Prospects For Infrared Quantum Gravity: From Cosmology To Black Holes, Basem K. Mahmoud El-Menoufi

Doctoral Dissertations

Although perturbatively non-renormalizable, general relativity is a perfectly valid quantum theory at low energies. Treated as an effective field theory one is able to make genuine quantum predictions by applying the conventional rules of quantum field theory. The low energy degrees of freedom and couplings of quantum gravity are fully dictated by the symmetries of general relativity. To realize the full EFT treatment one has to supplement the theory with experimental input necessary to fix the Wilson coefficients of the most general Lagrangian. In spite of the fact that this is not feasible, one can still extract the leading quantum …

Go to article

Aggregation And Coagulation Of C60 Fullerene As Affected By Natural Organic Matter And Ionic Strength, Hamid Mashayekhi Nov 2016

Aggregation And Coagulation Of C60 Fullerene As Affected By Natural Organic Matter And Ionic Strength, Hamid Mashayekhi

Doctoral Dissertations

With widespread production and use of C60 fullerene nanoparticles, their release to the environment and natural waters is inevitable. The colloidal nature of C60 fullerene in the aquatic environment significantly influences its behavior in the environment including its transport, bioavailability and toxicity to different organisms. Natural organic matter (NOM) is a ubiquitous and reactive material in aquatic environments with significant structural heterogeneity. Therefore, the effect of NOM molecules on the colloidal behavior of fullerene particles needs to be studied. A major part of NOM consists of humic acids (HA). HAs have pronounced effects on the aggregation of C …

Go to article

Learning From Pairwise Proximity Data, Hamid Dadkhahi Nov 2016

Learning From Pairwise Proximity Data, Hamid Dadkhahi

Doctoral Dissertations

In many areas of machine learning, the characterization of the input data is given by a form of proximity measure between data points. Examples of such representations are pairwise differences, pairwise distances, and pairwise comparisons. In this work, we investigate different learning problems on data represented in terms of such pairwise proximities. More specifically, we consider three problems: masking (feature selection) for dimensionality reduction, extension of the dimensionality reduction for time series, and online collaborative filtering. For each of these problems, we start with a form of pairwise proximity which is relevant in the problem at hand. We evaluate the …

Go to article

Cell Modulation Using Functionalized Nanoparticles, Rui Tang Nov 2016

Cell Modulation Using Functionalized Nanoparticles, Rui Tang

Doctoral Dissertations

Monolayer functionalized ultra-small gold nanoparticles (AuNPs) provide a versatile platform for applications in cell research. Through rational design of surface ligands, the chemistry of AuNPs are precisely regulated at atomic level. In this dissertation, applications of AuNPs in cell modulation are discussed. The topics are split into two categories. In the first category, functionalized AuNPs are harnessed to generate a robust monolayer on cell culture surface for cell modulation. The proliferation and behavior of different types of cancer cells and normal cells are modulated by tuning the surface ligands of AuNPs. Fate decision of mesenchymal stem cells are also modulated …

Go to article

Uptake And Accumulation Of Engineered Nanomaterials By Agricultural Crops And Associated Risks In The Environment And Food Safety, Yingqing Deng Nov 2016

Uptake And Accumulation Of Engineered Nanomaterials By Agricultural Crops And Associated Risks In The Environment And Food Safety, Yingqing Deng

Doctoral Dissertations

Engineered nanomaterials (ENMs) are being discharged into the environment and to agricultural fields, with unknown impacts on crop species. This study focused on the bioaccumulation of engineered nanomaterials into crops and the associated impact on plant growth and plant uptake of secondary contaminant. Investigations into the interactions between nanomaterials and agricultural plants will provide a more developed understanding of nanomaterials implications in the environment; in addition, evaluations of the risks associated with plant-nanomaterials interactions will provide guidelines for safe use of nanomaterials in agriculture. In the screening study on phytotoxicity, carbon-based nanoparticles (NPs) including C60, MWCNTs, NH2 …

Go to article

Combining Static And Dynamic Analysis For Bug Detection And Program Understanding, Kaituo Li Nov 2016

Combining Static And Dynamic Analysis For Bug Detection And Program Understanding, Kaituo Li

Doctoral Dissertations

This work proposes new combinations of static and dynamic analysis for bug detection and program understanding. There are 3 related but largely independent directions: a) In the area of dynamic invariant inference, we improve the consistency of dynamically discovered invariants by taking into account second-order constraints that encode knowledge about
invariants; the second-order constraints are either supplied by the programmer or vetted by the programmer (among candidate constraints suggested automatically); b) In the area of testing dataflow (esp. map-reduce) programs, our tool, SEDGE, achieves higher testing coverage by leveraging existing
input data and generalizing them using a symbolic reasoning engine …

Go to article

Functional Hydrophilic Polymers For Solution Assembly And Non-Viral Gene Therapy, Rachel A. Letteri Nov 2016

Functional Hydrophilic Polymers For Solution Assembly And Non-Viral Gene Therapy, Rachel A. Letteri

Doctoral Dissertations

This thesis examines functional hydrophilic polymers designed in linear and comb architectures and that carry functional moieties in the context of solution assembly and non-viral gene therapy. Specifically, polymers containing cations, zwitterions, and reactive groups are investigated as non-viral gene therapy reagents and at oil-water interfaces on droplets. Cations facilitate complexation of nucleic acids and interaction with cellular and nuclear membranes, while zwitterions impart stimuli-responsive solution properties and biocompatibility. Reactive groups, including alkenes, alkynes, and benzylic methylenes, permit post-polymerization modification leading to tunable polymer properties in solution and at interfaces. This work expands the knowledge base related to solution, interfacial, …

Go to article

Kinetics And Dynamics Of Electrophoretic Translocation Of Polyelectrolytes Through Nanopores, Harshwardhan Katkar Nov 2016

Kinetics And Dynamics Of Electrophoretic Translocation Of Polyelectrolytes Through Nanopores, Harshwardhan Katkar

Doctoral Dissertations

The idea of sequencing a DNA based on single-file translocation of the DNA through nanopores under the action of an electric field has received much attention over the past two decades due to the societal need for low cost and high-throughput sequencing. However, due to the high speed of translocation, interrogating individual bases with an acceptable signal to noise ratio as they traverse the pore has been a major problem. Experimental facts on this phenomenon are rich and the associated phenomenology is yet to be fully understood. This thesis focuses on understanding the underlying principles of polymer translocation, with an …

Go to article

Engineering The Nano-Bio Interface Of Gold Nanoparticles For Biomedical Applications, Ying Jiang Nov 2016

Engineering The Nano-Bio Interface Of Gold Nanoparticles For Biomedical Applications, Ying Jiang

Doctoral Dissertations

Gold nanoparticles (AuNPs) have emerged as a promising platform for a myriad of biomedical applications, including sensing, drug delivery, and antibiotics. In this thesis, I have studied and engineered the interface of AuNPs with different biological systems, demonstrating a large variety of biomedical applications by modulation of these interfaces. My research was initially focused on systematically tuning the physicochemical properties of nanoparticles to understand nano-bio interactions at the cellular level. The results demonstrate that size and surface charge of AuNP interact in an interrelated fashion to modulate nanoparticle internalization by cells, providing an engineering strategy for designing nanomaterials for drug …

Go to article

Polymer And Small Molecule Designs For Anion Conducting Membranes: Connected Ion-Channel Morphologies And Highly Alkaline Stable Ammonium Cations, Sedef P. Ertem Nov 2016

Polymer And Small Molecule Designs For Anion Conducting Membranes: Connected Ion-Channel Morphologies And Highly Alkaline Stable Ammonium Cations, Sedef P. Ertem

Doctoral Dissertations

Fuel cells are one of the oldest sustainable energy generation devices, converting chemical energy into electrical energy via reverse-electrolysis reactions. With the rapid development of polymer science, solid polymer electrolyte (SPE) membranes replaced the conventional liquid ion transport media, rendering low-temperature fuel cells more accessible for applications in portable electronics and transportation. However, SPE fuel cells are still far from commercialization due to high operation cost, and insufficient lifetime and performance limitations. Anion exchange membrane fuel cells (AEMFCs) are inexpensive alternatives to current proton exchange membrane fuel cell (PEMFC) technology, which relies on utilizing expensive noble-metal catalysts and perfluorinated SPE …

Go to article

The Cosmic Web, And The Role Of Environment In Galaxy Evolution, Ryan Cybulski Nov 2016

The Cosmic Web, And The Role Of Environment In Galaxy Evolution, Ryan Cybulski

Doctoral Dissertations

The Universe, on extra-galactic scales, is composed of a vast network of structures dubbed the “cosmic web”. One of the most fundamental discoveries about the evolution of galaxies is that their properties have a dependence on their location relative to this cosmic web (i.e., their environment). However, detailed studies of the environmental dependence on galaxy evolution have been extremely challenging due to the inherent complexity of the structures on the largest scales, a plethora of techniques being used to try to map the cosmic web, and other confounding factors, such as the masses of galaxies, that also affect their evolution. …

Go to article

Next Last